CN110423416A - A kind of reflective insulation PVC waterproof roll and preparation method thereof - Google Patents
A kind of reflective insulation PVC waterproof roll and preparation method thereof Download PDFInfo
- Publication number
- CN110423416A CN110423416A CN201910675578.XA CN201910675578A CN110423416A CN 110423416 A CN110423416 A CN 110423416A CN 201910675578 A CN201910675578 A CN 201910675578A CN 110423416 A CN110423416 A CN 110423416A
- Authority
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- China
- Prior art keywords
- parts
- reflective insulation
- waterproof roll
- pvc waterproof
- coupling agent
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- Granted
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- 238000009413 insulation Methods 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 238000005096 rolling process Methods 0.000 title description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 28
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000007822 coupling agent Substances 0.000 claims abstract description 21
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 17
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 17
- 239000011734 sodium Substances 0.000 claims abstract description 17
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 17
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011591 potassium Substances 0.000 claims abstract description 16
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000004014 plasticizer Substances 0.000 claims abstract description 14
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 13
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 13
- 239000003549 soybean oil Substances 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 11
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 11
- 239000012745 toughening agent Substances 0.000 claims abstract description 10
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 9
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000008116 calcium stearate Substances 0.000 claims abstract description 9
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 9
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 9
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000008117 stearic acid Substances 0.000 claims abstract description 9
- 239000004611 light stabiliser Substances 0.000 claims abstract description 6
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000012790 adhesive layer Substances 0.000 claims description 10
- 239000010410 layer Substances 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 238000003490 calendering Methods 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 claims description 7
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 238000002955 isolation Methods 0.000 claims description 4
- 238000004804 winding Methods 0.000 claims description 4
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 claims 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 31
- 230000003712 anti-aging effect Effects 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 238000004134 energy conservation Methods 0.000 abstract description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 35
- 229920000915 polyvinyl chloride Polymers 0.000 description 35
- 230000005855 radiation Effects 0.000 description 8
- 238000010276 construction Methods 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 230000032683 aging Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical group [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- BJAJDJDODCWPNS-UHFFFAOYSA-N dotp Chemical compound O=C1N2CCOC2=NC2=C1SC=C2 BJAJDJDODCWPNS-UHFFFAOYSA-N 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004605 External Lubricant Substances 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- -1 dioctyl ester Chemical class 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000002783 friction material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/245—Vinyl resins, e.g. polyvinyl chloride [PVC]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D5/00—Roof covering by making use of flexible material, e.g. supplied in roll form
- E04D5/10—Roof covering by making use of flexible material, e.g. supplied in roll form by making use of compounded or laminated materials, e.g. metal foils or plastic films coated with bitumen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2427/00—Presence of halogenated polymer
- C09J2427/006—Presence of halogenated polymer in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2495/00—Presence of bitume
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of reflective insulation PVC waterproof rolls and preparation method thereof.By weight, including component: 100 parts of PVC resin powder；20~60 parts of plasticizer；10~30 parts of toughener；4~6 parts of epoxidized soybean oil；2~5 parts of heat stabilizer；Potassium hexatitanate and/or 3~12 parts of sodium hexatitanate；3~5 parts of titanium dioxide；0.2~0.5 part of stearic acid；0.1~0.4 part of calcium stearate；0.2~2 part of antioxidant；0.2~2 part of light stabilizer；20~40 parts of calcium carbonate；0.1~0.5 part of coupling agent.The coiled material has excellent dimensional stability and reflective insulation performance, and preferable mechanical property, low-temperature flexibility and anti-aging property, long product lifecycle, energy conservation and environmental protection are particularly suitable for the exposed use of roofing.
Description
Technical field
The present invention relates to building material technical fields, and in particular to a kind of reflective insulation PVC waterproof roll and its preparation side
Method.
Background technique
PVC waterproof roll belongs to flexible waterproof material, compared with modified asphalt waterproof coiled material and water-repellent paint, has and uses
The convenient advantage of service life length, environmental protection, working drawing review.Currently, in the market PVC waterproof roll be used for roof waterproof when, there is also
Ageing-resistant performance and the bad defect of dimensional stability.
In addition, roofing contacts direct irradiation of sunlight, roof can only reflect the solar radiation of 10-20% under normal conditions,
Most solar radiation is all absorbed by building roof or exterior wall, and after absorbing solar radiation, interior of building temperature is increased, and is increased
Add air conditioner refrigerating electricity consumption, China is used for construction material heating every year and air-conditioning consumption accounts for about whole society's total energy consumption
20% or so.For this purpose, people have now been developed that many is anti-for roof reflector solar radiation or heat-insulated material, such as infrared ray
Insulating moulding coating, plastic foamboard, rock wool board, inorganic or organic heat-insulating slurry etc. are penetrated, these materials will be compound with waterproof material
Using to realize roof waterproof and heat insulation function, construction is mostly first to do insulating layer, and waterproof layer is re-layed on insulating layer, or
Reflective insulation layer is re-layed on waterproof layer, is separately constructed, process is more, and it is at high cost, and quality is difficult to ensure.
Summary of the invention
Existing PVC waterproof roll has that ageing-resistant performance, dimensional stability and heat-proof quality are bad, to solve this
One problem can reflect most solar radiation, and thermally conductive system in a first aspect, providing a kind of reflective insulation PVC waterproof roll
Number is low, has reflection and obstructs dual heat insulation prevention heat and transmit inwards, so that interior of building temperature be effectively reduced.Room
Face need to only be laid with one layer of coiled material, and heat preservation and water-proof function can be realized.Meanwhile the coiled material good stability of the dimension, ageing resistance
Can be excellent, service life extends, low in cost, it can be achieved that energy conservation and environmental protection purpose.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of reflective insulation PVC waterproof roll, by weight, including following components:
100 parts of PVC resin powder；20~60 parts of plasticizer；10~30 parts of toughener；4~6 parts of epoxidized soybean oil；Thermostabilization
2~5 parts of agent；Potassium hexatitanate and/or 3~12 parts of sodium hexatitanate；3~5 parts of titanium dioxide；0.2~0.5 part of stearic acid；Calcium stearate
0.1~0.4 part；0.2~2 part of antioxidant；0.2~2 part of light stabilizer；20~40 parts of calcium carbonate；0.1~0.5 part of coupling agent.
Preferably, the plasticizer is dioctyl phthalate (DOP), tributyl citrate (TBC), terephthalic acid (TPA)
At least one of dioctyl ester (DOTP), trioctyl trimellitate (TOTM) (TOTM).
Preferably, the heat stabilizer is lead salt stabilizer and/or Ca-Zn composite heat stabilizer.
Preferably, the coupling agent is at least one of silane coupling agent, titanate coupling agent, aluminate coupling agent.
Second aspect provides a kind of self-adhering-type reflective insulation PVC waterproof roll, including above-mentioned reflective insulation PVC waterproof roll
Material and the self-adhesive layer and separation layer being successively set on the reflective insulation PVC waterproof roll.
Preferably, the self-adhesive layer is non-bituminous base hot-fusible pressure-sensitive adhesive self-adhesive layer.
The third aspect provides a kind of preparation method of reflective insulation PVC waterproof roll, comprising steps of
Batch mixer is added in PVC resin powder, toughener, heat stabilizer, plasticizer, epoxy soybean are added under stirring
Oil, after plasticizer, epoxidized soybean oil are fully absorbed by PVC resin powder, be added sodium hexatitanate and/or potassium hexatitanate, calcium carbonate,
Titanium dioxide, coupling agent are uniformly mixed, and add remaining ingredient mixing, cooling, discharging；
Mixture is squeezed out through screw extruder, calendering formation, and winding obtains reflective insulation PVC waterproof roll.
Preferably, procession parameters are as follows: barrel temperatures set at 140~160 DEG C, die temperature 165~
175 DEG C, the control of driving screw machine revolving speed draws 230~270r/min of revolving speed in 25~35r/min.
Preferably, it before winding, further comprises the steps of: and the PVC sheet of calendering formation is coated into melt pressure sensitive by glue spreader
Glue, and cover isolation film.
The one or more embodiments of the present invention at least have the advantages that
Sodium hexatitanate, potassium hexatitanate have very high infrared reflection rate and low thermal conductivity, are applied to this formula
System can assign PVC waterproof roll excellent reflective insulation function, reduce absorption and transmission of the coiled material to solar radiation, rise
To the effect of cooling and insulating, and coiled material good stability of the dimension, product machine-shaping shrinking percentage is low, has preferable intensity, just
Degree and anti-aging property are particularly suitable for the exposed use of roofing, and only need to be laid with one layer of coiled material can be realized waterproof and heat-insulation and heat-preservation
Effect, long product lifecycle, energy conservation and environmental protection.
Specific embodiment
Below by specific embodiment, the present invention will be described in detail.
A kind of reflective insulation PVC waterproof roll, by weight, including following components: 100 parts of PVC resin powder；Plasticizer
20~60 parts；10~30 parts of toughener；4~6 parts of epoxidized soybean oil；2~5 parts of heat stabilizer；Potassium hexatitanate and/or sodium hexatitanate
3~12 parts；3~5 parts of titanium dioxide；0.2~0.5 part of stearic acid；0.1~0.4 part of calcium stearate；0.2~2 part of antioxidant；Light is steady
Determine 0.2~2 part of agent；20~40 parts of calcium carbonate；0.1~0.5 part of coupling agent.Each component is reasonably combined, can overcome well existing
There are PVC waterproof roll ageing-resistant performance, dimensional stability and the bad defect of heat-proof quality, for example, potassium hexatitanate, sodium hexatitanate
Heat insulating reflecting and humidification are mainly played, stearic acid and calcium stearate are used separately as in-lubricant and external lubricant, epoxy soybean
PVC anti-aging property can be improved in oil, and titanium dioxide plays reinforcement, anti-aging and filling effect etc..Due to leading to above-mentioned excellent properties
Crossing laying single layer coiled material can be realized excellent waterproof, heat-insulated dual function, and coiled material long service life is easy for construction, can extend
The application of PVC waterproof roll, particularly suitable for the waterproof construction of roofing or terrace etc., long product lifecycle, section
It can environmental protection.
Specifically, sodium hexatitanate microscopic appearance is column, potassium hexatitanate microscopic appearance is crystal whisker-shaped, is all had very high red
Outside line reflectivity and lower thermal coefficient can be reduced absorption and transmission of the coiled material to solar radiation, play cooling and insulating
Effect.Since sodium hexatitanate and/or potassium hexatitanate can be anti-most of infrared ray that object can be caused to heat up in solar radiation
It is emitted back towards in atmosphere, therefore coiled material surface temperature reduces, anti-aging property improves, and service life extends.
The prior art prepares friction material using potassium hexatitanate mostly, also discloses its application in insulating moulding coating, but
That the dispersity of potassium hexatitanate directly affects material or coating performance, it usually needs it is carried out individual surface it is modified at
Reason, technique is relatively complicated, in addition, the mode of coating insulating moulding coating is difficult to ensure prolonged heat insulating reflecting effect.Currently, having no
There is the report that sodium hexatitanate, potassium hexatitanate are used for PVC roll material, it is even more important that inventors have found that in this formula system
In, without carrying out surface modification treatment to inorganic material, coupling agent is directly added into it is dry-mixed in raw material, then can through extrusion molding
To obtain, heat-proof quality is good, product machine-shaping shrinking percentage is low, intensity, rigidity and the preferable PVC roll material of anti-aging property.Its
In, coupling agent can be silane coupling agent, titanate coupling agent, aluminate coupling agent etc..
Calcium carbonate is preferably precipitated calcium carbonate, and partial size preferably 2000~5000 mesh can reduce coiled material cost.For plasticising
Agent, toughener, heat stabilizer, antioxidant, light stabilizer can use type well known in the art.For example, plasticizer can be
DOP, TBC, DOTP, TOTM etc..Toughener can be CPE, NBR, MBS resin, esters of acrylic acid etc., wherein CPE chlorinty with
35%~37% be it is best, NBR be preferably in nitrile grade, acrylonitrile content is preferably near 30%.Heat stabilizer can be lead salt
Stabilizer and/or Ca-Zn composite heat stabilizer.Antioxidant is preferably composite antioxidant, can use antioxidant 1010 and antioxidant
168 compoundings.Light stabilizer can be ultraviolet absorbing agent.
Further, self-adhesive layer and separation layer are set gradually on reflective insulation PVC waterproof roll, self-adhering-type reflection is made
Heat-insulated PVC waterproof roll realizes using self-adhesive layer and base and completely glues that water-proof function is reliable, easy for construction, low in cost, can mention
High construction efficiency reduces construction cost.Wherein, self-adhesive layer is preferably non-bituminous base hot-fusible pressure-sensitive adhesive self-adhesive layer.
In the following Examples and Comparative Examples, PVC resin powder is SG-3 type, the degree of polymerization 1300；Toughener is CPE, and chlorine contains
Amount 37%, remaining percent crystallization in massecuite≤2% are purchased from Qingdao sea crystallization factory, or are NBR, trade mark NBR2707, acrylonitrile content 27
~30%, it is purchased from Lanzhou Petrochemical；0.2~1.0 μm of sodium hexatitanate diameter, 3~10 μm of length, 0.2~1.0 μ of potassium hexatitanate diameter
M, is purchased from Tangshan metal whisker composite Manufacturing Co., Ltd by 10~80 μm of length；Calcium carbonate is precipitated calcium carbonate, 3000 mesh；
Titanium dioxide is rutile-type R105；Light stabilizer is ultraviolet absorbent UV-531；Heat stabilizer is lead sulfate tribasic or calcium
Zn composite heat stabilizer；Plasticizer is DOP.
Embodiment 1
Coiled material formula includes following components: 100 parts of PVC resin powder, DOP35 parts, CPE15 parts, 5 parts of epoxidized soybean oil, three
5 parts of alkali lead sulfate, 10 parts of sodium hexatitanate, 5 parts of titanium dioxide, 0.5 part of titanate coupling agent, 0.3 part of stearic acid, calcium stearate
0.4 part, 0.4 part of antioxidant 1010,0.2 part of irgasfos 168,0.5 part of UV-531,30 parts of calcium carbonate.
Embodiment 2
Coiled material formula includes following components: 100 parts of PVC resin powder, DOP35 parts, CPE15 parts, 5 parts of epoxidized soybean oil, three
5 parts of alkali lead sulfate, 10 parts of potassium hexatitanate, 5 parts of titanium dioxide, 0.5 part of titanate coupling agent, 0.3 part of stearic acid, calcium stearate
0.4 part, 0.4 part of antioxidant 1010,0.2 part of irgasfos 168,0.5 part of UV-531,30 parts of calcium carbonate.
Embodiment 3
Coiled material formula includes following components: 100 parts of PVC resin powder, DOP35 parts, NBR15 parts, 5 parts of epoxidized soybean oil, calcium
5 parts of Zn composite heat stabilizer, 5 parts of potassium hexatitanate, 5 parts of sodium hexatitanate, 5 parts of titanium dioxide, 0.5 part of titanate coupling agent, stearic acid
0.3 part, 0.4 part of calcium stearate, 0.4 part of antioxidant 1010,0.2 part of irgasfos 168,0.5 part of UV-531,30 parts of calcium carbonate.
Embodiment 4
Coiled material formula includes component: 100 parts of PVC resin powder, DOP35 parts, CPE15 parts, 5 parts of epoxidized soybean oil, calcium zinc it is multiple
Close 5 parts of heat stabilizer, 5 parts of sodium hexatitanate, 5 parts of titanium dioxide, 0.5 part of titanate coupling agent, 0.3 part of stearic acid, calcium stearate 0.4
Part, 0.4 part of antioxidant 1010,0.2 part of irgasfos 168,0.5 part of UV-531,30 parts of calcium carbonate.
The coiled material preparation method of embodiment 1-4:
(1) material mixture: weighing each component by weight, and mixing first is added in PVC resin powder, toughener, heat stabilizer
Plasticizer, epoxidized soybean oil is added in mixing in machine, abundant by PVC resin powder in plasticizer, epoxidized soybean oil
After absorption, sodium hexatitanate, calcium carbonate, titanium dioxide, coupling agent is added, is uniformly mixed, is eventually adding remaining components mixing, works as mixing
When temperature is up to 120 DEG C, material is cooled to and is discharged lower than 40 DEG C.
(2) extrusion-calendering: mixture is squeezed out through screw extruder, calendering formation.Barrel temperatures set is 140~160
DEG C, for die temperature at 165~175 DEG C, the control of driving screw machine revolving speed draws 230~270r/ of revolving speed in 25~35r/min
min。
(3) gluing-covers isolation film: the PVC sheet through calendering formation coats non-bituminous base hot-fusible pressure-sensitive adhesive by glue spreader,
And isolation film is covered, it then winds, detect, cutting, packaging.
Comparative example 1
Referring to embodiment 1, difference is coiled material formula: 10 parts of sodium hexatitanate is replaced with to 8 parts of hollow glass micropearl
With 2 parts of titanium dioxide (i.e. titanium dioxide total amount is 7 parts).
Coiled material preparation method is same as Example 1, and difference is only that the type of above-mentioned inorganic filler is different.
Table 1
Product basic performance is detected according to GB 12952-2011 " polyvinylchloride waterproof roll " standard.
Reflective insulation performance is detected using self-control test device.Home-made contrivance: it is placed above polystyrene foam case
Test sample places an infrared lamp direct irradiation sample at 300mm right above sample, and a band insertion is fixed inside bubble chamber
Formula thermometer, precision ± 0.1 DEG C, -50 DEG C of range~110 DEG C, thermometer probe are close to below sample.Detection method: it opens red
Outer lamp, irradiating sample 60min, recording thermometer displays temperature.
Embodiment 1-4 prepares coiled material and comparative example 1 prepares the performance of coiled material and is relatively shown in Table 1.As can be seen that with comparative example 1
It is compared using the scheme of hollow glass micropearl, the coiled material of embodiment preparation obviously has better dimensional stability and reflective insulation
Performance, mechanical property, low-temperature flexibility and ageing resistance are also more excellent, higher than the standard requirements of GB 12952-2011.And comparative example
1 low-temperature bending is " -24.5 DEG C of flawlesses ", cannot reach the requirement of " -25 DEG C of flawlesses " as defined in the standard.
Above embodiments are explanation of the invention, and still, the invention is not limited to specific in above embodiment
Details, a variety of equivalent substitutes or simple variant side that those skilled in the art carries out within the scope of the technical concept of the present invention
Formula is within the scope of protection of the invention.
Claims (9)
1. a kind of reflective insulation PVC waterproof roll, which is characterized in that by weight, including following components:
100 parts of PVC resin powder；20~60 parts of plasticizer；10~30 parts of toughener；4~6 parts of epoxidized soybean oil；Heat stabilizer 2~
5 parts；Potassium hexatitanate and/or 3~12 parts of sodium hexatitanate；3~5 parts of titanium dioxide；0.2~0.5 part of stearic acid；Calcium stearate 0.1~
0.4 part；0.2~2 part of antioxidant；0.2~2 part of light stabilizer；20~40 parts of calcium carbonate；0.1~0.5 part of coupling agent.
2. reflective insulation PVC waterproof roll according to claim 1, which is characterized in that the plasticizer is O-phthalic
Dioctyl phthalate (DOP), tributyl citrate (TBC), dioctyl terephthalate (DOTP), in trioctyl trimellitate (TOTM) (TOTM)
At least one.
3. reflective insulation PVC waterproof roll according to claim 1, which is characterized in that the heat stabilizer is that lead salt is steady
Determine agent and/or Ca-Zn composite heat stabilizer.
4. reflective insulation PVC waterproof roll according to claim 1, which is characterized in that the coupling agent is silane coupled
At least one of agent, titanate coupling agent, aluminate coupling agent.
5. a kind of self-adhering-type reflective insulation PVC waterproof roll, which is characterized in that including described in claim 1-4 any one
Reflective insulation PVC waterproof roll, and the self-adhesive layer and separation layer that are successively set on the reflective insulation PVC waterproof roll.
6. self-adhering-type reflective insulation PVC waterproof roll according to claim 5, which is characterized in that the self-adhesive layer is non-
Asphaltic base hot-fusible pressure-sensitive adhesive self-adhesive layer.
7. a kind of method for preparing reflective insulation PVC waterproof roll described in claim 1-4 any one, which is characterized in that
Comprising steps of
Batch mixer is added in PVC resin powder, toughener, heat stabilizer, plasticizer, epoxidized soybean oil are added under stirring,
After plasticizer, epoxidized soybean oil are fully absorbed by PVC resin powder, sodium hexatitanate and/or potassium hexatitanate, calcium carbonate, titanium is added
White powder, coupling agent are uniformly mixed, and add remaining ingredient mixing, cooling, obtain mixture；
The mixture is squeezed out through screw extruder, calendering formation, and winding obtains reflective insulation PVC waterproof roll.
8. the method according to the description of claim 7 is characterized in that procession parameters are as follows: barrel temperatures set 140~
160 DEG C, die temperature at 165~175 DEG C, the control of driving screw machine revolving speed in 25~35r/min, draw revolving speed 230~
270r/min。
9. method according to claim 7 or 8, which is characterized in that before winding, further comprise the steps of: calendering formation
PVC sheet coats hot-fusible pressure-sensitive adhesive by glue spreader, and covers isolation film.
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| CN111378238A (en) * | 2020-04-29 | 2020-07-07 | 青岛鸿志道防水工程技术有限责任公司 | Anti-aging waterproof coiled material and preparation method thereof |
| CN114442229A (en) * | 2022-01-27 | 2022-05-06 | 江苏田信塑料光纤有限公司 | Hot-melt-resistant optical fiber and production process thereof |
| CN114479307A (en) * | 2020-10-27 | 2022-05-13 | 中国石油化工股份有限公司 | High-polymerization-degree polyvinyl chloride composition for waterproof roll isolating membrane |
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| CN110423416B (en) | 2022-03-11 |
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Denomination of invention: A reflective and heat-insulating PVC waterproof membrane and its preparation method Granted publication date: 20220311 Pledgee: Changsha Bank Co.,Ltd. Science and Technology Innovation Branch Pledgor: HUNAN SHENYU NEW MATERIAL CO.,LTD. Registration number: Y2024980020718 |