CN110467149A - A kind of carbon-based function element and preparation method thereof - Google Patents
A kind of carbon-based function element and preparation method thereof Download PDFInfo
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- CN110467149A CN110467149A CN201810443851.1A CN201810443851A CN110467149A CN 110467149 A CN110467149 A CN 110467149A CN 201810443851 A CN201810443851 A CN 201810443851A CN 110467149 A CN110467149 A CN 110467149A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 93
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 31
- 229920005989 resin Polymers 0.000 claims abstract description 31
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000003763 carbonization Methods 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims description 17
- 229910002804 graphite Inorganic materials 0.000 claims description 11
- 239000010439 graphite Substances 0.000 claims description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 9
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 7
- 239000004917 carbon fiber Substances 0.000 claims description 7
- 239000002041 carbon nanotube Substances 0.000 claims description 6
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 6
- 229910003460 diamond Inorganic materials 0.000 claims description 6
- 239000010432 diamond Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000007639 printing Methods 0.000 claims description 6
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 5
- 229910003472 fullerene Inorganic materials 0.000 claims description 5
- 229910021389 graphene Inorganic materials 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 4
- 238000000016 photochemical curing Methods 0.000 claims description 2
- 238000006392 deoxygenation reaction Methods 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 claims 1
- 239000011435 rock Substances 0.000 claims 1
- 238000010146 3D printing Methods 0.000 abstract description 15
- 238000003672 processing method Methods 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 16
- 239000011248 coating agent Substances 0.000 description 14
- 238000013461 design Methods 0.000 description 14
- 239000007789 gas Substances 0.000 description 8
- 238000012986 modification Methods 0.000 description 8
- 230000004048 modification Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 5
- 238000000151 deposition Methods 0.000 description 4
- 238000004146 energy storage Methods 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000011342 resin composition Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 210000003027 ear inner Anatomy 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B7/00—Microstructural systems; Auxiliary parts of microstructural devices or systems
- B81B7/04—Networks or arrays of similar microstructural devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C1/00—Manufacture or treatment of devices or systems in or on a substrate
- B81C1/00015—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
- B81C1/00214—Processes for the simultaneaous manufacturing of a network or an array of similar microstructural devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C2201/00—Manufacture or treatment of microstructural devices or systems
- B81C2201/01—Manufacture or treatment of microstructural devices or systems in or on a substrate
- B81C2201/0101—Shaping material; Structuring the bulk substrate or layers on the substrate; Film patterning
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Computer Hardware Design (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Microstructure, shape, hyperfine micrometre array carbon-based material functional device and its processing method received of scale are accurately controlled the invention discloses a kind of.The carbon-based function element has the fine structure of nano-micro level scale, is formed by carbon-based material ordered arrangement.The carbon-based function element the preparation method comprises the following steps: using high-precision 3D printing technique, print to have and receive the resin base device structure of micron accuracy resin base device is carbonized as carbon-based function element using heat treatment carbonization technique.
Description
Technical field
The invention belongs to the multi-field fusion skills such as 3D printing, carbon material, surface modification, engineering material or function element processing
A kind of art, and in particular to hyperfine macroscopic view, microstructure, composition, property for receiving the carbon-based engineering material of micrometre array or function element
Energy and its processing method.
Background technique
Lightweight, high strength structure, while having the function of the engineering components such as sound insulation, heat-insulated, decontamination, conduction or multi-functional recombiner
Part, the target for being always in national economy all trades and professions, tool, implements must being used to be pursued.Diamond, graphite,
The form of carbon nanotubes, fullerene, graphene, carbon is varied, the discovery of the form of each carbon, different shape carbon it is new
The invention of preparation method can cause the huge advance of scientific research, technical field；On the basis of simple substance carbon, it is doped or micro-
It is modified to see surface, forms carbon-based material, characteristic, structure are more varied, and performance is rich and varied, will lead the new era
It arrives.
Carbon fiber, graphite fibre, carbon nanotubes including diamond film or powder etc., for highest hardness, light specific gravity,
The thermally conductive performances such as good, have been the key that current high end composites form.But it not yet realizes in the prior art in microcosmic ruler
Spend and receive micron accuracy rank structure design and device configuration.
3D printing technique is increasingly paid attention to, and may be implemented to receive the device configuration of micron accuracy using 3D printing.But
The material that accurate hyperfine structure 3D printing technique is realized at present is photoresists, does not have carbon-based material product.
Summary of the invention
The present invention is intended to provide a kind of complex function receive micrometre array carbon-based material composition structure or function device, and
It designs, processes, manufacturing method.
It is characterized by: carbon-based material basic unit is to receive rodlike, the sheet of micro-meter scale；Again by parallel, oblique, more
The ordered arrangements such as retransposing form the oldered array that the size of space is millimicro meter level；By the orderly battle array of above-mentioned millimicro meter level
For column by way of combination, being formed has the carbon-based function element of geometry.The carbon-based function element have sound insulation, it is heat-insulated,
The functions such as decontamination, conduction, absorption, energy storage.
Preferably, the carbon-based function element a, its resemblance are the system of bar, plate or other labyrinths
Product, such as automobile, aircraft, engine, display, energy storage device, power generator, motor, in principle, it is possible to be any shape
The product of formula.B, its performance is in the performance basis needed for the engineering structure or functional characteristic for meeting device, also to surpass with density
The additional combinations performance such as low, intensity superelevation, sound-insulating and heat-insulating, energy-absorbing energy storage, brilliant substance or charge adsorption, conduction；Associativity
Energy can careful design, manufacture.C, its basic unit is that nano and micron rod, micron chip of receiving, so-called nano and micron rod refer to, the diameter of stick
For nano-micro level, and length is micron, submillimeter, even Centimeter Level；So-called micron chip of receiving refers to, piece with a thickness of receiving micron
Grade, and the area of piece is micron, millimeter, centimetre even more big order of magnitude.D, when basic unit combination is formed with sequence battle array, substantially
Connection, gap, distribution between unit can be controlled accurately.It e, can when orderly array is combined into the geometry of function element
To be the combination of a variety of different orderly non-duplicate formulas of array；It is also possible to single or multiple orderly array by repeating, having
The arrangement of sequence forms the combination of similar lattice structure；Any geometry design can also be carried out simultaneously according to performance requirement
Processing is realized.F, the wherein carbon-based material, it is single to can be graphite, diamond, graphene, carbon nanotubes, fullerene etc.
The carbon material of phase is also possible to diamond-like, carbon fiber, graphite fibre, a variety of carbon phase states of micron carbon plate etc. of receiving and is mixed to form
Carbon material；Carbon-based material can be the material of uniform microstructure, be also possible to multilayer tissue's material, for example, internal layer is carbon
Fiber, outer layer are the film of diamond-like or other tissues, component.
Realize that the preparation method for receiving micrometre array carbon-based material engineering component or function element is, firstly, beating using 3D
Print technology, which is obtained, receives what micrometre array formed by resin-based, the device architecture with geometry；Secondly, using resin carbonation
Technology, so that the carbonization of resin base device is carbon-based function material device；Specifically: a, the wherein 3D printing technique can be
Receive the photocuring 3D printing technique or heat cure 3D printing technique of micron printing precision；Tree used by corresponding 3D printing
Rouge, or be light-cured resin or be heat reactive resin.B, the wherein resin char process, is to set resin device
Under the temperature of resin carbonation, pressure, atmosphere, after the regular hour, the atoms such as O, H in resin are in gaseous form
Volatilization removal, leaves behind the carbon skeleton in resin, the configuration characteristic of resin does not have any change.Finally, in order to improve carbon-based function
The performance of energy device further can also carry out surface modification treatment to carbon-based function element using 3D coating technique.Wherein institute
The 3D coating technique stated is the carbon material device for obtaining resin device architecture after being carbonized, be placed in suitable temperature, pressure and
Under reaction atmosphere, by thermal decomposed deposition perhaps CVD method or the method for plasma enhancing reactive deposition, in carbon-based function
The surfaces externally and internally of energy device, deposits modified layer.The deposition modified layer, is carbon-base film.
It is all to be filled using carbon-based function element discussed in this patent or the correlation obtained based on the device preparation method
Standby, system, application are the franchise of this patent.
Beneficial effect
It receives the engineering structure part or function element formed based on micrometre array carbon-based material, on the one hand keeps even super
More there is the high-strength characteristic of conventional carbon fiber or graphite fibre class, simultaneously because there is a high proportion of gap, to have ultralight
High strength characteristics will play irreplaceable, unique effect in numerous areas such as automobile, aircraft, train, steamers；Another party
Micrometre array carbon-based material is especially received when forming macroscopical component or device in face, and having from the microcosmic structure to macroscopic view can set
Meter property, by be expected to manufacture and design obtain it is completely new, much surmount prior art characteristic, tool, the product that can not imagine.
Detailed description of the invention
Fig. 1 is carbon-based function element product schematic diagram disclosed by the invention.The carbon-based function element is square framework, group
At the material of frame, it is the carbon substrate charge bar or piece of micro-meter scale are received by carbon-based material basic unit, has with millimicron gap
It sequence connection, the oldered array of carbon-based millimicro meter level that intersects to form.
Specific embodiment
Present invention is further described in detail in the following with reference to the drawings and specific embodiments, but not as to limit of the invention
It is fixed.
Selection can be realized receive micron accuracy preparation 3D printing technique, select corresponding light-cured resin or heat cure tree
Rouge designs carbon-based material basic unit, the orderly array structure of micro-meter scale of receiving according to function element performance requirement as raw material
Type, and combinations thereof mode.
The component diagram that design is obtained is handled by business 3D printing software, obtains 3D printing slice；Print software makes
The work of 3D printing equipment, the resin base that micron accuracy accurately controls that obtains receiving, which receives a micron basic unit, resin material millimicron, to be had
Sequence array, and its device architecture of composition.
The device architecture for the resin material material that 3D printing is obtained carries out carbonization treatment using professional retort, passes through
Carbonization.In one or more embodiments disclosed by the invention, the device architecture of above-mentioned resin material material can be heated to big
About 550 degrees Celsius to about 2450 degrees Celsius are carbonized.By carbonization, resin Composition decomposes at high temperature, and is decomposed
At different gas and carbon.Carbon is retained on the position of carbonized components, and the non-carbon elements such as O, H are removed.According to existing carbon
Chemical industry skill can get carbon-based function element.
The carbon-based function element, carbon-based material basic unit are to receive rodlike, the sheet of micro-meter scale；It has leads to again
The ordered arrangements such as parallel, oblique, multiple cross are crossed, the fine structure that the size of space is millimicro meter level oldered array is formed；
Also have the function of sound insulation, heat-insulated, decontamination, conduction, absorption, energy storage etc..
It is above to obtain carbon-based function element.It can also continue to handle.Derived above micrometre array of receiving is carbon-based
Function element carries out comprehensive surface coating modification using professional 3D coating machine, and so-called comprehensive surface coating refers to not only
It is that the macro surface of component obtains coating film treatment, but the microscopic internal surface of component also obtains uniform outer surface coating film treatment.Such as
This obtains carbon-based material engineering component or function element by surface coating modification.
Embodiment one:
The carbon-based function element structure feature of design are as follows: shape is square box of the outer length and width having a size of 10mm, frame beam
Size be 2mm, thickness 2mm；That is, the carbon-based millimicron array composition outer dimension for being 2mm using length and width, thickness is 10X10mm
Square box.
Form the carbon-based millimicron array features of frame beam are as follows: the solid carbon-based material of strip for being 10 microns by side length is basic
Unit, forms the orderly array of carbon-based millimicron of 50X50X50 microns of cube structures, and the diagonal line of cube equally has side length
10 microns of solid resin；The carbon-based millimicron oldered array cycle arrangement of cube structure, forms the frame beam of function element
And frame.
It is beaten using 3D printing optical system disclosed in such as Chinese patent application of Publication No. CN106938544A
Print the printing of nanometer micrometer structure.The complete disclosure of this application is hereby incorporated herein by.And dedicated photosensitive tree
Rouge, printing obtain the above-mentioned square box device architecture of light-cured resin composition and its fine structure of millimicron oldered array.
By the square box device architecture of above-mentioned resin material material, be heated approximately at 550 degrees Celsius to about 2450 it is Celsius
Degree is carbonized.By carbonization, resin Composition decomposes at high temperature, and is broken down into different gas and carbon.Carbon is retained in
On the position of carbonized components, and the non-carbon elements such as O, H are removed.According to existing carbonization technique, base, which can get, meets design need
The carbon-based function element asked, and include the fine structures such as the millimicron oldered array for meeting design, the carbon-based basic unit of micron of receiving.
In other embodiments disclosed by the invention, it is also an option that using heat reactive resin as raw material, using can
Realize receive micron accuracy preparation 3D printing technique.
In multiple embodiments disclosed by the invention, the carbon-based function element of design, the carbon-based basic unit of micron of receiving is also
It can be the nano and micron rod of other forms and size, micron chip of receiving.The nano and micron rod refers to that the diameter of stick is nano-micro level,
And length is micron, submillimeter, even Centimeter Level；So-called micron chip of receiving refers to, piece with a thickness of nano-micro level, and the area of piece
For micron, millimeter, centimetre even more big order of magnitude.
In multiple embodiments disclosed by the invention, the carbon-based function element of design, a carbon-based micron elementary unit groups of receiving
When conjunction is formed with millimicron sequence battle array, arrangement mode that can be orderly by parallel, oblique, multiple cross etc., between basic unit
Connection, gap, distribution can control accurately.
In multiple embodiments disclosed by the invention, the carbon-based function element of design, orderly array is combined into function element
Geometry when, can be the combination of a variety of different orderly non-duplicate formulas of array；It is also possible to single or multiple orderly
Array forms the combination of similar lattice structure by repetition, orderly arrangement；It can also be carried out according to performance requirement any
Geometry design.
In multiple embodiments disclosed by the invention, it is formed by carbon-based material through carbonisation, can be graphite, Buddha's warrior attendant
The carbon material of the single phases such as stone, graphene, carbon nanotubes, fullerene, be also possible to diamond-like, carbon fiber, graphite fibre,
The carbon material that a variety of carbon phase states of micron carbon plate etc. of receiving are mixed to form.
In multiple embodiments disclosed by the invention, carbon-based function element is obtained.It can also continue to step processing.It will be with
On obtain receive the carbon-based component of micrometre array, comprehensive surface coating modification is carried out using professional 3D coating machine, it is so-called complete
Orientation surface coating refers to that the macro surface for being not only component obtains coating film treatment, but the microscopic internal surface of component also obtains
Uniform outer surface coating film treatment.So obtain carbon-based material engineering component or the function element by surface coating modification.Example
Such as, carbon-based function element is in coating process, can undergo the CVD in one or more periods with during being filled in carbonisation by
It sheds the device defects such as generated stomata, gap in gas.For example, coating process can undergo one or more periods
CVD is until material is shown closely knit density.Such as between about 1.6g/cc and about 1.9g/cc.
In multiple embodiments disclosed by the invention, the carbon-based function element obtained after carbonization is in pressurized tank in indifferent gas
Under the covering of body, such as 100 supports pressure below is heated.When carbon-based micrometre array of receiving reaches about 900 degrees Celsius and about 1200
When temperature between degree Celsius, inert gas is replaced by carbonaceous gas, all natural gases in this way of carbonaceous gas, methane, ethane, third
At least two combination in alkane, butane, propylene or acetylene or these gases.When carbonaceous gas flows around the prefabricated component of carbonization
Move and flow through it is carbon-based receive micrometre array when, dehydrogenation occurs, the complexity of condensation and polymerization reaction carbon-based receives table in micrometre array
On face and outer surface.Over time, since more and more carbon atoms are deposited and form corresponding carbon simple substance shape
The mixed style of state or carbon simple substance, to wait until the carbon-base film of deposition in carbon-based functional material surfaces externally and internally.
The above is only the preferable embodiment of the present invention, not does in any form to technical solution of the present invention
Limitation.Any simple modification, form variation and modification are made to above embodiments according to the technical essence of the invention, fallen
Enter protection scope of the present invention.
Claims (14)
1. a kind of preparation method of carbon-based function element, it is characterised in that use organic resin, utilize the 3D of nano-micro level precision
The basic unit of micron-scale is received in print system, printing；And then it prints and parallel or oblique or multiple friendship is passed through by basic unit
The mode of fork forms the oldered array of millimicro meter level；The device architecture being made of millimicro meter level oldered array is printed again.Then beat
The resin material device architecture printed off goes deoxygenation, hydrogen atom by carbonisation, obtain have receive the carbon-based basic unit of micron and
The carbon-based function element of the carbon-based oldered array fine structure of millimicron.
2. a kind of preparation method of carbon-based function element as described in claim 1, which is characterized in that in printing by basic unit
When forming the oldered array of millimicro meter level, connection, gap, distribution between the basic unit can be controlled accurately.
3. a kind of preparation method of carbon-based function element as described in claim 1, which is characterized in that in printing by millimicro meter level
When the device architecture of oldered array composition, the millimicro meter level oldered array is the orderly array of single type or multiple types,
Between each other by repeat, orderly mode arranges or the arrangement mode of non-duplicate formula.
4. a kind of preparation method of carbon-based function element as described in claim 1, which is characterized in that the described micron of receiving is carbon-based
It is nano-micro level that basic unit, which is diameter, length be micron, submillimeter, the nanometer rods of Centimeter Level or piece with a thickness of receiving
Micron order, and the area of piece is that micron, millimeter, Centimeter Level receive micron chip.
5. a kind of preparation method of carbon-based function element as described in claim 1, which is characterized in that the organic resin is selected from
Light-cured resin or heat reactive resin.
6. a kind of preparation method of carbon-based function element as claimed in claims 1-5, which is characterized in that the carbonisation is
Organic resin is carbonized as carbon-based material, wherein carbon-based material is selected from graphite, diamond, graphene, carbon nanotubes, fullerene
Single phase carbon material；Either it is selected from diamond, carbon fiber, graphite fibre, at least two carbon phase state of micron carbon plate of receiving
The carbon material being mixed to form.
7. a kind of preparation method of carbon-based function element as described in claim 1, which is characterized in that may further include carbon
Base function element surfaces externally and internally deposits carbon-base film.
8. a kind of carbon-based function element of method as described in claim 1 preparation, which is characterized in that the carbon-based function element is
It is prepared by organic resin carbonization, and is made of the carbon-based oldered array of millimicron.The carbon-based oldered array of millimicro meter level is
It is formed by way of receiving the carbon-based basic unit of micron by parallel or oblique or multiple cross.
9. a kind of carbon-based function element as claimed in claim 8, which is characterized in that the carbon-based oldered array of millimicro meter level,
Between the carbon-based basic unit of micron that it was included receive, there is connection, gap, the distribution accurately controlled.
10. a kind of carbon-based function element as claimed in claim 8, which is characterized in that the milli of the carbon-based function element of composition
The carbon-based oldered array of micron, is the orderly array of single type or multiple types, is arranged between each other by repetition, orderly mode
The arrangement mode of column or non-duplicate formula.
11. a kind of carbon-based function element as claimed in claim 8, which is characterized in that the described carbon-based basic unit of micron of receiving
It is diameter for nano-micro level, length is micron, submillimeter, the nanometer rods of Centimeter Level or piece with a thickness of nano-micro level, and
The area of piece is that micron, millimeter, Centimeter Level receive micron chip.
12. a kind of carbon-based function element as claimed in claim 8, which is characterized in that the organic resin is selected from photocuring tree
Rouge or heat reactive resin.
13. a kind of carbon-based function element as described in claim 8-12, which is characterized in that the carbon-based function element, carbon
Sill be selected from graphite, diamond, graphene, carbon nanotubes, the single phase of fullerene carbon material；Either selected from gold
The carbon material that hard rock, carbon fiber, graphite fibre, at least two carbon phase state of micron carbon plate of receiving are mixed to form.
14. a kind of carbon-based function element as claimed in claim 8, which is characterized in that may further include in function element
Outside deposition has carbon-base film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810443851.1A CN110467149A (en) | 2018-05-10 | 2018-05-10 | A kind of carbon-based function element and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810443851.1A CN110467149A (en) | 2018-05-10 | 2018-05-10 | A kind of carbon-based function element and preparation method thereof |
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| CN110467149A true CN110467149A (en) | 2019-11-19 |
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| CN201810443851.1A Pending CN110467149A (en) | 2018-05-10 | 2018-05-10 | A kind of carbon-based function element and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111007107A (en) * | 2019-12-05 | 2020-04-14 | 北京航空航天大学 | Dew point measuring method based on carbon-based flexible humidity-sensitive device |
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