CN110518307A - It is bent phase transformation heat pipe and the rectangular cell using it - Google Patents

It is bent phase transformation heat pipe and the rectangular cell using it Download PDF

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Publication number
CN110518307A
CN110518307A CN201810497650.XA CN201810497650A CN110518307A CN 110518307 A CN110518307 A CN 110518307A CN 201810497650 A CN201810497650 A CN 201810497650A CN 110518307 A CN110518307 A CN 110518307A
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CN
China
Prior art keywords
phase transformation
heat pipe
condensation segment
bending phase
transformation heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810497650.XA
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Chinese (zh)
Inventor
罗健
程阿鸿
蔡惠群
李海军
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Yinlong New Energy Co Ltd
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Yinlong New Energy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yinlong New Energy Co Ltd filed Critical Yinlong New Energy Co Ltd
Priority to CN201810497650.XA priority Critical patent/CN110518307A/en
Publication of CN110518307A publication Critical patent/CN110518307A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/613Cooling or keeping cold
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/617Types of temperature control for achieving uniformity or desired distribution of temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/64Heating or cooling; Temperature control characterised by the shape of the cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6552Closed pipes transferring heat by thermal conductivity or phase transition, e.g. heat pipes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/656Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
    • H01M10/6567Liquids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Secondary Cells (AREA)

Abstract

The invention discloses bending phase transformation heat pipes comprising sequentially connected evaporator section, isolation section and condensation segment, the evaporator section and condensation segment are connect with the pole of rectangular cell monomer and side wall respectively;The evaporator section absorbs the heat that pole generates, and is transferred to condensation segment by isolation section, heat is oriented to rectangular cell monomer bottom by the condensation segment;The invention also discloses the rectangular cells including above-mentioned bending phase transformation heat pipe;Evaporator section is fixed on the pole of battery cell by the present invention, the side wall of condensation segment and battery cell is fitted closely, evaporator section absorbs the heat that pole generates, condensation segment is transferred to by isolation section, the bottom of heat guiding rectangular cell monomer is realized at battery cell pole and the heat of bottom is average by condensation segment.

Description

It is bent phase transformation heat pipe and the rectangular cell using it
Technical field
The invention belongs to battery technical field of heat dissipation, and in particular to bending phase transformation heat pipe and the rectangular cell using it.
Background technique
During lithium ion battery high power charging-discharging, pole and battery body can generate rapidly a large amount of heat, directly It connects the heat accumulation for leading to battery and monomer heat is unevenly distributed problem;Thermal buildup issue inside battery cell is easy to cause The volume expansion of battery and electrolyte inside failure, and battery cell heat distribution unevenly then drastically influences inside battery electrification Learn the consistency of reaction.
Therefore, in order to extend the service life cycle of lithium ion battery and play the optimal performance of battery, battery list is solved The thermal buildup issue and heat distribution problem of non-uniform in internal portion have great importance, although the existing device for battery heat dissipation It can radiate to battery localized hyperthermia, but can not solve the problems, such as that heat is unevenly distributed.
Summary of the invention
The object of the present invention is to provide bending phase transformation heat pipes, by mutual between evaporator section, isolation section and condensation segment Cooperation, evaporator section absorb the heat that pole generates, are transferred to condensation segment by isolation section, heat is oriented to rectangular cell by condensation segment Monomer bottom, realizes at battery cell pole and the heat of bottom is average.
It is a further object of the present invention to provide a kind of rectangular cells.
The technical scheme adopted by the invention is that:
It is bent phase transformation heat pipe comprising sequentially connected evaporator section, isolation section and condensation segment, the evaporator section and condensation Section is connect with the pole of rectangular cell monomer and side wall respectively;
The evaporator section absorbs the heat that pole generates, and is transferred to condensation segment by isolation section, and the condensation segment is by heat It is oriented to rectangular cell monomer bottom.
The features of the present invention also characterized in that
It further comprise heat conductive insulating double-sided adhesive, the condensation segment is fixed on rectangular cell list by heat conductive insulating double-sided adhesive On the side wall of body.
The isolation section is the semi-circular structure for increasing heat transfer distances.
The evaporator section and isolation section pass through circular sliding slopes.
Capillary-porous material for fluid flow is provided in the bending phase transformation heat pipe.
A kind of rectangular cell comprising above-mentioned bending phase transformation heat pipe and battery body, the bending phase transformation heat pipe are set There are two setting, it is located at the two sides of battery body.
The features of the present invention also characterized in that
The evaporator section of the bending phase transformation heat pipe is welded on the pole of battery body, the condensation of the bending phase transformation heat pipe Section is bonded with the side wall of battery body.
Two bending phase transformation heat pipes shift to install.
The condensation segment of one bending phase transformation heat pipe is arranged on battery side wall and is arranged by front surface, another The condensation segment of the bending phase transformation heat pipe is arranged on another side wall of battery and is arranged close to rear surface.
Compared with prior art, the present invention is in use, evaporator section is fixed on the pole of battery cell, by condensation segment and The side wall of battery cell fits closely, and evaporator section absorbs the heat that pole generates, and is transferred to condensation segment, condensation segment by isolation section By the bottom of heat guiding rectangular cell monomer, realizes at battery cell pole and the heat of bottom is average.
Detailed description of the invention
Fig. 1 is that the embodiment of the present invention 1 provides the structural schematic diagram of bending phase transformation heat pipe;
Fig. 2 is that the embodiment of the present invention 2 provides the structural schematic diagram of bending phase transformation heat pipe;
Fig. 3 is that the embodiment of the present invention 3 provides the structural schematic diagram of rectangular cell;
Fig. 4 is the main view of Fig. 3;
Fig. 5 is the top view of Fig. 3;
Fig. 6 is that rectangular cell installs the Temperature Distribution cloud atlas before this bending phase transformation heat pipe additional;
Fig. 7 is that rectangular cell installs the Temperature Distribution cloud atlas after this bending phase transformation heat pipe additional.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.
The embodiment of the present invention 1 provides a kind of bending phase transformation heat pipe, as shown in Figure 1 comprising sequentially connected evaporator section 1, Isolation section 2 and condensation segment 3, evaporator section 1 and condensation segment 3 are connect with the pole of rectangular cell monomer and side wall respectively;
In this way, evaporator section 1 is fixed on the pole of battery cell, the side wall of condensation segment 3 and battery cell is closely pasted It closes, evaporator section 1 absorbs the heat that pole generates, and is transferred to condensation segment 3 by isolation section 2, heat is oriented to square electric by condensation segment 3 Pond monomer bottom.
The embodiment of the present invention 2 provides a kind of bending phase transformation heat pipe, as shown in Figure 2 comprising sequentially connected evaporator section 1, Isolation section 2 and condensation segment 3, evaporator section 1 and condensation segment 3 are connect with the pole of rectangular cell monomer and side wall respectively;
In this way, evaporator section 1 is fixed on the pole of battery cell, the side wall of condensation segment 3 and battery cell is closely pasted It closes, evaporator section 1 absorbs the heat that pole generates, and is transferred to condensation segment 3 by isolation section 2, heat is oriented to square electric by condensation segment 3 Pond monomer bottom.
It further comprise heat conductive insulating double-sided adhesive 4, condensation segment 3 is fixed on rectangular cell list by heat conductive insulating double-sided adhesive 4 It on the side wall of body, is in close contact in this way, being realized by heat conductive insulating double-sided adhesive 4, ensure that bending phase transformation heat pipe and rectangular cell Between heat transfer efficiency, be also prevented from battery occur short circuit.
Isolation section 2 is conducive to distributing for heat in this way, can increase the contact surface between air for semi-circular structure.
Capillary-porous material for fluid flow is provided in the bending phase transformation heat pipe.
In addition, in order to avoid the capillary-porous material that right-angle structure blocks bending phase transformation inside heat pipe, evaporator section 1 and heat-insulated Section 2 keeps media flow more unimpeded by circular sliding slopes.
The embodiment of the present invention 3 provides a kind of rectangular cell, as in Figure 3-5 comprising above-mentioned bending phase transformation heat pipe 5 with And battery body 6, there are two the bending settings of phase transformation heat pipe 5, the two of battery body 6 is located at, in this way, passing through two bending phases The heat of rectangular cell positive and negative terminals is averagely arrived battery bottom by heating pipe 5, realizes heat dissipation and the average effect of heat.
The evaporator section 1 of bending phase transformation heat pipe 5 is welded on the pole of battery body 6, is bent the condensation segment 3 of phase transformation heat pipe 5 It is bonded with the side wall of battery body 6, in this way, evaporator section 1 is fixed on pole by welding, realizes pole heat Quick export.
Two bending phase transformation heat pipes 5 shift to install, and the condensation segment 3 of one of bending phase transformation heat pipe 5 is arranged in battery It is arranged on side wall and by front surface, the condensation segment 3 of another bending phase transformation heat pipe 5 is arranged on another side wall of battery And it is arranged close to rear surface;
Because the effect for being bent phase transformation heat pipe 5 is better, and battery body when the temperature difference of evaporator section 1 and condensation segment 3 is bigger Temperature of 6 sides close to edge is lower, therefore condensation segment is arranged by proximal edge, but improves the effect of bending phase transformation heat pipe 5 Rate, and two bending phase transformation heat pipes 5 shift to install and make battery when in use and have enough connection spaces.
The course of work: the liquid evaporation vaporization when evaporator section 1 is heated in Mao Renxin, steam pass through under small pressure difference Isolation section 2 flows to condensation segment 3, and releases heat in condensation segment 3 and condense into liquid, and liquid is again along porous material by capillary force Evaporator section 1 is flowed back in effect, so recycles, and heat reaches another-end by one end of bending phase transformation heat pipe 5, realizes being averaged for heat, And reduce the heat at the higher pole of temperature, solve the problems, such as thermal accumlation in battery.
The heat dissipation of the bending phase transformation heat pipe and even temperature effect are described further below by Icepak emulation:
Simulation parameter:
1, the rectangular aluminum-shell battery of 60Ah LiFePO4, internal resistance are 0.6m Ω, and thermal coefficient is 57.25W/ (mK), than 1343.9J/kg DEG C of thermal capacitance, density 1990kg/m3
2, the main material for being bent phase transformation heat pipe is copper, and thermal coefficient is set as 10000W/ (mK);
3, the charge-discharge magnification of battery is set as 2C;
4, the battery entirety type of cooling is cooling for free convection.
Simulation result:
Fig. 6 is that rectangular cell installs the Temperature Distribution cloud atlas before this bending phase transformation heat pipe additional, it can be seen from the figure that battery fills The heat generated in discharge process does not focus primarily upon position among pole and battery body, not plus the battery list of bending phase transformation heat pipe Body maximum temperature reaches 315.4K (42.4 DEG C), and thermal buildup issue and monomer heat distribution unevenness problem are serious;
Fig. 7 is that rectangular cell installs the Temperature Distribution cloud atlas after this bending phase transformation heat pipe additional, it can be seen from the figure that plus bending After phase transformation heat pipe, the maximum temperature of battery cell is down to 313.4K (40.4 DEG C), and monomer cooling efficiency accordingly promotes 4.7%, this Outside, the heat at accumulation position among battery body is conducted along heat pipe direction originally, and the heat of pole is oriented to also by heat pipe The lower battery cell bottom of temperature, so that the thermal buildup issue of battery and monomer heat distribution unevenness problem be made effectively to be solved Certainly.
Using the above scheme, compared with prior art, evaporator section in use, is fixed on the pole of battery cell by the present invention On, the side wall of condensation segment and battery cell is fitted closely, evaporator section absorbs the heat that pole generates, and is transferred to by isolation section The bottom of heat guiding rectangular cell monomer is realized at battery cell pole and the heat of bottom is average by condensation segment, condensation segment.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, In the technical scope disclosed by the present invention, any changes or substitutions that can be easily thought of by anyone skilled in the art, It should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with scope of protection of the claims Subject to.

Claims (9)

1. a kind of bending phase transformation heat pipe, which is characterized in that it includes sequentially connected evaporator section, isolation section and condensation segment, institute Evaporator section and condensation segment is stated to connect with the pole of rectangular cell monomer and side wall respectively;
The evaporator section absorbs the heat that pole generates, and is transferred to condensation segment by isolation section, heat is oriented to by the condensation segment Rectangular cell monomer bottom.
2. bending phase transformation heat pipe according to claim 1, which is characterized in that further comprise heat conductive insulating double-sided adhesive, institute Condensation segment is stated to be fixed on by heat conductive insulating double-sided adhesive on the side wall of rectangular cell monomer.
3. bending phase transformation heat pipe according to claim 2, which is characterized in that the isolation section is for increasing heat transfer distances Semi-circular structure.
4. bending phase transformation heat pipe according to claim 1-3, which is characterized in that the evaporator section and isolation section are logical Cross circular sliding slopes.
5. bending phase transformation heat pipe according to claim 4, which is characterized in that be provided in the bending phase transformation heat pipe for liquid The capillary-porous material of body flowing.
6. a kind of rectangular cell, which is characterized in that it includes the described in any item bending phase transformation heat pipes of claim 1-5 and electricity Pond ontology, the bending phase transformation heat pipe are provided with two, are located at the two sides of battery body.
7. rectangular cell according to claim 6, which is characterized in that the evaporator section of the bending phase transformation heat pipe is welded on electricity On the pole of pond ontology, the condensation segment of the bending phase transformation heat pipe is bonded with the side wall of battery body.
8. rectangular cell according to claim 7, which is characterized in that two bending phase transformation heat pipes shift to install.
9. rectangular cell according to claim 8, which is characterized in that the condensation segment setting of a bending phase transformation heat pipe It is arranged on battery side wall and by front surface, the condensation segment of another bending phase transformation heat pipe is arranged in battery other one It is arranged on a side wall and close to rear surface.
CN201810497650.XA 2018-05-22 2018-05-22 It is bent phase transformation heat pipe and the rectangular cell using it Pending CN110518307A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112886090A (en) * 2021-01-12 2021-06-01 浙江南都电源动力股份有限公司 Double-layer aluminum shell

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204441415U (en) * 2015-01-12 2015-07-01 华南理工大学 The flat micro heat pipe heat abstractor of a kind of Vehicular dynamic battery interpolation
DE102014202129A1 (en) * 2014-02-06 2015-08-06 Siemens Aktiengesellschaft Battery cell cooling
CN204787967U (en) * 2015-05-22 2015-11-18 中国科学技术大学 Adiabatic segment has bending angle's heat pipe
CN205016639U (en) * 2015-08-14 2016-02-03 东莞市迈科科技有限公司 Heat radiator for lithium ion battery system
KR20160041411A (en) * 2014-10-07 2016-04-18 주식회사 엘지화학 Battery Module
CN106654430A (en) * 2016-12-07 2017-05-10 浙江大学 Heat pipe and phase-change material-based low-temperature power battery heat management system
CN106972219A (en) * 2017-03-22 2017-07-21 江苏中关村科技产业园节能环保研究有限公司 A kind of plate-type battery coldplate of application hot pipe technique
CN106972218A (en) * 2017-03-07 2017-07-21 华南理工大学 The cooling device and method of a kind of cylinder-type power battery group
CN208352486U (en) * 2018-05-22 2019-01-08 银隆新能源股份有限公司 A kind of bending phase transformation heat pipe and the rectangular cell using it

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014202129A1 (en) * 2014-02-06 2015-08-06 Siemens Aktiengesellschaft Battery cell cooling
KR20160041411A (en) * 2014-10-07 2016-04-18 주식회사 엘지화학 Battery Module
CN204441415U (en) * 2015-01-12 2015-07-01 华南理工大学 The flat micro heat pipe heat abstractor of a kind of Vehicular dynamic battery interpolation
CN204787967U (en) * 2015-05-22 2015-11-18 中国科学技术大学 Adiabatic segment has bending angle's heat pipe
CN205016639U (en) * 2015-08-14 2016-02-03 东莞市迈科科技有限公司 Heat radiator for lithium ion battery system
CN106654430A (en) * 2016-12-07 2017-05-10 浙江大学 Heat pipe and phase-change material-based low-temperature power battery heat management system
CN106972218A (en) * 2017-03-07 2017-07-21 华南理工大学 The cooling device and method of a kind of cylinder-type power battery group
CN106972219A (en) * 2017-03-22 2017-07-21 江苏中关村科技产业园节能环保研究有限公司 A kind of plate-type battery coldplate of application hot pipe technique
CN208352486U (en) * 2018-05-22 2019-01-08 银隆新能源股份有限公司 A kind of bending phase transformation heat pipe and the rectangular cell using it

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
龙妍 等: "节能概率", 31 December 2017, 华中科技大学出版社, pages: 141 - 142 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112886090A (en) * 2021-01-12 2021-06-01 浙江南都电源动力股份有限公司 Double-layer aluminum shell
CN112886090B (en) * 2021-01-12 2022-08-23 浙江南都电源动力股份有限公司 Double-layer aluminum shell

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