CN110433870A - A kind of catalysis material for airstrainer, preparation method and applications - Google Patents
A kind of catalysis material for airstrainer, preparation method and applications Download PDFInfo
- Publication number
- CN110433870A CN110433870A CN201910804066.9A CN201910804066A CN110433870A CN 110433870 A CN110433870 A CN 110433870A CN 201910804066 A CN201910804066 A CN 201910804066A CN 110433870 A CN110433870 A CN 110433870A
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- CN
- China
- Prior art keywords
- preparation
- acid solution
- airstrainer
- titanate
- catalysis material
- Prior art date
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- 239000000463 material Substances 0.000 title claims abstract description 63
- 238000006555 catalytic reaction Methods 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 230000001699 photocatalysis Effects 0.000 claims abstract description 26
- 238000007146 photocatalysis Methods 0.000 claims abstract description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- -1 titanate compound Chemical class 0.000 claims abstract description 19
- 230000015556 catabolic process Effects 0.000 claims abstract description 18
- 238000006731 degradation reaction Methods 0.000 claims abstract description 18
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 13
- 230000007062 hydrolysis Effects 0.000 claims abstract description 12
- 239000000809 air pollutant Substances 0.000 claims abstract description 10
- 231100001243 air pollutant Toxicity 0.000 claims abstract description 10
- 239000002344 surface layer Substances 0.000 claims abstract description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 33
- 239000002253 acid Substances 0.000 claims description 20
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 17
- 235000019441 ethanol Nutrition 0.000 claims description 17
- 229920001778 nylon Polymers 0.000 claims description 12
- 241000191967 Staphylococcus aureus Species 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 9
- 150000001298 alcohols Chemical class 0.000 claims description 8
- 239000004677 Nylon Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 238000013033 photocatalytic degradation reaction Methods 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 239000005864 Sulphur Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 claims description 3
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 3
- XGZNHFPFJRZBBT-UHFFFAOYSA-N ethanol;titanium Chemical compound [Ti].CCO.CCO.CCO.CCO XGZNHFPFJRZBBT-UHFFFAOYSA-N 0.000 claims description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 3
- 229960002715 nicotine Drugs 0.000 claims description 3
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium(IV) ethoxide Substances [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims description 2
- 229960002089 ferrous chloride Drugs 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 239000011964 heteropoly acid Substances 0.000 claims description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229940005657 pyrophosphoric acid Drugs 0.000 claims description 2
- 239000011592 zinc chloride Substances 0.000 claims description 2
- 235000005074 zinc chloride Nutrition 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000003963 dichloro group Chemical group Cl* 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 239000002657 fibrous material Substances 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 3
- 238000004887 air purification Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000000746 purification Methods 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 25
- 239000010410 layer Substances 0.000 description 20
- 238000001914 filtration Methods 0.000 description 14
- 239000003054 catalyst Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 239000004745 nonwoven fabric Substances 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 5
- 239000011941 photocatalyst Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 238000004378 air conditioning Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 1
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000011565 manganese chloride Substances 0.000 description 1
- 235000002867 manganese chloride Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 238000011045 prefiltration Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- B01J35/39—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7027—Aromatic hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/91—Bacteria; Microorganisms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
Abstract
The present invention relates to photocatalysis and technical field of environmental purification.The purpose is to be directed to indoor air purification problem, a kind of catalysis material for using and being prepared with common fiber material for basic material is provided, it can be fully exposed to strainer high molecular material surface layer, there is efficient degradation efficiency to air pollutants, and with polymer base material binding force with higher, it is water-fastness.Invention also provides the preparation method and applications of the catalysis material for airstrainer.The catalysis material for airstrainer is after being reacted in alcohol solution by the surface free group of high molecular material with titanate compound, it is obtained again via hydrolysis, wherein the mass ratio of surface free group, titanate compound and alcohol solution is 1:0.1~3:1~1000.
Description
Technical field
The present invention relates to photocatalysis and technical field of environmental purification, are the light being related to for airstrainer specifically
Catalysis material, further relate to the catalysis material preparation method and its to indoor air pollutants carry out photocatalytic degradation
In application.
Background technique
Airstrainer (Airstrainer) be lenticular honeycomb structure, can be widely applied to air-conditioning, air purifier or
Air filtering system in the equipment such as fresh air system.Airstrainer is divided into thick effect, middle effect, sub- efficient, efficient four types, root
The airstrainer of different number is installed in a pipeline according to air volume, fillter section is mounted in central air-conditioning system,
Feeding room air dust particle is filtered out, to reach the high-quality of room air.Airstrainer is typically mounted at air-conditioning
Among system air supply duct, the prefilter equipment that thick effect and middle effect air filtration section are used as plays protection high efficiency filter section
Effect, while also having good effect to noise elimination.High efficiency filter section should match front end pretreatment filtration equipment during installation, while right
Noise elimination effect is more preferable.Filter material in filter screen is generally fibrous material, and filter screen more than H11 grade is generally PP, compound PP-
PET, terylene and glass fibre etc. plant material.Feature is: dust containing capacity is big, filtering accuracy is high, can need to be processed into according to client
Various sizes and shape are suitble to different types to use.Strainer outline border is made of firm, moisture-proof hard material, it is ensured that Bu Huibian
Shape, rupture, distortion.When filtering net surface is very dirty, washed.Son is put into clear water and dish washing liquid in rinse bath, incited somebody to action
Strainer, which is put into slot, all to drown.It is rinsed several times, until finally being rinsed with clear water without dirt until water is clearly
Only, it takes out and is placed on stainless steel barrier draining, then tile and dry in the shade on the top of the shelf.
Photochemical catalyst is usually used for air purifier by using following manner by photocatalytic air filtering material at present:
(1) on by photocatalyst on the carriers such as active carbon, non-woven fabrics, harmful gas is adsorbed by porous carrier
Then body, bacterium, virus etc. rely on the catalytic effect of photochemical catalyst again, carry out sterilization or resolving harmful gas.
Such as: patent CN206688383U discloses a kind of air-filtering membrane, and composite filter includes successively fitting setting
Bamboo fibre layer and sepiolite fibre layer, the adsorption layer includes photocatalysis TiO2 nanoparticle layers, the stone for being successively bonded setting
Black alkene layer and active carbon layer.Patent CN205208737U discloses a kind of exterminating bacterium air filter plate, including carbon fiber layer, sea
Continuous layer, porous plate, active carbon layer, upper carbon fiber layer, photocatalyst layer, the photocatalyst layer are by titanium dioxide, zinc oxide
What particulate load was formed on more suction enclosure materials.Patent application CN103230812A discloses a kind of photocatalytic air filter material
Material, the zinc titanate photocatalysis porous membrane being supported on non-woven fabrics base material including non-woven fabrics base material and coupling.Patent
ZL02124137.6 is disclosed through colloidal sol in non-woven fabrics loaded on surface of flexible base material ferrous acid N-butyl, then in water heating kettle
Form titanium dioxide film photocatalyst.
Such method the problem is that: active carbon layer or other adsorbent materials are usually middle layer, light in actual production
Line can not be irradiated to the surface of photochemical catalyst, and photocatalytic effect is caused to cannot achieve.
(2) photochemical catalyst is coated in the surface of filtering material together using coating.This method especially needs to solve base
Interface compatibility between body material and photochemical catalyst.
Such as: patent CN204815964U discloses a kind of air filting material with disinfection function, including light
Catalyst layer, imported cotton fibrous layer, ultra-fine fibre glass layer and nano-silver layer, the photocatalyst layer are wrapped in import cotton fiber
The outermost of layer.Patent CN101618288B discloses a kind of glass fibre gluing photochemical catalyst.Patent CN2841143Y is disclosed
A kind of fiber being supported with semiconductor light-catalyst, fiber have supported the apatite with photo-catalysis function.
Such methods the problem is that: (a) due to having coated photochemical catalyst by coating agent, thus reduce photocatalysis
The contact area of agent and bacterium, virus and organic pernicious gas reduces its photocatalytic effect.(b) light coated in surface is urged
Catalyst particles adhesive force is poor, is easy to fall off, and does not adapt to filter gauze cleaning.(c) traditional to be urged in substrate material surface load light
The preparation process for changing film is required to high-temperature calcination (> 200 DEG C) and is activated, and preparation process is complicated, is not appropriate for industrial metaplasia
It produces.Base material generally selects sheet metal, sheet glass, wire mesh etc. as carrier, and just relatively difficult to achieve on polymer base material.
Summary of the invention
The purpose of the present invention is being directed to the shortcoming of existing catalysis material, a kind of improved catalysis material is provided
Preparation method, common fiber material can be used for basic material preparation, the catalysis material as made by this method can be with
It is fully exposed to screen material surface layer, there is efficient degradation efficiency to indoor air pollutants, and have with polymer base material
Higher binding force, it is water-fastness.
It is urged it is a further object of the present invention to provide a kind of using the light for airstrainer that the above method is prepared
Change material.
The above-mentioned catalysis material of what the present invention further also provided is carrying out photocatalytic degradation to indoor air pollutants
In application, especially PARA FORMALDEHYDE PRILLS(91,95), acetaldehyde, benzene homologues, amine system object, sulphur system object, nitrogen oxides, nicotine, Staphylococcus aureus
Bacterium carries out the application in photocatalytic degradation.
The purpose of the present invention is achieved through the following technical solutions:
A kind of preparation method of the catalysis material for airstrainer, the catalysis material are fully exposed to strainer
High molecular material surface layer carries out photocatalytic degradation to air pollutants, and the method includes the steps of: the surface of high molecular material
Free group carries out reacting the titanate esters group to form surface bond in alcohols solvent with titanate compound, and reaction temperature is
0~80 DEG C, the reaction time is 0.1~100h, in which: the mass ratio of surface free group, titanate compound and alcohols solvent
For 1:0.1~3:1~1000, preferably 1:0.5~2:50~300；PH value is adjusted to 1~6 using acid solution, surface bond
Titanate esters group obtains titanyl macromolecular structure via hydrolysis, and the temperature condition of the hydrolysis is 0~100 DEG C, the hydrolysis
Reaction time is 0.5~20h.
Further, the hydrolysis further includes that other metallic compounds are added, and the titanate esters group of surface bond can also be with
Cohydrolysis is carried out with other metallic compounds, forms heteropoly acid macromolecular structure, the additional amount of other metallic compounds is
The 0.01~0.99 of the quality of titanate compound, the preferably additional amount of other metallic compounds are the matter of titanate compound
The 0.02~0.2 of amount.Other described metallic compounds include but is not limited to be selected from: ferric trichloride, ferrous chloride, manganous chloride,
One or more of alchlor, cobalt chloride, nickel chloride, copper chloride or zinc chloride.
In view of production cost factor, in preparation method as described above, the acid solution is preferably selected from: hydrochloric acid is molten
One or more of liquid, sulfuric acid solution, phosphoric acid solution, formic acid solution or acetic acid solution.The mass percent of the acid solution
Solubility is 0.1~10%.
In view of production cost factor, in preparation method as described above, the alcohols is molten to be preferably selected from: methanol, second
One or more of alcohol or propyl alcohol.
Preparation method as described above, the surface free group are reacted in alcohols solvent with titanate compound
Reaction temperature be preferably 40~70 DEG C.
Preparation method as described above, the surface free group are reacted in alcohols solvent with titanate compound
Reaction time be preferably 0.5~10h.
Preparation method as described above is hydrolyzed after pH is preferably adjusted to 1~3 when adjusting pH value using acid solution.
Preparation method as described above, the temperature condition of the hydrolysis are preferably 30~60 DEG C.
Preparation method as described above, the reaction time of the hydrolysis are preferably 0.5~3h.
Wherein, the high molecular material, is including but not limited to selected from: polypropylene, polyethylene, polyester, nylon, polyurethane,
One or more of glass or cellulose blend or copolymer.The surface free group, including but not limited to contains: hydroxyl
One or more of base, amino, carboxyl, aldehyde radical or ester group.The titanate compound, is including but not limited to selected from: more alkane
One of oxygroup titanate esters, monoalkoxy pyrophosphoric acid base titanate esters, tetraethyl titanate, metatitanic acid orthocarbonate or butyl titanate or
It is several.
The content of preparation method as described above, the surface free group can be adjusted by blending or reaction modifying
It is whole.
Invention also provides it is a kind of using made from method as described above be used for airstrainer catalysis material,
The wave-length coverage of photocatalysis light source is 250~700nm.
The method catalysis material obtained for being used for airstrainer as described above increases high score by chemical bonding
Binding force between subbase material and photochemical catalyst can be solved the problems, such as effectively water-fastness and be not required to additional binder.It is surveyed through test
: surface bond substance can be water-fastness 5 times or more, photocatalysis efficiency rate of descent < 20%.
Catalysis material as described above for airstrainer is carrying out photocatalytic degradation to indoor air pollutants
In application.The catalysis material is fully exposed to the surface layer of screen material, and the air pollutants include but is not limited to: first
One or more of aldehyde, acetaldehyde, benzene homologues, amine system object, sulphur system object, nitrogen oxides, nicotine, staphylococcus aureus, drop
Solution efficiency can reach 90% or more.
According to People's Republic of China's light industry standard QB/T 2761-2006 " indoor air purification product clean-up effect
Measuring method " and National Standard of the People's Republic of China GB/T20944.2-2007 " evaluation of antibacterial textile performance " examine
It surveys, catalysis material as described above has outstanding photocatalysis effect, can reach 95% to the degradation efficiency of formaldehyde in air
More than, 90% or more can reach to the degradation efficiency of benzene homologues, 95% or more is reached to the bacteriostasis rate of staphylococcus aureus.
The catalysis material for airstrainer as described above can application field include but is not limited to air conditioner filter screen, sky
Gas purifier strainer or fresh air system strainer etc..Application system is expected from former material, is matched based on existing environment protection field supply chain
Set, implementation easy to spread.
Specific embodiment
The present invention is further explained in the light of specific embodiments.Embodiment is not only wrapped in technical solution of the present invention
Containing following embodiment, also comprising any combination between each example.
Embodiment 1
Appropriate nylon fiber (equivalent 1 gram of surface free amine group), two (triethanolamine) metatitanic acid diisopropyls are added in container
1 gram of ester, 200 grams of ethyl alcohol react 2 hours at 60 DEG C.It is added dropwise under the conditions of 3% salt acid for adjusting pH value is 2,50 DEG C and hydrolyzes 1 hour, mistake
Filter is dried to obtain surface bond titanium system photocatalysis nylon material.Under the irradiation of 1W 365nm LED light source, by standard QB/T
2761-2006 and GB/T20944.2-2007 detection, can reach 98% to the degradation efficiency of formaldehyde in air, to the drop of benzene homologues
Solution efficiency can reach 95%, reach 99% to the bacteriostasis rate of staphylococcus aureus.Washing 6 times, photocatalysis efficiency only declines
8%.
Embodiment 2
Appropriate polyester non-woven fabric (equivalent 1 gram of surface free hydroxyl group), three (dioctylphyrophosphoric acid of isopropyl are added in container
Acyloxy) 1.2 grams of titanate esters, 300 grams of ethyl alcohol, it reacts 2 hours at 60 DEG C.It is 1,50 DEG C of conditions that 2% sulphur acid for adjusting pH value, which is added dropwise,
Lower hydrolysis 1 hour, filtration drying obtains surface bond titanium system photocatalysis polyester non-woven fabric.It is irradiated in 1W 365nm LED light source
Under, it is detected by standard QB/T 2761-2006 and GB/T20944.2-2007, the degradation efficiency of formaldehyde in air can reach
99%, 96% can reach to the degradation efficiency of benzene homologues, 98% is reached to the bacteriostasis rate of staphylococcus aureus.Washing 6 times, light
Catalytic efficiency only declines 12%.
Embodiment 3
Appropriate nylon fiber (equivalent 1 gram of surface free amine group), two (triethanolamine) metatitanic acid diisopropyls are added in container
1 gram of ester, 200 grams of ethyl alcohol react 2 hours at 60 DEG C.It is added 0.05 gram of ferric trichloride, it is 2 that 0.5% phosphorus acid for adjusting pH value, which is added dropwise,
It is hydrolyzed 1 hour under the conditions of 50 DEG C, filtration drying obtains surface bond ferrotianium system photocatalysis nylon material.In 1W 365nm LED light
Under the irradiation of source, detected by standard QB/T 2761-2006 and GB/T20944.2-2007, it can to the degradation efficiency of formaldehyde in air
Reach 99%, 98% can reach to the degradation efficiency of benzene homologues, 99% is reached to the bacteriostasis rate of staphylococcus aureus.Washing 6
Secondary, photocatalysis efficiency only declines 15%.
Embodiment 4
Appropriate polyester polypropylene composite materials non-woven fabrics (equivalent 1 gram of surface free hydroxyl group), titanate esters CS- are added in container
101 1.5 grams, 280 grams of ethyl alcohol of (Nanjing Chuan Shi auxiliary chemicals Co., Ltd), it reacts 2 hours at 65 DEG C.The adjusting of 1% sulfuric acid is added dropwise
PH value hydrolyzes 1 hour under the conditions of being 1,50 DEG C, and filtration drying obtains surface bond titanium system photocatalysis polyester non-woven fabric.In 1W
Under the irradiation of 365nm LED light source, detected by standard QB/T 2761-2006 and GB/T20944.2-2007, to formaldehyde in air
Degradation efficiency can reach 97%, can reach 95% to the degradation efficiency of benzene homologues, reaches to the bacteriostasis rate of staphylococcus aureus
97%.Washing 6 times, photocatalysis efficiency only declines 7%.
Embodiment 5
Appropriate nylon fiber (equivalent 1 gram of surface free amine group), two (triethanolamine) metatitanic acid diisopropyls are added in container
1 gram of ester, 0.19 gram of copper chloride, 200 grams of ethyl alcohol react 50 hours at 80 DEG C.It is 2,30 DEG C of conditions that 3% salt acid for adjusting pH value, which is added dropwise,
Lower hydrolysis 1 hour, filtration drying obtains surface bond titanium system photocatalysis nylon material.Under the irradiation of 1W 365nm LED light source,
It is detected by standard QB/T 2761-2006 and GB/T20944.2-2007, the degradation efficiency of formaldehyde in air can reach
98.5%, 95.5% can reach to the degradation efficiency of benzene homologues, 99.2% is reached to the bacteriostasis rate of staphylococcus aureus.Washing
6 times, photocatalysis efficiency only declines 7%.
Comparative example 1
Appropriate nylon fiber (equivalent 1 gram of surface free amine group), 1 gram of tetraethyl titanate, ethyl alcohol 200 are added in container
Gram, it is reacted 2 hours at 60 DEG C.Filtration drying obtains surface attachment titanium system photocatalysis nylon material.In 1W 365nm LED light source
Under irradiation, detected by standard QB/T 2761-2006 and GB/T20944.2-2007, to the degradation efficiency 27% of formaldehyde in air,
To the degradation efficiency 15% of benzene homologues, 11% is reached to the bacteriostasis rate of staphylococcus aureus.Washing 1 time, photocatalysis efficiency is only
Decline 90%.
Comparative example 2
Appropriate nylon fiber (equivalent 1 gram of surface free amine group), two (triethanolamine) metatitanic acid diisopropyls are added in container
1 gram of ester, 200 grams of ethyl alcohol react 2 hours at 60 DEG C.Filtration drying obtains the nylon material of surface bond titanium sub-group compound.In
Under the irradiation of 1W365nm LED light source, detected by standard QB/T 2761-2006 and GB/T20944.2-2007, to formaldehyde in air
Degradation efficiency can reach 26%, 23% can reach to the degradation efficiency of benzene homologues, the bacteriostasis rate of staphylococcus aureus is reached
To 31%.
Only to explain more typical example of the invention as described in embodiment, not the present invention is made in any form
Limitation, it is all to make any modification or change for the present invention under identical spirit, it is intended to be included in that the invention is intended to protect
Within the scope of shield, i.e., with those skilled in the art, it can not depart from and its parameter is made into different journeys under basic principle of the invention
The variation of degree, to scheme to reach equivalent or similar effect, so it should all be considered as being defined without departing from above-described the scope of the patents
In.
Claims (10)
1. a kind of preparation method of the catalysis material for airstrainer, which is characterized in that the catalysis material is abundant
It is exposed to strainer high molecular material surface layer and photocatalytic degradation is carried out to air pollutants, which comprises the steps of:
The surface free group of high molecular material react forming surface bond with titanate compound in alcohols solvent
Titanate esters group, reaction temperature are 0~80 DEG C, and the reaction time is 0.1~100h, in which: surface free group, titanate esters chemical combination
The mass ratio of object and alcohols solvent is 1:0.1~3:1~1000；
Using acid solution adjusting pH value to 1~6, the titanate esters group of surface bond obtains titanyl macromolecular structure via hydrolysis,
The temperature condition of the hydrolysis is 0~100 DEG C, and the reaction time of the hydrolysis is 0.5~20h.
2. preparation method as described in claim 1, it is characterised in that: the hydrolysis further includes that other metallic compounds are added
Cohydrolysis is carried out, heteropoly acid macromolecular structure is formed, the additional amount of other metallic compounds is the matter of titanate compound
The 0.01~0.99, preferably 0.02~0.2 of amount, other described metallic compounds are selected from: ferric trichloride, ferrous chloride, dichloro
Change one or more of manganese, alchlor, cobalt chloride, nickel chloride, copper chloride or zinc chloride.
3. preparation method as described in claim 1, it is characterised in that: the acid solution is selected from: hydrochloric acid solution, sulfuric acid solution,
One or more of phosphoric acid solution, formic acid solution or acetic acid solution, the mass percent solubility of the acid solution is 0.1~
10%.
4. preparation method as described in claim 1, it is characterised in that: the alcohols solvent is selected from: in methanol, ethyl alcohol or propyl alcohol
One or more.
5. preparation method as described in claim 1, it is characterised in that: the high molecular material is selected from: polypropylene, polyethylene,
One or more of polyester, nylon, polyurethane, glass or cellulose blend or copolymer.
6. preparation method as described in claim 1, it is characterised in that: the surface free group contains hydroxyl, amino, carboxylic
One or more of base, aldehyde radical or ester group.
7. preparation method as described in claim 1, it is characterised in that: the titanate compound is selected from: more alkoxy metatitanic acids
One or more of ester, monoalkoxy pyrophosphoric acid base titanate esters, tetraethyl titanate, metatitanic acid orthocarbonate or butyl titanate.
8. a kind of catalysis material for airstrainer, it is characterised in that: wanted using any right in such as claim 1-7
The method is asked to be prepared, the wave-length coverage of the photocatalysis light source of the catalysis material is 250~700nm.
9. carrying out photocatalysis to indoor air pollutants for the catalysis material of airstrainer as claimed in claim 8
Application in degradation.
10. application as claimed in claim 9, the air pollutants include: formaldehyde, acetaldehyde, benzene homologues, amine system object, sulphur system
One or more of object, nitrogen oxides, nicotine, staphylococcus aureus.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11128681A (en) * | 1997-10-31 | 1999-05-18 | Hitachi Ltd | Air cleaner |
| CN1756599A (en) * | 2003-03-05 | 2006-04-05 | Nbc株式会社 | Photocatalytic material |
| CN102600905A (en) * | 2012-02-20 | 2012-07-25 | 合肥工业大学 | Semiconductor hetero-junction/conductive polymer fiber membrane composite photocatalyst and preparation method thereof |
| CN103230812A (en) * | 2013-03-07 | 2013-08-07 | 苏州新纶超净技术有限公司 | Photocatalytic air filtering material and preparation method thereof |
| CN107308992A (en) * | 2017-08-23 | 2017-11-03 | 浙江理工大学 | A kind of photocatalytic fiber net and its preparation method and application |
-
2019
- 2019-08-28 CN CN201910804066.9A patent/CN110433870A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11128681A (en) * | 1997-10-31 | 1999-05-18 | Hitachi Ltd | Air cleaner |
| CN1756599A (en) * | 2003-03-05 | 2006-04-05 | Nbc株式会社 | Photocatalytic material |
| CN102600905A (en) * | 2012-02-20 | 2012-07-25 | 合肥工业大学 | Semiconductor hetero-junction/conductive polymer fiber membrane composite photocatalyst and preparation method thereof |
| CN103230812A (en) * | 2013-03-07 | 2013-08-07 | 苏州新纶超净技术有限公司 | Photocatalytic air filtering material and preparation method thereof |
| CN107308992A (en) * | 2017-08-23 | 2017-11-03 | 浙江理工大学 | A kind of photocatalytic fiber net and its preparation method and application |
Non-Patent Citations (1)
| Title |
|---|
| 董永春, 上海：东华大学出版社 * |
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