CN110483075A - A kind of hot-metal bottle is along castable - Google Patents

A kind of hot-metal bottle is along castable Download PDF

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Publication number
CN110483075A
CN110483075A CN201910764328.3A CN201910764328A CN110483075A CN 110483075 A CN110483075 A CN 110483075A CN 201910764328 A CN201910764328 A CN 201910764328A CN 110483075 A CN110483075 A CN 110483075A
Authority
CN
China
Prior art keywords
silicon carbide
hot
aluminum
metal bottle
brick
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910764328.3A
Other languages
Chinese (zh)
Inventor
徐志华
孙枫
蔡长秀
姚亚双
王志强
秦常杰
周辉
黄彦进
王�忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHAN IRON AND STEEL GROUP REFRACTORIES CO Ltd
Original Assignee
WUHAN IRON AND STEEL GROUP REFRACTORIES CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHAN IRON AND STEEL GROUP REFRACTORIES CO Ltd filed Critical WUHAN IRON AND STEEL GROUP REFRACTORIES CO Ltd
Priority to CN201910764328.3A priority Critical patent/CN110483075A/en
Publication of CN110483075A publication Critical patent/CN110483075A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/02Linings
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/447Phosphates or phosphites, e.g. orthophosphate, hypophosphite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Products (AREA)

Abstract

The present invention relates to metallurgical fire resisting material fields more particularly to a kind of hot-metal bottle along castable.Hot-metal bottle designed by the present invention is to regenerate aluminum-silicon carbide brick 49.9%~80%, alumina cement 19.8~50%, sodium tripolyphosphate 0.1~0.2% along castable, including component and mass percent;The regeneration aluminum-silicon carbide brick when hot-metal bottle overhaul by generating with rear aluminum-silicon carbide brick through live directly broken gained, and the particle size after cracking of the regeneration aluminum-silicon carbide brick is in 8mm or less.For the hot-metal bottle that the present invention obtains along castable under the premise of guaranteeing compressive resistance, price is significantly lower than existing product.

Description

A kind of hot-metal bottle is along castable
Technical field
The present invention relates to metallurgical fire resisting material fields more particularly to a kind of hot-metal bottle along castable.
Background technique
Hot-metal bottle is blast-melted collection, the important equipment of iron making inside transport and steel mill.Water pot edge and permanent layer position Molten iron is not contacted, fixed indentured brick, under the heat radiation and conduction of heat of molten iron, about 700 DEG C of operating temperature are played the role of. Traditional hot-metal bottle is generally high alumina castable along castable, can be divided into non-renewable resistance to material series and regeneration according to raw material type Resistance to material series, the non-renewable series of products of resistance to material add calcium aluminate water by the aluminium silicon systems raw material such as bauxite clinker, mullite, flint clay The refractory materials such as mud, micro mist, additive composition, has the characteristics that intensity is high, but cost of material is excessively high;Resistance to material series is regenerated to produce After product are by obtaining finished product waste material after corundum reworked material, alumina reworked material, the recovered working process of mullite reworked material, then add aluminium The refractory materials such as sour calcium cement, micro mist, additive composition, cost has certain advantage, but its intensity is lower, and regenerates resistance to Material is had bad luck, there is still a need for costs for working process.
Summary of the invention
In order to solve problem above, the object of the present invention is to provide a kind of hot-metal bottle edge casting low in cost, intensity is high Material.
To achieve the above object, the present invention designed by hot-metal bottle be along castable, including component and mass percent, Regenerate aluminum-silicon carbide brick 49.9%~80%, alumina cement 19.8~50%, sodium tripolyphosphate 0.1~0.2%;The regeneration Aluminum-silicon carbide brick when hot-metal bottle overhaul by generating with rear aluminum-silicon carbide brick through live directly broken gained, the secondary aluminium The particle size after cracking of silicon carbide carbon brick is in 8mm or less.
Preferably, the regeneration aluminum-silicon carbide brick includes the regeneration aluminum-silicon carbide brick that granularity is 8~0.5mm With granularity in 0.5mm regeneration aluminum-silicon carbide brick below, the granularity is the regeneration aluminum-silicon carbide brick conduct of 8~0.5mm Refractory aggregate uses, and the granularity is used in 0.5mm regeneration aluminum-silicon carbide brick below as brickwork joint filler.
Hot-metal bottle of the invention generated when hot-metal bottle overhaul is directly utilized along castable with rear aluminum-silicon carbide brick, use Aluminum-silicon carbide brick is there are metamorphic layer and a small amount of residue afterwards, but 700 DEG C of its fusing point >, meets tank along castable requirement, because This is without individually handling metamorphic layer and residue;And after crushing with rear aluminum-silicon carbide brick brick, partial size be 8~ For the oversize of 0.5mm as refractory aggregate, partial size is used as 0.5mm screenings below can be directly used in filling brick at the scene Seam;Alumina cement can be used as fine powder and be filled to the regeneration aluminum-silicon carbide brick of 8~0.5mm, improve intensity.
The present invention has the advantages that
(1) compared with existing hot-metal bottle is along castable, hot-metal bottle is directly utilized along castable in hot-metal bottle of the invention Generated when overhaul with rear aluminum-silicon carbide brick, and without carrying out recycling working process to rear aluminum-silicon carbide brick, make It is crushed, sieved with scene, then directly utilized, saved and transported with rear resistance to material, working process cost.
(2) it is of the invention with rear aluminum-silicon carbide brick after scene is directly broken, oversize work that partial size is 8~0.5mm For refractory aggregate, and partial size is to contain a small amount of carbon and silicon carbide in the oversize of 8~0.5mm, and scum can be effectively prevent viscous It is attached, reduce scarfing cinder frequency, improves hot-metal bottle running efficiency.Partial size is used as 0.5mm screenings below can be straight at the scene It connects for filling brickwork joint.
(3) present invention increases the dosage of alumina cement, and alumina cement can be filled uniformly as fine powder to broken partial size To promote the intensity of castable in the regeneration aluminum-silicon carbide brick of 8~0.5mm.
Specific embodiment
For a better understanding of the invention, invention is described in detail below with reference to specific example.
Examples 1 to 7
Hot-metal bottle is shown in Table 1 along the component and its mass percent of castable in Examples 1 to 7:
Table 1
Wherein, regeneration aluminum-silicon carbide brick is to generate when hot-metal bottle overhaul with rear aluminum-silicon carbide brick, through it is live directly Broken, being crushed to partial size is 8mm particle below.The above component is uniformly mixed in blender according to the proportion, adds water and stirs 5 Minute, it can construction usage after discharging.
Examples 1 to 7 and 2 are shown in Table with the performance of existing product:
Table 2
Due to the regeneration aluminum-silicon carbide brick in the present invention be crushed using scene with rear aluminum-silicon carbide brick, Screening gained is transported without having saved to other working process is carried out with rear aluminum-silicon carbide brick with rear resistance to material, working process Cost, therefore the cost of Examples 1 to 7 is significantly lower than traditional hot-metal bottle along castable.
In addition, the present invention increases the dosage of alumina cement, alumina cement can be filled uniformly as fine powder to broken kernel Diameter is to increase the intensity of castable in the regeneration aluminum-silicon carbide brick of 8~0.5mm, and being crushed partial size is 0.5mm secondary aluminium below Silicon carbide carbon brick directly fills brickwork joint for scene, further increases the intensity of castable, therefore, Examples 1 to 7 castable Intensity is above traditional hot-metal bottle along castable.
In conclusion as can be seen from Table 1 and Table 2, the hot-metal bottle that the present invention obtains have along castable it is cheap, The high advantage of intensity.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.

Claims (2)

1. a kind of hot-metal bottle is along castable, which is characterized in that hot-metal bottle includes component and its mass percent along castable are as follows: again Raw aluminum-silicon carbide brick 49.9%~80%, alumina cement 19.8~50%, sodium tripolyphosphate 0.1~0.2%;The secondary aluminium Silicon carbide carbon brick when hot-metal bottle overhaul by generating with rear aluminum-silicon carbide brick through live directly broken gained, the secondary aluminium carbon The particle size after cracking of SiClx carbon brick is in 8mm or less.
2. hot-metal bottle according to claim 1 is along castable, it is characterised in that: the regeneration aluminum-silicon carbide brick includes grain For the regeneration aluminum-silicon carbide brick and granularity that degree is 8~0.5mm in 0.5mm regeneration aluminum-silicon carbide brick below, the granularity is 8 The regeneration aluminum-silicon carbide brick of~0.5mm is used as refractory aggregate, and the granularity is in 0.5mm regeneration aluminum silicon carbide carbon below Brick is used as brickwork joint filler.
CN201910764328.3A 2019-08-19 2019-08-19 A kind of hot-metal bottle is along castable Pending CN110483075A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910764328.3A CN110483075A (en) 2019-08-19 2019-08-19 A kind of hot-metal bottle is along castable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910764328.3A CN110483075A (en) 2019-08-19 2019-08-19 A kind of hot-metal bottle is along castable

Publications (1)

Publication Number Publication Date
CN110483075A true CN110483075A (en) 2019-11-22

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Country Status (1)

Country Link
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112645722A (en) * 2020-12-24 2021-04-13 河北鑫达钢铁集团有限公司 Preparation method of iron-making plant ladle edge castable
CN115925396A (en) * 2022-11-30 2023-04-07 钢城集团凉山瑞海实业有限公司 Slag line repairing material for prolonging service life of magnesia carbon brick

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004083361A (en) * 2002-08-28 2004-03-18 Toshiba Ceramics Co Ltd Regenerated castable refractory
CN101353260A (en) * 2008-08-26 2009-01-28 武汉钢铁(集团)公司 Desulphurization hot-metal bottle edge steel fibre enhanced fire resistant castable refractory
CN102757249A (en) * 2012-08-01 2012-10-31 山国强 Refractory castable for molten iron tank
CN103396134A (en) * 2013-07-30 2013-11-20 中冶武汉冶金建筑研究院有限公司 Iron runner casting material using waste alumino-silicon-carbide carbon bricks as aggregate

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004083361A (en) * 2002-08-28 2004-03-18 Toshiba Ceramics Co Ltd Regenerated castable refractory
CN101353260A (en) * 2008-08-26 2009-01-28 武汉钢铁(集团)公司 Desulphurization hot-metal bottle edge steel fibre enhanced fire resistant castable refractory
CN102757249A (en) * 2012-08-01 2012-10-31 山国强 Refractory castable for molten iron tank
CN103396134A (en) * 2013-07-30 2013-11-20 中冶武汉冶金建筑研究院有限公司 Iron runner casting material using waste alumino-silicon-carbide carbon bricks as aggregate

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
冶金工业出版社《中国冶金百科全书》编辑部编: "《中国冶金百科全书 耐火材料》", 31 October 1997, 冶金工业出版社1997年10月第1版 *
钱之荣等编: "《耐火材料使用手册》", 30 September 1992, 冶金工业出版社1992年9月第一版 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112645722A (en) * 2020-12-24 2021-04-13 河北鑫达钢铁集团有限公司 Preparation method of iron-making plant ladle edge castable
CN115925396A (en) * 2022-11-30 2023-04-07 钢城集团凉山瑞海实业有限公司 Slag line repairing material for prolonging service life of magnesia carbon brick
CN115925396B (en) * 2022-11-30 2023-10-10 钢城集团凉山瑞海实业有限公司 Slag line repairing material for prolonging service life of magnesia carbon brick

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Application publication date: 20191122

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