CN110500824A - A kind of non-azeotropic working medium supercharging mechanical supercooling CO2Transcritical cooling system - Google Patents

A kind of non-azeotropic working medium supercharging mechanical supercooling CO2Transcritical cooling system Download PDF

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Publication number
CN110500824A
CN110500824A CN201910834735.7A CN201910834735A CN110500824A CN 110500824 A CN110500824 A CN 110500824A CN 201910834735 A CN201910834735 A CN 201910834735A CN 110500824 A CN110500824 A CN 110500824A
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China
Prior art keywords
temperature
evaporator
low
outlet
compressor
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CN201910834735.7A
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Chinese (zh)
Inventor
代宝民
孙悦桐
杨茜茹
马牧宇
王璐
何小敏
杨和澄
郭梦迪
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Tianjin University of Commerce
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Tianjin University of Commerce
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Priority to CN201910834735.7A priority Critical patent/CN110500824A/en
Publication of CN110500824A publication Critical patent/CN110500824A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B41/00Fluid-circulation arrangements
    • F25B41/20Disposition of valves, e.g. of on-off valves or flow control valves
    • F25B41/22Disposition of valves, e.g. of on-off valves or flow control valves between evaporator and compressor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B41/00Fluid-circulation arrangements
    • F25B41/30Expansion means; Dispositions thereof
    • F25B41/31Expansion valves
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B43/00Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat
    • F25B43/006Accumulators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/10Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point with several cooling stages

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Power Engineering (AREA)
  • Compression-Type Refrigeration Machines With Reversible Cycles (AREA)

Abstract

The invention discloses a kind of non-azeotropic working medium supercharging mechanicals, and CO is subcooled2Transcritical cooling system.CO of the invention2Trans-critical cycle cooling cycle system includes gas cooler, medium temperature grade cooling evaporator, low-temperature level cooling evaporator, throttle valve, evaporator, compressor;The non-azeotropic working medium supercharging mechanical supercooling circulatory system includes medium temperature grade compressor, condenser, high-temperature level throttle valve, liquid storage device, medium temperature grade throttle valve, by-passing valve, low-temperature level throttle valve, low-temperature level compressor.The present invention assisted SAPMAC method by non-azeotropic working medium supercharging mechanical, heat exchange is set to form more good Temperature Matching, it reduces heat transfer temperature difference, reduce the irreversible loss of heat transfer process, and then reduce the heat transfer irreversible loss of condenser and evaporator, be improved the efficiency of refrigeration cycle.

Description

A kind of non-azeotropic working medium supercharging mechanical supercooling CO2Transcritical cooling system
Technical field
The present invention relates to refrigeration technology fields, and CO is subcooled more particularly to a kind of non-azeotropic working medium supercharging mechanical2Trans-critical cycle Refrigeration system.
Background technique
As global warming, ozone layer such as are destroyed at the getting worse for environmental problems, for air-conditioning and refrigeration industry, most Important research topic is to find new environmentally friendly natural refrigerants, and substitution has destruction to ozone layer and can generate The working medium such as CFCs, HCFCs of greenhouse effects.CO2As refrigerant, due to its is nontoxic, abundance, with plain oil phase Molten, the advantages that refrigerating effect per unit swept volume is big, more and more attention has been paid to.
But due to CO2Lower critical-temperature and higher critical pressure, cause refrigerating efficiency lower, especially work as environment When temperature is higher, CO2Refrigerating capacity sharply decline, and power consumption increase.If to the CO of gas cooler outlet2Fluid carries out Supercooling, with the increase of degree of supercooling, restriction loss is reduced, and circulation cooling capacity increases, and then can promote circulation COP.It is steamed by auxiliary Vapour pressure contraction SAPMAC method, to CO2The CO of Trans-critical cycle refrigeration cycle gas cooler outlet2It carries out cooling method and is known as mechanical mistake It is cold.Mechanical super cooling can not only increase refrigerating capacity, and can reduce the operation high pressure of major cycle, reduce compressor air-discharging pressure Power extends the service life of compressor.
When mechanical super cooling circulation using pure refrigerant as refrigerant when, evaporative phase-change process temperature remains unchanged, but across facing Boundary CO2Fluid cooling procedure is temperature-fall period, and the two heat transfer process temperature mismatches, and causes heat transfer process irreversible loss big. And, evaporating temperature lower application higher for environment temperature, such as freezer, CO2Degree of supercooling is up to 20 DEG C or more.It is mechanical Supercooling refrigeration cycle condensation side exchanges heat with air, evaporation side and CO2Fluid exchanges heat, and the temperature rise of air side does not surpass generally Cross 8 DEG C, and CO2Temperature drop be 20 DEG C or so, and non-azeotropic working medium evaporation and the slip temperature of condensation process are not much different, and such as adopt It is subcooled with conventional non-azeotropic working medium refrigeration cycle single-stage, air side and CO cannot be met simultaneously2The Temperature Matching of fluid side, thus It can cause biggish irreversible loss again.
Therefore, the condensation and evaporation process point for improving with while realizing mechanical super cooling circulation need to be recycled to mechanical super cooling Not with air and CO2Fluid forms good Temperature Matching, and then reduces the whole irreversible loss of circulation to the greatest extent, from And lifting system entirety efficiency.
Summary of the invention
Present invention aims at, overcome above-mentioned the deficiencies in the prior art, and a kind of non-azeotropic working medium pressurization is provided Mechanical super cooling CO2Trans-critical cycle cooling cycle system,
The present invention is by mechanical super cooling cooling cycle system and CO2Trans-critical cycle cooling cycle system forms, wherein mechanical super cooling Cooling cycle system is that both vapor compression is pressurized refrigeration cycle, and refrigerant is low GWP mixed non-azeotropic refrigerant CO2/R1234ze、 CO2/ R1234yf, R41/R1234ze, R41/R1234yf, R32/R1234ze, R32/R1234yf or R32/R600a.
The technical solution used in the present invention is:
A kind of non-azeotropic working medium mechanical-assisted supercooling CO2Trans-critical cycle cooling cycle system, including non-azeotropic mixed working medium machine Cooling cycle system and CO is subcooled in tool2Trans-critical cycle cooling cycle system;
The CO2Trans-critical cycle cooling cycle system includes gas cooler, medium temperature grade cooling evaporator, the cooling steaming of low-temperature level Send out device, throttle valve, evaporator, compressor;The compressor outlet is connected with gas cooler entrance, gas cooler outlet with Medium temperature grade cooling evaporator entrance is connected, and the outlet of medium temperature grade cooling evaporator is connected with low-temperature level cooling evaporator entrance, low temperature The outlet of grade cooling evaporator is connect with expansion valve inlet, and expansion valve outlet is connected with evaporator inlet, evaporator inlet and compression Machine is connected;
The non-azeotropic working medium supercharging mechanical supercooling circulatory system includes medium temperature grade compressor, condenser, high-temperature level throttling Valve, liquid storage device, medium temperature grade throttle valve, by-passing valve, low-temperature level throttle valve, low-temperature level compressor;The medium temperature stage compressor outlet It is connected with condenser inlet, condensator outlet is connected with high-temperature level throttling valve inlet, and high-temperature level throttling valve outlet enters with liquid storage device Mouth is connected, and reservoir outlet is connected with bypass valve inlet, and bypass valve outlet is connected with medium temperature grade suction port of compressor;Liquid storage device is in Warm grade throttling valve inlet is connected, and medium temperature grade throttling valve outlet is connected with medium temperature grade cooling evaporator entrance, the cooling evaporation of medium temperature grade Device outlet is connected with medium temperature grade suction port of compressor;The liquid storage device is connected with low-temperature level throttling valve inlet, and low-temperature level throttle valve goes out Mouth is connected with low-temperature level cooling evaporator entrance, and the outlet of low-temperature level cooling evaporator is connected with low-temperature level suction port of compressor, low temperature Stage compressor outlet is connected with medium temperature grade suction port of compressor.
The medium temperature cooling evaporator, sub-cooled evaporator and condenser are counter-flow heat exchanger.
Non-azeotropic working medium supercharging mechanical is subcooled circularly cooling agent and uses natural refrigerant CO2, CO2The system of Trans-critical cycle refrigeration cycle Cryogen is CO2/R1234ze、CO2/R1234yf、R41/R1234ze、R41/R1234yf、R32/R1234ze、R32/R1234yf Or R32/R600a.
The low-temperature level compressor of non-azeotropic mixed working medium mechanical-assisted supercooling refrigeration system goes out low-temperature level cooling evaporator Mouthful mixed non-azeotropic refrigerant be compressed to medium temperature grade evaporating pressure, with medium temperature cooling evaporator outlet medium temperature and medium pressure gas with And the gas mixing in the gas-liquid separation through by-passing valve, enter medium temperature grade compressor later.Gas is compressed into high temperature and pressure gas Body, enters condenser later, and the liquid of condensator outlet is first that gas-liquid two-phase fluid enters liquid storage through the throttling of medium temperature grade throttle valve In device, realize gas-liquid separation in liquid storage device, liquid pass through in mild low-temperature level throttle valve throttled respectively to medium temperature and low-temperature level Cooling evaporator, and evaporated in the cooling evaporator respectively, CO2Fluid is real followed by medium temperature and low-temperature level evaporator Now to CO2Fluid carries out once cooling and secondary cooling, so that CO2Obtain higher degree of supercooling, the non-azeotrope work after heat absorption evaporation Matter all becomes saturated air, respectively enters low temperature and medium temperature grade compressor is compressed, and completes mechanical super cooling circulation.
CO2The working medium filled in cooling cycle system is CO2, compressor by refrigerant compression at high temperature and high pressure gas, first Exchange heat into gas cooler and air, later followed by medium temperature supercooling evaporator and low temperature supercooling evaporator and with it is non- Azeotropic working medium is carried out continuously to exchange heat twice, after in throttle valve expand decompression, CO2Decompression becomes the biphase gas and liquid flow of low-temp low-pressure Then body flows into evaporator and absorbs heat, sucks suction port of compressor after becoming low temperature low pressure gas, complete circulation.
Compared with prior art, the advantages and positive effects of the present invention are:
(1)CO2The refrigerant of refrigeration system is natural refrigerant CO2。CO2GWP be 1, ODP 0, it is safe and non-toxic it is non-combustible, It is cheap easily to obtain, do not decompose generation pernicious gas, mechanical super cooling cycle fluid CO under the high temperature conditions yet2/R1234ze、CO2/ The GWP of R1234yf, R41/R1234ze, R41/R1234yf, R32/R1234ze, R32/R1234yf or R32/R600a are lower, Refrigerant used in system is environmental-friendly refrigerant.
(2) mechanical super cooling circulation uses mixed non-azeotropic refrigerant, and temperature glide is suitable with the inlet and outlet temperature difference of air, Refrigerant is alternating temperature process in condenser and evaporator phase transition process, wherein condenser side non-azeotropic refrigerant and air shape At good Temperature Matching.Supercritical CO2It is cooled down twice in fluid subcooling process, the temperature drop of each subcooling process is not Height forms good Temperature Matching with non-azeotropic refrigerant low temperature and medium temperature evaporation process, and heat exchange irreversible loss greatly reduces. In conclusion the irreversible damage of heat exchange of the condenser and cooling evaporator recycled by lesser mechanical super cooling, obtains higher CO2The degree of supercooling of gas cooler improves system energy efficiency, increases refrigerating capacity.
(3) by mechanical super cooling system to CO2The CO of system gas cooler outlet2It is subcooled, is lowered into expansion valve Preceding CO2Temperature reduces expansion-loss, and further decreases CO2Run high pressure.
(4) mechanical-assisted crosses SAPMAC method liquid storage device and plays the role of flash tank, reduces evaporator inlet refrigerant enthalpy Value, improves system performance.
(5) opposite CO2 transcritical cooling system, the small in size of mechanical super cooling circulation, wasted work are few, by configuring small refrigeration Being obviously improved for performance can be realized in system, and at low cost, economic advantages are obvious.
Detailed description of the invention
Fig. 1 is that CO is subcooled in non-azeotropic working medium supercharging mechanical of the present invention2The CO of Trans-critical cycle cooling cycle system2Trans-critical cycle refrigeration The Sweet service of circulation;
Fig. 2 is that CO is subcooled in non-azeotropic working medium supercharging mechanical of the present invention2Refrigeration is subcooled in the auxiliary of Trans-critical cycle cooling cycle system The Sweet service of circulation;
Fig. 3 is that CO is subcooled in non-azeotropic working medium supercharging mechanical of the present invention2The schematic diagram of Trans-critical cycle cooling cycle system.
Specific embodiment
The present invention will be further described with reference to the accompanying drawing.
The present invention includes the both vapor compression supercharging mechanical supercooling circulatory system and CO as shown in Figure 12Trans-critical cycle refrigeration cycle system System, heavy line CO2Trans critical cycle (1 ' -2 ' -3 ' -4 ' -5 ' -6 ' -1 '), fine line are that the supercooling of both vapor compression supercharging mechanical follows The low-temperature evaporation process (10-12) and high temperature evaporation process (6-7) of ring.Fig. 2 is non-azeotropic working medium supercharging mechanical of the present invention supercooling CO2The Sweet service of the auxiliary supercooling refrigeration cycle of Trans-critical cycle cooling cycle system, wherein 3 ' -4 ' be CO2Level-one subcooling process, 6 ' -5 ' be CO2Second level subcooling process.
Present system is as shown in Figure 3:
Step 1: compressor 1 sucks the saturation CO of the low-temp low-pressure in 6 exit of evaporator2Gas compresses it into high temperature The gas of high pressure, temperature reduces after being exchanged heat in gas cooler 2 with air, flows separately through medium temperature cooling evaporator later 3 exchange heat with sub-cooled evaporator 4 with mixed non-azeotropic refrigerant, realize CO2Supercooling enters back into the throttling drop of throttle valve 5 Pressure, becomes gas-liquid two-phase state.Become overheated gas after 6 evaporation endothermic of evaporator again and enter compressor, completes CO2Trans-critical cycle Circulation.
Step 2: mechanical super cooling circulation low-temperature level compressor 14 absorbs the low-temp low-pressure in 4 exit of sub-cooled evaporator Refrigerant compresses it into the overheated gas of medium temperature and medium pressure, with the saturated gas of medium temperature cooling evaporator 3 and from liquid storage device 10 Enter medium temperature grade compressor 7 after the gas-liquid two-phase state working medium mixing of bypass, high temperature and high pressure gas is compressed into, into condenser 8 With air heat-exchange.It is that gas-liquid two-phase enters in liquid storage device 10 through the throttling of medium temperature grade throttle valve 9, realizes gas-liquid point in liquid storage device 10 From, liquid flows to evaporator, gas bypass into 7 suction line of high-temperature level compressor, with medium temperature cooling evaporator 3 outlet and Low-temperature level compressor 14, which exports after refrigerant is mixed together, enters medium temperature grade compressor 7.
Step 3: the gas-liquid two-phase fluid of medium temperature and medium pressure passes through medium temperature cooling evaporator 3 and CO2Primary heat exchange is carried out to become The gas-liquid two-phase fluid of superheated vapor, low-temp low-pressure passes through sub-cooled evaporator 4 and CO2It carries out secondary heat exchange and becomes overheat steaming Gas.It completes mechanical-assisted and crosses SAPMAC method.
Although the preferred embodiment of the present invention is described above in conjunction with attached drawing, the invention is not limited to upper The specific embodiment stated, the above mentioned embodiment is only schematical, be not it is restrictive, this field it is common Technical staff under the inspiration of the present invention, without breaking away from the scope protected by the purposes and claims of the present invention, may be used also By make it is many in the form of, within these are all belonged to the scope of protection of the present invention.

Claims (3)

1. CO is subcooled in a kind of non-azeotropic working medium supercharging mechanical2Trans critical cycle refrigeration system, which is characterized in that by non-azeotropic working medium The circulatory system and CO is subcooled in supercharging mechanical2Trans-critical cycle cooling cycle system coupling composition;
The CO2Trans-critical cycle cooling cycle system include gas cooler, medium temperature grade cooling evaporator, low-temperature level cooling evaporator, Throttle valve, evaporator, compressor;The compressor outlet is connected with gas cooler entrance, gas cooler outlet and medium temperature Grade cooling evaporator entrance is connected, and the outlet of medium temperature grade cooling evaporator is connected with low-temperature level cooling evaporator entrance, and low-temperature level is cold But evaporator outlet is connect with expansion valve inlet, and expansion valve outlet is connected with evaporator inlet, evaporator inlet and compressor phase Even;
The non-azeotropic working medium supercharging mechanical supercooling circulatory system includes medium temperature grade compressor, condenser, high-temperature level throttle valve, storage Liquid device, medium temperature grade throttle valve, by-passing valve, low-temperature level throttle valve, low-temperature level compressor;The medium temperature stage compressor outlet and condensation Device entrance is connected, and condensator outlet is connected with high-temperature level throttling valve inlet, and high-temperature level throttling valve outlet is connected with liquid storage device entrance, Reservoir outlet is connected with bypass valve inlet, and bypass valve outlet is connected with medium temperature grade suction port of compressor;Liquid storage device and medium temperature grade section It flows valve inlet to be connected, medium temperature grade throttling valve outlet is connected with medium temperature grade cooling evaporator entrance, the outlet of medium temperature grade cooling evaporator It is connected with medium temperature grade suction port of compressor;The liquid storage device and low-temperature level throttling valve inlet are connected, low-temperature level throttling valve outlet with it is low Warm grade cooling evaporator entrance is connected, and the outlet of low-temperature level cooling evaporator is connected with low-temperature level suction port of compressor, low-temperature level compression Machine outlet is connected with medium temperature grade suction port of compressor.
2. CO is subcooled in non-azeotropic working medium supercharging mechanical according to claim 12Trans critical cycle refrigeration system, feature exist In the medium temperature cooling evaporator, sub-cooled evaporator and condenser are counter-flow heat exchanger.
3. CO is subcooled in non-azeotropic working medium supercharging mechanical according to claim 12Trans critical cycle refrigeration system, feature exist In non-azeotropic working medium supercharging mechanical is subcooled circularly cooling agent and uses natural refrigerant CO2, CO2The refrigerant of Trans-critical cycle refrigeration cycle is CO2/R1234ze、CO2/ R1234yf, R41/R1234ze, R41/R1234yf, R32/R1234ze, R32/R1234yf or R32/ R600a。
CN201910834735.7A 2019-09-05 2019-09-05 A kind of non-azeotropic working medium supercharging mechanical supercooling CO2Transcritical cooling system Pending CN110500824A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113776214A (en) * 2021-09-18 2021-12-10 青岛科技大学 Cascade refrigeration cycle system coupled with ejector and supercooling method
CN113776215A (en) * 2021-09-18 2021-12-10 青岛科技大学 Circulating system applied to cascade refrigeration or heat pump system and supercooling method
CN113956850A (en) * 2021-10-18 2022-01-21 珠海格力电器股份有限公司 Environment-friendly mixed refrigerant, preparation method thereof and refrigeration system

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WO2008019689A2 (en) * 2006-08-18 2008-02-21 Knudsen Køling A/S A transcritical refrigeration system with a booster
CN101476793A (en) * 2009-01-22 2009-07-08 合肥工业大学 Ultra-high temperature air conditioner cooling cycle system
CN106828032A (en) * 2017-01-24 2017-06-13 天津商业大学 A kind of carbon dioxide automobile air conditioner system of both vapor compression auxiliary supercooling
US20190153283A1 (en) * 2017-11-17 2019-05-23 Honeywell International Inc. Heat transfer compositions, methods and systems
CN210861778U (en) * 2019-09-05 2020-06-26 天津商业大学 Super-cooled CO of non-azeotropic working medium supercharging machinery2Transcritical circulation refrigerating system

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Publication number Priority date Publication date Assignee Title
JP2000161805A (en) * 1998-11-27 2000-06-16 Daikin Ind Ltd Refrigerating apparatus
WO2008019689A2 (en) * 2006-08-18 2008-02-21 Knudsen Køling A/S A transcritical refrigeration system with a booster
CN101476793A (en) * 2009-01-22 2009-07-08 合肥工业大学 Ultra-high temperature air conditioner cooling cycle system
CN106828032A (en) * 2017-01-24 2017-06-13 天津商业大学 A kind of carbon dioxide automobile air conditioner system of both vapor compression auxiliary supercooling
US20190153283A1 (en) * 2017-11-17 2019-05-23 Honeywell International Inc. Heat transfer compositions, methods and systems
CN210861778U (en) * 2019-09-05 2020-06-26 天津商业大学 Super-cooled CO of non-azeotropic working medium supercharging machinery2Transcritical circulation refrigerating system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113776214A (en) * 2021-09-18 2021-12-10 青岛科技大学 Cascade refrigeration cycle system coupled with ejector and supercooling method
CN113776215A (en) * 2021-09-18 2021-12-10 青岛科技大学 Circulating system applied to cascade refrigeration or heat pump system and supercooling method
CN113956850A (en) * 2021-10-18 2022-01-21 珠海格力电器股份有限公司 Environment-friendly mixed refrigerant, preparation method thereof and refrigeration system

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Application publication date: 20191126