CN110504111A - A kind of paper base capacitor laser engraving preparation method with three-dimensional energy storing structure - Google Patents
A kind of paper base capacitor laser engraving preparation method with three-dimensional energy storing structure Download PDFInfo
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- CN110504111A CN110504111A CN201910838104.2A CN201910838104A CN110504111A CN 110504111 A CN110504111 A CN 110504111A CN 201910838104 A CN201910838104 A CN 201910838104A CN 110504111 A CN110504111 A CN 110504111A
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- 239000003990 capacitor Substances 0.000 title claims abstract description 71
- 238000002360 preparation method Methods 0.000 title claims abstract description 48
- 238000010147 laser engraving Methods 0.000 title claims abstract description 22
- 239000000758 substrate Substances 0.000 claims abstract description 40
- 239000007772 electrode material Substances 0.000 claims abstract description 30
- 239000003792 electrolyte Substances 0.000 claims abstract description 29
- 230000008595 infiltration Effects 0.000 claims abstract description 3
- 238000001764 infiltration Methods 0.000 claims abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 51
- 229910021389 graphene Inorganic materials 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 23
- 239000000017 hydrogel Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 229910052799 carbon Inorganic materials 0.000 claims description 17
- 239000002002 slurry Substances 0.000 claims description 14
- 238000003491 array Methods 0.000 claims description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 11
- 229910021641 deionized water Inorganic materials 0.000 claims description 11
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 10
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- 238000007598 dipping method Methods 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 239000002041 carbon nanotube Substances 0.000 claims description 6
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 239000003575 carbonaceous material Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 239000002322 conducting polymer Substances 0.000 claims description 4
- 229920001940 conductive polymer Polymers 0.000 claims description 4
- 230000009977 dual effect Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000012046 mixed solvent Substances 0.000 claims description 4
- 239000011368 organic material Substances 0.000 claims description 4
- 230000010355 oscillation Effects 0.000 claims description 4
- 230000000717 retained effect Effects 0.000 claims description 4
- 239000006228 supernatant Substances 0.000 claims description 4
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 3
- -1 polyoxyethylene Polymers 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims description 2
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 claims description 2
- 239000011812 mixed powder Substances 0.000 claims description 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229920000767 polyaniline Polymers 0.000 claims description 2
- 229920000128 polypyrrole Polymers 0.000 claims description 2
- 229920000123 polythiophene Polymers 0.000 claims description 2
- 238000000967 suction filtration Methods 0.000 claims description 2
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 claims description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 19
- 238000004146 energy storage Methods 0.000 abstract description 10
- 238000001035 drying Methods 0.000 abstract description 8
- 239000011232 storage material Substances 0.000 abstract description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 10
- 239000002131 composite material Substances 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 230000005611 electricity Effects 0.000 description 4
- 238000003828 vacuum filtration Methods 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 239000011267 electrode slurry Substances 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010041 electrostatic spinning Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 238000010329 laser etching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000010129 solution processing Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003503 terephthalic acid derivatives Chemical class 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/10—Multiple hybrid or EDL capacitors, e.g. arrays or modules
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/26—Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/46—Metal oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/48—Conductive polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/56—Solid electrolytes, e.g. gels; Additives therein
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
A kind of paper base capacitor laser engraving preparation method with three-dimensional energy storing structure, belongs to energy storage material and technical field.Preparation step is as follows: preparing papery three-dimensional conductive substrate first, then laser engraving is carried out on conductive substrate, obtains three-dimensional structure electrod-array, finally carries out electrolyte double-coated and infiltration, by drying, the paper base flexible capacitor with three-dimensional energy storing structure is obtained.This method is by carrying out laser engraving to electrode material papery three-dimensional conductive substrate, it can simply, efficiently realize the preparation of different configuration paper base capacitor, preparation process is simple, at low cost, simultaneously because the capacitor of this method preparation has three-dimensional energy storing structure, device has good energy storage characteristic and flexibility.
Description
Technical field
The paper base capacitor laser engraving preparation method with three-dimensional energy storing structure that the present invention relates to a kind of, belongs to energy storage material
Material and technical field.
Background technique
Capacitor is also referred to as electrochemical capacitor, is a kind of novel energy storage device.The power density and energy of capacitor
Density is between traditional capacitor and battery, and relative to battery and fuel cell, capacitor has high power density, quickly fills
The advantage of electric discharge and long circulation life；Relative to traditional capacitor, capacitor has the advantage of high-energy density.Wherein, paper base
Capacitor is due to its unique high-flexibility and Miniaturized advantage, it is considered to be wearable and portable electronic device novel
Energy storage device.
The micromation paper base capacitor explored effective way and research and develop new technology preparation high quality is the weight in the current field
Want developing direction.Zhaoyang Liu et al. (Advanced Materials 2016,28,2217) has prepared graphite first
Then the combination electrode slurry that alkene and electro-chemical activity organic polymer PH1000 are constituted assists spraying printing, In by template
Interdigitation planar capacitor is prepared in paper substrates；This method is conducive to prepare the series and parallel structure of capacitor, but needs spy
Different lithographic equipment carries out electrode template preparation, and complex process is at high cost；And the capacitor obtained has planar structure, storage
Charge active area is small, cause the energy-storage property of capacitor it is not high (under the sweep speed of 1mV/s area specific capacitance be 5.4mF/
cm2).Zhang Haixia et al. discloses a kind of free style button capacitor based on laser graphics and manufacturing method (patent application
Number 201610953666.8), preparation step specifically includes that (1) prepares PVDF Nanowire by electrostatic spinning on back electrode
Dimension；(2) carbon nanotube neopelex solution is added dropwise on PVDF nanofiber and is used as flexible electrode；It (3) will be electric
Pole is transferred to PVA-H3On PO4 solid electrolyte；(4) Au electrode layer is sputtered on electrolyte-flexible electrode, as capacitor collection
Fluid；(5) by laser graphics mode, metal collector layer, flexible electrode layer are cut into interdigitated electrode structure, and it is following
Solid-state electrolyte layer remain unchanged, obtain free style button capacitor.This method preparation capacitor have high-flexibility and
It is Miniaturized, but equally there is the deficiencies of preparation step is complicated, at high cost.Wenli Zhang et al. (Adv. Energy
Mater. 2018,1801840) use laser etching method by lignin conversion for graphene, it then will be without laser spoke
According to lignin carry out water dissolution and remove, to obtain the interdigital electrode with three-dimensional grapheme structure, and further coating electricity
Xie Zhi obtains micromation capacitor.The preparation of Different electrodes pattern can be carried out on multiple polymers substrate using this method,
But lignin is influenced to the carbonisation of graphene by many factors such as laser power density and irradiation time, is not allowed
The grapheme material for easily obtaining high quality, on interdigital electrode surface, vapor deposition golden film can be improved the electric conductivity and capacitor of electrode
Energy storage characteristic, but process complications and cost is caused to improve；In addition, using polymethyl methacrylate in this method
(PMMA), the polymer matrix films such as poly terephthalic acid class plastics (PET) are as capacitor supporter, increase device volume and
Without flexibility.
Summary of the invention
In order to overcome problems of the prior art, the present invention provides a kind of paper base capacitor with three-dimensional energy storing structure
Device laser engraving preparation method, this method by carrying out laser engraving to electrode material papery three-dimensional conductive substrate, can it is easy,
Efficiently realize the preparation of different configuration paper base capacitor, preparation process is simple, at low cost, simultaneously because the electricity of this method preparation
Container has three-dimensional energy storing structure, and the energy storage characteristic of device is optimized.
The technical solution adopted by the present invention is that: a kind of paper base capacitor laser engraving preparation side with three-dimensional energy storing structure
Method, specific preparation process is as follows:
Step 1: the preparation of papery three-dimensional conductive substrate
Electrode material slurry is prepared, using double-face vacuum suction filtration or dipping method, electrode material slurry is made to penetrate into porous flexible paper
Matter base internal is attached to surface simultaneously, is then dried in 25-100 DEG C of vacuum drying oven 5-30 hours, forms papery
Three-dimensional conductive substrate；
Step 2: prepared by the laser engraving of three-dimensional electrode arrays configuration
Using the three-dimensional electrode arrays configuration of computer software design, laser pattern engraving is carried out on papery conductive substrate,
During laser scanning, laser power is 1-30 watts, laser scan rate 100-10000 mm/second, and in paper substrates
Upper dropwise addition deionized water or distilled water are to reduce temperature；Iterative cycles scanning is carried out, until in laser-scanning position papery matrix
Electrode material be carbonized or aoxidize removing, and paper substrates are retained, to obtain three-dimensional electrode arrays configuration；
Step 3: the dual coating of electrolyte and the formation of three-dimensional structure capacitor
Hydrogel electrolyte is prepared, then applies hydrogel electrolyte in the three-dimensional electrode arrays configuration tow sides prepared,
Promote infiltration of the hydrogel electrolyte in paper substrates, is finally dried 5-30 hour at 25-50 DEG C in air, acquisition
Paper base capacitor with three-dimensional energy storing structure.
The three-dimensional electrode arrays configuration includes interdigital electrode configuration and other shaped electrode structures, wherein special-shaped battery
Pole structure including but not limited to S type, L-type, A type, H-type configuration electrode structure, and due to electrode material permeate in entire papery
Base internal, so that electrode has three-dimensional conductive characteristic.
The paper base capacitor with three-dimensional energy storing structure includes the single paper base capacitor with three-dimensional energy storing structure,
It also include cascaded structure, parallel-connection structure and the serial-parallel knot being made of multiple paper base capacitors with three-dimensional energy storing structure
Structure.
The composition of the electrode material are as follows: the carbon materials powder and transition metal oxide powder that mass content is 40-95%
The combination electrode material powder that body or conducting polymer materials powder are constituted；Wherein, the carbon materials powder is graphene, carbon
The mixed powder of one or more of nanometer rods, carbon nanotube and activated carbon, transition metal oxide powder are vanadium oxide, oxygen
Change cobalt, manganese oxide, nickel oxide or ferric oxide powder, conducting polymer materials powder is polyaniline, polypyrrole or polythiophene powder.
The preparation steps of the electrode material slurry are as follows: disperse combination electrode material powder in solvent, be placed in ice bath
Middle sonic oscillation 30-90 minutes, then dispersion liquid is placed in and stands 5-24 hours at room temperature, finally extracts uniform and stable supernatant
Liquid is as electrode material slurry；Wherein, solvent is dimethylformamide, ethyl alcohol, dimethyl sulfoxide, N-Methyl pyrrolidone, goes
The mixed solvent of one or more of ionized water, isopropanol.
The composition of the hydrogel electrolyte are as follows: deionized water includes carboxymethyl cellulose, polyvinyl alcohol or polyoxyethylene
The high-molecular organic material of alkene and the inorganic matter comprising phosphoric acid, sulfuric acid, sodium sulphate, potassium hydroxide, lithium sulfate or lithium perchlorate, institute
State deionized water: high-molecular organic material: the mass ratio of inorganic matter is 8-16:1-3:1；By the mixture matched above in 60-
Magnetic agitation is carried out in 100 DEG C of water-baths, until solution becomes clear, obtains hydrogel electrolyte.
The beneficial effects of the present invention are:
1. in the preparation process of the paper base capacitor with three-dimensional energy storing structure described in, electrode material papery conductive substrate is adopted
It can be realized, do not need using common commercialization laser with vacuum filtration or dipping method preparation, the engraving of electrod-array
Instrument and equipment costly；In addition, prepared electrode conductivuty containing carbon materials is good, do not need additionally to prepare metal afflux
Body, entire device preparation technology is simple, low in cost；
2. in the paper base capacitor with three-dimensional energy storing structure described in, electrode material, which is impregnated with, to be distributed in entire paper substrates
Portion and surface, laser engraving runs through entire paper substrates, while realizing electrolyte in substrate by the coating of face electrolyte anyway
It is fully penetrated, therefore the capacitor prepared has three-dimensional energy storing structure, for common two-dimentional paper base capacitor, storage
Energy characteristic is optimized and is improved；
3. micromation and the special-shaped preparation of capacitor and its preparation of series and parallel structure, energy can be conveniently realized using this method
Enough meet portable, wearable electronic application demand.
Detailed description of the invention
Fig. 1 is the interdigitation Graphene electrodes three-dimensional energy storing structure paper base capacitor for preparing in embodiment one in different electric currents
Constant current charge-discharge curve under density, current density are respectively 0.3mA/cm2And 0.5mA/cm2。
Fig. 2 be the interdigitation Graphene electrodes three-dimensional energy storing structure paper base capacitor that is prepared in embodiment one 0.5 mA/
cm2Under current density in closed loop folding process area specific capacitance with folding times variation diagram.
Specific embodiment
With reference to the accompanying drawing, it is described further by specific embodiment.
Embodiment one
The preparation of interdigitation Graphene electrodes three-dimensional energy storing structure paper base capacitor is carried out, it is poly- using Graphene electrodes material, sulfuric acid-
Polyvinyl alcohol hydrogel electrolyte and use for laboratory qualitative filter paper are as substrate.
One, the vacuum filtration preparation of graphene papery three-dimensional conductive substrate:
The preparation of Graphene electrodes slurry: weighing 0.1g graphene powder, is scattered in 500ml solvent dimethylformamide, sets
Sonic oscillation 30-60 minutes in ice bath, then solution is put in and stands 24 hours at room temperature, is finally extracted uniform and stable
Supernatant is as Graphene electrodes slurry.
Electrode slurry vacuum filtration: using use for laboratory qualitative filter paper as substrate, by ready Graphene electrodes slurry into
Row vacuum filtration, to realize that electrode material is fully penetrated in paper substrates, carrying out filter paper, face is filtered anyway, until filter paper is anyway
Face blackening and filtrate become clarification.
The drying process of conductive substrate: two-sided filtered substrate is 5 hours dry in 80 DEG C of vacuum drying ovens, obtain graphite
Alkene papery three-dimensional conductive substrate.
Two, the laser engraving preparation of interdigitation graphene three-dimensional electrode arrays
Interdigitated electrodes array configuration is designed using computer software AutoCAD, controls CO using computer2It is prepared by laser engraving machine
Pattern engraving is carried out on good graphene papery conductive substrate, the laser power used is 3W, 5000 milli of laser scan rate
Meter per second；During laser scanning, deionized water, which is added dropwise, in paper substrates reduces temperature；It is repeatedly scanned with, until laser
The intracorporal graphene of scan position base is completely removed, and paper substrates are retained, and finally obtains designed graphene fork
Refer to electrod-array.Refer to electrode including 5 finger electrodes on every set comb electrode in prepared graphene interdigital electrode array structure
Length 10mm, width 1.0mm, electrode gap 0.5mm.
Three, sulfuric acid-polyvinyl alcohol hydrogel electrolyte dual coating preparation has the paper base capacitor of three-dimensional energy storing structure
The preparation of sulfuric acid-polyvinyl alcohol hydrogel electrolyte: concentrated sulfuric acid 0.3g is weighed, polyvinyl alcohol 0.3g is put in 3ml deionization
In water, magnetic agitation is carried out in 85 DEG C of water-baths, until solution becomes clear, obtains sulfuric acid-polyvinyl alcohol hydrogel electricity
Xie Zhi；
Hydrogel electrolyte double-coated: a small amount of prepared sulfuric acid-polyvinyl alcohol hydrogel electrolyte is dipped with glass bar,
The even surface coated in good Graphene electrodes array configuration made above, after being dried at room temperature for 1 hour, according still further to same
Operation carries out electrolyte coating in electrode reverse side；Finally capacitor is placed in 35 DEG C of drying boxes and is dried 24 hours, is obtained
Interdigitation Graphene electrodes paper base three-dimensional capacitor.The paper base three-dimensional capacitor area prepared in the present embodiment is 1.5cm2, it is thick
Degree is 0.2mm, volume 0.3cm3, have the characteristics that light weight, small in size.
Four, the performance characterization of the paper base capacitor of interdigitation Graphene electrodes three-dimensional energy storing structure
Fig. 1 is the interdigitation Graphene electrodes three-dimensional energy storing structure paper base capacitor for preparing in 0.3mA/cm2And 0.5mA/cm2Electricity
Constant current charge-discharge curve under current density, the symmetrical triangle shape of curve illustrate that capacitor manufactured in the present embodiment has very
Good electric double layer energy storage characteristic and charge and discharge invertibity；The capacitor prepared in the present embodiment is calculated by the curve to exist
0.3mA/cm2And 0.5mA/cm2Specific area capacitor under current density is 8.20mF/cm2And 7.81mF/cm2, illustrate that device has
There is good energy storage characteristic.
Fig. 2 is the interdigitation Graphene electrodes three-dimensional energy storing structure paper base capacitor for preparing in 0.5 mA/cm2Current density
In lower closed loop folding process area specific capacitance with folding times variation, the results showed that capacitor is protected after 1000 closed loops fold
Holdup is still up to 90%, it was demonstrated that using the height of paper base capacitor flexibility prepared by this method, can satisfy flexible electronic device
Application requirement.
Embodiment two
The preparation of L-type three-dimensional energy storing structure paper base capacitor is carried out using the method for the invention, wherein use carbon nanotube-two
Manganese oxide composite electrodes material, sodium sulphate-carboxymethyl cellulose hydrogel electrolyte and use for laboratory lens wiping paper are papery base
Bottom.It is described that specific preparation process is as follows.
One, prepared by carbon nanotube-manganese dioxide papery three-dimensional conductive substrate dipping:
1. prepared by carbon nanotube-manganese dioxide composite electrode material hydro-thermal method:
It is dissolved in 60mL deionized water firstly, measuring the 0.5mL concentrated sulfuric acid, adds 0.2g carbon nanotube, ultrasound is carried out to solution
Processing 3 hours；Then 0.6g potassium permanganate is added into solution, magnetic agitation 3h is carried out to solution at room temperature；It then will be molten
Liquid is fitted into autoclave, is reacted 6 hours at 150 DEG C, is after the reaction was completed taken out solution, and it is small to stand cooling 24 at room temperature
When；Finally solution is filtered by vacuum, obtained atrament is put into drying 12 hours in 100 DEG C of vacuum ovens, is obtained
To carbon nanotube-manganese dioxide composite powder of black.The mass content of carbon nanotube is 65%, titanium dioxide in the composite granule
The mass content of manganese is 35%.
2. the preparation of carbon nanotube-manganese dioxide composite electrode material slurry: weighing carbon nanotube-titanium dioxide of synthesis
20 milliliters of dimethylformamides-deionized water in the mixed solvent, mixed solvent is added in 0.2 milligram of manganese combination electrode material powder
The volume ratio of middle dimethylformamide and deionized water is 4:1, and solution is carried out sonic oscillation 60 minutes, is then put in solution
5 hours are stood at room temperature, finally extracts uniform and stable supernatant as electrode slurry.
3. carbon nanotube-manganese dioxide composite electrode material slurry dipping and drying: use for laboratory lens wiping paper is impregnated
In above prepared carbon nanotube-manganese dioxide composite electrode material slurry, dipping takes out after 1-5 minutes, does at room temperature
It is 5-30 minutes dry；To realize that electrode material is fully penetrated in paper substrates, dipping-drying process is repeated, until wiping mirror
The complete blackening of paper；It is finally that the substrate of complete blackening is 10 hours dry in 60 DEG C of vacuum drying ovens, obtain carbon nanotube-manganese dioxide
Papery three-dimensional conductive substrate.
Two, prepared by L-type carbon nanotube-manganese oxide three-dimensional electrode arrays laser engraving
L-type electrod-array configuration is designed using computer software AutoCAD, controls CO using computer2Laser engraving machine is preparing
Carbon nanotube-manganese oxide three-dimensional conductive substrate on carry out pattern engraving, the laser power used is 5W, laser scan rate
8000 mm/seconds；During laser scanning, distilled water, which is added dropwise, in paper substrates reduces temperature；It is repeatedly scanned with, until
Intracorporal carbon nanotube-the manganese bioxide electrode material of laser-scanning position base is completely removed, and paper substrates are retained, most
Designed L-type carbon nanotube-manganese dioxide three-dimensional electrod-array is obtained afterwards.Prepared L-type carbon nanotube-manganese dioxide three
Tie up electrode length 15mm, electrode width 0.8mm, electrode gap 0.2mm in electrode array configurations.
Three, sodium sulphate-carboxymethyl cellulose hydrogel electrolyte dual coating prepares three-dimensional paper base capacitor
1. the preparation of sodium sulphate-carboxymethyl cellulose hydrogel electrolyte: it is molten to weigh carboxymethyl cellulose 1g, sodium sulphate 0.72g
In 15ml deionized water, magnetic agitation 3 hours becomes clear until solution at 80 DEG C, obtains sodium sulphate-carboxymethyl
Cellulose aquagel electrolyte；
2. sodium sulphate-carboxymethyl cellulose hydrogel electrolyte double-coated: dipping a small amount of prepared sulfuric acid with glass bar
Sodium-carboxymethyl cellulose hydrogel electrolyte, even application is in good L-type carbon nanotube made above-manganese dioxide three-dimensional electricity
The surface of pole array configuration is put in after drying 2 hours at room temperature, according still further to same operation in three-dimensional electrode arrays configuration reverse side
Carry out electrolyte coating；Finally capacitor is placed in 40 DEG C of drying boxes and is dried 20 hours, L-type carbon nanotube-two is obtained
Manganese oxide electrode has the paper base capacitor of three-dimensional energy storing structure.
There is the paper base capacitor of three-dimensional energy storing structure to have good technique as L-type for above-mentioned S type, A type, H-type
Property and excellent performance, specific preparation process and L-type three-dimensional structure paper base capacitor preparation process are similar, repeat no more.
Claims (6)
1. a kind of paper base capacitor laser engraving preparation method with three-dimensional energy storing structure, it is characterized in that: specific preparation step
It is as follows:
Step 1: the preparation of papery three-dimensional conductive substrate
Electrode material slurry is prepared, using double-face vacuum suction filtration or dipping method, electrode material slurry is made to penetrate into porous flexible paper
Matter base internal is attached to surface simultaneously, is then dried in 25-100 DEG C of vacuum drying oven 5-30 hours, forms papery
Three-dimensional conductive substrate；
Step 2: prepared by the laser engraving of three-dimensional electrode arrays
Using the three-dimensional electrode arrays configuration of computer software design, laser pattern engraving is carried out on papery conductive substrate,
During laser scanning, laser power is 1-30 watts, laser scan rate 100-10000 mm/second, and in paper substrates
Upper dropwise addition deionized water or distilled water are to reduce temperature；Iterative cycles scanning is carried out, until in laser-scanning position papery matrix
Electrode material be carbonized or aoxidize removing, and paper substrates are retained, to obtain three-dimensional electrode arrays configuration；
Step 3: the dual coating of electrolyte and the formation with three-dimensional energy storing structure paper base capacitor
Hydrogel electrolyte is prepared, then applies hydrogel electrolyte in the three-dimensional electrode arrays configuration tow sides prepared,
Promote infiltration of the hydrogel electrolyte in paper substrates, is finally dried 5-30 hour at 25-50 DEG C in air, acquisition
Paper base capacitor with three-dimensional energy storing structure.
2. a kind of paper base capacitor laser engraving preparation method with three-dimensional energy storing structure according to claim 1,
Be characterized in: the three-dimensional electrode arrays configuration includes interdigital electrode configuration and other shaped electrode structures, wherein special-shaped battery
Pole structure includes but is not limited to S type, L-type, A type, H-type electrode structure, and since electrode material is permeated in entire paper substrates
Inside, so that electrode has three-dimensional conductive characteristic.
3. a kind of three-dimensional structure paper base capacitor laser engraving preparation method according to claim 1, it is characterized in that: described
Paper base capacitor with three-dimensional energy storing structure includes the single paper base capacitor with three-dimensional energy storing structure, also includes by multiple
Cascaded structure, parallel-connection structure and the serial-parallel structure that paper base capacitor with three-dimensional energy storing structure is constituted.
4. a kind of paper base capacitor laser engraving preparation method with three-dimensional energy storing structure according to claim 1,
It is characterized in: the composition of the electrode material are as follows: the carbon materials powder and transition metal oxide powder that mass content is 40-95%
The combination electrode material powder that body or conducting polymer materials powder are constituted；Wherein, the carbon materials powder is graphene, carbon
The mixed powder of one or more of nanometer rods, carbon nanotube and activated carbon, transition metal oxide powder are vanadium oxide, oxygen
Change cobalt, manganese oxide, nickel oxide or ferric oxide powder, conducting polymer materials powder is polyaniline, polypyrrole or polythiophene powder.
5. a kind of paper base capacitor laser engraving preparation method with three-dimensional energy storing structure according to claim 1,
It is characterized in: the preparation steps of the electrode material slurry are as follows: disperse combination electrode material powder in solvent, be placed in ice bath
Sonic oscillation 30-90 minutes, then dispersion liquid is placed in and stands 5-24 hours at room temperature, finally extracts uniform and stable supernatant
As electrode material slurry；Wherein, solvent be dimethylformamide, ethyl alcohol, dimethyl sulfoxide, N-Methyl pyrrolidone, go from
The mixed solvent of one or more of sub- water, isopropanol.
6. a kind of paper base capacitor laser engraving preparation method with three-dimensional energy storing structure according to claim 1,
It is characterized in: the composition of the hydrogel electrolyte are as follows: deionized water includes carboxymethyl cellulose, polyvinyl alcohol or polyoxyethylene
The high-molecular organic material of alkene and the inorganic matter comprising phosphoric acid, sulfuric acid, sodium sulphate, potassium hydroxide, lithium sulfate or lithium perchlorate, institute
State deionized water: high-molecular organic material: the mass ratio of inorganic matter is 8-16:1-3:1；By the mixture matched above in 60-
Magnetic agitation is carried out in 100 DEG C of water-baths, until solution becomes clear, obtains hydrogel electrolyte.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111354576A (en) * | 2020-03-03 | 2020-06-30 | 华东理工大学 | Fabric-based flexible supercapacitor and manufacturing method thereof |
| CN111430155A (en) * | 2020-03-03 | 2020-07-17 | 南京邮电大学 | graphene/CoOxPreparation method and application of composite electrode |
| CN111934030A (en) * | 2020-07-25 | 2020-11-13 | 浙江理工大学 | Flexible planar micro energy storage device and preparation method thereof |
| CN114659619A (en) * | 2022-03-22 | 2022-06-24 | 浙江大学 | Full-soft self-driven vibration sensor and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107946091A (en) * | 2017-11-14 | 2018-04-20 | 大连理工大学 | A kind of paper substrate flexible flat ultracapacitor preparation method |
| CN108257791A (en) * | 2018-01-22 | 2018-07-06 | 西南交通大学 | A kind of MXene paper electrodes and preparation method thereof and micro super capacitor and preparation method thereof |
| CN109003840A (en) * | 2018-08-09 | 2018-12-14 | 北京林业大学 | A kind of preparation method of compound paper base flexible electrode material |
-
2019
- 2019-09-05 CN CN201910838104.2A patent/CN110504111A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107946091A (en) * | 2017-11-14 | 2018-04-20 | 大连理工大学 | A kind of paper substrate flexible flat ultracapacitor preparation method |
| CN108257791A (en) * | 2018-01-22 | 2018-07-06 | 西南交通大学 | A kind of MXene paper electrodes and preparation method thereof and micro super capacitor and preparation method thereof |
| CN109003840A (en) * | 2018-08-09 | 2018-12-14 | 北京林业大学 | A kind of preparation method of compound paper base flexible electrode material |
Non-Patent Citations (1)
| Title |
|---|
| 刘冈: ""高性能纸基石墨烯电极超级电容器激光雕刻法制备与性能研究"", 《中国学位论文全文数据库》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111354576A (en) * | 2020-03-03 | 2020-06-30 | 华东理工大学 | Fabric-based flexible supercapacitor and manufacturing method thereof |
| CN111430155A (en) * | 2020-03-03 | 2020-07-17 | 南京邮电大学 | graphene/CoOxPreparation method and application of composite electrode |
| CN111934030A (en) * | 2020-07-25 | 2020-11-13 | 浙江理工大学 | Flexible planar micro energy storage device and preparation method thereof |
| CN111934030B (en) * | 2020-07-25 | 2021-07-16 | 浙江理工大学 | Flexible planar micro energy storage device and preparation method thereof |
| CN114659619A (en) * | 2022-03-22 | 2022-06-24 | 浙江大学 | Full-soft self-driven vibration sensor and preparation method thereof |
| CN114659619B (en) * | 2022-03-22 | 2023-03-17 | 浙江大学 | Full-soft self-driven vibration sensor and preparation method thereof |
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