CN110499046A - A kind of abrasion resistant anticorrosive paint and application - Google Patents

A kind of abrasion resistant anticorrosive paint and application Download PDF

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Publication number
CN110499046A
CN110499046A CN201910748397.5A CN201910748397A CN110499046A CN 110499046 A CN110499046 A CN 110499046A CN 201910748397 A CN201910748397 A CN 201910748397A CN 110499046 A CN110499046 A CN 110499046A
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CN
China
Prior art keywords
component
parts
abrasion resistant
anticorrosive paint
resistant anticorrosive
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910748397.5A
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Chinese (zh)
Inventor
汪培庆
黄承暄
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Sichuan Xuanyang New Material Technology Co Ltd
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Sichuan Xuanyang New Material Technology Co Ltd
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Priority to CN201910748397.5A priority Critical patent/CN110499046A/en
Publication of CN110499046A publication Critical patent/CN110499046A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/103Anti-corrosive paints containing metal dust containing Al
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/106Anti-corrosive paints containing metal dust containing Zn
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

Abstract

The present invention provides a kind of abrasion resistant anticorrosive paint, specifically the wear-and corrosion-resistant coating of refractory ceramics and metal mixed, the two kinds of components of A, B for being 1~3:1 including mixing ratio;Wherein, component A includes modified ZrO colloidal sol, Al (OH)3The hydrosol, oxide, carbonaceous material are sanded in 1500rpm~3500rpm 30~200min of high speed dispersion to 2~45 μm of fineness;B component includes aluminium powder, zinc powder, titanium valve, alloyed powder, dispersing agent, anti-settling agent, isopropanol;In 1500rpm~3500rpm 30~200min of high speed dispersion, it is sanded to 2~45 μm of fineness.Coating provided by the invention makes it be provided simultaneously with performance wear-resisting, corrosion-resistant, resistant to high temperature by refractory ceramics and metal mixed, can be used for steel and iron parts, the anti-corrosion of ironcasting of various needs under high temperature environment, under rotating ring border.

Description

A kind of abrasion resistant anticorrosive paint and application
Technical field
The present invention relates to anti-corrosion material, specifically a kind of abrasion resistant anticorrosive paint and application.
Background technique
The characteristics of existing inorganic coating includes is that can only have high temperature resistant or corrosion resistance under static environment, such as Aluminium phosphate magnesium coating, phosphoric acid copper coating etc.;It protrudes disadvantage: 1, the up time is short after the mixing of two components;Or it needs to toast Solidification;2, it cannot be used under rotating ring border, wearability is inadequate, and coating hardness is big, and ductility is inadequate.
For this purpose, the present invention comes into being.
Summary of the invention
In view of the foregoing, the present invention intends to provide a kind of abrasion resistant anticorrosive paint, specifically refractory ceramics and metal Mixed wear-and corrosion-resistant coating.The coating based on parts by weight, including following components:
Component A:
Modified ZrO colloidal sol 5%~45%, Al (OH)3The hydrosol 5%~50%, oxide 0%~75%, carbon containing object Matter 0%~80%;In 1500rpm~3500rpm 30~200min of high speed dispersion, it is sanded to 2~45 μm of fineness;
B component:
Aluminium powder 5%~40%, zinc powder 0%~10%, titanium valve 0%~10%, alloyed powder 0%~10%, dispersing agent 0.1%~1%, anti-settling agent 0.1%~1%, isopropanol 10%~70%;1500rpm~3500rpm high speed dispersion 30~ 200min is sanded to 2~45 μm of fineness;
Mixing ratio A:B=1~3:1.
The invention has the benefit that
Coating provided by the invention is by refractory ceramics and metal mixed;It is set to be provided simultaneously with wear-resisting, corrosion-resistant, resistance to height The performance of temperature can be used for steel and iron parts, the anti-corrosion of ironcasting of various needs under high temperature environment, under rotating ring border.
Further, the modified ZrO colloidal sol of component A includes the ZrO colloidal sol that standby Y is modified or Ce is modified.
Further, component A oxide includes one of magnesia, silica, zirconium oxide, aluminium oxide or a variety of.
Further, component A carbonaceous material includes one of silicon carbide, carbon fiber, dispersed graphite alkene etc. or a variety of.
Further, B component dispersing agent be polyacrylic, modified alkyd resin, poly-vinegar resin, derivative of fatty acid, One or more of the product of lecithin lipid and hydramine vinegar class.
Further, B component anti-settling agent includes organobentonite, castor oil derivative, fumed silica, modified hydrogen Change one of the product or a variety of of castor oil, polyamide wax series.
The anticorrosion application that the present invention also provides above-mentioned abrasion resistant anticorrosive paints on metal component, this is wear-resisting anti- Rotten coating coating can be played the role of etch-proof on steel and iron parts, ironcasting.
Specific embodiment
Illustrate embodiments of the present invention below by way of specific specific example, those skilled in the art can be by this explanation Other advantages and efficacy of the present invention can be easily understood for content disclosed by book.The present invention can also pass through in addition different tools Body embodiment is embodied or practiced, and the various details in this specification can also not had based on different viewpoints and application Various modifications or alterations are carried out under spirit of the invention.
Embodiment 1:
Component A:
Modified 26 parts of ZrO colloidal sol, 18 parts, 35 parts of oxide of 3 hydrosol of Al (OH) of Y: 4 parts of magnesia, 1 part of silica, 10 parts of zirconium oxide, 15 parts of aluminium oxide, 15 parts of carbonaceous material: 12 parts of silicon carbide, 1.5 parts of carbon fiber, 1.5 parts of dispersed graphite alkene, 3500rpm high speed dispersion 30min is sanded to fineness to 5 μm;
B component:
25 parts of aluminium powder, 1 part of zinc powder, 1 part of titanium valve, 1 part of alloyed powder, 0.5 part of dispersing agent, 0.5 part of anti-settling agent, isopropanol 20 Part, 3500rpm high speed dispersion 30min is sanded to fineness to 5 μm;
It is uniformly mixed by mixing ratio A:B=1:1.
Embodiment 2:
Component A:
30 parts of ZrO colloidal sol, 10 parts, 50 parts of oxide of 3 hydrosol of Al (OH): 10 parts of magnesia, silica 3 of Ce modification Part, 7 parts of zirconium oxide, 15 parts of aluminium oxide, 50 parts of carbon containing object: 40 parts of silicon carbide, 5 parts of carbon fiber, 5 parts of dispersed graphite alkene, 3000rpm high speed dispersion 50min is sanded to fineness to 8 μm;
B component:
25 parts of aluminium powder, 0.5 part of dispersing agent, 0.5 part of anti-settling agent, 20 parts of isopropanol, 3000rpm high speed dispersion 50min, sand Fineness is milled to 9 μm;
It is uniformly mixed by mixing ratio A:B=1.3:1.
Embodiment 3:
Component A:
35 parts of ZrO colloidal sol, 10 parts, 70 parts of oxide of 3 hydrosol of Al (OH): 20 parts of magnesia, silica 10 of Y modification Part, 10 parts of zirconium oxide, 30 parts of aluminium oxide, 20 parts of carbon containing object: 4 parts of silicon carbide, 5 parts of carbon fiber, 11 parts of dispersed graphite alkene, 2500rpm high speed dispersion 70min is sanded to fineness to 11 μm;
B component:
15 parts of aluminium powder, 2 parts of titanium valve, 1 part of alloyed powder, 0.8 part of dispersing agent, 0.3 part of anti-settling agent, 28 parts of isopropanol, 2500rpm high speed dispersion 70min is sanded to fineness to 10 μm;
It is uniformly mixed by mixing ratio A:B=1.5:1.
Embodiment 4:
Component A:
30 parts of ZrO colloidal sol, 20 parts, 65 parts of oxide of 3 hydrosol of Al (OH): 5 parts of magnesia, silica 2 of Ce modification Part, 28 parts of zirconium oxide, 30 parts of aluminium oxide, 13 parts of carbon containing object: 10 parts of silicon carbide, 2 parts of carbon fiber, 1 part of dispersed graphite alkene, 2000rpm high speed dispersion 90min is sanded to fineness to 13 μm;
B component:
20 parts of aluminium powder, 2 parts of zinc powder, 2 parts of titanium valve, 2 parts of alloyed powder, 0.2 part of dispersing agent, 0.1 part of anti-settling agent, isopropanol 16 Part, 2000rpm high speed dispersion 90min is sanded to fineness to 12 μm;
It is uniformly mixed by mixing ratio A:B=2:1.
Embodiment 5:
Component A:
Modified 16 parts of ZrO colloidal sol, 13 parts, 38 parts of oxide of 3 hydrosol of Al (OH) of Y: 4 parts of magnesia, 1 part of silica, 18 parts of zirconium oxide, 15 parts of aluminium oxide, 21 parts of carbonaceous material: 16 parts of silicon carbide, 1.5 parts of carbon fiber, 3.5 parts of dispersed graphite alkene, 1500rpm high speed dispersion 120min is sanded to fineness to 33 μm;
B component:
33 parts of aluminium powder, 0.8 part of dispersing agent, 0.2 part of anti-settling agent, 26 parts of isopropanol, 1500rpm high speed dispersion 120min, sand Fineness is milled to 35 μm;
It is uniformly mixed by mixing ratio A:B=2.6:1.
Embodiment 6:
Component A:
29 parts of ZrO colloidal sol of Ce modification, 13 parts, 57 parts of oxide: 57 parts of magnesia of 3 hydrosol of Al (OH), carbon containing object 50 Part: it 50 parts of dispersed graphite alkene, 1000rpm high speed dispersion 150min, is sanded to fineness to 38 μm;
B component:
30 parts of aluminium powder, 3 parts of alloyed powder, 1 part of dispersing agent, 0.9 part of anti-settling agent, 26 parts of isopropanol, 1000rpm high speed dispersion 150min is sanded to fineness to 37 μm;
It is uniformly mixed by mixing ratio A:B=3:1.
Application Example:
The abrasion resistant anticorrosive paint of any of the above-described embodiment can be played into corrosion-resisting function on metal component, i.e., should Abrasion resistant anticorrosive paint coating can be played the role of etch-proof on steel and iron parts, ironcasting.
Effect example:
The key technical indexes is as follows:
Serial number Measure the item Performance indicator Measurement standard/method
1 Wearability 0.002mg/1kg,500r GB/T1768
2 Adhesive force ≥4Mpa GB/T5210
3 Hardness ≥4H GB/T13452
4 High temperature resistant 1000℃ From survey
Main effect comparison:
It should be noted that structure depicted in this specification, ratio, size etc., only to cooperate specification to be taken off The content shown is not intended to limit the invention enforceable qualifications so that those skilled in the art understands and reads, Therefore not having technical essential meaning, the modification of any structure, the change of proportionate relationship or the adjustment of size are not influencing this Under the effect of invention can be generated and the purpose that can reach, it should all still fall in disclosed technology contents and obtain and can contain In the range of lid.Meanwhile cited such as "upper" in this specification, "lower", "left", "right", the use of " centre " and " one " Language is merely convenient to being illustrated for narration, rather than to limit the scope of the invention, the change of relativeness or tune It is whole, under the content of no substantial changes in technology, when being also considered as the enforceable scope of the present invention.
Those skilled in the art can make a variety of variations to the present invention according to the above description.Thus, it is not violating Under the premise of claim objective of the invention, certain details in embodiment should not constitute limitation of the invention, the present invention It will be using the range that the appended claims define as protection scope.

Claims (7)

1. a kind of abrasion resistant anticorrosive paint, which is characterized in that based on parts by weight, including following components:
Component A:
Modified ZrO colloidal sol 5%~45%, Al (OH)3The hydrosol 5%~50%, oxide 0%~75%, carbonaceous material 0% ~80%;In 1500rpm~3500rpm 30~200min of high speed dispersion, it is sanded to 2~45 μm of fineness;
B component:
Aluminium powder 5%~40%, zinc powder 0%~10%, titanium valve 0%~10%, alloyed powder 0%~10%, dispersing agent 0.1%~ 1%, anti-settling agent 0.1%~1%, isopropanol 10%~70%;In 1500rpm~3500rpm 30~200min of high speed dispersion, sand It is milled to 2~45 μm of fineness;
Mixing ratio A:B=1~3:1.
2. abrasion resistant anticorrosive paint according to claim 1, it is characterised in that: the modified ZrO colloidal sol of component A includes that standby Y changes Property or the modified ZrO colloidal sol of Ce.
3. abrasion resistant anticorrosive paint according to claim 1, it is characterised in that: component A oxide includes magnesia, oxidation One of silicon, zirconium oxide, aluminium oxide are a variety of.
4. abrasion resistant anticorrosive paint according to claim 1, it is characterised in that: component A carbonaceous material includes silicon carbide, carbon fiber One of dimension, dispersed graphite alkene etc. are a variety of.
5. abrasion resistant anticorrosive paint according to claim 1, it is characterised in that: B component dispersing agent is polyacrylic, modification One or more of alkyd resin, poly-vinegar resin, derivative of fatty acid, lecithin lipid and product of hydramine vinegar class.
6. abrasion resistant anticorrosive paint according to claim 1, it is characterised in that: B component anti-settling agent includes organobentonite, castor Sesame oil derivative, fumed silica, modified hydrogenated castor oil, polyamide wax series one of product or a variety of.
7. a kind of metal component anticorrosion application of abrasion resistant anticorrosive paint described in any of the above embodiments.
CN201910748397.5A 2019-08-14 2019-08-14 A kind of abrasion resistant anticorrosive paint and application Pending CN110499046A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111763091A (en) * 2020-06-17 2020-10-13 林国强 High-thermal-shock wear-resistant coating and preparation method thereof

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Publication number Priority date Publication date Assignee Title
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Publication number Priority date Publication date Assignee Title
US20050051057A1 (en) * 2003-09-09 2005-03-10 Evans Timothy O. Thermal protective coating for ceramic surfaces
KR101201756B1 (en) * 2011-08-18 2012-11-15 김춘식 Water-soluble inoganic hard coating composition for protecting of metal surface
KR101860896B1 (en) * 2017-04-14 2018-07-02 웰머 주식회사 Ceramic coating layer and forming method thereof
CN108793929A (en) * 2018-06-20 2018-11-13 深圳陶金材料科技有限公司 A kind of ceramal coating and coating
CN109021633A (en) * 2018-06-21 2018-12-18 深圳陶金材料科技有限公司 A kind of graphene-based high-temperature coatings and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111763091A (en) * 2020-06-17 2020-10-13 林国强 High-thermal-shock wear-resistant coating and preparation method thereof

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Application publication date: 20191126

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