CN110407588A - A kind of preparation method coating far infrared glaze layer stuffing sand - Google Patents
A kind of preparation method coating far infrared glaze layer stuffing sand Download PDFInfo
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- CN110407588A CN110407588A CN201910539774.4A CN201910539774A CN110407588A CN 110407588 A CN110407588 A CN 110407588A CN 201910539774 A CN201910539774 A CN 201910539774A CN 110407588 A CN110407588 A CN 110407588A
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- far infrared
- stuffing sand
- glaze layer
- parts
- sand
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- 239000004576 sand Substances 0.000 title claims abstract description 81
- 238000002360 preparation method Methods 0.000 title claims abstract description 43
- 239000011248 coating agent Substances 0.000 title claims abstract description 14
- 238000000576 coating method Methods 0.000 title claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 104
- 239000000919 ceramic Substances 0.000 claims abstract description 75
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 28
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000006004 Quartz sand Substances 0.000 claims abstract description 18
- 229910021343 molybdenum disilicide Inorganic materials 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 9
- YXTPWUNVHCYOSP-UHFFFAOYSA-N bis($l^{2}-silanylidene)molybdenum Chemical compound [Si]=[Mo]=[Si] YXTPWUNVHCYOSP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002002 slurry Substances 0.000 claims description 52
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 39
- 238000009413 insulation Methods 0.000 claims description 32
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 16
- 238000000498 ball milling Methods 0.000 claims description 14
- 238000004939 coking Methods 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 238000005253 cladding Methods 0.000 claims description 11
- 239000003292 glue Substances 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 10
- 235000012241 calcium silicate Nutrition 0.000 claims description 9
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 9
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 9
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 7
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 7
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 6
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 6
- 239000004570 mortar (masonry) Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 6
- 239000010453 quartz Substances 0.000 claims description 4
- 239000002390 adhesive tape Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 3
- 238000004033 diameter control Methods 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 abstract description 44
- 239000010959 steel Substances 0.000 abstract description 44
- 238000005266 casting Methods 0.000 abstract description 12
- 229910052710 silicon Inorganic materials 0.000 abstract description 8
- 239000010703 silicon Substances 0.000 abstract description 8
- 238000010079 rubber tapping Methods 0.000 abstract description 5
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- 230000017525 heat dissipation Effects 0.000 abstract description 3
- 238000005245 sintering Methods 0.000 abstract description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 2
- 238000009833 condensation Methods 0.000 abstract description 2
- 230000005494 condensation Effects 0.000 abstract description 2
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 abstract description 2
- 239000013078 crystal Substances 0.000 abstract description 2
- 230000009970 fire resistant effect Effects 0.000 abstract description 2
- 230000008595 infiltration Effects 0.000 abstract description 2
- 238000001764 infiltration Methods 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 2
- 239000011733 molybdenum Substances 0.000 abstract description 2
- 239000012466 permeate Substances 0.000 abstract description 2
- 230000009466 transformation Effects 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 17
- 238000004519 manufacturing process Methods 0.000 description 10
- 239000011651 chromium Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000009749 continuous casting Methods 0.000 description 4
- 239000010433 feldspar Substances 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 238000004321 preservation Methods 0.000 description 4
- 238000007670 refining Methods 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- PNEFIWYZWIQKEK-UHFFFAOYSA-N carbonic acid;lithium Chemical compound [Li].OC(O)=O PNEFIWYZWIQKEK-UHFFFAOYSA-N 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- -1 which is added Chemical compound 0.000 description 3
- 229910052845 zircon Inorganic materials 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 229910052839 forsterite Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052609 olivine Inorganic materials 0.000 description 2
- 239000010450 olivine Substances 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910000604 Ferrochrome Inorganic materials 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011233 carbonaceous binding agent Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
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- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
- C04B35/62886—Coating the powders or the macroscopic reinforcing agents by wet chemical techniques
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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Abstract
The invention discloses a kind of preparation methods for coating far infrared glaze layer stuffing sand, belong to technical field of fire-resistant material preparation.Certain content chrome ore, potassium feldspar is added in stuffing sand of the invention, sinter layer is quickly formed conducive in tapping, wherein chrome ore and quartz sand, potassium feldspar Fast Sintering, it prevents from stuffing sand from being broken up to permeate with molten steel, the fusing of potassium feldspar can effectively absorb the expansion that the phase transformation of quartz sand generates, the expansion rate for reducing entire stuffing sand, prevents the infiltration of molten steel, and improves casting rate;In molybdenum disilicide used in far-infrared ceramic of the invention molybdenum between silicon with metallic bond in conjunction with, then linked between silicon and silicon with covalent bond, for grey tetragonal crystal, with good high-temperature oxidation resistance, for far-infrared ceramic glaze layer, play the role of bonding other high-melting-point stuffing sand ingredients, it is put in time longer situation in molten steel biography, the heat dissipation that molten steel can be substantially reduced avoids generating condensation steel, additionally it is possible to improve the refractoriness of stuffing sand.
Description
Technical field
The invention discloses a kind of preparation methods for coating far infrared glaze layer stuffing sand, belong to refractory material technology of preparing neck
Domain.
Background technique
A kind of bias furnace tapping essential refractory material, i.e. stuffing sand, it is mainly with Henan forsterite, Liaoning
The fused magnesite of Dashiqiao is primary raw material, and Yichang carbon materials are additive, by specific partial size and weight percent
It is combined, is mixed and be prepared into stuffing sand, proved after on probation, which has good dispersion flows, fire resisting
Degree is high, is not sintered, do not block, tapping rate drainage rate is up to 100%, using temperature >=1750 DEG C, does not occur with molten steel and alloying component
Chemical reaction, store quality do not occur changeability, are able to satisfy process for making requirement, are that eccentric furnace makes steel optimal fire proofed wood
Material.
It requires to be sintered at a lower temperature using stuffing sand, causes thing to avoid stuffing sand floating when molten steel is added
Therefore;It is required that meeting molten steel face under high temperature and long-time smelting state cannot be sintered too thick, in the hope of reaching automatic casting, production is improved
Efficiency reduces molten steel pollution, reduces flue gas consumption, improves production safety coefficient.
If refining ladle is unable to automatic casting when pouring steel, understands some molten steel and opens wide casting, secondary oxidation occurs,
Field trash is brought into crystallizer simultaneously, makes that casting billet surface is cracked, the defects of being mingled with, reduces the quality of slab, this is right
The production of high standard variety steel is particularly disadvantageous.
In the prior art, stuffing sand usually has following four classes: chromium matter stuffing sand, using ferrochrome sand, quartz sand as main material, adds
Carbonaceous binder mixing drying is added to be made.The casting rate of chromium matter stuffing sand is high, and still, contained chromium oxide can produce molten steel and environment
Raw pollution, SiO2 also pollute molten steel.Forsterite is mixed drying with raw materials such as additives by white olivine stuffing sand
It is made.White olivine stuffing sand it is cheap, but continuous casting automatic casting ratio is low, and silicon in stuffing sand and magnesium may also
Molten steel is polluted, is especially not suitable for limiting stringenter high-grade steel smelting to silicon, magnesium.Siliceous stuffing sand, by sea sand or stone
Sand, potassium feldspar and additive mixing drying are made.Although the fusing point of silica sand is 1680~1700 DEG C, siliceous stuffing sand exists
1200 DEG C can undergo phase transition, and thus cause biggish volume expansion, cause the adhesive force of back-up sand and mouth of a river inner wall to increase, serious shadow
The mobility for ringing stuffing sand, is unfavorable for opening the free-falling of stuffing sand when pouring.Siliceous stuffing sand is although cheap, but opens and pour
Rate is lower, and silicone content is too high, can generate pollution to molten steel, be not suitable for the needs of high-grade refining steel grade.Zirconium matter stuffing sand, with
Zircon is primary raw material, and a small amount of carbon dust mixing is added and dries.The content of zirconium silicate is resistance to not less than 97% in zircon
Fiery degree is higher than 1800 DEG C, and zircon, which has, corrodes the excellent performances such as penetrating power is strong and stability is strong than great, anti-molten steel, is
The desirable feedstock of ladle draining sand is done, but it is expensive, it does not use substantially in the actual production process.
With the development of world economy and the progress of science and technology, social every field proposes the quality of steel higher
Requirement." fine work steel theory " deepens constantly in iron and steel enterprise, and domestic large size steel mill is while improving iron and steel output, more
Focus on the production of high standard variety steel.The development of continuous casting and external refining is so that production efficiency is improved, but taps simultaneously
Temperature becomes higher, and molten steel biography, which puts the time, becomes longer, and traditional stopper system has been difficult to meet the requirements, instead then
It is ladle nozzle system.
Therefore, it is high and will not influence the stuffing sand of casting rate and be to technical field of fire-resistant material preparation to invent a kind of refractoriness
It is necessary to.
Summary of the invention
Present invention mainly solves the technical issues of, for the development of current continuous casting and external refining so that production efficiency obtains
It improves, but simultaneously tapping temperature becomes higher, molten steel biography, which puts the time, becomes longer, and such as under this condition, molten steel is easy to produce cold
Solidifying steel, expansion rate is higher at high temperature with chromium matter stuffing sand for commonly siliceous, seriously affects casting rate, while stuffing sand refractoriness
Also defect to be improved provides a kind of preparation method for coating far infrared glaze layer stuffing sand.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
It is a kind of cladding far infrared glaze layer stuffing sand the preparation method comprises the following steps:
Chrome ore and quartz sand are added in blender, stir 2~3min, then potassium feldspar is added in the blender, stirring 5~
10min is continued thereafter with and far infrared thermal insulation ceramic slurry is added, and is stirred 10~15min, then pour out from blender, is transferred to rotation
Turn in drying oven, 30~40min is toasted under the conditions of 180~220 DEG C, obtains cladding far infrared glaze layer stuffing sand;
The preparation of far infrared thermal insulation ceramic slurry are as follows:
(1) 40~50mL butyl titanate is added in the beaker equipped with 180~200mL ethylene glycol solution, it is heated to 80~
100 DEG C, 30~35g citric acid is added into beaker, starts blender, is stirred with the revolving speed of 300~350r/min, until
Citric acid is completely dissolved, and obtains transparent glue;
(2) above-mentioned transparent glue, silicon carbide, molybdenum disilicide, calcium silicates, lithium carbonate, zirconium oxide are mixed and is placed in water-bath, added
Heat is warming up to 80~85 DEG C, keeps the temperature 2~3h, continues to be heated to 130~150 DEG C, keeps the temperature 1~2h, obtains concentration ceramic slurry
Material;
(3) above-mentioned concentration ceramic slurry is put into coking furnace, is passed through nitrogen, be heated to 230~250 DEG C, keep the temperature coking
After 30~35min, it is put into 3~4h of crushing in pulverizer, far-infrared ceramic particle is obtained, far-infrared ceramic particle is placed in kiln
In, in a nitrogen atmosphere, 850~950 DEG C are heated to, after roasting 3~4h, are put into agate mortar and are ground up, sieved, obtain
Far-infrared ceramic powder;
(4) in mass ratio it is that 1 ︰ 2 is mixed with the poly-vinyl alcohol solution that mass fraction is 5% by far-infrared ceramic powder, is put into ball milling
10~15h of ball milling in machine crosses 200 meshes, and dilutes ball milling slurry with deionized water, obtains far infrared thermal insulation ceramic slurry.
Each component raw material in the preparation of far infrared glaze layer stuffing sand is coated, according to parts by weight, including 45~55 parts of chrome ores
Sand, 18~20 parts of quartz sands, 10~12 parts of potassium feldspar, far infrared thermal insulation ceramic slurry.
Cr in chrome ore in the preparation of cladding far infrared glaze layer stuffing sand2O3Mass content is greater than 49%, further preferred chromium
1~3mm of control accounts for 20% to each particle size interval grain graininess physics proportion of ore in sand form by mass percentage, and 0.5~1.0mm accounts for 75%, 0.15
~0.50mm accounts for 3%, and 0.15mm or less accounts for 2%.
Coat SiO in quartz sand described in the preparation of far infrared glaze layer stuffing sand2Mass content is greater than 99%, particle
Diameter control is 100~150 mesh.
Coat the K of potassium feldspar described in the preparation of far infrared glaze layer stuffing sand2O mass content is greater than 15%, Na2O mass
Content is less than 3%.
Ethylene glycol solution mass fraction is preferably 25% in the preparation of far infrared thermal insulation ceramic slurry.
Each component raw material in the preparation of far infrared thermal insulation ceramic slurry, according to parts by weight, including 70~80 parts of transparent adhesive tapes
Liquid, 15~20 parts of silicon carbide, 10~12 parts of molybdenum disilicides, 4~5 parts of calcium silicates, 6~7 parts of lithium carbonates, 40~50 parts of zirconium oxides.
Gained far-infrared ceramic powder partial size is preferably 200 mesh in the preparation of far infrared thermal insulation ceramic slurry.
Gained far infrared thermal insulation ceramic slurry density after being diluted in the preparation of far infrared thermal insulation ceramic slurry with deionized water
For 2.2~2.5g/cm3。
The beneficial effects of the present invention are:
(1) present invention is using butyl titanate, ethylene glycol solution, citric acid as raw material, and agitated dispersion obtains clear solution, thereto
Be added calcium silicates, lithium carbonate, zirconium oxide, silicon carbide, through heat preservation complex reaction obtain concentration ceramic slurry, ceramic slurry will be concentrated
Material coking, crushing, sintering obtain infra-red china powder, infra-red china powder are obtained with poly-vinyl alcohol solution mixing defibrination far red
Far infrared thermal insulation ceramic slurry is added in external thermal insulation ceramic slurry after finally stirring chrome ore, quartz sand, potassium feldspar with blender
Material, stirs evenly, and is placed in baking in rotary drying furnace and obtains cladding far infrared glaze layer stuffing sand, stuffing sand of the invention is added one
Determine content chrome ore, potassium feldspar, quickly forms sinter layer conducive in tapping, wherein chrome ore and quartz sand, potassium feldspar are quick
Sintering prevents stuffing sand from being broken up and permeates with molten steel, and chrome ore fineness of sand used is smaller, can effectively fill stomata, hinders steel
Water penetration, chrome ore is than great, and un-sintered layer flows out automatically after opening conducive to slide plate, and the fusing point of potassium feldspar compares chrome ore and stone
Sand is lower, first starts to melt, and since its viscosity is larger, the table of quartz sand and chrome ore can be effectively adhered under high temperature
Face is conducive to stuffing sand sinter layer and is quickly formed, and prevents the floating of stuffing sand, while the fusing of potassium feldspar can effectively absorb
The expansion that the phase transformation of quartz sand generates, reduces the expansion rate of entire stuffing sand, effectively prevents the infiltration of molten steel, and improve
Casting rate;
(2) in molybdenum disilicide used in far-infrared ceramic of the invention molybdenum between silicon with metallic bond in conjunction with, between silicon and silicon
Then linked with covalent bond, be grey tetragonal crystal, there is good high-temperature oxidation resistance, the burning of oxidizing atmosphere high temperature is fine and close
Quartz form protective film layer on molybdenum disilicide surface, to prevent molybdenum disilicide continuous oxidation, when heating temperature be higher than 1600
DEG C when will form SiO2Protective film, at 1700 DEG C or more, molybdenum disilicide can be condensed, and filling stuffing sand is destroyed by molten steel
Hole plays the not oxidized effect of protection molten steel and plays for far-infrared ceramic glaze layer and bond other high-melting-points
The effect of stuffing sand ingredient, and the key effect of far infrared glaze layer is that the heat dissipation of molten steel can be reflected, and puts the time in molten steel biography
In longer situation, the heat dissipation of molten steel can be substantially reduced, avoids generating condensation steel, additionally it is possible to the refractoriness of stuffing sand is improved,
The service life of stuffing sand is lengthened, production cost is reduced, improves the quality of production and yield, more securely and reliably, is had wide
Application prospect.
Specific embodiment
40~50mL butyl titanate is added and is equipped in the beaker that 180~200mL mass fraction is 25% ethylene glycol solution,
80~100 DEG C are heated to, 30~35g citric acid is added into beaker, starts blender, with turning for 300~350r/min
Speed is stirred, until citric acid is completely dissolved, obtains transparent glue;According to parts by weight, by 70~80 parts of above-mentioned transparent adhesive tapes
Liquid, 15~20 parts of silicon carbide, 10~12 parts of molybdenum disilicides, 4~5 parts of calcium silicates, 6~7 parts of lithium carbonates, 40~50 parts of zirconium oxides are mixed
Conjunction is placed in water-bath, is heated to 80~85 DEG C, keeps the temperature 2~3h, continues to be heated to 130~150 DEG C, and heat preservation 1~
2h obtains concentration ceramic slurry;Above-mentioned concentration ceramic slurry is put into coking furnace, nitrogen is passed through, it is heated to 230~
250 DEG C, after keeping the temperature 30~35min of coking, it is put into 3~4h of crushing in pulverizer, far-infrared ceramic particle is obtained, far infrared is made pottery
Porcelain particle is placed in kiln, in a nitrogen atmosphere, is heated to 850~950 DEG C, after roasting 3~4h, is put into agate mortar
Ground 200 mesh, obtains far-infrared ceramic powder;The polyvinyl alcohol for being 5% by above-mentioned far-infrared ceramic powder and mass fraction
Solution is 1 ︰ 2 mixing in mass ratio, is put into 10~15h of ball milling in ball mill, crosses 200 meshes, and dilute ball milling with deionized water
Slurry density is 2.2~2.5g/cm3, obtain far infrared thermal insulation ceramic slurry;According to parts by weight, by 45~55 parts of chrome ore
Sand and 18~20 parts of quartz sand are added in blender, stir 2~3min, then the blender is added in 10~12 parts of potassium feldspar
In, 5~10min is stirred, continues thereafter with 30~35 parts of addition above-mentioned far infrared thermal insulation ceramic slurries, stirs 10~15min, then from
It is poured out in blender, is transferred in rotary drying furnace, 30~40min is toasted under the conditions of 180~220 DEG C, it is remote red to obtain cladding
Outer glaze layer stuffing sand, Cr in the chrome ore2O3Mass content is greater than 49%, and each particle size interval grain graininess physics proportion presses matter
Amount 1~3mm of percentage control accounts for 20%, and 0.5~1mm accounts for 75%, and 0.15~0.5mm accounts for 3%, and 0.15mm or less accounts for 2%, the quartz
SiO in sand2Mass content is greater than 99%, and grain diameter is 100~150 mesh, K in the potassium feldspar2O mass content is greater than 15%,
Na2O mass content is less than 3%.
Embodiment 1
The preparation of far infrared thermal insulation ceramic slurry:
It is to be heated to 80 in the beaker of 25% ethylene glycol solution equipped with 180mL mass fraction that 40mL butyl titanate, which is added,
DEG C, 30g citric acid is added into beaker, starts blender, is stirred with the revolving speed of 300r/min, until citric acid is completely molten
Solution, obtains transparent glue;
According to parts by weight, by 70 parts of above-mentioned transparent glues, 15 parts of silicon carbide, 10 parts of molybdenum disilicides, 4 parts of calcium silicates, 6 parts of carbonic acid
Lithium, 40 parts of zirconium oxide mixing are placed in water-bath, are heated to 80 DEG C, are kept the temperature 2h, continue to be heated to 130 DEG C, heat preservation
1h obtains concentration ceramic slurry;
Above-mentioned concentration ceramic slurry is put into coking furnace, nitrogen is passed through, is heated to 230 DEG C, after keeping the temperature coking 30min,
It is put into pulverizer and crushes 3h, obtain far-infrared ceramic particle, far-infrared ceramic particle is placed in kiln, in nitrogen atmosphere
Under, 850 DEG C are heated to, after roasting 3h, ground 200 mesh in agate mortar is put into, obtains far-infrared ceramic powder;
With the poly-vinyl alcohol solution that mass fraction is 5% in mass ratio it is that 1 ︰ 2 is mixed by above-mentioned far-infrared ceramic powder, is put into ball
Ball milling 10h in grinding machine crosses 200 meshes, and is 2.2g/cm with deionized water dilution ball milling slurry density3, obtain far infrared thermal insulation
Ceramic slurry;
Coat the preparation of far infrared glaze layer stuffing sand:
According to parts by weight, 45 parts of chrome ore and 18 parts of quartz sand are added in blender, stir 2min, then by 10 parts
Potassium feldspar is added in the blender, stirs 5min, continues thereafter with and 30 parts of above-mentioned far infrared thermal insulation ceramic slurries are added, stirring
10min, then poured out from blender, it is transferred in rotary drying furnace, toasts 30min under the conditions of 180 DEG C, it is remote red to obtain cladding
Outer glaze layer stuffing sand, Cr in the chrome ore2O3Mass content is greater than 49%, and each particle size interval grain graininess physics proportion presses matter
Amount percentage control 1mm, which accounts for 20%, 0.5mm and accounts for 75%, 0.15mm, accounts for 3%, and 0.15mm or less accounts for 2%, SiO in the quartz sand2Matter
It measures content and is greater than 99%, grain diameter is 100 mesh, K in the potassium feldspar2O mass content is greater than 15%, Na2O mass content is small
In 3%.
Embodiment 2
The preparation of far infrared thermal insulation ceramic slurry:
It is to be heated to 90 in the beaker of 25% ethylene glycol solution equipped with 190mL mass fraction that 45mL butyl titanate, which is added,
DEG C, 32g citric acid is added into beaker, starts blender, is stirred with the revolving speed of 320r/min, until citric acid is completely molten
Solution, obtains transparent glue;
According to parts by weight, by 75 parts of above-mentioned transparent glues, 17 parts of silicon carbide, 11 parts of molybdenum disilicides, 4 parts of calcium silicates, 6 parts of carbonic acid
Lithium, 45 parts of zirconium oxide mixing are placed in water-bath, are heated to 82 DEG C, are kept the temperature 2.5h, continue to be heated to 140 DEG C, protect
Warm 1.5h obtains concentration ceramic slurry;
Above-mentioned concentration ceramic slurry is put into coking furnace, nitrogen is passed through, is heated to 240 DEG C, after keeping the temperature coking 32min,
It is put into pulverizer and crushes 3.5h, obtain far-infrared ceramic particle, far-infrared ceramic particle is placed in kiln, in nitrogen atmosphere
Under, 900 DEG C are heated to, after roasting 3.5h, ground 200 mesh in agate mortar is put into, obtains far-infrared ceramic powder;
With the poly-vinyl alcohol solution that mass fraction is 5% in mass ratio it is that 1 ︰ 2 is mixed by above-mentioned far-infrared ceramic powder, is put into ball
Ball milling 12h in grinding machine crosses 200 meshes, and is 2.4g/cm with deionized water dilution ball milling slurry density3, obtain far infrared thermal insulation
Ceramic slurry;
Coat the preparation of far infrared glaze layer stuffing sand:
According to parts by weight, 50 parts of chrome ore and 19 parts of quartz sand are added in blender, stir 2min, then by 11 parts
Potassium feldspar is added in the blender, stirs 7min, continues thereafter with and 32 parts of above-mentioned far infrared thermal insulation ceramic slurries are added, stirring
12min, then poured out from blender, it is transferred in rotary drying furnace, toasts 35min under the conditions of 200 DEG C, it is remote red to obtain cladding
Outer glaze layer stuffing sand, Cr in the chrome ore2O3Mass content is greater than 49%, and each particle size interval grain graininess physics proportion presses matter
Amount percentage control 2mm, which accounts for 20%, 0.7mm and accounts for 75%, 0.30mm, accounts for 3%, and 0.15mm or less accounts for 2%, SiO in the quartz sand2Matter
It measures content and is greater than 99%, grain diameter is 120 mesh, K in the potassium feldspar2O mass content is greater than 15%, Na2O mass content is small
In 3%.
Embodiment 3
The preparation of far infrared thermal insulation ceramic slurry:
It is to be heated to 100 in the beaker of 25% ethylene glycol solution equipped with 200mL mass fraction that 50mL butyl titanate, which is added,
DEG C, 35g citric acid is added into beaker, starts blender, is stirred with the revolving speed of 350r/min, until citric acid is completely molten
Solution, obtains transparent glue;
According to parts by weight, by 80 parts of above-mentioned transparent glues, 20 parts of silicon carbide, 12 parts of molybdenum disilicides, 5 parts of calcium silicates, 7 parts of carbonic acid
Lithium, 50 parts of zirconium oxide mixing are placed in water-bath, are heated to 85 DEG C, are kept the temperature 3h, continue to be heated to 150 DEG C, heat preservation
2h obtains concentration ceramic slurry;
Above-mentioned concentration ceramic slurry is put into coking furnace, nitrogen is passed through, is heated to 250 DEG C, after keeping the temperature coking 35min,
It is put into pulverizer and crushes 4h, obtain far-infrared ceramic particle, far-infrared ceramic particle is placed in kiln, in nitrogen atmosphere
Under, 950 DEG C are heated to, after roasting 4h, ground 200 mesh in agate mortar is put into, obtains far-infrared ceramic powder;
With the poly-vinyl alcohol solution that mass fraction is 5% in mass ratio it is that 1 ︰ 2 is mixed by above-mentioned far-infrared ceramic powder, is put into ball
Ball milling 15h in grinding machine crosses 200 meshes, and is 2.5g/cm with deionized water dilution ball milling slurry density3, obtain far infrared thermal insulation
Ceramic slurry;
Coat the preparation of far infrared glaze layer stuffing sand:
According to parts by weight, 55 parts of chrome ore and 20 parts of quartz sand are added in blender, stir 3min, then by 12 parts
Potassium feldspar is added in the blender, stirs 10min, continues thereafter with and 35 parts of above-mentioned far infrared thermal insulation ceramic slurries are added, stirring
15min, then poured out from blender, it is transferred in rotary drying furnace, toasts 40min under the conditions of 220 DEG C, it is remote red to obtain cladding
Outer glaze layer stuffing sand, Cr in the chrome ore2O3Mass content is greater than 49%, and each particle size interval grain graininess physics proportion presses matter
Amount percentage control 3mm, which accounts for 20%, 1mm and accounts for 75%, 0.5mm, accounts for 3%, and 0.15mm or less accounts for 2%, SiO in the quartz sand2Quality contains
Amount is greater than 99%, and grain diameter is 150 mesh, K in the potassium feldspar2O mass content is greater than 15%, Na2O mass content is less than 3%.
Comparative example 1: it is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking far infrared thermal insulation ceramic slurry
Material.
Comparative example 2: the stuffing sand of Shanghai company production.
YB/T190 " People's Republic of China's iron and steel industry professional standard --- fusion temperature of continuous casting protection slag is pressed in fusing point test
Test method " it is detected.
Table 1: stuffing sand performance measurement result
Detection project | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 |
It counts furnace number (furnace) | 1068 | 1078 | 1089 | 1045 | 1052 |
It opens and pours furnace number (furnace) | 1064 | 1074 | 1085 | 946 | 1002 |
Molten steel biography puts the time (h) | 1.7 | 1.6 | 1.5 | 3.2 | 2.8 |
Automatic casting ratio (%) | 99.5 | 99.6 | 99.8 | 92.6 | 96.8 |
Fusing point (DEG C) | 1745 | 1748 | 1750 | 1224 | 1315 |
In summary, as can be seen from Table 1 cladding far infrared glaze layer stuffing sand fusing point of the invention between 1745~1750 DEG C,
Therefore refractoriness with higher is opened and pours that furnace number is high, and casting rate is high, and coefficient of thermal expansion is small, and molten steel biography puts that the time is short, and molten steel is not easy to produce
The solidifying steel of raw food, has broad prospect of application.
The foregoing is merely preferred modes of the invention, are not intended to limit the invention, all in spirit and original of the invention
Within then, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of preparation method for coating far infrared glaze layer stuffing sand, it is characterised in that specific preparation step are as follows:
Chrome ore and quartz sand are added in blender, stir 2~3min, then potassium feldspar is added in the blender, stirring 5~
10min is continued thereafter with and far infrared thermal insulation ceramic slurry is added, and is stirred 10~15min, then pour out from blender, is transferred to rotation
Turn in drying oven, 30~40min is toasted under the conditions of 180~220 DEG C, obtains cladding far infrared glaze layer stuffing sand;
The specific preparation step of far infrared thermal insulation ceramic slurry are as follows:
(1) 40~50mL butyl titanate is added in the beaker equipped with 180~200mL ethylene glycol solution, it is heated to 80~
100 DEG C, 30~35g citric acid is added into beaker, starts blender, is stirred with the revolving speed of 300~350r/min, until
Citric acid is completely dissolved, and obtains transparent glue;
(2) above-mentioned transparent glue, silicon carbide, molybdenum disilicide, calcium silicates, lithium carbonate, zirconium oxide are mixed and is placed in water-bath, added
Heat is warming up to 80~85 DEG C, keeps the temperature 2~3h, continues to be heated to 130~150 DEG C, keeps the temperature 1~2h, obtains concentration ceramic slurry
Material;
(3) above-mentioned concentration ceramic slurry is put into coking furnace, is passed through nitrogen, be heated to 230~250 DEG C, keep the temperature coking
After 30~35min, it is put into 3~4h of crushing in pulverizer, far-infrared ceramic particle is obtained, far-infrared ceramic particle is placed in kiln
In, in a nitrogen atmosphere, 850~950 DEG C are heated to, after roasting 3~4h, are put into agate mortar and are ground up, sieved, obtain
Far-infrared ceramic powder;
(4) in mass ratio it is that 1 ︰ 2 is mixed with the poly-vinyl alcohol solution that mass fraction is 5% by far-infrared ceramic powder, is put into ball milling
10~15h of ball milling in machine crosses 200 meshes, and dilutes ball milling slurry with deionized water, obtains far infrared thermal insulation ceramic slurry.
2. a kind of preparation method for coating far infrared glaze layer stuffing sand according to claim 1, it is characterised in that: described
Each component raw material in the specific preparation step of far infrared glaze layer stuffing sand is coated, according to parts by weight, including 45~55 parts of chrome ores,
18~20 parts of quartz sands, 10~12 parts of potassium feldspar, far infrared thermal insulation ceramic slurry.
3. a kind of preparation method for coating far infrared glaze layer stuffing sand according to claim 1, it is characterised in that: described
Cr in chrome ore in the cladding specific preparation step of far infrared glaze layer stuffing sand2O3Mass content is greater than 49%, further preferred chrome ore
1~3mm of control accounts for 20% to each particle size interval grain graininess physics of sand proportion by mass percentage, and 0.5~1.0mm accounts for 75%, 0.15~
0.50mm accounts for 3%, and 0.15mm or less accounts for 2%.
4. a kind of preparation method for coating far infrared glaze layer stuffing sand according to claim 1, it is characterised in that: described
Coat SiO in quartz sand described in the specific preparation step of far infrared glaze layer stuffing sand2Mass content is greater than 99%, grain diameter
Control is 100~150 mesh.
5. a kind of preparation method for coating far infrared glaze layer stuffing sand according to claim 1, it is characterised in that: described
Coat the K of potassium feldspar described in the specific preparation step of far infrared glaze layer stuffing sand2O mass content is greater than 15%, Na2O mass contains
Amount is less than 3%.
6. a kind of preparation method for coating far infrared glaze layer stuffing sand according to claim 1, it is characterised in that: described
Ethylene glycol solution mass fraction is preferably 25% in the specific preparation step of far infrared thermal insulation ceramic slurry (1).
7. a kind of preparation method for coating far infrared glaze layer stuffing sand according to claim 1, it is characterised in that: described
Each component raw material in the specific preparation step of far infrared thermal insulation ceramic slurry (2), according to parts by weight, including 70~80 parts of transparent adhesive tapes
Liquid, 15~20 parts of silicon carbide, 10~12 parts of molybdenum disilicides, 4~5 parts of calcium silicates, 6~7 parts of lithium carbonates, 40~50 parts of zirconium oxides.
8. a kind of preparation method for coating far infrared glaze layer stuffing sand according to claim 1, it is characterised in that: described
Gained far-infrared ceramic powder partial size is preferably 200 mesh in the specific preparation step of far infrared thermal insulation ceramic slurry (3).
9. a kind of preparation method for coating far infrared glaze layer stuffing sand according to claim 1, it is characterised in that: described
Gained far infrared thermal insulation ceramic slurry density after being diluted in the specific preparation step of far infrared thermal insulation ceramic slurry (4) with deionized water
For 2.2~2.5g/cm3。
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