CN110510870A - Glass door - Google Patents
Glass door Download PDFInfo
- Publication number
- CN110510870A CN110510870A CN201810492862.9A CN201810492862A CN110510870A CN 110510870 A CN110510870 A CN 110510870A CN 201810492862 A CN201810492862 A CN 201810492862A CN 110510870 A CN110510870 A CN 110510870A
- Authority
- CN
- China
- Prior art keywords
- glass
- parts
- oxide
- stone
- pseudo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
- A47B61/00—Wardrobes
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
- A47B7/00—Tables of rigid construction
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47C—CHAIRS; SOFAS; BEDS
- A47C5/00—Chairs of special materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/02—Other methods of shaping glass by casting molten glass, e.g. injection moulding
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
- C03C3/068—Glass compositions containing silica with less than 40% silica by weight containing boron containing rare earths
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- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/70—Door leaves
- E06B3/72—Door leaves consisting of frame and panels, e.g. of raised panel type
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Glass Compositions (AREA)
Abstract
The invention proposes a kind of glass doors, are made of doorframe and door-plate, and the door-plate is made of stone-pseudo glass, belong to glass ceramics.Contain more crystal in this stone-pseudo glass, the ratio of crystal is about 70%.Opaque, preparation process is simple.Its mechanical performance is excellent, and appearance is in light green color or white, and glossiness is good, is excellent stone imitation material.Its component that can be used as high-grade stone furniture.
Description
Technical field
The present invention relates to a kind of glass doors, and devitrified glass is used to be made.
Background technique
Microcrystal is by glass phase and crystallization phase composition.The distribution situation of the two changes with its ratio.Control can be passed through
The ratio and nucleus diameter of its crystalline phase adjust refractive index.
Glass contains silicon, aluminium, zirconium, hafnium, titanium, calcium, magnesium, zinc, potassium, sodium, antimony, ferriferous oxide, sulfate and chloride, with
And at least one component selected from erbium, neodymium, cerium, cobalt, nickel, Mn oxide and selenium compound.The devitrified glass can be used for manufacturing
Glassware, refractive index is higher, and glossiness is good.It as described in that patent, is leadless crystal glass.
Its SiO2 by 50-60 weight %, the K2O of 4-14 weight %, the BaO of 10-20 weight % and
The TiO2 of 3-10 weight % is formed.The component is also to improve glass refraction.
It includes surface layer, middle layer, bottom and structural fibers net, and surface layer, middle layer and bottom are by metal salt
It is formed with metal oxide.The mechanical performance of the substrate meets needs.
The preparation method of aventurine fluoride-free opal glass: 65~75 parts of silica, 0.5~2.0 part of oxygen
Change aluminium, 8.0~12.0 parts of calcium oxide, 2.0~5.0 parts of magnesia, 9~15 parts of sodium oxide molybdena, 1~5
Phosphorus pentoxide, 0.5~1 part of the boron oxide, 0.5~1.5 part of zinc oxide, 0.5~1 part of oxidation of part
Zirconium, 0.5~1 part of bismuth oxide and 0.2~0.5 part of cerous carbonate.The glass has certain light transmittance, white
It is translucent.
Transparent glass-ceramics containing fluorapatite crystal is grouped as: SiO225.9 by the group of following molar percentage
~45%, AlPO412~36%, Al2O36~19%, CaO15~30%, CaF212~24%, Eu2O30~2%,
EuF30~2%, Yb2O30~5%, YbF30~5%, CeO20~2%, CeF30~2%；Wherein, described
The total amount of Eu2O3, EuF3, CeO2 and CeF 3 is no less than 0.1%；The total amount of Yb 2O3 and YbF 3 is no less than 0.2%.It should
Crystalline solid ratio in devitrified glass is low, refractive index with higher.
The low in glossiness of the devitrified glass of the prior art, hardness and mechanical strength cannot meet the needs, and be not easy to be made often
Furniture item.Therefore, the prior art has further improved necessity.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of glass doors, and stone-pseudo glass is used to be made, the stone-pseudo glass
With low-refraction, high intensity, high rigidity etc. performances, instead of the high-grade imitative stone furniture of stone material production.
A kind of stone-pseudo glass, which is characterized in that mass percent meter consists of the following compositions: 33 ~ 36 parts of silica,
9 ~ 10 parts of calcium oxide, 10 ~ 12 parts of magnesia, 8 ~ 12 parts of aluminium oxide, 8 ~ 10 parts of aluminum phosphate, 5 ~ 6 parts of calcirm-fluoride, potassium oxide
0.1 ~ 2 part, 0.01 ~ 0.1 part of sodium oxide molybdena, 0.01 ~ 0.016 part of gold trichloride, 0.01 ~ 0.02 part of stannic oxide, copper sulphate
0.01 ~ 0.1 part, 1 ~ 3 part of boron oxide, 5 ~ 6 parts of zirconium oxide, 5 ~ 6 parts of lithia, 0.1 ~ 3 part of bismuth oxide, titanium oxide
1 ~ 3 part, 1 ~ 3 part of barium monoxide, 1 ~ 1.5 part of antimony oxide, 1 ~ 1.9 part of vanadic anhydride, 1 ~ 1.5 part of lanthana, carbonic acid
1 ~ 1.5 part of cerium, 0.01 ~ 0.04 part of zinc oxide, 0.01 ~ 0.1 part of iron oxide.
Preferably, the aluminium oxide is 11 ~ 12 parts.Intensity can be improved in high-alumina.
Preferably, the aluminium oxide is 8 ~ 10 parts.Al suboxide is conducive to form.
Preferably, the content of the magnesia is 1.2 times of calcium oxide, and the content of the silica is calcium oxide
3.7 again.The ratio of silica, magnesia and calcium oxide is more important in the present invention, and under the ratio, devitrified glass exists
The viscosity of molten state is low, and manufactured product intensity is high.In addition, crystallization temperature line is sharp under the ratio, it is easy to nucleus molding, this
It is also that the prior art is inaccessiable, is the further improvement of the application.
Preferably, 33.3 parts of silica, 9 parts of calcium oxide, 10.8 parts of magnesia, 8 parts of aluminium oxide, aluminum phosphate
10 parts, 5.6 parts of calcirm-fluoride, 1 part of potassium oxide, 0.05 part of sodium oxide molybdena, 0.012 part of gold trichloride, stannic oxide
0.012 part, 0.08 part of copper sulphate, 2 parts of boron oxide, 6 parts of zirconium oxide, 6 parts of lithia, 1 part of bismuth oxide, oxidation
2 parts of titanium, 2 parts of barium monoxide, 1.4 parts of antimony oxide, 1.2 parts of vanadic anhydride, 1.4 parts of lanthana, cerous carbonate 1.4
Part, 0.02 part of zinc oxide, 0.05 part of iron oxide.
Preferably, 35 parts of silica, 9.46 parts of calcium oxide, 11.35 parts of magnesia, 10 parts of aluminium oxide, phosphoric acid
9 parts of aluminium, 5.8 parts of calcirm-fluoride, 0.1 part of potassium oxide, 0.03 part of sodium oxide molybdena, 0.015 part of gold trichloride, titanium dioxide
0.018 part of tin, 0.02 part of copper sulphate, 1.5 parts of boron oxide, 5 parts of zirconium oxide, 5 parts of lithia, bismuth oxide 0.2
Part, 2 parts of titanium oxide, 2 parts of barium monoxide, 1.2 parts of antimony oxide, 1.6 parts of vanadic anhydride, 1.2 parts of lanthana, carbonic acid
1.2 parts of cerium, 0.03 part of zinc oxide, 0.03 part of iron oxide.
Preferably, 35 parts of silica, 9.46 parts of calcium oxide, 11.35 parts of magnesia, 12 parts of aluminium oxide, phosphoric acid
9 parts of aluminium, 5.2 parts of calcirm-fluoride, 1.5 parts of potassium oxide, 0.08 part of sodium oxide molybdena, 0.014 part of gold trichloride, titanium dioxide
0.016 part of tin, 0.05 part of copper sulphate, 2.5 parts of boron oxide, 5 parts of zirconium oxide, 5 parts of lithia, bismuth oxide 0.2
Part, 2 parts of titanium oxide, 2 parts of barium monoxide, 1.2 parts of antimony oxide, 1.6 parts of vanadic anhydride, 1.2 parts of lanthana, carbonic acid
1.2 parts of cerium, 0.035 part of zinc oxide, 0.01 part of iron oxide.
The present invention does not limit the preparation method of stone-pseudo glass, using existing fusing crystallization method or sintering process.
A kind of preparation method of stone-pseudo glass configures raw material as required, melts after mixing, forms melten glass liquid, then
Homogenizing, clarification, then kept for 1 to 10 hour in the range of temperature is 1320 DEG C to 1400 DEG C, glass is taken out after cooling,
The stone-pseudo glass is made in re-annealing.
A kind of preparation method of stone-pseudo glass, configures raw material as required, and raw material are passed through melting end, are melted after mixing,
Melten glass liquid is formed, glass metal is then passed through cooling end, is homogenized in cooling end, is clarified, bubble is discharged, then by glass
Liquid drains into forming part, takes out glass after molding, and stone-pseudo glass is made in annealing, wherein in the forming part extremely with 1320 DEG C
1400 DEG C of temperature, glass metal are 1 to 10 hour in the time that forming part saves.
The melt temperature is 1500 DEG C to 1700 DEG C.
The annealing temperature is 500 DEG C to 800 DEG C, and cooling rate is 1 to 10 DEG C/min.
A kind of partition, which is characterized in that be made of the stone-pseudo glass.
A kind of glass door, it is characterised in that be made of doorframe and door-plate, the door-plate is made of the stone-pseudo glass.
A kind of glass wardrobe, it is characterised in that be made of skeleton and multiple plates, the plate is by the stone-pseudo glass system
At.
A kind of glass tables and chairs, it is characterised in that be made of skeleton and multiple plates, the plate is by the stone-pseudo glass system
At.
Contain more crystal in this stone-pseudo glass of the invention, the ratio of crystal is about 70%.It is opaque, prepare work
Skill is simple.Its mechanical performance is excellent, and appearance is in light green color or white, and glossiness is good, is excellent stone imitation material.It can make
For the component of high-grade stone furniture.
Claims (7)
1. kind of glass door, it is characterised in that be made of doorframe and door-plate, the door-plate is made of stone-pseudo glass.
2. the glass door according to claim 1, which is characterized in that the stone-pseudo glass contains 0.05 part of sodium oxide molybdena.
3. the glass door according to claim 1, which is characterized in that the aluminium oxide is 11 ~ 12 parts.
4. the glass door according to claim 1, which is characterized in that the aluminium oxide is 8 ~ 10 parts.
5. the glass door according to claim 1, which is characterized in that the content of the magnesia is the 1.2 of calcium oxide
Times, the content of the silica is 3.7 times of calcium oxide.
6. a kind of preparation method of glass door, which is characterized in that the proportion configures raw material, fusing according to claim 1
After crystallization, stone-pseudo glass is made in re-annealing, then glass door is made by stone-pseudo glass.
7. a kind of preparation method of glass door, which is characterized in that the proportion configures raw material, sintering according to claim 1
After crystallization, stone-pseudo glass is made in re-annealing, then glass door is made by stone-pseudo glass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810492862.9A CN110510870A (en) | 2018-05-22 | 2018-05-22 | Glass door |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810492862.9A CN110510870A (en) | 2018-05-22 | 2018-05-22 | Glass door |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110510870A true CN110510870A (en) | 2019-11-29 |
Family
ID=68622053
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810492862.9A Withdrawn CN110510870A (en) | 2018-05-22 | 2018-05-22 | Glass door |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110510870A (en) |
-
2018
- 2018-05-22 CN CN201810492862.9A patent/CN110510870A/en not_active Withdrawn
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20191129 |