CN110408262A - A kind of ultraviolet light solidification metal powder texture ink and preparation method thereof - Google Patents
A kind of ultraviolet light solidification metal powder texture ink and preparation method thereof Download PDFInfo
- Publication number
- CN110408262A CN110408262A CN201910865067.4A CN201910865067A CN110408262A CN 110408262 A CN110408262 A CN 110408262A CN 201910865067 A CN201910865067 A CN 201910865067A CN 110408262 A CN110408262 A CN 110408262A
- Authority
- CN
- China
- Prior art keywords
- ultraviolet light
- metal powder
- agent
- ink
- texture ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
Abstract
The invention discloses a kind of ultraviolet light solidification metal powder texture ink and preparation method thereof, its key points of the technical solution are that: by the material composition of following components by weight percent: aliphatic urethane acrylate 60~75%, reactive diluent 3~8%, photoinitiator 2~4%, auxiliary agent 5.2~7.8%, silver powder 15~20%, silane coupling agent 2~3%.The object of the present invention is to provide the ultraviolet lights of a kind of film forming water-tolerant, high-tenacity and high stability to solidify metal powder texture ink.
Description
[technical field]
The invention belongs to color crystal glass technical field of ink, and in particular to a kind of ultraviolet light solidification metal powder texture ink
And its preparation and application.
[background technique]
Most of color crystal glass metal ink is all traditional solvent-borne product currently on the market, (such as: poly- by solvent type resin
Ester, aldehyde ketone, CAB, NC, acrylic acid resin, PVB resin), auxiliary agent, the composition such as silver powder, while the solid content of resin only has 10-
15% or so, remaining is entirely that the volatilization of solvent (such as: BCS, PMA, BBE, trimethylbenzene) these organic solvents is big, influences environment
And human health, a small number of qualified ink producers start to substitute traditional solvent based product with UV metal ink thus, due to
There are many disadvantages for UV raw material at present, cause many producers that can not introduce to the market, reason has:
1, not enough, metal-like does not reach requirement for silver powder arrangement；
2, adhesive force is inadequate, it is difficult to deep cure；
3, seriously fall silver, cause intermediate peeling；
4, change colour after boiling, without metal-like, surface of the paint film blistering.
[summary of the invention]
The object of the present invention is to provide the ultraviolet lights of a kind of film forming water-tolerant, high-tenacity and high stability to solidify metal powder
Texture ink.
A kind of of the invention preparation method that ultraviolet light is also provided and solidifies metal powder texture ink.
A kind of ultraviolet light solidification metal powder texture ink, by the material composition of following components by weight percent:
Preferably, the activity is diluted to isobornyl propylene acid esters IBOA and 2- phenoxyethyl acrylate PHEA's
Mixture.Isobornyl propylene acid esters has tough and hard wear resistant, heat-resisting, while having good adhesive force and water resistance.
Preferably, the smooth light lead agent be 1- hydroxyl-cyclohexyl phenyl ketone, -2 methyl-1 phenyl-propanone of 2- hydroxyl, 2,
4,6 trimethylbenzoic acid base diphenyl phosphine oxides, 2,4,6- trimethylbenzoyl phenyl phosphinic acid ethyl esters, isopropyl thioxanthone
One or more of mixture.Photoinitiator is divided into cracking type light lead agent and takes two class of hydrogen photoinitiator by force, and photoinitiator is necessary
When be also used together with other auxiliary components such as photosensitizer with sensitizer, effect be exactly the molecular photoactive in Light Curing
Agent absorbs luminous energy and adjourns to excited state, and by energy transfer to photoinitiator, photoinitiator absorbs can be across adjourning by base after energy
Excited state chemically reacts, and reactive intermediate is generated, thus initiated polymerization.
Preferably, the auxiliary agent includes levelling agent, defoaming agent, wetting dispersing agent, silver powder aligns agent, adhesive force promotes
Agent, anti-lost silver-colored auxiliary agent.
Preferably, the levelling agent provides for Germany BYK, model: BYK323；The product being capable of slight decrease surface
Tension and slipping, the ply adhesion that coating will not be influenced at 250 DEG C, BYK-323 levelling agent, which has, in low luster coating disappears
Light powder orientation；
The defoaming agent provides for the modest chemistry of Taiwan moral, model: 6800；The defoaming agent polysiloxanes is to be suitable for solvent type
The organic silicon defoamer of system has stronger brokenly bubble and foam inhibition ability, while having high efficiency, in low-down additive amount
In the case where have good effect, be particularly suitable for eliminating microvesicle in highly viscous coating and ink system, have and more preferably disappear
Bubble ability；
The wetting dispersing agent provides for Foshan Tag Polymer Sciences Ltd., model: TECH-504S；Wetting effect
Fruit is excellent, can prevent metal oxide and other pigment cooperation in formulation for coating material from making color separation phenomenon, dumb light powder can be improved
Proper alignment keeps paint film more smooth, and scleroma is effectively prevent to generate, and contained polysilane ingredient will not be bad to paint film generation, has
Effect promotes levelling, improves feel；
The silver powder aligns agent and provides for Ji Yan chemical materials Co., Ltd, model: 1468；
The adhesion promoter provides for Changxing Chemical Material (Zhuhai) Co., Ltd., model: 909-X-75；
The anti-lost silver-colored auxiliary agent provides for Chuan Ying Science and Technology Ltd., model: LTW；For solvent-borne formulation adherence resin
Solution improves product corrosion protection performance, improves silver powder adhesion, while improving product flexibility.
Preferably, the silver powder is nano-silver powder, and the particle diameter of the silver powder is less than or equal to 15 nanometers.This product uses
Imitative plating silver powder, metal-like is strong, moderate.
Preferably, the silane coupling agent is one in gamma-mercaptopropyltriethoxysilane or propyl trimethoxy silicane
Kind.Epoxy group is water-fast and heat-resisting better than amido, but amido is relatively more preferable to glass baseplate adhesive force, due to chasing after in our formulas
Seek adhesive force, while comprehensive performance such as water resistance and chemical resistance must be taken into consideration, preferably amino silicane coupling agent as glass lacquer,
The adhesive force such as metallic paint, sulphurated siliastic.
A kind of ultraviolet light solidifies the preparation method of metal powder texture ink, comprising the following steps:
First aliphatic urethane acrylate, reactive diluent, photoinitiator and auxiliary agent are stirred in 600 revs/min of conditions
It mixes 8~10 minutes, silver powder (need to feed intake while stirring) is added in 200 revs/min of stirrings of low speed later, and it is even to add silane after ten minutes
Join agent, then 600 revs/min are stirred 20 minutes, are filtered and packaged.
The present invention compared with the existing technology, has the advantage that
It is the metal ink suitable for color crystal glass that a kind of ultraviolet light of the invention, which solidifies metal powder texture ink, and design exists
Isobornyl propylene acid esters and 2- phenoxyethyl acrylate are introduced in aliphatic urethane acrylate as diluent, are adopted
With nano-silver powder is added in amino silicane coupling agent balanced constant, and silver powder particles solidify less than 15 nanometers by ultraviolet light, make
Film forming system have preferable adhesion while, also have preferable surface hardness, surface because nano-silver powder particle addition,
Silver powder can be effectively improved and arrange inadequate defect, the fine and close surface layer with metal powder perception and feel is formed, due to its energy
It is enough to agree with well with system component, enable film layer deep cure, obtains the film with water resistance, high-tenacity and high stability
Layer；
A kind of ultraviolet light of the invention solidifies the preparation method of metal powder texture ink, process warm and, process is pollution-free row
It puts, is suitble to industrialized production.
[specific embodiment]
1-6 makees ultraviolet light solidification metal powder texture ink and preparation method thereof of the invention combined with specific embodiments below
Further instruction.
A kind of ultraviolet light solidifies the preparation method of metal powder texture ink, comprising the following steps:
First aliphatic urethane acrylate, reactive diluent, photoinitiator and auxiliary agent are stirred in 600 revs/min of conditions
It mixes 8~10 minutes, silver powder (need to feed intake while stirring) is added in 200 revs/min of stirrings of low speed later, and it is even to add silane after ten minutes
Join agent, then 600 revs/min are stirred 20 minutes, are filtered and packaged.
Table 1: embodiment 1-6 each group distribution ratio
Ultraviolet light obtained by Examples 1 to 6 solidifies metal powder texture ink coating color crystal glass paint film, carries out physicochemical property inspection
It is as shown in the table to survey result:
Table 2: coated solidified product paint film test result obtained by Examples 1 to 6
The present invention provides excellent silver arrangements, so that plate face is reached metal effect, while having excellent to glass baseplate
Adhesive force, resistance to 100 DEG C of constant temperature boilings 1 hour, paint film was not any change, and 5 grades of adhesive force, and energy conservation and environmental protection, to human health
Harmless environment-friendly products.
It is the metal ink suitable for color crystal glass that a kind of ultraviolet light of the invention, which solidifies metal powder texture ink, and design exists
Isobornyl propylene acid esters and 2- phenoxyethyl acrylate are introduced in aliphatic urethane acrylate as diluent, are adopted
With nano-silver powder is added in amino silicane coupling agent balanced constant, and silver powder particles solidify less than 15 nanometers by ultraviolet light, make
Film forming system have preferable adhesion while, also have preferable surface hardness, surface because nano-silver powder particle addition,
The fine and close surface layer with metal powder perception and feel is formed, the film layer with water resistance, high-tenacity and high stability is obtained.
Claims (7)
1. a kind of ultraviolet light solidifies metal powder texture ink, it is characterised in that by the material composition of following components by weight percent:
2. a kind of ultraviolet light according to claim 1 solidifies metal powder texture ink, it is characterised in that: the activity dilution
For the mixture of isobornyl propylene acid esters IBOA and 2- phenoxyethyl acrylate PHEA.
3. a kind of ultraviolet light according to claim 1 solidifies metal powder texture ink, it is characterised in that: the smooth light lead agent
For 1- hydroxyl-cyclohexyl phenyl ketone, -2 methyl-1 phenyl-propanone of 2- hydroxyl, the oxidation of 2,4,6 trimethylbenzoic acid base diphenyl
Phosphine, 2, one or more of 4,6- trimethylbenzoyl phenyl phosphinic acid ethyl esters, isopropyl thioxanthone mixture.
4. a kind of ultraviolet light according to claim 1 solidifies metal powder texture ink, it is characterised in that: the auxiliary agent includes
Levelling agent, defoaming agent, wetting dispersing agent, silver powder align agent, adhesion promoter, anti-lost silver-colored auxiliary agent.
5. a kind of ultraviolet light according to claim 1 solidifies metal powder texture ink, it is characterised in that: the silver powder is to receive
The particle diameter of rice silver powder, the silver powder is less than or equal to 15 nanometers.
6. a kind of ultraviolet light according to claim 1 solidifies metal powder texture ink, it is characterised in that: described silane coupled
Agent is one of gamma-mercaptopropyltriethoxysilane or propyl trimethoxy silicane.
7. the preparation method that a kind of ultraviolet light solidifies metal powder texture ink, it is characterised in that the following steps are included:
First by aliphatic urethane acrylate, reactive diluent, photoinitiator and auxiliary agent 600 revs/min of conditions stirring 8~
10 minutes, silver powder (need to feed intake while stirring) was added in 200 revs/min of stirrings of low speed later, added silane coupling agent after ten minutes,
It stirs 20 minutes for 600 revs/min, filters and packages again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910865067.4A CN110408262A (en) | 2019-09-12 | 2019-09-12 | A kind of ultraviolet light solidification metal powder texture ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910865067.4A CN110408262A (en) | 2019-09-12 | 2019-09-12 | A kind of ultraviolet light solidification metal powder texture ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110408262A true CN110408262A (en) | 2019-11-05 |
Family
ID=68370567
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910865067.4A Pending CN110408262A (en) | 2019-09-12 | 2019-09-12 | A kind of ultraviolet light solidification metal powder texture ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110408262A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787235A (en) * | 2009-12-30 | 2010-07-28 | 苏州金海薄膜科技发展有限公司 | Printing ink used for transparent anti-ultraviolet insulating film, insulating film adopting same and fabrication process thereof |
| CN102492330A (en) * | 2011-12-02 | 2012-06-13 | 中山大学 | Ultraviolet (UV) photocurable inkjet ink for glass substrate and preparation method for UV photocurable inkjet ink |
| CN105199476A (en) * | 2015-11-04 | 2015-12-30 | 华南农业大学 | UV-curing transparent insulating ink, and preparation method and application thereof |
| CN108948867A (en) * | 2018-08-17 | 2018-12-07 | 东华大学 | A kind of UV electrically conductive ink and its preparation method and application of suitable fabric silk-screen |
-
2019
- 2019-09-12 CN CN201910865067.4A patent/CN110408262A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787235A (en) * | 2009-12-30 | 2010-07-28 | 苏州金海薄膜科技发展有限公司 | Printing ink used for transparent anti-ultraviolet insulating film, insulating film adopting same and fabrication process thereof |
| CN102492330A (en) * | 2011-12-02 | 2012-06-13 | 中山大学 | Ultraviolet (UV) photocurable inkjet ink for glass substrate and preparation method for UV photocurable inkjet ink |
| CN105199476A (en) * | 2015-11-04 | 2015-12-30 | 华南农业大学 | UV-curing transparent insulating ink, and preparation method and application thereof |
| CN108948867A (en) * | 2018-08-17 | 2018-12-07 | 东华大学 | A kind of UV electrically conductive ink and its preparation method and application of suitable fabric silk-screen |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105176296B (en) | The high-temperature resistant coating being modified based on polysilsesquioxane and its application | |
| CN104530852B (en) | A kind of preparation method of photovoltaic component back plate with high hydrophobic fluorocarbon coating | |
| CN102492330B (en) | Ultraviolet (UV) photocurable inkjet ink for glass substrate and preparation method for UV photocurable inkjet ink | |
| CN102061127B (en) | UV-solidified nanometer inorganic/organic hybrid painting preparation method and application thereof | |
| CN106280698B (en) | High-temperature-resistant PI white label ink and preparation method thereof | |
| CN104194562B (en) | A kind of normal temperature cure monocomponent nanocomposite composite aqueous paint preparation method | |
| CN105969132A (en) | Sanding-free high-fullness unsaturated polyester white primer and preparation method thereof | |
| CN101386765A (en) | Epoxy priming lacquer and method of use thereof | |
| CN109181486A (en) | A kind of epoxy primer and preparation method thereof of low VOC | |
| CN113861808B (en) | Roller-coated UV white primer with excellent UV ink wettability and preparation method thereof | |
| CN102167943A (en) | Black paint for automobile wheel hubs | |
| CN103436124A (en) | Special stoving varnish for oil drum and preparation method of special stoving varnish | |
| CN105802462B (en) | A kind of MODIFIED PP material polyurethane paint and preparation method thereof | |
| CN104726014A (en) | Ultraviolet curing coating raw material and coating prepared from same | |
| CN109868029A (en) | Organic protection coating for reduction process aluminum alloy surface | |
| CN102146228A (en) | UV (Ultra Voilet) radiation curing coating matched with waterborne primer and production and using methods thereof | |
| CN102477246A (en) | High adhesion paint used for a plurality of substrates, and its preparation method and application | |
| CN102863888B (en) | Strippable heat-proof antirust protective film coating and preparation method thereof | |
| CN110982387B (en) | Water-based epoxy coating with good adhesive force and corrosion resistance on surface of metal substrate and preparation method thereof | |
| CN110408262A (en) | A kind of ultraviolet light solidification metal powder texture ink and preparation method thereof | |
| CN113214727A (en) | Preparation method of photo-cured diamond resin composite wear-resistant coating | |
| CN106128549B (en) | A kind of high thixotropic conductive silver paste | |
| CN105315769B (en) | A kind of coloured UV ink of glass | |
| CN104194593A (en) | Ultrahigh-water-resistance coating varnish for artificial stone water transfer printing, and preparation and application methods thereof | |
| CN103387759A (en) | Organic/inorganic hybrid hardening agent, and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191105 |
|
| RJ01 | Rejection of invention patent application after publication |