CN110492037A - A kind of startup power supply - Google Patents

A kind of startup power supply Download PDF

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Publication number
CN110492037A
CN110492037A CN201910777729.2A CN201910777729A CN110492037A CN 110492037 A CN110492037 A CN 110492037A CN 201910777729 A CN201910777729 A CN 201910777729A CN 110492037 A CN110492037 A CN 110492037A
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CN
China
Prior art keywords
battery pack
power supply
battery
startup power
cabinet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910777729.2A
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Chinese (zh)
Inventor
陈世廪
王夺
徐圣楠
李红兵
于洪海
王新华
赵丽丽
陈世鏊
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Jilin Polytron Technologies Inc
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Jilin Polytron Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jilin Polytron Technologies Inc filed Critical Jilin Polytron Technologies Inc
Priority to CN201910777729.2A priority Critical patent/CN110492037A/en
Publication of CN110492037A publication Critical patent/CN110492037A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/24Alkaline accumulators
    • H01M10/30Nickel accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The invention discloses a kind of startup power supply, which includes cabinet, and partition is equipped among the cabinet, cabinet is divided into two cavitys, the first battery pack and the second battery pack of series connection are respectively equipped in two cavitys;It in first battery pack and the second battery is composed in series by several monomer nickel-metal hydride batteries;The negative electrode material of the monomer nickel-metal hydride battery are as follows: La0.8Ce0.2Ni(5‑x)Cu0.1Co0.3Al0.1Mg(x-0.5),Wherein 0.5≤X≤0.8.The startup power supply low temperature performance well, it is -45 DEG C -60 DEG C of use temperature range, stable and reliable for performance.

Description

A kind of startup power supply
Technical field
The invention belongs to power technique fields, and in particular to a kind of startup power supply.
Background technique
The various equipment vehicle such as ordnance, plate armour still uses lead-acid battery as startup power supply at present, and lead-acid battery removes Outside with pollution weight, the drawback that volume is big, cycle life is short, self-discharge rate is high, also there is very poor cryogenic property, in temperature (- 15 DEG C or less) working efficiency is extremely low under the operating condition of inclement condition, and the equipment vehicle number of starts is caused to die-off or can not normally open It is dynamic.
Summary of the invention
The purpose of the present invention is to solve existing power supplys the poor performance at low temperatures the problem of, and provides a kind of starting electricity Source.
The present invention provides a kind of startup power supply, including cabinet, is equipped with partition among the cabinet, cabinet is divided into two A cavity is respectively equipped with the first battery pack and the second battery pack of series connection in two cavitys;
It in first battery pack and the second battery is composed in series by several monomer nickel-metal hydride batteries;
The negative electrode material of the monomer nickel-metal hydride battery are as follows: La0.8Ce0.2Ni(5-x)Cu0.1Co0.3Al0.1Mg(x-0.5), wherein 0.5≤X≤0.8。
Preferably, the preparation method of the negative electrode material includes:
Step 1: the reguline metal La, Ce, Ni, Cu, Co, Al, Mg is weighed according to material composition expression formula;
Step 2: reguline metal material described in step 1 is placed in induction melting from top to bottom in the following order In furnace, putting sequence is Mg, La, Ce, Al, Cu, Ni, Co, and vacuum degree adjustable range is 1 × 10-3Pa to 1.5 × 10-3Pa;
Step 3: output voltage of intermediate frequency is 360V, smelting time 25min-40min, and after melting, molten iron is cooling Afterwards, negative electrode material is obtained.
Preferably, the body side is equipped with positive terminal and negative terminal, and positive terminal and cathode connect Terminal is connect with the anode and cathode of the first battery pack and the second battery pack respectively.
Preferably, first battery pack and the second battery pack respectively include 11 monomer nickel-metal hydride batteries.
Preferably, each monomer nickel-metal hydride battery upper end is respectively equipped with a positive terminal and a negative terminal.
Preferably, in first battery pack and the second battery pack, two neighboring monomer anode of nickel-metal hydride battery and negative It is extremely oppositely positioned, it is connected between ipsilateral pole by cell connector.
Preferably, first battery pack and the second battery pack are connected in series using cell connector.
Preferably, the cell connector copper bar.
Preferably, pass through the first battery mounting and the second battery respectively in first battery pack and the second battery Fixed frame is fixed in cabinet.
Preferably, the cabinet side is equipped with remaining capacity display screen, and remaining capacity display screen is connect with circuit board, Integrated charge monitoring module, electric discharge monitoring module, electric power detection module, temperature detecting module and electric current electricity on the circuit board Press monitoring module.
Beneficial effects of the present invention
The present invention provides a kind of startup power supply, which includes cabinet, and partition is equipped among the cabinet, by cabinet point Two cavitys are divided into, the first battery pack and the second battery pack of series connection are respectively equipped in two cavitys;First electricity It is to be composed in series by several monomer nickel-metal hydride batteries in pond group and the second battery;The negative electrode material of the monomer nickel-metal hydride battery Are as follows: La0.8Ce0.2Ni(5-x)Cu0.1Co0.3Al0.1Mg(x-0.5), wherein 0.5≤X≤0.8.Due to the good performance of the negative electrode material, Startup power supply of the invention is set to run well under -45 DEG C of -60 DEG C of operating conditions, startup power supply structure of the invention is simple, internal junction Structure is secured, and shock resistance vibration resistance is strong, small in size, light-weight, easy to carry.
Detailed description of the invention
Fig. 1 is the appearance diagram of startup power supply of the present invention.
Fig. 2 is the schematic diagram of internal structure of startup power supply of the present invention.
Fig. 3 is that battery of the invention carries out charging and discharging curve figure under -40 DEG C of environment;
Fig. 4 is that battery of the invention carries out charging and discharging curve figure under -40 DEG C of environment.
In figure, 1, remaining capacity display screen, 2, positive terminal, 3, negative terminal, 4, cabinet, 5, handle, 6, monomer Nickel-metal hydride battery, the 7, first battery pack holder, 8, partition, the 9, second battery pack holder, 10, cabinet heelpiece, the 11, first battery Group, the 12, second battery pack, 13, positive terminal mark, 14, negative terminal mark, 15 heat release holes.
Specific embodiment
The invention will be further described below in conjunction with the accompanying drawings.
Referring to Figures 1 and 2, a kind of startup power supply, including cabinet 4 are equipped with partition 8 among the cabinet 4, by cabinet point Two cavitys are divided into, the first battery pack 11 and the second battery pack 12 of series connection are respectively equipped in two cavitys;
Heretofore described first battery pack 11 and the second battery pack 12 are connected by several monomer nickel-metal hydride batteries 6 respectively It forms, preferably 11;6 upper end of monomer nickel-metal hydride battery is respectively equipped with a positive terminal and a negative terminal, the nickel-metal hydride battery Have the advantages that environmental protection, cryogenic property are good.
The negative electrode material of monomer nickel-metal hydride battery of the present invention are as follows: La0.8Ce0.2Ni(5-x) Cu0.1Co0.3Al0.1Mg(x-0.5), wherein 0.5≤X≤0.8.
According to the present invention, the preparation method of the negative electrode material includes:
Step 1: the reguline metal La, Ce, Ni, Cu, Co, Al, Mg is weighed according to material composition expression formula;
Step 2: reguline metal material described in step 1 is placed in induction melting from top to bottom in the following order In furnace, putting sequence is Mg, La, Ce, Al, Cu, Ni, Co, and vacuum degree adjustable range is 1 × 10-3Pa to 1.5 × 10-3Pa;
Step 3: output voltage of intermediate frequency is 360V, smelting time 25min-40min, and after melting, molten iron is cooling Afterwards, negative electrode material is obtained.
Body side of the invention is equipped with positive terminal 2 and negative terminal 3;
Two neighboring monomer anode of nickel-metal hydride battery and cathode in the present invention is oppositely positioned, passes through battery between ipsilateral pole Connection strap is (not shown) to be connected, and is provided with and the consistent connection of pole diameter on monomer nickel-metal hydride battery on the cell connector Hole, the connection strap are covered on the ipsilateral pole of neighboring unit cell by 2 connecting holes, and are tightened using nut.
It is connected between the first battery pack 11 and the second battery pack 12 in the present invention using cell connector, the first electricity The anode of pond group 11 is connect with the positive terminal 2 on cabinet, and the negative terminal 3 on the cathode and cabinet of the second battery pack connects It connects.
It further include the first battery mounting 7 and the second battery mounting 9 in cabinet 4 of the present invention, first battery is solid Determine frame 7 and the second battery mounting 9 be respectively placed in the first battery pack 11 and the second battery 12 surrounding, will using hex bolts Nickel-metal hydride battery group is fixed in battery frame, and internal structure can be made secured, enhances shock resistance vibration resistance.
Cabinet of the present invention includes cabinet shell and case lid (not shown), is all made of iron plate and is made, the cabinet shell, case It can adopt and be screwed between lid, be easily installed and dismantle.
Positive terminal 2 of the present invention, negative terminal 3 expose to cabinet shell, and the positive terminal 2, cathode connect 3 one end of terminal stretches out in outside cabinet shell, and the other end stretches out in inside cabinet shell to connect with the positive and negative anodes of battery pack.
Be respectively equipped on heretofore described cabinet shell with positive and negative terminal corresponding section positive terminal mark 13 and Negative terminal mark 14, the positive terminal mark 13 and negative terminal mark 14 are made of organic glass, in this way may be used Occurred with the situation for effectively avoiding positive terminal 2, negative terminal 3 reversed, protection is played to startup power supply to a certain extent and is made With.
Cell connector of the present invention is copper bar;First and second battery mountings are made of No. 45 steel.
Cabinet side of the present invention is equipped with remaining capacity display screen 1, and remaining capacity display screen 1 is connect with circuit board, Integrated charge monitoring module, electric discharge monitoring module, electric power detection module, temperature detecting module and electric current electricity on the circuit board Monitoring module is pressed, the charging monitoring module, electric discharge monitoring module are respectively used to the charging and discharging situation of monitoring battery pack, Electric power detection module is used to show that the electricity residue situation of battery pack, temperature detecting module to be used to monitor in the use of the battery pack Real time temperature, Current Voltage monitoring module is used to monitor the Current Voltage situation of battery pack, can by remaining capacity display screen 1 So that startup power supply has the function of intuitively to show remaining capacity, charge reminder and abnormal alarm.
Further detailed description is done to the present invention combined with specific embodiments below.
1 negative electrode material La of embodiment0.8Ce0.2Ni(4.4)Cu0.1Co0.3Al0.1Mg(0.1)Preparation
Step 1: the reguline metal La, Ce, Ni, Cu, Co, Al, Mg is weighed according to material composition expression formula;
Step 2: reguline metal material described in step 1 is placed in induction melting from top to bottom in the following order In furnace, putting sequence is Mg, La, Ce, Al, Cu, Ni, Co, and vacuum degree adjustable range is 1 × 10-3Pa;
Step 3: output voltage of intermediate frequency is 360V, smelting time 30min, after melting, after molten iron is cooling, is obtained Negative electrode material.
By cylindrical battery traditional handicraft, using the material of embodiment 1 as negative electrode material, just extremely hickelous nydroxide, electrolysis Liquid is 7.5mol/L potassium hydroxide aqueous solution, and battery membranes are polyethylene nonwoven sulfonated membranes;D type 8Ah battery is produced, at -40 DEG C Charge-discharge test is carried out under environment, test condition such as table 1 and 2 is as follows, as a result as shown in Figure 3 and Figure 4,
Table 1
Process Electric current (A) Time (h) Voltage (V)
0.2C charging 1.6 6
0.2C electric discharge 1.6 1
0.2C charging 1.6 6
0.5C electric discharge 4 1
0.2C charging 1.6 6
1C electric discharge 8 1
Table 2
Process Electric current (A) Time (h) Voltage (V)
0.2C charging 1.6 6
0.2C electric discharge 1.6 1
0.5C charging 4 2
0.2C electric discharge 1.6 1
1C charging 8 1
0.2C electric discharge 1.6 1
Fig. 3 and 4 is respectively that battery of the invention carries out charging and discharging curve figure under -40 DEG C of environment, illustrates the battery low It is with good performance under temperature, it is relatively high with large current charge efficiency and discharging efficiency.
The above-mentioned battery applications being prepared are carried out in startup power supply of the invention with existing startup power supply performance Comparison, the results are shown in Table 3:
Table 3
In conclusion under voltage conditions, small in size, the applicable work temperature of the startup power supply of startup power supply of the invention Degree is at -45 DEG C -60 DEG C, and cannot having started at -15 DEG C or less for existing startup power supply, equally also can not at 40 DEG C or more It can work normally.Startup power supply of the present invention also has the charging time short, the simple advantage of daily maintenance.Shown by above data Invention startup power supply is substantially better than the startup power supply of the prior art, is able to solve what army's equipment cart under bad working environments was encountered Power supply problem is of great significance to hoisting device fight capability and equipment Safeguard ability.

Claims (10)

1. a kind of startup power supply, which is characterized in that including cabinet, partition is equipped among the cabinet, cabinet is divided into two A cavity is respectively equipped with the first battery pack and the second battery pack of series connection in two cavitys;
It in first battery pack and the second battery is composed in series by several monomer nickel-metal hydride batteries;
The negative electrode material of the monomer nickel-metal hydride battery are as follows: La0.8Ce0.2Ni(5-x)Cu0.1Co0.3Al0.1Mg(x-0.5), wherein 0.5≤ X≤0.8。
2. a kind of startup power supply according to claim 1, which is characterized in that the preparation method packet of the negative electrode material It includes:
Step 1: the reguline metal La, Ce, Ni, Cu, Co, Al, Mg is weighed according to material composition expression formula;
Step 2: reguline metal material described in step 1 is placed in induction melting furnace from top to bottom in the following order In, putting sequence is Mg, La, Ce, Al, Cu, Ni, Co, and vacuum degree adjustable range is 1 × 10-3Pa to 1.5 × 10-3Pa;
Step 3: output voltage of intermediate frequency is 360V, smelting time 25min-40min, after melting, after molten iron is cooling, is obtained To negative electrode material.
3. a kind of startup power supply according to claim 1, which is characterized in that the body side is equipped with positive terminal And negative terminal, the anode and cathode of positive terminal and negative terminal respectively with the first battery pack and the second battery pack connect It connects.
4. a kind of startup power supply according to claim 1, which is characterized in that first battery pack and the second battery pack Respectively include 11 monomer nickel-metal hydride batteries.
5. a kind of startup power supply according to claim 1, which is characterized in that each monomer nickel-metal hydride battery upper end point It She You not a positive terminal and a negative terminal.
6. a kind of startup power supply according to claim 1, which is characterized in that first battery pack and the second battery pack In, two neighboring monomer anode of nickel-metal hydride battery and cathode are oppositely positioned, are connected between ipsilateral pole by cell connector.
7. a kind of startup power supply according to claim 1, which is characterized in that first battery pack and the second battery pack It is connected in series using cell connector.
8. a kind of startup power supply according to claim 7, which is characterized in that the cell connector copper bar.
9. a kind of startup power supply according to claim 1, which is characterized in that in first battery pack and the second battery It is fixed in cabinet by the first battery mounting and the second battery mounting respectively.
10. a kind of startup power supply according to claim 1, which is characterized in that the cabinet side is equipped with remaining capacity Display screen, remaining capacity display screen are connect with circuit board, integrated charge monitoring module, electric discharge monitoring mould on the circuit board Block, electric power detection module, temperature detecting module and Current Voltage monitoring module.
CN201910777729.2A 2019-08-22 2019-08-22 A kind of startup power supply Pending CN110492037A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111864827A (en) * 2020-06-10 2020-10-30 包头昊明稀土新电源科技有限公司 Hybrid power supply starting system and control method thereof
CN112165132A (en) * 2020-09-25 2021-01-01 包头昊明稀土新电源科技有限公司 Independent power supply and operation method thereof
CN114552070A (en) * 2022-02-22 2022-05-27 成都市锐柯机械有限责任公司 Convenient start power of graphite alkene heating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130029221A1 (en) * 2011-07-29 2013-01-31 Saft Electrode for an alkaline accumulator
CN104195372A (en) * 2014-05-23 2014-12-10 四会市达博文实业有限公司 Rare earth-magnesium-nickel system heterogeneous hydrogen storage alloys used for nickel-hydrogen batteries and preparing method thereof
CN206022453U (en) * 2016-08-03 2017-03-15 深圳市沃特玛电池有限公司 Battery modules fixed structure and electric automobile startup power supply

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130029221A1 (en) * 2011-07-29 2013-01-31 Saft Electrode for an alkaline accumulator
CN104195372A (en) * 2014-05-23 2014-12-10 四会市达博文实业有限公司 Rare earth-magnesium-nickel system heterogeneous hydrogen storage alloys used for nickel-hydrogen batteries and preparing method thereof
CN206022453U (en) * 2016-08-03 2017-03-15 深圳市沃特玛电池有限公司 Battery modules fixed structure and electric automobile startup power supply

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111864827A (en) * 2020-06-10 2020-10-30 包头昊明稀土新电源科技有限公司 Hybrid power supply starting system and control method thereof
CN112165132A (en) * 2020-09-25 2021-01-01 包头昊明稀土新电源科技有限公司 Independent power supply and operation method thereof
CN114552070A (en) * 2022-02-22 2022-05-27 成都市锐柯机械有限责任公司 Convenient start power of graphite alkene heating

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Application publication date: 20191122