CN110484109A - A kind of aqueous maleic anhydride alkyd paint and preparation method thereof - Google Patents
A kind of aqueous maleic anhydride alkyd paint and preparation method thereof Download PDFInfo
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- CN110484109A CN110484109A CN201910852467.1A CN201910852467A CN110484109A CN 110484109 A CN110484109 A CN 110484109A CN 201910852467 A CN201910852467 A CN 201910852467A CN 110484109 A CN110484109 A CN 110484109A
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- maleic anhydride
- aqueous
- aqueous maleic
- alkyd resin
- anhydride alkyd
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/46—Polyesters chemically modified by esterification
- C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous maleic anhydride alkyd paints and preparation method thereof, the specific preparation process of the aqueous maleic anhydride alkyd paint are as follows: (1) first using linoleic acid, M-phthalic acid, trimethylolpropane, polyester slice, trimellitic anhydride, maleic anhydride, propylene glycol monomethyl ether as raw material, aqueous maleic anhydride alkyd resin is synthesized using normal pressure melt-polycondensation, wherein the addition of maleic anhydride and polyester slice substantially increases the water resistance and intensity of resin；(2) aqueous maleic anhydride alkyd resin, triethylamine, dispersing agent, deionized water are added in grinding pot, pigments and fillers are added after being uniformly dispersed, after ground machine is ground to fineness qualification after mixing evenly, aqueous drier is added after filtering and is uniformly mixing to obtain aqueous maleic anhydride alkyd paint.Aqueous maleic anhydride alkyd paint preparation method provided by the invention has many advantages, such as that simple process, safety and environmental protection, at low cost, paint film property is excellent, excellent water resistance.
Description
Technical field
The invention belongs to coating preparation technology, in particular to a kind of aqueous maleic anhydride alkyd paint and preparation method thereof.
Background technique
Water alcohol acid coating significantly reduces the row of volatile organic matter (VOC) as a kind of coating taken water as a solvent
It puts, reduces the pollution to environment and the harm of human health, be a kind of important environment-friendly aqueous coating.Water alcohol acid
Resin takes water as a solvent, since the evaporation latent heat of water is big, so that the drying time of paint film extends；The surface tension of water is big, easily produces
The problems such as raw shrinkage cavity；In weak alkaline aqueous solution, the storage stability of Hydrolysis coating easily occurs for ester bond, and it is water-fast to reduce paint film
Dissolubility；Due to the design feature of resin itself, difference of hardness is made it have, water resistance is bad, the characteristics of.
The present invention improves the hardness and water resistance of aqueous alkide resin by the polyester slice of introducing long-chain-segment；And Malaysia
The addition of acid anhydrides can introduce double bond on strand, improve the rate of drying of paint film, simultaneously because maleic anhydride molecule structure
Ester bond can be effectively protected in space steric effect, improve the storage stability of resin.
Summary of the invention
To solve the above problems, the purpose of the present invention is to provide the water of a kind of simple process, energy conservation and environmental protection, function admirable
Property maleic anhydride alkyd paint and preparation method thereof.
A kind of aqueous maleic anhydride alkyd paint, it is characterised in that be made of the raw material of following weight percents:
Aqueous maleic anhydride alkyd resin 30~50
Triethylamine 2~8
Dispersing agent 0.5~2
Defoaming agent 0.2~1
Titanium dioxide 5~10
Carbon black 0.3~1
Blanc fixe 5~20
Powdered whiting 5~35
Deionized water 8~30
Aqueous drier 0.5~3
The above components add up to weight percent to be 100%；
Wherein the aqueous maleic anhydride alkyd resin is made of following materials:
Linoleic acid 18~30
M-phthalic acid 5~10
Trimethylolpropane 7~13
Maleic anhydride 5~8
Trimellitic anhydride 3~7
Polyester slice 10~20
Propylene glycol monomethyl ether 28~35
The above components add up to weight percent to be 100%.
The aqueous maleic anhydride alkyd paint, it is characterised in that be made of the raw material of following weight percents:
Aqueous maleic anhydride alkyd resin 32
Triethylamine 2.5
Dispersing agent 1
Defoaming agent 0.3
Titanium dioxide 7.4
Carbon black 0.8
Blanc fixe 10
Powdered whiting 24
Deionized water 20
Aqueous drier 2；
Wherein the aqueous maleic anhydride alkyd resin is made of following materials:
Linoleic acid 25
M-phthalic acid 6
Trimethylolpropane 12
Maleic anhydride 7
Trimellitic anhydride 4
Polyester slice 12
Propylene glycol monomethyl ether 34.
The preparation method of the aqueous maleic anhydride alkyd paint, it is characterised in that specific step is as follows:
(1) melt-polycondensation prepares aqueous maleic anhydride alkyd resin
Linoleic acid, M-phthalic acid, trimethylolpropane, polyester slice, maleic anhydride are added in the reaction vessel, heating is stirred
It mixes, carries out melt polycondensation；Reaction condition is to carry out one-step polymerization in 240~300 DEG C of heat preservations, is added after being cooled to 150~250 DEG C
Enter trimellitic anhydride to keep carrying out two sections of polymerizations；The water that esterification generates is removed in reaction process；After reaction, it will react
Mixture, which cools, is added propylene glycol monomethyl ether, is uniformly mixed and aqueous maleic anhydride alkyd resin can be obtained；
(2) target product is prepared: aqueous maleic anhydride alkyd paint
The raw materials such as the aqueous maleic anhydride alkyd resin of measuring requirement, triethylamine, dispersing agent, deionized water are mixed, stirring is equal
It is ground after even through grinder, aqueous drier is eventually adding after filtering stirring evenly can be obtained product of the present invention: aqueous Malaysia
Acid anhydrides alkyd paint.
The preparation method of the aqueous maleic anhydride alkyd paint, it is characterised in that specific step is as follows:
(1) melt-polycondensation prepares aqueous maleic anhydride alkyd resin
Linoleic acid, M-phthalic acid, trimethylolpropane, polyester slice, maleic anhydride are being added in the reaction vessel, heating is stirred
It mixes, carries out melt polycondensation；Reaction condition is in 260~270 DEG C of 0.5~1.5h of heat preservation progress one-step polymerizations, it is cooled to 190~
Trimellitic anhydride is added after 200 DEG C keeps 2~3h to carry out two sections of polymerizations；The water that esterification generates is removed in reaction process；Instead
After answering, reaction mixture is cooled to propylene glycol monomethyl ether is added after 80~90 DEG C, being uniformly mixed can be obtained
Aqueous maleic anhydride alkyd resin；
(2) target product is prepared: aqueous maleic anhydride alkyd paint
The raw materials such as the aqueous maleic anhydride alkyd resin of measuring requirement, triethylamine, dispersing agent, deionized water are mixed, stirring
Being eventually adding aqueous drier after grinder is ground to fineness≤50 μm, after filtering after uniformly and stir evenly can be obtained this hair
Bright product: aqueous maleic anhydride alkyd paint.
Beneficial effects of the present invention are as follows:
The present invention improves the hardness and water resistance of aqueous maleic anhydride alkyd resin by the polyester slice of introducing long-chain-segment；And
The addition of maleic anhydride can introduce double bond on strand, improve the rate of drying of paint film, simultaneously because maleic anhydride molecule knot
Ester bond can be effectively protected in the space steric effect of structure, improve the storage stability of aqueous maleic anhydride alkyd resin.
The present invention prepares aqueous maleic anhydride alkyd resin using normal pressure melt-polycondensation, without the dimethylbenzene being more toxic
As solvent or water entrainer, production process is avoided because of dimethylbenzene volatilization bring environmental pollution and to the danger of operator
Evil, while solvent removal technique is also eliminated, simplify aqueous maleic anhydride alkyd resin synthesis technology.The present invention use two
Section polymerization technique synthesizes aqueous maleic anhydride alkyd, solves the low water resistance difference stability of water alcohol acid coating hardness of paint film
The defects of bad, the drying time of paint film is improved, so that construction efficiency be made to be improved.Therefore aqueous horse provided by the invention
Carrying out acid anhydrides alkyd paint preparation method has many advantages, such as that simple process, at low cost, paint film property is excellent.
Specific embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
Aqueous maleic anhydride alkyd paint preparation:
(1) preparation of aqueous maleic anhydride alkyd resin, is made of the raw material of following weight percents:
25% linoleic acid, 6% M-phthalic acid, 12% trihydroxy methyl is added in the three-necked flask equipped with water segregator, spherical condensation tube
Propane, 12% polyester slice, 7% maleic anhydride are placed in heating stirring in electric jacket, carry out melt polycondensation；Reaction condition be
260~270 DEG C of 0.5~1.5h of heat preservation carry out one-step polymerizations, be added after being cooled to 190~200 DEG C 4% trimellitic anhydride keep 2~
3h carries out two sections of polymerizations.The water that esterification generates is removed with water segregator in reaction process.After reaction, by reaction mixture
It cools to 34% propylene glycol monomethyl ether is added after 80~90 DEG C, is uniformly mixed and aqueous maleic anhydride alkyd tree can be obtained
Rouge.
(2) preparation of aqueous maleic anhydride alkyd paint
Aqueous maleic anhydride alkyd resin 32%, triethylamine 2.5%, SN-5040 dispersing agent 1%, 810 defoaming agent 0.3% of Digao, go from
Sub- water 20% is added in grinding pot, it is fully dispersed uniformly after, sequentially add titanium dioxide 7.4%, carbon black 0.8%, blanc fixe 10%,
After ground machine is ground to fineness≤50 μm after mixing evenly, the aqueous drier of WD016 is added in powdered whiting 24% after filtering
2% stirs evenly product of the present invention can be obtained: aqueous maleic anhydride alkyd paint.
Embodiment 2
Aqueous maleic anhydride alkyd paint preparation:
(1) preparation of aqueous maleic anhydride alkyd resin, is made of the raw material of following weight percents:
27% linoleic acid, 6.5% M-phthalic acid, 11.5% 3 hydroxyl is added in the three-necked flask equipped with water segregator, spherical condensation tube
Methylpropane, 11% polyester slice, 6% maleic anhydride are placed in heating stirring in electric jacket, carry out melt polycondensation；Reaction condition is
One-step polymerization is carried out in 260~270 DEG C of 0.5~1.5h of heat preservation, 4% trimellitic anhydride is added after being cooled to 190~200 DEG C and keeps 2
~3h carries out two sections of polymerizations.The water that esterification generates is removed with water segregator in reaction process.After reaction, reaction is mixed
Object cools to 34% propylene glycol monomethyl ether is added after 80~90 DEG C, is uniformly mixed and aqueous maleic anhydride alkyd can be obtained
Resin.
(2) preparation of aqueous maleic anhydride alkyd paint
Aqueous maleic anhydride alkyd resin 30%, triethylamine 2%, SN-5040 dispersing agent 1%, 810 defoaming agent 0.5% of Digao, deionization
Water 18% be added grinding pot in, it is fully dispersed uniformly after, sequentially add titanium dioxide 8, carbon black 0.8%, blanc fixe 15%, heavy
After ground machine is ground to fineness≤50 μm after mixing evenly, the aqueous drier 2.7% of WD016 is added in calcium carbonate 22% after filtering
It stirs evenly and product of the present invention can be obtained: aqueous maleic anhydride alkyd paint.
Embodiment 3
(1) preparation of aqueous maleic anhydride alkyd resin: with embodiment 1.
(2) preparation of aqueous maleic anhydride alkyd paint: with embodiment 2.
Embodiment 3
(1) preparation of aqueous maleic anhydride alkyd resin: with embodiment 2.
(2) preparation of aqueous maleic anhydride alkyd paint: with embodiment 1.
The performance technologies index of coating of the present invention is as follows:
Solid content >=55%
Surface drying 1h
Do solid work 8h
1 grade of adhesive force (scratch)
Hardness (pencil method) 3H
Impact resistance 50cm
Bend test 2mm
Water resistance >=15d is not blistering, does not fall off
Resistance to salt water >=7d
Salt fog resistance >=360h
Freeze-thaw stability (3 circulations) never degenerates
Hot storage stability (50 ± 2 DEG C of 7d) passes through.
Claims (4)
1. a kind of aqueous maleic anhydride alkyd paint, it is characterised in that be made of the raw material of following weight percents:
Aqueous maleic anhydride alkyd resin 30~50
Triethylamine 2~8
Dispersing agent 0.5~2
Defoaming agent 0.2~1
Titanium dioxide 5~10
Carbon black 0.3~1
Blanc fixe 5~20
Powdered whiting 5~35
Deionized water 8~30
Aqueous drier 0.5~3
The above components add up to weight percent to be 100%；
Wherein the aqueous maleic anhydride alkyd resin is made of following materials:
Linoleic acid 18~30
M-phthalic acid 5~10
Trimethylolpropane 7~13
Maleic anhydride 5~8
Trimellitic anhydride 3~7
Polyester slice 10~20
Propylene glycol monomethyl ether 28~35
The above components add up to weight percent to be 100%.
2. aqueous maleic anhydride alkyd paint according to claim 1, it is characterised in that by the original of following weight percents
Material is made:
Aqueous maleic anhydride alkyd resin 32
Triethylamine 2.5
Dispersing agent 1
Defoaming agent 0.3
Titanium dioxide 7.4
Carbon black 0.8
Blanc fixe 10
Powdered whiting 24
Deionized water 20
Aqueous drier 2；
Wherein the aqueous maleic anhydride alkyd resin is made of following materials:
Linoleic acid 25
M-phthalic acid 6
Trimethylolpropane 12
Maleic anhydride 7
Trimellitic anhydride 4
Polyester slice 12
Propylene glycol monomethyl ether 34.
3. the preparation method of aqueous maleic anhydride alkyd paint according to claim 1 or 2, it is characterised in that specific steps
It is as follows:
(1) melt-polycondensation prepares aqueous maleic anhydride alkyd resin
Linoleic acid, M-phthalic acid, trimethylolpropane, polyester slice, maleic anhydride are added in the reaction vessel, heating is stirred
It mixes, carries out melt polycondensation；Reaction condition is to carry out one-step polymerization in 240~300 DEG C of heat preservations, is added after being cooled to 150~250 DEG C
Enter trimellitic anhydride to keep carrying out two sections of polymerizations；The water that esterification generates is removed in reaction process；After reaction, it will react
Mixture, which cools, is added propylene glycol monomethyl ether, is uniformly mixed and aqueous maleic anhydride alkyd resin can be obtained；
(2) target product is prepared: aqueous maleic anhydride alkyd paint
The raw materials such as the aqueous maleic anhydride alkyd resin of measuring requirement, triethylamine, dispersing agent, deionized water are mixed, stirring is equal
It is ground after even through grinder, aqueous drier is eventually adding after filtering stirring evenly can be obtained product of the present invention: aqueous Malaysia
Acid anhydrides alkyd paint.
4. the preparation method of aqueous maleic anhydride alkyd paint according to claim 3, it is characterised in that specific steps are such as
Under:
(1) melt-polycondensation prepares aqueous maleic anhydride alkyd resin
Linoleic acid, M-phthalic acid, trimethylolpropane, polyester slice, maleic anhydride are being added in the reaction vessel, heating is stirred
It mixes, carries out melt polycondensation；Reaction condition is in 260~270 DEG C of 0.5~1.5h of heat preservation progress one-step polymerizations, it is cooled to 190~
Trimellitic anhydride is added after 200 DEG C keeps 2~3h to carry out two sections of polymerizations；The water that esterification generates is removed in reaction process；Instead
After answering, reaction mixture is cooled to propylene glycol monomethyl ether is added after 80~90 DEG C, being uniformly mixed can be obtained
Aqueous maleic anhydride alkyd resin；
(2) target product is prepared: aqueous maleic anhydride alkyd paint
The raw materials such as the aqueous maleic anhydride alkyd resin of measuring requirement, triethylamine, dispersing agent, deionized water are mixed, stirring is equal
It it is eventually adding aqueous drier after even after grinder is ground to fineness≤50 μm, after filtering stirs evenly and the present invention can be obtained
Product: aqueous maleic anhydride alkyd paint.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910852467.1A CN110484109A (en) | 2019-09-09 | 2019-09-09 | A kind of aqueous maleic anhydride alkyd paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910852467.1A CN110484109A (en) | 2019-09-09 | 2019-09-09 | A kind of aqueous maleic anhydride alkyd paint and preparation method thereof |
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| CN201910852467.1A Pending CN110484109A (en) | 2019-09-09 | 2019-09-09 | A kind of aqueous maleic anhydride alkyd paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116082934A (en) * | 2023-02-15 | 2023-05-09 | 山东奔腾漆业股份有限公司 | Environment-friendly multifunctional water-based alkyd paint and preparation method thereof |
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| US4058497A (en) * | 1974-09-10 | 1977-11-15 | Mitsubishi Gas Chemical Company, Inc. | One package system cold-setting coating compositions |
| WO2014087418A1 (en) * | 2012-12-05 | 2014-06-12 | Asian Paints Ltd. | Waterborne acrylic modified alkyd dispersions |
| WO2016062999A1 (en) * | 2014-10-22 | 2016-04-28 | Croda International Plc | Polyesters |
| CN107513340A (en) * | 2017-10-10 | 2017-12-26 | 临汾铁环漆业有限公司 | A kind of self-drying aqueous alkyd paint of high rigidity and preparation method thereof |
| CN107556890A (en) * | 2017-09-06 | 2018-01-09 | 马鞍山采石矶涂料有限公司 | A kind of water alcohol acid coating and preparation method thereof |
| CN108997905A (en) * | 2018-09-17 | 2018-12-14 | 佛山市森昂生物科技有限公司 | A kind of preparation method of aqueous alkide resin |
-
2019
- 2019-09-09 CN CN201910852467.1A patent/CN110484109A/en active Pending
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|---|---|---|---|---|
| US4058497A (en) * | 1974-09-10 | 1977-11-15 | Mitsubishi Gas Chemical Company, Inc. | One package system cold-setting coating compositions |
| WO2014087418A1 (en) * | 2012-12-05 | 2014-06-12 | Asian Paints Ltd. | Waterborne acrylic modified alkyd dispersions |
| WO2016062999A1 (en) * | 2014-10-22 | 2016-04-28 | Croda International Plc | Polyesters |
| CN107556890A (en) * | 2017-09-06 | 2018-01-09 | 马鞍山采石矶涂料有限公司 | A kind of water alcohol acid coating and preparation method thereof |
| CN107513340A (en) * | 2017-10-10 | 2017-12-26 | 临汾铁环漆业有限公司 | A kind of self-drying aqueous alkyd paint of high rigidity and preparation method thereof |
| CN108997905A (en) * | 2018-09-17 | 2018-12-14 | 佛山市森昂生物科技有限公司 | A kind of preparation method of aqueous alkide resin |
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| Title |
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| （加）FEREIDOON SHAHIDI: "《贝雷油脂化学与工艺学（第六版） 第6卷 油脂的工业产品与非食用产品》", 31 December 2016, 中国轻工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116082934A (en) * | 2023-02-15 | 2023-05-09 | 山东奔腾漆业股份有限公司 | Environment-friendly multifunctional water-based alkyd paint and preparation method thereof |
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