CN110423534A - A kind of transparent fireproof coating system and its application in wood-structure old building - Google Patents
A kind of transparent fireproof coating system and its application in wood-structure old building Download PDFInfo
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- CN110423534A CN110423534A CN201910693411.6A CN201910693411A CN110423534A CN 110423534 A CN110423534 A CN 110423534A CN 201910693411 A CN201910693411 A CN 201910693411A CN 110423534 A CN110423534 A CN 110423534A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/16—Homopolymers or copolymers of vinylidene fluoride
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of transparent fireproof coating system, it is made of transparent fire-resisting paint coating and transparent protective coating coating two parts, the transparent fire-resisting paint is made of component A and component B, the component A based on parts by weight, is made of following component: 10-40 parts of epoxy resin, 10-30 parts of pentaerythrite, 0-40 parts of phosphatase 11,15-30 parts of solvent, 0.5-5 parts of auxiliary agent, 0.5-5 parts of fire-retardant filler;Melamine 20-50 parts in component B, 10-40 parts of urea, 15-40 parts of solvent, 0.5-5 parts of auxiliary agent, 0.5-5 parts of fire-retardant filler, 20-45 parts of formaldehyde.The transparent protective coating based on parts by weight, is made of following component: 20-40 parts of fluororesin, 0.05-2 parts of coupling agent, 50-70 parts of solvent, 1-10 parts of auxiliary agent.The coating system is used for wood-structure old building, has excellent adhesive force, transparency, environmental suitability etc..
Description
Technical field
The present invention relates to historic building structure fireproofing technique field, in particular to a kind of transparent fireproof coating system and its
Application in wood-structure old building.
Background technique
Ancient building is the rarity of world civilization, has special historical value, cultureal value.Once being caught fire etc. no by appearance
Reversible destruction, loss be it is immeasurable, 2018,2019 occur Brazilian museums and Notre Dame de Paris high fire
Caused loss, it may be said that be the disaster of the whole mankind.China is ancient building historical relic big country, is especially possessed numerous excellent exhausted
Human relations, highly skilled wood-structure old building;In history, it is exactly fire that wood-structure old building, which saves a difficult big reason,.Existing rank
Section fireproof coating is widely used in steel construction, concrete tunnel field, but leads in timber structure field, especially historic building structure
There is also following disadvantages in domain:
(1) poor transparency.Any additional safeguard procedures cannot all influence the aesthetic effect of historic building structure itself, and mesh
Preceding transparent fireproof coating, transparency are generally bad.
(2) environmental suitability is poor.The coating that any one is used in timber outmost surface, it is necessary to have good water-fast, resistance to
The performances such as light aging, resistance to alternation of wetting and drying, just can guarantee long-term effect, and this exactly existing transparent fireproof coating is more difficult overcomes
The problem of.
(3) fire protecting performance is poor.According to test method specified in GB12441-2018 " finishing fire retardant paint ", timber structure
Fire resistant coating is 220 DEG C by areographic pole limit temperature, fire resistance period >=15min, but for wooden structures, 180 DEG C or more timber tables
There is irreversible destruction (charing) in face, and historic building structure category historical relic scarce resource, be impatient at it is any irreversible
Destruction.Obviously, it is excessively high for limiting 220 DEG C of temperature for ancient building by areographic pole, it is therefore necessary to further increase fire prevention
Performance enhances heat insulation.
Summary of the invention
In order to overcome the deficiencies of the prior art, transparency, environmental resistance, the fire protecting performance of timber structure fire resistant coating are improved,
The present invention provides a kind of historic building structure dedicated transparent fire resistant coating system.
Technical scheme is as follows:
A kind of transparent fireproof coating system is made of transparent fire-resisting paint coating and transparent protective coating coating two parts,
Wherein transparent fire-resisting paint coating layer thickness is 0.5-1mm, and overweight coating, the transparency is bad, will affect historic building structure itself
Aesthetic effect, cover light, fire protecting performance be deteriorated;The transparent protective coating coating layer thickness is 0.01-0.02mm.
The transparent fire-resisting paint is made of component A and component B, the component A based on parts by weight, by following component system
At:
10-40 parts of epoxy resin, 10-30 parts of pentaerythrite, 0-40 parts of phosphatase 11,15-30 parts of solvent, 0.5-5 parts of auxiliary agent,
0.5-5 parts of fire-retardant filler.
The component B based on parts by weight, is made of following component: 20-50 parts of melamine, 10-40 parts of urea, and solvent
15-40 parts, 0.5-5 parts of auxiliary agent, 0.5-5 parts of fire-retardant filler, 20-45 parts of formaldehyde.
Wherein, component A and component B be in mass ratio are as follows: and component A: component B=80-100:100-150, it is used after mixing,
Component B dosage is too large or too small, will affect fire protecting performance, and requirement of the invention is not achieved.
Wherein, it is preferred that the epoxy resin is any one or a few in E-03, E-09, E-12, E-20, E-51.
Wherein, it is preferred that the fire-retardant filler is ammonium polyphosphate (degree of polymerization be greater than 1000), aluminium hydroxide, zinc borate, double
Any one or a few in cyanamide etc.;The wherein preferred ammonium polyphosphate of fire-retardant filler in component A, the fire-retardant filler in component B
It is preferred that aluminium hydroxide and dicyandiamide compounding, compound proportion 1:(1-1.5).
Wherein, it is preferred that selected solvent is any one or a few in formaldehyde, ethyl alcohol, ring ethyl ketone, n-butanol etc..
Wherein, it is preferred that selected auxiliary agent is the high-molecular block copolymer wetting and dispersing of the affinity groups of activity containing pigment
Agent, polyester modification dimethyl silicone polymer surface modifier, any one or a few in modified polyurea auxiliary rheological agents.
The preparation method of component A in turn includes the following steps:
(1) epoxy resin is stirred to 20min-40min in cyclohexanone until homogeneous transparent;(2) by pentaerythrite and molten
Agent is added in phosphoric acid, stirring, until sufficiently esterification, coreaction 1h-1.5h;(3) liquid that will be prepared in epoxy resin, step (2)
Body, fire-retardant filler, auxiliary agent mixing, stir 10min-15min, grind into sand mill, fineness≤10 μm, filter, packaging.
The preparation method of component B in turn includes the following steps: (1) melamine, urea, formaldehyde in a solvent stirred,
It is heated to certain temperature, starts synthetic reaction, until homogeneous transparent, 2h-2.5h;(2) step is added in fire-retardant filler, auxiliary agent
(1) the liquid mixing prepared in, stirs 10min-15min, grinds into sand mill, fineness≤10 μm, filter, packaging.
The transparent protective coating coating is historic building structure special protection coating, is one-component coating, with parts by weight
Number meter, is made of following component:
20-40 parts of fluororesin, 0.05-2 parts of coupling agent, 50-70 parts of solvent, 1-10 parts of auxiliary agent.Wherein, it is preferred that described
Fluororesin be vinylidene fluoride, chlorotrifluoroethylene, containing any two in the fluorochemical monomers such as fluorobenzene ethene or it is several be copolymerized, fluorine
Resin weight average molecular weight (Mw) is 5-8 ten thousand, and inherent viscosity (deciliter/gram) is 0.6-0.9.
The molecular weight of fluororesin is controlled 50,000-8 ten thousand, the hydrophobicity and reduction of transparent protective coating can be effectively improved
Flue gas content in fire resisting test improves fire prevention expander consistency;Meanwhile molecular weight is too low, the mechanical properties such as toughness of coating
It is deteriorated, molecular weight is excessively high, and not readily dissolves in a solvent, carries out coating.In addition, although the fluororesin of perfluorocarbon backbone is with excellent
Different hydrophobicity, ageing-resistant performance, but usually molecular-chain polarr is lower, and physical and chemical adsorption ability is poor, and coating is caused to adhere to
Power is bad.Therefore select it is one or more of with fluororesin coupling agent excellent in compatibility, by in transparent fire-resisting paint coating
The mode that active function groups generate chemical bonding improves the adhesive force of transparent protective coating coating and transparent fire-resisting paint coating, thoroughly
The adhesive force of bright protective coating coating and transparent fire-resisting paint coating is too low, will affect coating system overall adhesion of the present invention,
Coating system is easy to fall off, and the adhesive force of transparent protective coating coating and transparent fire-resisting paint coating is excessively high, transparent protective coating
Coating solvents will cause volume contraction when volatilizing, and be easy to influence the adhesive force of transparent fire-resisting paint coating and historic building structure.
Preferably, selected coupling agent is selected from ammonia (amine) hydrocarbyl si lanes coupling agent, epoxyhydrocarbyl silane coupling agent, methacryloxypropyl hydrocarbon
The one or more of base silane coupling agent, these types of coupling agent can satisfy the requirement of coating system adhesive force.
Preferably, selected solvent is any one or a few in ethyl acetate, toluene, acetone, butyl acetate etc..
The preparation method of the transparent protective coating in turn includes the following steps: (1) by fluororesin, solvent, auxiliary agent, coupling
30min~1h is stirred in agent, is stirred evenly, clear, colorless, can be packed.
It, will be transparent anti-when use the invention also includes application of the above transparent fireproof coating system in wood-structure old building
Fiery coating and transparent protective coating are coated on wood-structure old building.
The invention has the following advantages:
1, historic building structure dedicated transparent fire resistant coating system has excellent adhesive force, transparency, environmental suitability
Etc. mechanical properties.
2, fire protecting performance is excellent, good heat-insulation effect, and fire resistant coating is 180 DEG C by areographic pole limit temperature, and fire resistance period >=
15min。
Specific embodiment
It is below that the technical scheme in the embodiment of the invention is clearly and completely described to the present invention.It is stated
Embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff every other embodiment obtained without making creative work, belongs to guarantor of the invention
Protect range.
Auxiliary agent in component A is high molecular weight polyurethane type dispersing agent: trade mark BYK163.
The ammonium polyphosphate trade mark in component A is AP422.
Auxiliary agent in component B are as follows: BYK163, organosilicon wetting agent BYK306 or anti-settling agent BYK410.
Coupling agent in transparent protective coating coating are as follows: N- (β-aminoethyl)-γ-aminopropyltrimethoxysilane, the trade mark
6020。
Auxiliary agent in protective coating coating are as follows: (trade mark) BYK410 or BYK306.
A kind of historic building structure transparent fire-resisting paint, comprising two components of A and B (separately packaging), component A is shown in Table 1, list
Position is parts by weight.
1 component A of table formula
The preparation process of component A: epoxy resin (1) is stirred to 30min in cyclohexanone until homogeneous transparent;(2) by season
Penta tetrol and solvent are added in phosphoric acid, stirring, until sufficiently esterification, 1h;(3) liquid that will be prepared in epoxy resin, step (2)
Body, ammonium polyphosphate, auxiliary agent mixing, stir 10min, grind into sand mill, fineness≤10 μm, filter, packaging.
Component B is shown in Table 2, and unit is parts by weight.
2 component B of table formula
Serial number | Constituent | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
1 | Melamine | 20 | 25 | 22 | 30 |
2 | Urea | 20 | 25 | 20 | 25 |
3 | Formaldehyde | 44 | 32.5 | 37 | 23 |
4 | N-butanol | 22 | 15 | 27 | 20 |
5 | BYK163 | 1 | 0.5 | 1 | 0.5 |
6 | BYK306 | 0.5 | 0.5 | 0.5 | — |
7 | BYK410 | 0.5 | 0.5 | 0.5 | 0.5 |
9 | Aluminium hydroxide | 1 | 0.5 | 1 | 0.5 |
10 | Dicyandiamide | 1 | 0.5 | 1 | 0.5 |
The preparation process of component B: (1) stirring melamine, urea, formaldehyde in a solvent, is heated to certain temperature 70
DEG C -75 DEG C, start synthetic reaction, until homogeneous transparent, total 2h;(2) dicyandiamide, aluminium hydroxide, auxiliary agent are added in step (1)
The liquid of preparation mixes, and stirs 10min, grinds into sand mill, fineness≤10 μm, filters, packaging.
A kind of historic building structure dedicated transparent protective coating, wherein fluororesin vinylidene fluoride, chlorotrifluoroethylene pass through
Emulsion polymerization copolymerization, wherein vinylidene fluoride, chlorotrifluoroethylene comonomer molar ratio be 4:1, weight average molecular weight (Mw) is
5-8 ten thousand, inherent viscosity are 0.6-0.9 deciliter/gram.
Transparent protective coating formula is shown in Table 3, and unit is parts by weight.
The transparent protective coating formula of table 3
Serial number | Constituent | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
1 | Fluororesin | 20 | 25 | 30 | 40 |
2 | Ethyl acetate | 77 | 72 | 68 | 57.5 |
3 | BYK306 | 1 | 1 | 1 | 1 |
4 | BYK410 | 1 | 1 | 0.5 | 0.5 |
5 | Coupling agent | 1 | 1 | 1 | 1 |
The preparation process of historic building structure dedicated transparent protective coating: (1) fluororesin, solvent, auxiliary agent, coupling agent are stirred
30min is mixed, is stirred evenly, clear, colorless, packaging.
The component A of each embodiment transparent fire-resisting paint and component B is mixed by weight 1:1.5 when use, coated in wood
Transparent protective coating is applied on structure ancient building, after surface drying.
A kind of historic building structure dedicated transparent fire resistant coating system (design of matching system), is shown in Table 4.
Table 4
Above-described embodiment product is pressed into GB12441-2018 " finishing fire retardant paint ", GB/T1738-1979 " insulated paint paint
Film water absorption rate measuring method ", GB/T1865-2009 " paint and varnish artificial weathering aging and man-made radiation exposure ", GB/T2410-
2008 " measurements of transparent plastic light transmittance and mist degree " have carried out performance test respectively, and test result is shown in Table 5.
Table 5
A kind of historic building structure dedicated transparent fire resistant coating system of the invention as can be seen from Table 5, hence it is evident that improve
Fire protecting performance, environmental resistance, the transparency of conventional transparent fireproof coating system, test index are significantly better than standard requirements.
Comparative example 1
The coupling agent of transparent protective coating is replaced with into vinyl dimethoxysilane on the basis of embodiment 1, it is other
It is same as Example 1.
Comparative example 2
The coupling agent dosage of transparent protective coating is increased to 2.5 parts on the basis of embodiment 1, solvent ethyl acetate
Dosage is 75.5 parts, other same as Example 1.
Comparative example 3
The fire-retardant filler dicyandiamide that example 1 group is divided in B is removed, aluminium hydroxide dosage is changed to 2 parts, other and embodiment
1 is identical.
Comparative example 4
The fire-retardant filler aluminium hydroxide that example 1 group is divided in B is removed, dicyandiamide dosage is changed to 2 parts, other and embodiment
1 is identical.
Above-mentioned comparative example product is pressed into GB12441-2018 " finishing fire retardant paint ", GB/T1738-1979 " insulated paint paint
Film water absorption rate measuring method ", GB/T1865-2009 " paint and varnish artificial weathering aging and man-made radiation exposure ", GB/T2410-
2008 " measurements of transparent plastic light transmittance and mist degree " have carried out performance test respectively, and test result is shown in Table 6.
Table 6
From comparative example 1 as can be seen that the silane few using active group, can make transparent protective coating coating prevent with transparent
The adhesive force of fiery paint coatings is too low, influences coating system overall adhesion of the present invention, and coating is easy to fall off;The survey of comparative example 2
Test result quite, is not listed herein with embodiment 1, it is seen that is increased the dosage of coupling agent, is acted on unobvious;From comparative example 3-4
As can be seen that fire-retardant filler dicyandiamide and aluminium hydroxide is in transparent fire-resisting paint formula system of the invention, fire protecting performance and
There is synergistic effect in terms of heat insulation.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, made any modification, equivalent replacement, improvement etc. should all be within protection scope of the present invention.
Claims (10)
1. a kind of transparent fireproof coating system, which is characterized in that by transparent fire-resisting paint coating and transparent protective coating coating two
Part forms, wherein the transparent fire-resisting paint coating layer thickness is 0.5-1mm, the transparent protective coating coating layer thickness is
0.01-0.02mm。
2. transparent fireproof coating system according to claim 1, it is characterised in that the transparent fire-resisting paint by component A and
Component B is made, and the component A based on parts by weight, is made of following component: 10-40 parts of epoxy resin, pentaerythrite 10-30
Part, 0-40 parts of phosphatase 11,15-30 parts of solvent, 0.5-5 parts of auxiliary agent, 0.5-5 parts of fire-retardant filler;
The component B based on parts by weight, is made of following component: 20-50 parts of melamine, 10-40 parts of urea, and solvent 15-
40 parts, 0.5-5 parts of auxiliary agent, 0.5-5 parts of fire-retardant filler, 20-45 parts of formaldehyde.
3. transparent fireproof coating system according to claim 2, it is characterised in that component A and component B are in mass ratio are as follows: group
Divide A: component B=80-100:100-150.
4. transparent fireproof coating system according to claim 2, it is characterised in that the epoxy resin be E-03, E-09,
Any one or a few in E-12, E-20, E-51.
5. transparent fireproof coating system according to claim 2, it is characterised in that the fire-retardant filler is ammonium polyphosphate, hydrogen
Aluminium oxide, zinc borate, any one or a few in dicyandiamide;The solvent is formaldehyde, in ethyl alcohol, cyclohexanone, n-butanol
Any one or a few;The auxiliary agent be the affinity groups of activity containing pigment high-molecular block copolymer wetting dispersing agent,
Any one or a few in polyester modification dimethyl silicone polymer surface modifier, modified polyurea auxiliary rheological agents.
6. transparent fireproof coating system according to claim 2, it is characterised in that the preparation method of the component A is successively wrapped
Include following steps:
(1) epoxy resin is stirred to 20min~40min in cyclohexanone until homogeneous transparent;(2) pentaerythrite and solvent are added
Enter in phosphoric acid, stir, until sufficiently esterification;(3) liquid, fire-retardant filler, auxiliary agent that prepare in epoxy resin, step (2) is mixed
It closes, stirs 10min-15min, ground into sand mill, fineness≤10 μm, filtered, packaging;
The preparation method of the component B in turn includes the following steps: (1) melamine, urea, formaldehyde in a solvent stirred,
60 DEG C -80 DEG C are heated to, synthetic reaction is started, until homogeneous transparent;(2) preparation in step (1) is added in fire-retardant filler, auxiliary agent
Liquid mixing, stir 10min-15min, into sand mill grind, fineness≤10 μm, filter, packaging.
7. transparent fireproof coating system according to claim 1, it is characterised in that the transparent protective coating coating is single
Component coating is made of following component based on parts by weight: 20-40 parts of fluororesin, 0.05-2 parts of coupling agent, and solvent 50-70
Part, 1-10 parts of auxiliary agent.
8. transparent fireproof coating system according to claim 7, it is characterised in that the fluororesin is vinylidene fluoride, three
Fluorine vinyl chloride, containing any two in the fluorochemical monomers such as fluorobenzene ethene or it is several be copolymerized, fluororesin weight average molecular weight be 5-8
Ten thousand, inherent viscosity is 0.6~0.9 deciliter/gram.
9. transparent fireproof coating system according to claim 7, it is characterised in that the coupling agent is selected from amino-alkyl silicane
One or more of coupling agent, epoxyhydrocarbyl silane coupling agent, methacryloxypropyl hydrocarbyl si lanes coupling agent;The solvent
For any one or a few in ethyl acetate, toluene, acetone, butyl acetate.
10. application of -9 any transparent fireproof coating systems in wood-structure old building according to claim 1.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111004560A (en) * | 2019-12-24 | 2020-04-14 | 青海民族大学 | Coating for protecting ancient buildings |
CN113277884A (en) * | 2021-04-20 | 2021-08-20 | 福建省晋江市丹豪陶瓷有限公司 | High-temperature-resistant wear-resistant all-digital rock plate and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1789349A (en) * | 2005-12-02 | 2006-06-21 | 袁雪祥 | Dedicated overprint varnish for fire retardant coating on steel structure and its production method |
CN105907232A (en) * | 2016-06-08 | 2016-08-31 | 四川卓安新材料科技有限公司 | Wood structure flame-retardant transparent paint |
-
2019
- 2019-07-30 CN CN201910693411.6A patent/CN110423534B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1789349A (en) * | 2005-12-02 | 2006-06-21 | 袁雪祥 | Dedicated overprint varnish for fire retardant coating on steel structure and its production method |
CN105907232A (en) * | 2016-06-08 | 2016-08-31 | 四川卓安新材料科技有限公司 | Wood structure flame-retardant transparent paint |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111004560A (en) * | 2019-12-24 | 2020-04-14 | 青海民族大学 | Coating for protecting ancient buildings |
CN113277884A (en) * | 2021-04-20 | 2021-08-20 | 福建省晋江市丹豪陶瓷有限公司 | High-temperature-resistant wear-resistant all-digital rock plate and preparation method thereof |
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