CN110467347A - A kind of anti-dazzling glass for vehicle window - Google Patents

A kind of anti-dazzling glass for vehicle window Download PDF

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Publication number
CN110467347A
CN110467347A CN201910792895.XA CN201910792895A CN110467347A CN 110467347 A CN110467347 A CN 110467347A CN 201910792895 A CN201910792895 A CN 201910792895A CN 110467347 A CN110467347 A CN 110467347A
Authority
CN
China
Prior art keywords
glass
dazzling
vehicle window
silver halide
ion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910792895.XA
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Chinese (zh)
Inventor
王家琦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Golden Dragon New Energy Automotive Research Institute Co Ltd
Original Assignee
Nanjing Golden Dragon New Energy Automotive Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Golden Dragon New Energy Automotive Research Institute Co Ltd filed Critical Nanjing Golden Dragon New Energy Automotive Research Institute Co Ltd
Priority to CN201910792895.XA priority Critical patent/CN110467347A/en
Publication of CN110467347A publication Critical patent/CN110467347A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/12Silica-free oxide glass compositions
    • C03C3/23Silica-free oxide glass compositions containing halogen and at least one oxide, e.g. oxide of boron
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/04Compositions for glass with special properties for photosensitive glass
    • C03C4/06Compositions for glass with special properties for photosensitive glass for phototropic or photochromic glass

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of anti-dazzling glasss for vehicle window, include consisting of (weight %): sodium aluminium borate 55-70%, silver halide 10-13%, silver halide is added in sodium aluminium borate and makees emulsion by copper ion 8-15%, cadmium ion 1-2%, it adds copper ion and cadmium ion makees sensitizer, after being melting into glass, it is heat-treated through 300 DEG C of temperatures above, silver halide is polymerized to microgranular.Anti-dazzling glass for vehicle window of the present invention can flexibly change the light transmittance of glass for vehicle window under different light, to achieve the purpose that prevent driver from dazzling the eyes in sunburst irradiation, play the role of improving driver's drive safety.

Description

A kind of anti-dazzling glass for vehicle window
Technical field:
The present invention relates to a kind of anti-dazzling glasss for vehicle window, belong to glass for vehicle window technical field.
Background technique:
Vehicle glass is to primarily serve protective action as part essential in automobile body accessories.Automobile at present With glass, based on interlayer tempered glass and sandwiched area tempered glass, impact resistance is stronger.
In routine use, one layer of solar film is sticked on vehicle front and rear windshield, side window glass and skylight glass is Conventional selection.The measure energy hermetic section ultraviolet light and heat, effectively prevent splashing glass to hurt sb.'s feelings, but there are still anti-dazzle abilities Insufficient problem.Especially morning and dusk, the sun slants the eyes into driver at this time, be easy to cause and dazzles the eyes problem, generates Security risk.
Summary of the invention:
The present invention is to provide a kind of anti-dazzling glass for vehicle window to solve the above-mentioned problems of the prior art, will be passed System vehicle glass is changed to photo chromic glass.
The technical solution adopted in the present invention has: a kind of anti-dazzling glass for vehicle window, includes consisting of (weight %): sodium aluminium Silver halide is added in sodium aluminium borate and makees by borate 55-70%, silver halide 10-13%, copper ion 8-15%, cadmium ion 1-2% Emulsion, adds copper ion and cadmium ion makees sensitizer, after being melting into glass, is heat-treated through 300 DEG C of temperatures above, silver halide It is polymerized to microgranular.
The invention has the following beneficial effects: anti-dazzling glasss for vehicle window of the present invention flexibly to change vehicle under different light The light transmittance of glass pane plays raising driver and drives to achieve the purpose that prevent driver from dazzling the eyes in sunburst irradiation Sail the effect of safety.
Specific embodiment:
Anti-dazzling glass for vehicle window of the present invention, it includes consisting of (weight %): sodium aluminium borate 55-70%, silver halide 10-13%, copper ion 8-15%, cadmium ion 1-2%.The present invention by sodium aluminum borate glass be added silver halide make it is photosensitive Agent, adds copper ion and cadmium ion makees sensitizer, after being melting into glass, is heat-treated through appropriate 300 DEG C of temperatures above, makes halogenation Silver is polymerized to microgranular and obtained, referred to as silver halide glass.When it is irradiated by ultraviolet light or visible light shortwave, silver ion reduction is Silver atoms, several silver atoms are gathered into colloid and glass are made to develop the color;After illumination stops, in heat radiation or the long glistening light of waves, (feux rouges is red Under irradiating outside), silver atoms become silver ion and fade.Such glass has two different configuration states, has in visible region Two different absorption coefficients.The light absorption of visible light region can be generated under the visible light action of ultraviolet light or specific wavelength, To be transformed into another structure from a kind of structure, the light transmittance of glass is caused to reduce or occur color change.And in illumination Original pellucidity can be automatically restored to after stopping again.Anti-dazzling glass for vehicle window of the present invention is not easily tied, and can undergo 30 Ten thousand times or more light and shade variations.
Therefore, if automotive window use photo chromic glass, light brighter areas when driving, pass through glass discoloration reduce glass Glass light transmittance enhances anti-dazzle light ability, reduces accident rate.In the more darker region of light, glass become again it is transparent, to drive Person provides the clearly visual field.
The present invention adds copper ion, cadmium ion is made by making emulsion a small amount of silver halide is added in Conventional glass Sensitizer after being melting into glass, is heat-treated through appropriate 300 DEG C of temperatures above, is polymerized to silver halide microgranular, will conventional automobile-used glass Photo chromic glass is made in glass.Under the performance for not influencing Conventional glass, when ambient change is strong, photo chromic glass darkens, thoroughly Luminosity reduces;When ambient dies down, photo chromic glass color bleach, light transmittance is got higher.The light transmittance of vehicle glass with Ambient flexibly changes, to prevent driver from generating the case where dazzling the eyes.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art It for member, can also make several improvements without departing from the principle of the present invention, these improvement also should be regarded as of the invention Protection scope.

Claims (1)

1. a kind of anti-dazzling glass for vehicle window, it is characterised in that: include consisting of (weight %): sodium aluminium borate 55-70%, halogen Change silver 10-13%, copper ion 8-15%, cadmium ion 1-2%, silver halide is added in sodium aluminium borate and makees emulsion, adds copper Ion and cadmium ion make sensitizer, after being melting into glass, are heat-treated through 300 DEG C of temperatures above, silver halide is polymerized to microgranular.
CN201910792895.XA 2019-08-26 2019-08-26 A kind of anti-dazzling glass for vehicle window Pending CN110467347A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910792895.XA CN110467347A (en) 2019-08-26 2019-08-26 A kind of anti-dazzling glass for vehicle window

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910792895.XA CN110467347A (en) 2019-08-26 2019-08-26 A kind of anti-dazzling glass for vehicle window

Publications (1)

Publication Number Publication Date
CN110467347A true CN110467347A (en) 2019-11-19

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910792895.XA Pending CN110467347A (en) 2019-08-26 2019-08-26 A kind of anti-dazzling glass for vehicle window

Country Status (1)

Country Link
CN (1) CN110467347A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113666633A (en) * 2021-08-23 2021-11-19 中方县明兴玻璃有限公司 Color-changing glass and preparation method thereof
CN114349337A (en) * 2022-01-13 2022-04-15 广东电网有限责任公司 Vehicle window glass device and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2805481A1 (en) * 1977-02-21 1978-09-21 Saale Glas Gmbh Photochromic borate glass free from silver - contains halide(s) and at least one of copper cadmium, thallium, tin and lead
CN1031826A (en) * 1987-09-08 1989-03-22 国营光明器材厂 Blue discolouration glass
CN206799441U (en) * 2017-03-20 2017-12-26 河南万航航空发展有限公司 A kind of flight simulation cabin cabin light adjusting device
CN206983682U (en) * 2017-06-16 2018-02-09 乔健桐 Brightness degree adjusting means applied to windshield
CN107718777A (en) * 2017-09-08 2018-02-23 安徽光为智能科技有限公司 A kind of photo chromic glass

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2805481A1 (en) * 1977-02-21 1978-09-21 Saale Glas Gmbh Photochromic borate glass free from silver - contains halide(s) and at least one of copper cadmium, thallium, tin and lead
CN1031826A (en) * 1987-09-08 1989-03-22 国营光明器材厂 Blue discolouration glass
CN206799441U (en) * 2017-03-20 2017-12-26 河南万航航空发展有限公司 A kind of flight simulation cabin cabin light adjusting device
CN206983682U (en) * 2017-06-16 2018-02-09 乔健桐 Brightness degree adjusting means applied to windshield
CN107718777A (en) * 2017-09-08 2018-02-23 安徽光为智能科技有限公司 A kind of photo chromic glass

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李乡状等: "《未来的化学科技》", 31 October 2012, 长春:东北师范大学出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113666633A (en) * 2021-08-23 2021-11-19 中方县明兴玻璃有限公司 Color-changing glass and preparation method thereof
CN114349337A (en) * 2022-01-13 2022-04-15 广东电网有限责任公司 Vehicle window glass device and preparation method and application thereof

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SE01 Entry into force of request for substantive examination
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Application publication date: 20191119