CN110433643A - A kind of highly effective energy-conserving environmental-protecting type chilling tower - Google Patents

A kind of highly effective energy-conserving environmental-protecting type chilling tower Download PDF

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Publication number
CN110433643A
CN110433643A CN201910800790.4A CN201910800790A CN110433643A CN 110433643 A CN110433643 A CN 110433643A CN 201910800790 A CN201910800790 A CN 201910800790A CN 110433643 A CN110433643 A CN 110433643A
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CN
China
Prior art keywords
section
chilling tower
flue gas
waste heat
temperature flue
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910800790.4A
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Chinese (zh)
Inventor
周长城
林则全
周良
杨云周
卢翔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huatian Engineering and Technology Corp MCC
Original Assignee
Huatian Engineering and Technology Corp MCC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huatian Engineering and Technology Corp MCC filed Critical Huatian Engineering and Technology Corp MCC
Priority to CN201910800790.4A priority Critical patent/CN110433643A/en
Publication of CN110433643A publication Critical patent/CN110433643A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/60Simultaneously removing sulfur oxides and nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/68Halogens or halogen compounds
    • B01D53/70Organic halogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/30Alkali metal compounds
    • B01D2251/304Alkali metal compounds of sodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/30Alkali metal compounds
    • B01D2251/306Alkali metal compounds of potassium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/20Halogens or halogen compounds
    • B01D2257/206Organic halogen compounds
    • B01D2257/2064Chlorine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Abstract

The invention discloses a kind of highly effective energy-conserving environmental-protecting type chilling towers, belong to fume treatment technical field.The present invention includes chilling tower ontology, the chilling tower ontology is made of spray section, waste heat exhausting section and high-temperature flue gas entry section, the top of chilling tower ontology offers cryogenic gas outlet, the bottom end of chilling tower ontology offers dirt mud outlet, the inside of the spray section is arranged at intervals with spray head, the outer wall of the waste heat exhausting section is equipped with waste heat recovery pipe road, and the surface of high-temperature flue gas entry section is communicated with venturi nozzle, fume treatment pipe is provided at the nozzle of venturi nozzle.The present invention is ensured using chilling and chemical method are double, has not only guaranteed efficiently quickly cooling, dedusting, desulphurization denitration and removal dioxins concentration, but also can make full use of flue gas heat, effectively energy-saving, reduces production cost.

Description

A kind of highly effective energy-conserving environmental-protecting type chilling tower
Technical field
The present invention relates to fume treatment technical fields, more specifically to a kind of highly effective energy-conserving environmental-protecting type chilling tower.
Background technique
Currently, national environmental protection regulation is increasingly strict, proposes rigors to the discharge aspect of atmosphere pollution, burns in rubbish It burns, dangerous waste incineration system and field of steel metallurgy, chilling tower is chilling and dust removal process are carried out to high-temperature dust-containing flue gas important Equipment, and existing chilling tower has some limitations in terms of energy conservation and environmental protection, does not have for the sensible heat of high-temperature flue gas Effect utilizes, and causes a degree of waste, and dioxin is mostly to be adsorbed on flue dust in solid form under cryogenic Surface (primary attachment is on fine grained surface), therefore efficiently chilling and dedusting are that the means of dioxin are effectively reduced.For above Problem, need to design one kind can efficiently chilling, dedusting, effectively absorb and removal dioxin, and high-temperature flue gas can be made full use of aobvious The energy saving and environment friendly chilling tower of heat, solves the above problems.
Summary of the invention
1. technical problems to be solved by the inivention
In view of the defects existing in the prior art with deficiency, the present invention provides a kind of highly effective energy-conserving environmental-protecting type chilling towers, originally Invention can either substantially reduce dust, desulphurization denitration, removal dioxin, and can sufficiently recycle high-temperature flue gas sensible heat, using chilling With the double guarantees of chemical method, quickly cooling, dedusting, desulphurization denitration and removal dioxins concentration were not only guaranteed efficiently, but also can be abundant It is effectively energy-saving using flue gas heat, reduce production cost.
2. technical solution
In order to achieve the above objectives, technical solution provided by the invention are as follows:
A kind of highly effective energy-conserving environmental-protecting type chilling tower of the invention, including chilling tower ontology, the chilling tower ontology is by spraying Section, waste heat exhausting section and high-temperature flue gas entry section composition are drenched, the top of chilling tower ontology offers cryogenic gas outlet, chilling tower The bottom end of ontology offers dirt mud outlet, and the inside of the spray section is arranged at intervals with spray head, the output end of spray head Embedded with atomizer, the bottom of spray section is connected to waste heat exhausting section, and the outer wall laying of the waste heat exhausting section has surplus heat back Closed tube road, waste heat recovery pipe road are intervally arranged on the surface of waste heat exhausting section, and the bottom of the waste heat exhausting section is connected to high temperature Smoke inlet section, the surface of high-temperature flue gas entry section are communicated with venturi nozzle, the external high-temperature flue gas of venturi nozzle, venturi Be provided with fume treatment pipe at the nozzle of nozzle, the fume treatment pipe pass through from bottom to top the inner wall of chilling tower ontology and with Venturi nozzle is connected to, and is passed through alkaline solution inside fume treatment pipe.
Further, the spray head input terminal is by the external alkaline solution of pipeline, alkaline solution select NaOH, KOH, Ca(OH)2Or ammonium hydroxide.
Further, the waste heat recovery pipe road upper and lower ends are circulating line, and middle part uses the vertical segment pipe of solid matter It is attached, water or air is passed through in pipeline.
Further, the spray section, the inner wall masonry of high-temperature flue gas entry section have refractory material.
3. beneficial effect
Using technical solution provided by the invention, compared with prior art, have the following beneficial effects:
The present invention can either substantially reduce dust, desulphurization denitration, removal dioxin, and it is aobvious sufficiently to recycle high-temperature flue gas Heat, by the way that high-temperature dust-containing flue gas is carried out step cooling, make flue-gas temperature be chilled to from 1000 DEG C of high temperature or more 200 DEG C hereinafter, Dust-laden high-temperature flue gas is sprayed into chilling tower by inlet high speed, while being passed through alkaline solution in inlet, and alkaline solution is by high speed Air-flow hits and is atomized, and preliminary cooling dedusting and removal dioxin and acidic materials etc. is carried out, when flue gas enters chilling tower sheet When internal, chilling tower top continue spray alkaline solution further cool down, dedusting and absorption dioxin, using chilling with Chemical method is double to be ensured, has not only guaranteed efficient quickly cooling, dedusting, desulphurization denitration and removal dioxins concentration, but also can be sufficiently sharp It is effectively energy-saving with flue gas heat, reduce production cost.
Detailed description of the invention
Fig. 1 is overall structure figure of the invention.
In figure: 1, chilling tower ontology;11, spray section;12, waste heat exhausting section;13, high-temperature flue gas entry section;14, low temperature gas Body outlet;15, dirt mud outlet;2, spray head;21, atomizer;3, waste heat recovery pipe road;4, venturi nozzle;5, flue gas Processing pipe.
Specific embodiment
The invention will be further described with reference to the accompanying drawings and examples:
Embodiment 1
It will be seen from figure 1 that a kind of highly effective energy-conserving environmental-protecting type chilling tower of the present embodiment, including chilling tower ontology 1, chilling Tower ontology 1 is made of spray section 11, waste heat exhausting section 12 and high-temperature flue gas entry section 13, spray section 11, high-temperature flue gas entry section 13 inner wall masonry has refractory material, in order to fully ensure that waste heat recovering effect, 12 inner wall of waste heat exhausting section do not build fire proofed wood Material, the top of chilling tower ontology 1 offer cryogenic gas outlet 14, and the bottom end of chilling tower ontology 1 offers dirt mud outlet 15, The inside of spray section 11 is arranged at intervals with spray head 2, and 2 input terminal of spray head passes through the external alkaline solution of pipeline, alkaline solution choosing With NaOH, KOH, Ca (OH)2Or ammonium hydroxide, the output end of spray head 2 are embedded with atomizer 21, spray head 2 sprays into from top to bottom Alkaline solution makes final outlet cigarette to SOx, NOx in the cooling of high-temperature dust-containing flue gas further chilling, dedusting and removal flue gas Temperature degree is quickly down to 200 DEG C hereinafter, dioxin effectively removes rate up to 99%, and flue dust is greatly reduced, subsequent to reduce Dedusting investment cost, the bottom of spray section 11 are connected to waste heat exhausting section 12, and the outer wall of waste heat exhausting section 12 is laid with the recycling that has surplus heat Pipeline 3, waste heat recovery pipe road 3 are intervally arranged on the surface of waste heat exhausting section 12, and 3 upper and lower ends of waste heat recovery pipe road are ring pipe Road, middle part are attached using the vertical segment pipe of solid matter, water or air are passed through in pipeline, when flue gas enters in chilling tower ontology 1 When, it can be passed through water in waste heat recovery pipe road 3 or air carries out heat exchange, with obvious heat of smoke in abundant recovery tower, after heating High temperature air or vapor can be used as secondary energy sources recycling, reduce production cost, the bottom connection of waste heat exhausting section 12 High-temperature flue gas entry section 13, the surface of high-temperature flue gas entry section 13 are communicated with venturi nozzle 4, the external high temperature of venturi nozzle 4 Flue gas, fume treatment pipe 5 is provided at the nozzle of venturi nozzle 4, and fume treatment pipe 5 passes through chilling tower ontology 1 from bottom to top Inner wall and be connected to venturi nozzle 4,4 internal diameter of venturi nozzle be in local contraction shape, when high-temperature dust-containing flue gas passes through contraction Duan Shi, because contraction section sectional area becomes smaller, so that flue gas flow rate is increased rapidly along pipe, in inlet, high speed sprays into chilling tower ontology 1 Interior, speed at aditus laryngis is passed through alkaline solution inside fume treatment pipe 5, alkaline solution is selected generally up to 50~60m/s NaOH、KOH、Ca(OH)2Or ammonium hydroxide, alkaline solution are hit and be atomized by high-speed flows, as high-temperature dust-containing flue gas is high together Speed sprays into chilling tower ontology 1, high velocity impact and mixing due to the two, not only carries out preliminary cooling dedusting to high-temperature flue gas, The effective chlorine source of producible dioxin can be reduced, to achieve the purpose that reduce dioxin production quantity, and one can also be reached Determine degree desulfurization off sulfide effect.
High-temperature flue gas entry section 13 uses venturi-type structure, when high-temperature dust-containing flue gas passes through contraction section, flue gas flow rate It increases rapidly along pipe, is contacted rapidly with the alkaline solution being passed through in fume treatment pipe 5, form high speed atomisation shape jet stream and spray into rapidly In chilling tower ontology 1.
SOx, NOx acidic materials in alkaline solution absorption high-temperature flue gas, by alkaline solution in high-temperature flue gas SOx, NOx acidic materials carry out abundant neutralization reaction, generate sulfate or Nitrates substance etc., play the role of desulphurization denitration, Alkaline solution can also absorb HCl and Cl in high-temperature flue gas2Substance, principle pass through alkaline solution (such as NaOH, KOH, Ca (OH)2Or ammonium hydroxide etc.) coming into full contact with and mixing with high-temperature flue gas, absorb the HCl and Cl in flue gas2Generation NaCl (KCl, NH4Cl or CaCl2) etc. substances, and in turn inhibit HCl decompose generate Cl2, to achieve the purpose that reduce effective chlorine source, can make can The chlorine source for generating dioxin reduces 60%~80%, and dioxin production quantity is effectively reduced.
The present invention can either substantially reduce dust, desulphurization denitration, removal dioxin, and it is aobvious sufficiently to recycle high-temperature flue gas Heat, by the way that high-temperature dust-containing flue gas is carried out step cooling, make flue-gas temperature be chilled to from 1000 DEG C of high temperature or more 200 DEG C hereinafter, Dust-laden high-temperature flue gas is sprayed into chilling tower by inlet high speed, while being passed through alkaline solution in inlet, and alkaline solution is by high speed Air-flow hits and is atomized, and preliminary cooling dedusting and removal dioxin and acidic materials etc. is carried out, when flue gas enters chilling tower sheet When in body 1, chilling tower top continue spray alkaline solution further cooled down, dedusting and absorption dioxin, using chilling With the double guarantees of chemical method, quickly cooling, dedusting, desulphurization denitration and removal dioxins concentration were not only guaranteed efficiently, but also can be abundant It is effectively energy-saving using flue gas heat, reduce production cost.
Schematically the present invention and embodiments thereof are described above, description is not limiting, institute in attached drawing What is shown is also one of embodiments of the present invention, and actual structure is not limited to this.So if the common skill of this field Art personnel are enlightened by it, without departing from the spirit of the invention, are not inventively designed and the technical solution Similar frame mode and embodiment, are within the scope of protection of the invention.

Claims (4)

1. a kind of highly effective energy-conserving environmental-protecting type chilling tower, including chilling tower ontology (1), it is characterised in that: the chilling tower ontology (1) it is made of spray section (11), waste heat exhausting section (12) and high-temperature flue gas entry section (13), the top of chilling tower ontology (1) is opened (14) are exported equipped with cryogenic gas, the bottom end of chilling tower ontology (1) offers dirt mud outlet (15), the spray section (11) Inside be arranged at intervals with spray head (2), the output end of spray head (2) is embedded with atomizer (21), the bottom of spray section (11) Portion is connected to waste heat exhausting section (12), and the outer wall of the waste heat exhausting section (12) is equipped with waste heat recovery pipe road (3), waste heat recycling Pipeline (3) is intervally arranged on the surface of waste heat exhausting section (12), and the bottom of the waste heat exhausting section (12) is connected to high-temperature flue gas Entrance (13), the surface of high-temperature flue gas entry section (13) are communicated with venturi nozzle (4), venturi nozzle (4) external high temperature Flue gas is provided with fume treatment pipe (5) at the nozzle of venturi nozzle (4), and the fume treatment pipe (5) passes through from bottom to top The inner wall of chilling tower ontology (1) is simultaneously connected to venturi nozzle (4), is passed through alkaline solution inside fume treatment pipe (5).
2. a kind of highly effective energy-conserving environmental-protecting type chilling tower according to claim 1, it is characterised in that: the spray head (2) Input terminal selects NaOH, KOH, Ca (OH) by the external alkaline solution of pipeline, alkaline solution2Or ammonium hydroxide.
3. a kind of highly effective energy-conserving environmental-protecting type chilling tower according to claim 1, it is characterised in that: the waste heat recovery pipe Road (3) upper and lower ends are circulating line, and middle part is attached using the vertical segment pipe of solid matter, and water or air are passed through in pipeline.
4. a kind of highly effective energy-conserving environmental-protecting type chilling tower according to claim 1, it is characterised in that: the spray section (11), the inner wall masonry of high-temperature flue gas entry section (13) has refractory material.
CN201910800790.4A 2019-08-28 2019-08-28 A kind of highly effective energy-conserving environmental-protecting type chilling tower Pending CN110433643A (en)

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CN201910800790.4A CN110433643A (en) 2019-08-28 2019-08-28 A kind of highly effective energy-conserving environmental-protecting type chilling tower

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Application Number Priority Date Filing Date Title
CN201910800790.4A CN110433643A (en) 2019-08-28 2019-08-28 A kind of highly effective energy-conserving environmental-protecting type chilling tower

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110906751A (en) * 2019-12-05 2020-03-24 中冶华天南京工程技术有限公司 Electric furnace flue gas quenching device
CN111974726A (en) * 2020-08-31 2020-11-24 合肥江海智慧泵站数据科技有限责任公司 Ash discharging device of quenching pump station

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201832555U (en) * 2010-11-05 2011-05-18 中国石油化工股份有限公司 Optimized two-circulating flue gas dust removal and desulfurization device
JP2012081451A (en) * 2010-10-14 2012-04-26 Babcock Hitachi Kk Apparatus and method for treating flue gas coming from combustion apparatus of oxygen combustion type, and wet-type method and apparatus for desulfurizing flue gas for use therein
CN206549365U (en) * 2017-01-11 2017-10-13 丁顺成 Emission-control equipment
CN108325275A (en) * 2018-03-15 2018-07-27 无锡市泰新环保科技有限公司 The combined cooling method and combined cooler of high-temperature oil gas
CN108534564A (en) * 2018-05-31 2018-09-14 北京宏帆态金节能科技有限公司 A kind of high-temperature flue gas quenching apparatus

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012081451A (en) * 2010-10-14 2012-04-26 Babcock Hitachi Kk Apparatus and method for treating flue gas coming from combustion apparatus of oxygen combustion type, and wet-type method and apparatus for desulfurizing flue gas for use therein
CN201832555U (en) * 2010-11-05 2011-05-18 中国石油化工股份有限公司 Optimized two-circulating flue gas dust removal and desulfurization device
CN206549365U (en) * 2017-01-11 2017-10-13 丁顺成 Emission-control equipment
CN108325275A (en) * 2018-03-15 2018-07-27 无锡市泰新环保科技有限公司 The combined cooling method and combined cooler of high-temperature oil gas
CN108534564A (en) * 2018-05-31 2018-09-14 北京宏帆态金节能科技有限公司 A kind of high-temperature flue gas quenching apparatus

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110906751A (en) * 2019-12-05 2020-03-24 中冶华天南京工程技术有限公司 Electric furnace flue gas quenching device
CN111974726A (en) * 2020-08-31 2020-11-24 合肥江海智慧泵站数据科技有限责任公司 Ash discharging device of quenching pump station

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Application publication date: 20191112