CN110408433A - A kind of method of coal tar production needle coke and BTX - Google Patents
A kind of method of coal tar production needle coke and BTX Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/06—Catalytic processes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
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Abstract
The present invention relates to coal chemical technologies, the method for a kind of coal tar production needle coke and BTX are disclosed, this method comprises: full fraction of coal tar is cut into coal tar light component and coal tar heavy duty component;Coal tar light component enters the first hydrogenation unit and is reacted, the clarified oil of coal tar heavy duty component enters the second hydrogenation unit and is reacted, obtain the raw material of production needle coke, needle coke product is made by delayed coking and calcine technology again, the coal tar light component rich in BTX obtains BTX product by Aromatics Extractive Project.Using method of the invention, thermal expansion coefficient low needle coke product and BTX industrial chemicals can be produced.
Description
Technical field
The present invention relates to coal chemical technologies, and in particular, to a kind of full fraction of coal tar raw material production needle coke and BTX's
Method.
Background technique
Coal is the important fossil energy in China, is accounted in China's non-renewable energy consumption result relatively high.China experienced
30 years rapid economic developments, the consumption of coal resources also increase rapidly.In recent years, China's economic growth rate is gradually
Reduce, and will the long-term growth rate for maintaining high speed, the following industrial transformation upgrading by be China's economy face one
A problem.Cleaning, environmental protection and it is efficient using coal resources by be coal in China industry development inexorable trend.Coal classification benefit
With being developing direction that China vigorously advocated in recent years, objective is efficiently to utilize coal resources.The pass of coal classified utilization
Key link is pyrolysis and the subsequent product processing scheme of coal, and wherein the coai-tar product deep processing of coal pyrolysis produces high value
Product is one of the core technology of coal classified utilization.
Currently, coal tar is mainly for the production of large transportation fuel such as petrol and diesel oil, it is long-term however as oil price
40~60 U.S. dollars/bucket is maintained, the processing scheme for producing transportation fuel by coal tar hydrogenating is economical increasingly to be reduced, special
It is not to be maintained essentially on break even line with the processing scheme of coal tar cutting fraction production petrol and diesel oil product.Therefore, pass through
Coal tar production higher value product is the committed step of coal classified utilization.
Needle coke is the raw material for manufacturing high power and ultra-high power graphite electrode, is had using graphite electrode prepared by needle coke
The advantages that thermal expansion coefficient is low, high mechanical strength, small oxidation susceptibility, currently, needle coke is divided into petroleum base according to the difference of raw material
Needle coke and coal-based needle are burnt, and petroleum-based needle coke is using residual oil or catalytic cracked oil pulp as raw material, and coal-based needle coke is with coal tar
Double distilled be divided into raw material.The needle coke that the country is able to produce at present is petroleum-based needle coke, and the production of coal-based needle coke is not yet
It appears in the newspapers.The country has had been provided with the technology using needle coke production high power electrodes, but there is still a need for a large amount of for needle-shape coke raw material
Import.Therefore, producing needle coke by coal tar has biggish market prospects.
It is produced currently, the progress hydrogenation technique processing of middle coalite tar is prepared diesel oil by domestic coal tar processing corporate boss
Product and a small amount of naphtha product, diesel product have faced the situation that supply exceed demand, therefore the warp of this processing technology at home
Ji property is poor.The heavy constituent of middle coalite tar is and unprocessed because having the characteristics that residual carbon content is high, asphaltene colloid content
Middle coalite tar heavy constituent cannot be directly as the raw material of production needle coke, general enterprises be difficult have suitable process
This part heavy constituent.
CN103013566A discloses a kind of technique using coal tar asphalt production needle-shape coke raw material, and the technique is by pitch
Most of quinoline insolubles in asphalt stock are removed after being sufficiently mixed with solvent, and the pitch of low quinoline insolubles is being carried out to add hydrogen
Thermal decomposition prepares the raw material of needle coke to acquisition.Solvent in this method is the aromatic mixture of BTX or coal base.The party
Method fails organically to tie and the product property feature after coal tar light fraction working process.
CN103509572A discloses a kind of technique using using solvent method preparation high-quality coal-based needle coke, the technique
Solvent insolubles are removed using the method for physical separation after coal measures raw material and solvent are mixed evenly and obtain clarified solution, wherein
Solvent include hydro carbons that 200 DEG C~350 DEG C fraction sections of coal tar or coal tar fraction add 200 DEG C~300 DEG C fractions after hydrogen.It should
Method underuses the property feature production of coal tar light fraction using the coal tar fraction section rich in aromatic hydrocarbons as solvent
High-value product.
CN101538482B discloses a kind of middle coalite tar deep working method, and this method locates middle coalite tar in advance
It is fractionated to obtain light fraction, carbolic oil and heavy distillat after reason, heavy distillat carries out coking and handles to obtain coking gasoline and diesel, coking vapour bavin
Oil mixes the naphtha being hydrocracked as hydrofinishing and the raw material being hydrocracked with light fraction as catalytic reforming
Raw material carries out aromatic hydrocarbons drawer after catalytic reforming and obtains the industrial chemicals such as BTX.This method process is complicated, and fails to make full use of coal
Heavy distillat in tar, therefore the economy of technique is poor.
CN106782979A discloses the technique that coalite tar and hard pitch prepare needle coke in a kind of utilization.The work
The heavy distillat for being greater than 350 DEG C in middle coalite tar is carried out hydropyrolysis reaction by skill, and the heavy constituent of generation is by centrifuge separation
Obtained heavy distillat can be used as the raw material of production needle coke.The technique reduces the quinoline non-soluble in raw material by hydrogenation reaction
The heavy distillat of object, plant investment higher cost, and hydrogenation reaction needs to remove consolidating in heavy distillat by the method for centrifuge separation
Body catalyst, complex process, and underuse the light component of middle coalite tar.
Summary of the invention
The object of the present invention is to provide a kind of full fraction of coal tar raw material production needle coke and BTX (benzene,toluene,xylene)
Method.
To achieve the goals above, this method comprises:
A kind of method of coal tar production needle coke and BTX, this method comprises:
(1) full fraction of coal tar raw material after pretreatment, is cut into coal tar light component and coal tar heavy duty component, coal tar
The cut point of light component and coal tar heavy duty component is 350 DEG C~400 DEG C;
(2) coal tar light component enters the first hydrogenation unit, contacts and is reacted with hydrocracking catalyst, reaction stream
Object obtains adding hydrogen light naphthar plus hydrogen heavy naphtha and hydrogenated diesel oil after separation and fractionation out;
(3) the resulting coal tar heavy duty component of step (1) adds hydrogen heavy naphtha to be mixed with obtained by step (2), obtains clear
Clear liquid and insoluble matter;
(4) clarified solution obtained by step (3) obtains fraction I and fraction II through separation process;
(5) fraction II obtained by step (4) is the coal tar heavy duty component containing low quinoline insolubles, and fraction II enters second plus hydrogen
Unit is contacted with hydrogenation catalyst and is reacted under hydrogenation conditions, and reaction effluent obtains after separation and fractionation
To hydrogen coal tar asphalt is added, the described plus delayed coking of hydrogen coal tar asphalt and calcination process obtain needle coke product;
(6) the fraction I that step (3) obtains is the coal tar light component rich in BTX, and the fraction I is obtained after Aromatics Extractive Project
To BTX product.
Method provided by the invention makes full use of light component and heavy constituent in conjunction with the molecule feature of coal tar different component
Middle composition converts the aromatic hydrocarbons in coal tar light component to the BTX product of high value, and will be polycyclic in coal tar heavy duty component
Aromatic component is converted into the needle coke product of high value, realizes that the utilization efficiency of full fraction of coal tar raw material maximizes and economy is imitated
Benefit maximizes.
Specific embodiment
Detailed description of the preferred embodiments below.It should be understood that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
The endpoint of disclosed range and any value are not limited to the accurate range or value herein, these ranges or
Value should be understood as comprising the value close to these ranges or value.For numberical range, between the endpoint value of each range, respectively
It can be combined with each other between the endpoint value of a range and individual point value, and individually between point value and obtain one or more
New numberical range, these numberical ranges should be considered as specific open herein.
The object of the present invention is to provide it is a kind of by full fraction of coal tar produce the chemical industry material such as needle coke and BTX technique,
This method comprises:
(1) full fraction of coal tar raw material after pretreatment, is cut into coal tar light component and coal tar heavy duty component, coal tar
The cut point of light component and coal tar heavy duty component is 350 DEG C~400 DEG C;
(2) coal tar light component enters the first hydrogenation unit, contacts and is reacted with hydrocracking catalyst, reaction stream
Object obtains adding hydrogen light naphthar plus hydrogen heavy naphtha and hydrogenated diesel oil after separation and fractionation out;
(3) the resulting coal tar heavy duty component of step (1) adds hydrogen heavy naphtha to be mixed with obtained by step (2), obtains clear
Clear liquid and insoluble matter;
(4) clarified solution obtained by step (3) obtains fraction I and fraction II through separation process;
(5) fraction II obtained by step (4) is the coal tar heavy duty component containing low quinoline insolubles, and fraction II enters second plus hydrogen
Unit is contacted with hydrogenation catalyst and is reacted under hydrogenation conditions, and reaction effluent obtains after separation and fractionation
To hydrogen coal tar asphalt is added, the described plus delayed coking of hydrogen coal tar asphalt and calcination process obtain needle coke product;
(6) the fraction I that step (3) obtains is the coal tar light component rich in BTX, and the fraction I is obtained after Aromatics Extractive Project
To BTX product.
In the present invention, the preprocessing process of full fraction of coal tar raw material includes but is not limited to boiling bed hydrogenation process, slurry
Bed hydroprocessing process or other preprocessing process, main purpose are most of metal, the ash contents removed in full fraction of coal tar raw material
Equal impurity.It is preferred that tenor is less than 50 μ g/g, and water content is less than 300 μ in full fraction of coal tar raw material after pretreatment
G/g, content of ashes is less than 0.01 weight %.
In the present invention, full fraction of coal tar raw material after pretreatment, is cut into coal tar light component and coal tar heavy duty component,
The cut point of the preferred coal tar light component and coal tar heavy duty component is 360 DEG C~390 DEG C.
In the one of embodiment of the present invention, the first hydrogenation unit is fixed bed hydrogenation Cracking Unit or slurry bed hydroprocessing
Cracking Unit or boiling bed hydrogenation Cracking Unit.The reaction condition of first hydrogenation unit includes: that reaction pressure is 6~30MPa, instead
Answering temperature is 320~490 DEG C, and volume space velocity is 0.1~5.0h when liquid-1, hydrogen to oil volume ratio is 200~2000.
In the present invention, the first hydrogenation unit is preferably fixed bed hydrogenation Cracking Unit.The fixed bed hydrogenation cracking list
Member is one-part form fixed bed hydrogenation cracking process or is two-part fixed bed hydrogenation cracking process.It is preferred that the fixed bed hydrogenation
The reaction condition of Cracking Unit includes: that reaction pressure is 10~13MPa, and reaction temperature is 350~410 DEG C, volume space velocity when liquid
For 0.5~2.0h-1, hydrogen to oil volume ratio is 800~1500.
Preferably, Hydrobon catalyst and hydrocracking catalyst are loaded in the fixed bed hydrogenation Cracking Unit, with
The filling ratio of stereometer, Hydrobon catalyst and hydrocracking catalyst is 2:8~8:2.Coal tar light component and plus hydrogen
The hetero atoms such as sulphur, nitrogen, the metal in coal tar light component are removed after catalyst for refining contact, and are saturated part aromatic hydrocarbons.Then, with
Hydrocracking catalyst contact carries out hydrocracking reaction, generates dry gas, liquefied gas plus hydrogen light naphthar plus hydrogen heavy naphtha
And hydrogenated diesel oil.
Preferably, the active metal member in the Hydrobon catalyst containing carrier and load on the carrier
Element, the carrier are selected from least one of aluminium oxide, aluminium oxide-silicon oxide and titanium oxide, and the active metallic element is selected from
At least one of nickel, cobalt, molybdenum and tungsten;It is further preferred that in Hydrobon catalyst, with the total of Hydrobon catalyst
The content of poidometer, nickel and/or cobalt in terms of oxide is 1~30 weight %, and the content of molybdenum and/or tungsten in terms of oxide is
5~35 weight %.
Preferably, the active metal member in the hydrocracking catalyst containing carrier and load on the carrier
Element, the carrier contain molecular sieve and selected from least one of aluminium oxide, aluminium oxide-silicon oxide and titanium oxide, the activity
Metallic element is selected from least one of nickel, cobalt, molybdenum and tungsten;The heap density of the hydrocracking catalyst is 0.4~1.3g/
cm3, hydrocracking catalyst average grain diameter is 0.08~1.2mm, and specific surface area is 100~300m2/g;Further preferably
Ground, in hydrocracking catalyst, with the total weight of hydrocracking catalyst, molecular sieve content is 10~60 weight %, with
The nickel of oxide meter and/or the content of cobalt are 1~30%, and the content of molybdenum and/or tungsten in terms of oxide is 5~40 weight %.
In the present invention, the first hydrogenation unit reaction effluent of step (2) obtains after separation and fractionation plus hydrogen pumice brain
Oil plus hydrogen heavy naphtha and hydrogenated diesel oil, it is preferable that add hydrogen light naphthar and the cut point between hydrogen heavy naphtha is added to be 60~85
DEG C, adding the cut point between hydrogen heavy naphtha and hydrogenated diesel oil is 175~190 DEG C;Wherein, the yield for adding hydrogen light naphthar is 10
~20%, adding the yield of hydrogen heavy naphtha is 15~70%, and hydrogenated diesel oil yield is 5~60%.
Preferably, hydrogenated diesel oil is recycled to the first hydrogenation unit entrance and continues to react, and further generates and adds hydrogen scheelite
Cerebrol.
In step of the present invention (3), hydrogen scheelite brain will be added obtained by the resulting coal tar heavy duty component of step (1) and step (2)
Oil is mixed, and clarified solution and insoluble matter are obtained.Wherein the predominant amount of insoluble matter is quinoline insolubles.It is preferred that coal tar heavy duty
Component is 0.1~10 with the mass ratio for adding hydrogen heavy naphtha, and preferred mass ratio is 2~5.
Preferably, in step (3) coal tar heavy duty component with plus hydrogen heavy naphtha mix when temperature be 40 DEG C~120 DEG C,
More preferably 60 DEG C~90 DEG C.
In step of the present invention (4), clarified solution obtained by step (3) obtains fraction I and fraction II through separation process.It is preferred that
Separation process described in step (4) is physical partition method, and the physical partition method includes the separation such as the way of distillation and centrifugal separation
Method, further preferably centrifugal separation.
In the present invention, gained fraction II is the coal tar heavy duty component containing low quinoline insolubles, and fraction II enters second and adds
Hydrogen unit is contacted with hydrogenation catalyst and is reacted under hydrogenation conditions.
Preferably, the hydrogenation catalyst is Fe-series catalyst, more preferably vulcanization iron powder.
Preferably, the mass ratio 0.1~3% of hydrogenation catalyst and fraction II, preferred mass ratio be 0.005~
0.015。
Preferably, auxiliary agent is contained in the Fe-series catalyst, auxiliary agent is oil-soluble CoO and/or MoO3, auxiliary agent and fraction
The mass ratio of II is 0.001~0.02, and preferred mass ratio is 0.005~0.008.
Preferably, in step (5) hydrogenation conditions include: reaction temperature be 350~450 DEG C, hydrogen partial pressure be 4.5~
13.0MPa, hydrogen-oil ratio are 300~1500.
In the present invention, the described plus delayed coking of hydrogen coal tar asphalt and calcination process obtain needle coke product;Described
Delayed coking and calcination process are the technical process of conventional production needle coke.
In the present invention, the fraction I that step (3) obtains is the coal tar light component rich in BTX, and the fraction I takes out through aromatic hydrocarbons
BTX product is obtained after mentioning.The Aromatics Extractive Project is conventional aromatics extraction process.
The present invention will be further described through by embodiment below, but not thereby limiting the invention.
Embodiment 1
The full feedstock of middle coalite tar is pre-processed, the property of the middle full fraction of coalite tar is shown in Table 1.Through pre-
In treated full fraction of coal tar raw material, tenor is 20 μ g/g, and 200 μ g/g of water content, content of ashes is 0.005 weight
Measure %.Full fraction of coal tar raw material after pretreatment is cut into coal tar light component and coal tar heavy duty component by fractionating column,
The cut point of coal tar light component and coal tar heavy duty component is 380 DEG C.
Gained coal tar light component enters the first hydrogenation unit, and the first hydrogenation unit is fixed bed hydrogenation Cracking Unit, according to
Secondary filling Hydrobon catalyst and hydrocracking catalyst, admission space ratio are 1:1.The group of the Hydrobon catalyst
As NiMoW/Al2O3, the group of hydrocracking catalyst is as NiMoW/Al2O3, wherein the mass content of molecular sieve is 31%.
The reaction condition of fixed bed hydrogenation Cracking Unit include: reaction pressure 10.0MPa, hydrofining reaction temperature be 360 DEG C, add hydrogen
Cracking reaction temperature is 370 DEG C, and total volume air speed is 1.0h-1, hydrogen to oil volume ratio 1200.
The reaction effluent of first hydrogenation unit is separated and is fractionated, and the yield for obtaining dry gas is 2%, the receipts of liquefied gas
Rate is 4.0%, and adding the yield of hydrogen light naphthar is 15%, and adding the yield of hydrogen heavy naphtha is 40%, and the yield of hydrogenated diesel oil is
39%.The property of hydrogen weight naphtha and diesel oil is added to be shown in Table 2.
Hydrogen heavy naphtha is added to be mixed in temperature 70 C with coal tar heavy duty component, coal tar heavy duty component and plus hydrogen scheelite brain
The mass ratio of oil after filtering, obtains clarified solution through being sufficiently stirred to obtain clarified solution and insoluble matter after mixing for 5:1.
Gained clarified solution passes through centrifugal separation, obtains fraction I and fraction II.
Gained fraction II, which is contacted into the second hydrogenation unit with hydrogenation catalyst, to be reacted, and the hydrogenation catalyst is sulphur
Change iron powder, vulcanizes iron powder and fraction II and mixed with the ratio of mass ratio 1.5/100, and add the CoO of mass fraction 0.5%
Solution, reaction condition are as follows: hydrogen partial pressure 7.0MPa, 400 DEG C of reaction temperature, the ratio of hydrogen and reaction raw materials is 800Nm3/ ton,
Its reaction effluent obtains adding hydrogen coal tar asphalt after separation and fractionation.
Add hydrogen coal tar asphalt to enter coking tower, in 580 DEG C of coking temperature Coke-oven 6h, obtains the yield of needle coke
45%;The needle coke is calcined under the conditions of 1500 DEG C and obtains ripe coke, thermal expansion coefficient can be obtained by graphitization processing
Graphite electrode less than 1 × 10-6/ DEG C.
The property analysis data of 1 full fraction of coal tar of table
Analysis project | Data |
20 DEG C of density/(g/cm3) | 0.9802 |
Carbon residue/% | 3.98 |
Phenol content/% | 13.92 |
Sulfur content/% | 0.28 |
Nitrogen content/% | 0.67 |
Saturated hydrocarbons/% | 29 |
Aromatic hydrocarbons/% | 49 |
Colloid+asphalitine/% | 22 |
Table 2 plus hydrogen weight naphtha and diesel oil property
Claims (18)
1. a kind of method of coal tar production needle coke and BTX, this method comprises:
(1) full fraction of coal tar raw material after pretreatment, is cut into coal tar light component and coal tar heavy duty component, and light group of coal tar
Divide and the cut point of coal tar heavy duty component is 350 DEG C~400 DEG C;
(2) coal tar light component enters the first hydrogenation unit, contacts and is reacted with hydrocracking catalyst, reaction effluent
It obtains adding hydrogen light naphthar plus hydrogen heavy naphtha and hydrogenated diesel oil after separation and fractionation;
(3) the resulting coal tar heavy duty component of step (1) adds hydrogen heavy naphtha to be mixed with obtained by step (2), obtains clarified solution
And insoluble matter;
(4) clarified solution obtained by step (3) obtains fraction I and fraction II through separation process;
(5) fraction II obtained by step (4) is the coal tar heavy duty component containing low quinoline insolubles, and fraction II enters second plus hydrogen list
Member is contacted with hydrogenation catalyst and is reacted under hydrogenation conditions, and reaction effluent obtains after separation and fractionation
Add hydrogen coal tar asphalt, the described plus delayed coking of hydrogen coal tar asphalt and calcination process obtain needle coke product;
(6) the fraction I that step (3) obtains is the coal tar light component rich in BTX, and the fraction I obtains BTX after Aromatics Extractive Project
Product.
2. the method according to claim 1, wherein in full fraction of coal tar raw material after pretreatment, metal
50 μ g/g of content, 300 μ g/g of water content, 0.01 weight % of content of ashes.
3. the method according to claim 1, wherein the cutting of the coal tar light component and coal tar heavy duty component
Point is 360 DEG C~390 DEG C.
4. the method according to claim 1, wherein the first hydrogenation unit is fixed bed hydrogenation Cracking Unit or slurry
State bed hydroprocessing Cracking Unit or boiling bed hydrogenation Cracking Unit, preferably fixed bed hydrogenation Cracking Unit.
5. method according to claim 1 or 4, which is characterized in that the reaction condition of the first hydrogenation unit includes: reaction pressure
Power is 6~30MPa, and reaction temperature is 320~490 DEG C, and volume space velocity is 0.1~5.0h when liquid-1, hydrogen to oil volume ratio be 200~
2000。
6. according to the method described in claim 4, it is characterized in that, the reaction condition of fixed bed hydrogenation Cracking Unit includes: anti-
Answering pressure is 10~13MPa, and reaction temperature is 350~410 DEG C, and volume space velocity is 0.5~2.0h when liquid-1, hydrogen to oil volume ratio is
800~1500.
7. according to the method described in claim 4, it is characterized in that, loading hydrofinishing in the fixed bed hydrogenation Cracking Unit
Catalyst and hydrocracking catalyst, by volume, the filling ratio of Hydrobon catalyst and hydrocracking catalyst are 2:8
~8:2.
8. the method according to the description of claim 7 is characterized in that containing carrier and load in the Hydrobon catalyst
Active metallic element on the carrier, the carrier in aluminium oxide, aluminium oxide-silicon oxide and titanium oxide at least one
Kind, the active metallic element is selected from least one of nickel, cobalt, molybdenum and tungsten;Preferably, in Hydrobon catalyst, with
The content of the total weight of Hydrobon catalyst, nickel and/or cobalt in terms of oxide is 1~30 weight %, in terms of oxide
Molybdenum and/or tungsten content be 5~35 weight %.
9. the method according to the description of claim 7 is characterized in that containing carrier and load in the hydrocracking catalyst
Active metallic element on the carrier, the carrier contain molecular sieve and selected from aluminium oxide, aluminium oxide-silicon oxide and oxidations
At least one of titanium, the active metallic element are selected from least one of nickel, cobalt, molybdenum and tungsten;The hydrocracking catalyst
The heap density of agent is 0.4~1.3g/cm3, hydrocracking catalyst average grain diameter is 0.08~1.2mm, and specific surface area is
100~300m2/g;Preferably, in hydrocracking catalyst, with the total weight of hydrocracking catalyst, molecular sieve content
For 10~60 weight %, the content of nickel and/or cobalt in terms of oxide is 1~30%, and the molybdenum and/or tungsten in terms of oxide contain
Amount is 5~40 weight %.
10. the method according to claim 1, wherein the first hydrogenation unit reaction effluent is separated and is fractionated
After obtain plus hydrogen light naphthar, plus hydrogen heavy naphtha and hydrogenated diesel oil, add hydrogen light naphthar and add cutting between hydrogen heavy naphtha
Cutpoint is 60~85 DEG C, and adding the cut point between hydrogen heavy naphtha and hydrogenated diesel oil is 175~190 DEG C;Wherein, add hydrogen pumice brain
The yield of oil is 10~20%, and adding the yield of hydrogen heavy naphtha is 15~70%, and hydrogenated diesel oil yield is 5~60%.
11. the method according to claim 1, wherein coal tar heavy duty component and plus hydrogen heavy naphtha in step (3)
Mass ratio be 0.1~10, preferred mass ratio be 2~5.
12. the method according to claim 1, wherein coal tar heavy duty component and plus hydrogen heavy naphtha in step (3)
Temperature when mixing is 40 DEG C~120 DEG C, preferably 60 DEG C~90 DEG C.
13. the method according to claim 1, wherein separation process described in step (4) be physical partition method,
Preferably centrifugal separation.
14. the method according to claim 1, wherein hydrogenation catalyst described in step (5) is iron series catalysis
Agent, preferably vulcanization iron powder.
15. according to claim 1 or method described in 14, which is characterized in that the mass ratio 0.001 of hydrogenation catalyst and fraction II
~0.03, preferred mass ratio is 0.005~0.015.
16. according to the method for claim 14, which is characterized in that contain auxiliary agent in the Fe-series catalyst, auxiliary agent is oil
The CoO and/or MoO of dissolubility3, the mass ratio of auxiliary agent and fraction II are 0.001~0.02, preferred mass ratio is 0.005~
0.008。
17. according to the method described in claim 1, it is 350~450 that hydrogenation conditions, which include: reaction temperature, in step (5)
DEG C, hydrogen partial pressure is 4.5~13.0MPa, and hydrogen-oil ratio is 300~1500.
18. the method according to claim 1, wherein full fraction of coal tar raw material is middle coalite tar raw material.
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CN114395411A (en) * | 2021-12-28 | 2022-04-26 | 陕西凯德利能源科技有限公司 | System and method for preparing mesophase pitch and oil product based on coal tar hydrogenation |
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CN204151302U (en) * | 2014-08-25 | 2015-02-11 | 中国昆仑工程公司 | The device of aromatic hydrocarbons is produced in the multistage deep processing of coalite tar |
CN106281449A (en) * | 2016-10-17 | 2017-01-04 | 北京神雾环境能源科技集团股份有限公司 | A kind of coal tar produces light Fuel and the method and system of needle coke |
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CN114395411A (en) * | 2021-12-28 | 2022-04-26 | 陕西凯德利能源科技有限公司 | System and method for preparing mesophase pitch and oil product based on coal tar hydrogenation |
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