CN110479143A - A kind of venetian blind type agitating device of the secondary dilution process for macromolecule concentrated solution - Google Patents

A kind of venetian blind type agitating device of the secondary dilution process for macromolecule concentrated solution Download PDF

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Publication number
CN110479143A
CN110479143A CN201910358076.4A CN201910358076A CN110479143A CN 110479143 A CN110479143 A CN 110479143A CN 201910358076 A CN201910358076 A CN 201910358076A CN 110479143 A CN110479143 A CN 110479143A
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CN
China
Prior art keywords
support bar
sawtooth
saw
lower support
scraper plate
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Pending
Application number
CN201910358076.4A
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Chinese (zh)
Inventor
张敏革
李一鑫
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Tianjin University of Science and Technology
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Tianjin University of Science and Technology
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Priority to CN201910358076.4A priority Critical patent/CN110479143A/en
Publication of CN110479143A publication Critical patent/CN110479143A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F21/00Dissolving
    • B01F21/10Dissolving using driven stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05Stirrers
    • B01F27/11Stirrers characterised by the configuration of the stirrers
    • B01F27/17Stirrers with additional elements mounted on the stirrer, for purposes other than mixing
    • B01F27/172Stirrers with additional elements mounted on the stirrer, for purposes other than mixing for cutting, e.g. with knives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05Stirrers
    • B01F27/11Stirrers characterised by the configuration of the stirrers
    • B01F27/19Stirrers with two or more mixing elements mounted in sequence on the same axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05Stirrers
    • B01F27/11Stirrers characterised by the configuration of the stirrers
    • B01F27/19Stirrers with two or more mixing elements mounted in sequence on the same axis
    • B01F27/191Stirrers with two or more mixing elements mounted in sequence on the same axis with similar elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/90Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms 

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)

Abstract

The invention proposes a kind of venetian blind type agitating devices of secondary dilution process for macromolecule concentrated solution, are made of agitating shaft 1, upper support bar 2, lower support bar 3, saw-toothed blade 4, sawtooth scraper plate 5, stirred tank 6, driving mechanism 7, attachment screw 8.Wherein, upper support bar 2 and lower support bar 3 respectively have two, play the role of fixed saw-toothed blade 4.Saw-toothed blade 4 has multi-disc, and saw-toothed blade 4 is equidistantly connected and fixed with upper support bar 2 and lower support bar 3 by attachment screw 8, and sawtooth scraper plate 5 is fixed on the end of upper support bar 2 and lower support bar 3 by attachment screw 8.Agitating device of the invention has more saw-toothed blade features, and blade sharping can be adjusted at any time, and have the characteristics that use scope is wide.When the device rotates in stirred tank 6, the macromolecule large crumb that can quickly wind resolves into small agglomerate, further loosens the long chain macromolecule of small agglomerate, unlocks, spreads, and substantially reduces the incorporation time of macromolecule concentrated solution.Simultaneously as the presence of sawtooth scraper plate 5, can effectively avoid macromolecule agglomerate in the caking phenomenon of 6 wall surface of stirred tank.

Description

A kind of venetian blind type agitating device of the secondary dilution process for macromolecule concentrated solution
Technical field
The present invention relates to the highly viscous fluids hybrid technology such as petrochemical industry, food, pharmacy fields, especially a kind of to be used for high score The agitating device of sub- concentrated solution secondary dilution process.
Background technique
In industries such as petrochemical industry, food and pharmacy, a kind of Dilute Polymer Solutions are needed to configure.Usual way is by high score Son first configures a kind of concentrated solution or semidilute, so that small solvent molecule first permeated, be diffused between macromolecular, slackens macromolecular Between interaction force, complete high molecular swelling process;Then secondary dilution is carried out again and obtains Dilute Polymer Solutions, completes high score The course of dissolution of son, in this process, the movement of segment and the whole chain of molecule accelerates after swelling, strand loosening, disentanglement, high It is uniform that molecule and solvent molecule reach directional diffusion.This way can greatly reduce setup time, improve efficiency.
Change procedure of the Polymer Solution solubility from dense to dilute is exactly that molecule Chain System turns from the multichain state being intertwined Become single-stranded process.The essential distinction of weak solution and concentrated solution is in weak solution that a single molecular chain ball of string is isolated existing, Between each other without overlapping, and in dense system, aggregation and winding occur between macromolecular chain.
The essence of whipping process is exactly to pass through the rotation of impeller mechanical energy is passed to liquid, to make liquid in equipment Forced convertion is done in portion, and reaches uniform admixture.What stirring was focused on is the motion mode and severe degree of material in stirred tank, And this moving situation is for the adaptability of given process.There are three kinds of diffusion ways during being stirred: overall right Stream diffusion, eddy diffusivity and molecule diffusion.Convention diffusion is to exclude stream and stream is induced to cause a wide range of macroscopic motion of tank liquid, And fluid flow circuit in entire slot is generated, this mixing is also known as the mixing of large scale.This stage, which needs to rationally design, stirs Device and groove body are mixed, pays attention to eliminating immobilising dead zone.
The present invention develops a kind of agitating device for the macromolecule concentrated solution progress secondary dilution process after swelling.
Summary of the invention
It is an object of the invention to propose a kind of secondary dilution agitating device for macromolecule concentrated solution.This stirring dress Macromolecule large crumb after swelling when rotated, can be decomposed into small agglomerate by the agitating paddle set, so that the strand loosening of winding, Dispersion, reaches rapidly-soluble process.
A kind of agitating device for macromolecule concentrated solution secondary dilution process of the invention is leafy laciniation, right The macromolecule of entanglement has disentanglement and loosening effect.
Technical solution of the present invention is as follows:
A kind of venetian blind type agitating device for macromolecule concentrated solution secondary dilution process, by agitating shaft 1, upper support bar 2, lower support bar 3, saw-toothed blade 4, sawtooth scraper plate 5, stirred tank 6, driving mechanism 7 and connection bolt 8 are constituted.Wherein, upper support Bar 2 and lower support bar 3 respectively have two, play the role of fixed saw-toothed blade 4.
The agitating shaft 1 can be a hollow or solid metal, and specific diameter and wall thickness can be according to needed for stirring materials Torque, intensity is calculated.
The upper support bar 2, lower support bar 3 are equal diameter metallic rod, and specific diameter can be according to specific intensity, rigidity Depending on it is required that.Two upper support bars 2 are mutually 180 ° and are vertically connected on together with agitating shaft 1.Two lower support bars 3 are respectively at two The underface of support rod 2 and the end of agitating shaft 1 connect.
The saw-toothed blade 4 has muti-piece, is guarantee device to molding, the sum of saw-toothed blade 4 is even number.Sawtooth leaf Piece 4 is equally vertically connected between upper support bar 2 and lower support bar 3, and spacing size is generally 1~3 times of sawtooth blade Width;The width direction and support rod of saw-toothed blade 4 are in 45 °~90 °.The thickness on sawtooth blade face is generally 3mm-12mm, height Depending on the distance between upper support bar 2 and lower support bar 3.
The saw-toothed blade 4 told about, sawtooth are spaced about 20 times of saw-toothed blade thickness, the depth and sawtooth spacing of sawtooth It is equal.
The sawtooth scraper plate 5 has two pieces, and sawtooth scraper plate 5 does not open sawtooth up and down, and two sides only have side and open sawtooth.Saw Tooth scraper plate 5 is vertical with the outermost end of upper support bar 2 and lower support bar 3 respectively to be connect, in 5 width direction of sawtooth scraper plate with upper support Bar 2 is parallel with the length direction of lower support bar 3.There are a small gap between sawtooth scraper plate 5 and stirred tank 6, gap width is general It is the 10% of 6 diameter of stirred tank
The stirred tank 6 can be cylinder-shaped flat or ellipsoid, and the ratio of height to diameter of stirred tank 6 is to select according to specific needs It selects, generally 1~5, settable baffle or without baffle on 1 inner wall of stirred tank.
The driving mechanism 7 is made of speed reducer, motor and shaft coupling etc., design parameter determine according to actual needs, Driving mechanism 7 is that agitating shaft 1 provides power.
The component being formed by connecting by agitating shaft 1, saw-toothed blade 4, upper support bar 2, lower support bar 3 and sawtooth scraper plate 5, can claim Ratio of height to diameter for agitating paddle, ratio of height to diameter and stirred tank 1 is not much different, and mechanical energy is passed to solution by agitating paddle, make solution into Row convection circulation, achievees the purpose that mixed solution.
Innovation of the invention is to develop a kind of agitating device with the leafy structure of zigzag, in the device Saw-toothed blade can adjust specifically used angle by connecting bolt 8, which is suitable for the secondary dilute of macromolecule concentrated solution Release process.The possessed leafy structure of zigzag can dissolve initial stage in macromolecule concentrated solution, by the macromolecule agglomerate of swelling point It is segmented into small agglomerate, then small agglomerate is decomposed into more tiny agglomerate, the macromolecule of winding is loosened in the process, is unfolded, finally Reach uniform weak solution in conjunction with the diffusion of high molecular molecule.
The present invention provides a kind of use for the secondary dilution process of this special high viscosity fluid of macromolecule concentrated solution The strategy that range is wide, rate of dispersion is fast, prevented from caking.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this hair Bright some embodiments for those of ordinary skill in the art without any creative labor, can be with It obtains other drawings based on these drawings.
Fig. 1 is the agitating device main view of present application example
Fig. 2 is the stirred tank and agitating paddle top view of present application example
Fig. 3 is the agitating paddle 3-D view of present application example
In Fig. 1-Fig. 3,1. agitating shafts, 2. upper support bars, 3. lower support bars, 4. saw-toothed blades, 5. sawtooth scraper plates, 6. are stirred Mix slot, 7. driving mechanisms, 8. attachment screws.
Specific embodiment
The invention proposes a kind of quick agitator of secondary dilution process for macromolecule concentrated solution, agitating paddles It is welded as a whole by muti-piece zigzag blade and support rod, agitating shaft, which has saw-toothed blade adjustable angle, use scope Wide feature.At work, agitating paddle rotates counterclockwise, and mechanical energy is passed to solution by zigzag blade, makes solution generation pair Stream circulates, and in the process, the macromolecule that is intertwined of large crumb is loosened, is dispersed into small agglomerate, then by small group Block is decomposed into more tiny agglomerate, provides precondition for the diffusion of further rapid molecular.
In order to better understand the above technical scheme, in conjunction with appended figures and specific embodiments to upper Technical solution is stated to be described in detail.
As shown in Figure 1-Figure 3, a kind of quick agitator of the secondary dilution process for macromolecule concentrated solution, including stir Mix axis 1, upper support bar 2, lower support bar 3, saw-toothed blade 4, sawtooth scraper plate 5, stirred tank 6, driving mechanism 7 and attachment screw 8.Its Middle upper support bar 2 and lower support bar 3 have two, can be circular pin or rectangular shaft, specific sectional dimension and diameter make specifically Depending on intensity requirement, diameter is generally 10mm~40mm, and two lower support bars 3 are in horizontal linear shape and 1 end vertical of agitating shaft Weld together, two upper support bars 2 are respectively in the top certain altitude of two lower support bars 3 and 1 vertical welding of agitating shaft.
Wherein, agitating shaft 1 is made of the hollow metallic rod of certain diameter and thickness, and diameter is about 20~80mm, wall thickness one As be 2-5mm, the length of agitating shaft is generally 40~500mm higher than saw-toothed blade 4 depending on particular condition in use.
Wherein, saw-toothed blade 4 has a muti-piece, first by certain thickness metal plate according to required width, be highly cut into item Then shape plate is opened sawtooth in stripe board and is made.The width of saw-toothed blade 4 is generally 20-200mm, and thickness is generally 5- 12mm, the sawtooth spacing and serration depth opened are equal sized, generally 10~50mm.The upper and lower part of saw-toothed blade 4 is not Sawtooth is opened, sawtooth is opened in two sides.Saw-toothed blade 4 by attachment screw 8 equidistantly with upper support bar 2 and lower support bar 3 is vertical connects It is connected together.In orientation, the width direction of saw-toothed blade 4 and the orientation of upper support bar 2 and lower support bar 3 are adjustable, generally It is at 45 °~90 °.
Wherein, sawtooth scraper plate 5 first by certain thickness metal plate according to required width, be highly cut into stripe board, so Sawtooth is opened in the side of stripe board afterwards to be made.The width of sawtooth scraper plate 5 is generally 20-200mm, and thickness is generally 5-12mm, institute The sawtooth spacing and serration depth opened are equal sized, generally 10~50mm.Do not open sawtooth in the upper and lower part of sawtooth scraper plate 5. Sawtooth scraper plate 5 is fixed between upper support bar 2 and lower support bar 3 by attachment screw 8.In orientation, the width of sawtooth scraper plate 5 Direction is parallel with upper support bar 2 and lower support bar 3.Sawtooth scraper plate 5 and the inner wall of stirred tank 6 have the gap, and gap width is general It is the 10% of 1 diameter of stirred tank.
Wherein, stirred tank 6 is round metal drum ladle, and it is also spheroid shape bottom that bottom, which can be flat,.The Gao Jing of stirred tank 6 Than being generally 1~3.6 top of stirred tank can be that opening is also closing mouth, and top, lower part and the side of stirred tank 6 can bases The entrance and exit etc. for needing to add materials.The inner wall of stirred tank 6 can add baffle also without baffle.
Wherein, driving mechanism 7 be made of speed reducer, motor and shaft coupling etc., design parameter determine according to actual needs, Driving mechanism 7 is that agitating shaft 1 provides power.
Wherein, the structure being formed by connecting by agitating shaft 1, saw-toothed blade 4, upper support bar 2, lower support bar 3 and sawtooth scraper plate 5 Part can be described as agitating paddle, and the ratio of height to diameter of ratio of height to diameter and stirred tank 1 is not much different, and mechanical energy is passed to solution by agitating paddle, is made Solution carries out convection circulation, achievees the purpose that mixed solution.
Wherein, when practical application, by driving part 7 drive agitating shaft 1 rotate counterclockwise, revolving speed be generally 30~300 turns/ Point, stirring material is the dilution of xanthan gum concentrated solution in water, and the volume of stirred tank 6 is 500~5000L, due to stirring Device has multiple zigzag blades, and it is at fritter and thinner the macromolecule of xanthan gum can be wound to blob segmentation at stirring initial stage Fritter;Mid-term is stirred, tiny piece of xanthan gum macromolecule agglomerate can be loosened, be unlocked, disperse;The later period is stirred, with high molecular Diffusion ultimately forms uniform Dilute Polymer Solutions, is about 10~120 points the time required to whole.
Wherein, when practical application, by 4 He of saw-toothed blade for driving part drive agitating shaft 1 and being welded on agitating shaft 1 Sawtooth scraper plate 5 rotates, and mechanical energy is passed to solution, and speed of agitator is 20~250 revs/min.Handled material is poly- third The course of dissolution of acrylamide concentrated solution in water.The volume of stirred tank 6 is 300~3000L, since agitating device has multiple saws The macromolecule of polyacrylamide can be wound blob segmentation into fritter and more tiny piece, stirring at stirring initial stage by dentate leaf Tiny piece of polyacrylamide molecule agglomerate can be loosened, unlock, disperse by mid-term, stir the later period, with high molecular diffusion, most End form is about 5~110 points the time required to whole at uniform Dilute Polymer Solutions.
Wherein, when practical application, since there is only a small gap, slit widths between the position and stirred tank 6 of sawtooth scraper plate 5 Degree is generally the 10% of 6 diameter of stirred tank.Therefore, while sawtooth scraper plate 5 rotates, on the one hand by macromolecule winding agglomerate pine On the other hand the macromolecule agglomerate at nearly cell wall, wall surface agglomeration are removed in dynamic, dispersion, dissolution in time.
The above is only the novel preferred embodiment of the present invention, not in any form to the novel work of the present invention Limitation, although the present invention it is novel have been disclosed in a preferred embodiment above, it is novel that however, it is not intended to limit the invention, any ripe Professional and technical personnel is known, is not being departed from new technique aspects of the present invention, when in the technology using the disclosure above Hold the equivalent embodiment made a little change or be modified to equivalent variations, but all without departing from new technique scheme of the present invention Hold, according to the present invention novel technical spirit any simple modification, equivalent change and modification to the above embodiments, still Belong in the range of new technique scheme of the present invention.

Claims (5)

1. a kind of venetian blind type agitating device for macromolecule concentrated solution secondary dilution process, including agitating shaft 1, upper support bar 2, lower support bar 3, saw-toothed blade 4, sawtooth scraper plate 5, stirred tank 6, driving mechanism 7 and attachment screw 8.Wherein 2 He of upper support bar Lower support bar 3 has two, can be rectangular metal bar or circular metal bar, two lower support bars 3 are in horizontal linear shape and stirring 1 end vertical of axis welds together, and two upper support bars 2 are respectively in the top certain altitude of two lower support bars 3 and agitating shaft 1 Vertical welding.
2. a kind of venetian blind type agitating device for macromolecule concentrated solution secondary dilution process according to claim 1, It is characterized in that, agitating shaft 1 is made of the hollow metallic rod of certain diameter and thickness, diameter is about 20~80mm, and wall thickness is general For 2-5mm, the length of agitating shaft is generally 40~500mm higher than saw-toothed blade 4 depending on particular condition in use.
3. a kind of venetian blind type agitating device for macromolecule concentrated solution secondary dilution process according to claim 1, It is characterized in that, saw-toothed blade 4 has muti-piece, first it is in strip by certain thickness metal plate according to required width, height cutting Then plate is opened sawtooth in stripe board and is made.The width of saw-toothed blade 4 is generally 20-200mm, and thickness is generally 5-12mm, institute The sawtooth spacing and serration depth opened are equal sized, generally 10~50mm.Sawtooth is not opened in the upper and lower part of saw-toothed blade 4, Open sawtooth in two sides.Saw-toothed blade 4 is equidistantly vertically connected on one with upper support bar 2 and lower support bar 3 by attachment screw 8 It rises.Orientation is adjustable, in general, the width direction of saw-toothed blade 4 and upper support bar 2 and lower support bar 3 it is at 45 °~90 °.
4. a kind of venetian blind type agitating device for macromolecule concentrated solution secondary dilution process according to claim 1, It is characterized in that, sawtooth scraper plate 5 first by certain thickness metal plate according to required width, be highly cut into stripe board, then Sawtooth is opened in the side of stripe board to be made.The width of sawtooth scraper plate 5 is generally 20-200mm, and thickness is generally 5-12mm, is opened Sawtooth spacing and serration depth it is equal sized, generally 10~50mm.Sawtooth is not opened in the upper and lower part of sawtooth scraper plate 5, leans on Open sawtooth in the side of 6 inner wall of nearly stirred tank.Sawtooth scraper plate 5 is connect by attachment screw 8 with upper support bar 2 and lower support bar 3. In orientation, the width direction of sawtooth scraper plate 5 is parallel with upper support bar 2 and lower support bar 3.Sawtooth scraper plate 5 is interior with stirred tank 6 Wall surface has the gap, and gap width is generally the 10% of 1 diameter of stirred tank.
5. a kind of venetian blind type agitating device for macromolecule concentrated solution secondary dilution process according to claim 1, It is characterized in that, the component being formed by connecting by agitating shaft 1, saw-toothed blade 4, upper support bar 2, lower support bar 3 and sawtooth scraper plate 5, It can be described as agitating paddle, the ratio of height to diameter of ratio of height to diameter and stirred tank 1 is not much different, and mechanical energy is passed to solution by agitating paddle, makes molten Liquid carries out convection circulation, achievees the purpose that mixed solution.
CN201910358076.4A 2019-04-26 2019-04-26 A kind of venetian blind type agitating device of the secondary dilution process for macromolecule concentrated solution Pending CN110479143A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113398788A (en) * 2021-06-22 2021-09-17 刘颖 Gouache pigment processing equipment
CN114682132A (en) * 2022-04-12 2022-07-01 渤瑞环保股份有限公司 Full-automatic high-molecular medicament dissolving and adding all-in-one machine and use method thereof
CN115890869A (en) * 2022-11-14 2023-04-04 安徽省公路桥梁工程有限公司 Light foam soil mixing equipment

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CN105013370A (en) * 2015-07-09 2015-11-04 安徽省光明粮油工业有限公司 Vegetable seed stirring machine capable of performing multidimensional adjustment
CN105413540A (en) * 2015-12-21 2016-03-23 天津焜日科技开发有限公司 Stirring device for sewage treatment
CN207951231U (en) * 2018-02-09 2018-10-12 福建南少林药业有限公司 A kind of pharmaceutical mixing arrangement
CN210584569U (en) * 2019-04-26 2020-05-22 天津科技大学 Shutter type stirring device for secondary dilution process of high-molecular concentrated solution

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Publication number Priority date Publication date Assignee Title
CN102641681A (en) * 2012-04-27 2012-08-22 苏州市金翔钛设备有限公司 Stirring device for leaching tank
CN105013370A (en) * 2015-07-09 2015-11-04 安徽省光明粮油工业有限公司 Vegetable seed stirring machine capable of performing multidimensional adjustment
CN105413540A (en) * 2015-12-21 2016-03-23 天津焜日科技开发有限公司 Stirring device for sewage treatment
CN207951231U (en) * 2018-02-09 2018-10-12 福建南少林药业有限公司 A kind of pharmaceutical mixing arrangement
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113398788A (en) * 2021-06-22 2021-09-17 刘颖 Gouache pigment processing equipment
CN114682132A (en) * 2022-04-12 2022-07-01 渤瑞环保股份有限公司 Full-automatic high-molecular medicament dissolving and adding all-in-one machine and use method thereof
CN114682132B (en) * 2022-04-12 2024-02-09 渤瑞环保股份有限公司 Full-automatic polymer medicament dissolving and adding integrated machine and use method thereof
CN115890869A (en) * 2022-11-14 2023-04-04 安徽省公路桥梁工程有限公司 Light foam soil mixing equipment

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Application publication date: 20191122