CN110407233A - Aluminium ash recovery process and system - Google Patents

Aluminium ash recovery process and system Download PDF

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Publication number
CN110407233A
CN110407233A CN201910774006.7A CN201910774006A CN110407233A CN 110407233 A CN110407233 A CN 110407233A CN 201910774006 A CN201910774006 A CN 201910774006A CN 110407233 A CN110407233 A CN 110407233A
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China
Prior art keywords
aluminium
aluminium ash
ash
hydrolysis
water
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CN201910774006.7A
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Chinese (zh)
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于沛洲
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Individual
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/02Preparation, purification or separation of ammonia
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/24Sulfates of ammonium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00Compounds of aluminium
    • C01F7/02Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/44Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water
    • C01F7/441Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by calcination
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C3/00Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/442Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4693Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Analytical Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A kind of aluminium ash recovery process and system, belong to environmental technology field, its recovery process is: the hydrolysis of 1. aluminium ashes, Ammonia recovery, so that its fineness is reached 200 mesh or more including aluminium ash is carried out repeatedly ball milling, is separated by solid-liquid separation with sorting sieve separation, 2. recycling aluminium oxide, including aluminium hydroxide, wastewater treatment, it is precipitated using nanofiltration, reverse osmosis, electrodialysis and diffusion dialysis Combined Treatment waste water, 3. Sewage treatments, including mixed salt concentration, evaporation, salt low temperature.Beneficial effect is: the various compositions in aluminium ash being separately recovered by class, restore the self-value of various compositions, removal process zero-emission;Equipment used 80% is traditional chemical industry equipment and solid-liquid separating equipment, and equipment maturity is high, price is low, good operation stability, processing capacity are big.

Description

Aluminium ash recovery process and system
Technical field
The invention belongs to environmental technology field, it is related to the improvement of a kind of old metal recovery method and device.
Background technique
When aluminum profile enterprise produces aluminum profile, first has to aluminium ingot founding into aluminium bar and reconcile alloy content, then use aluminium bar Profile is squeezed out on extruder.The fusion-casting process of aluminium bar can generate a large amount of aluminium lime-ash, wherein when containing aluminium alloy composition, founding Additive salt and aluminium nitride of addition etc..Usual method is that aluminium lime-ash is carried out a series of alum recovery processing, is finally become At the aluminium ash that composition containing pure aluminum is considerably less.Main ingredient in aluminium ash is aluminium nitride, aluminium oxide and additive salt, and meeting water can Release a large amount of ammonia and heat, water-soluble aobvious strong basicity and the soluble-salt containing high concentration.This aluminium ash is wanted in environmental protection It asks not tight period arbitrarily to be filled, is identified as danger wastes in the recent period, need to carry out harmless treatment.
Summary of the invention
The object of the present invention is to provide a kind of aluminium ash recovery process and systems, it uses wet recycling process, will be in aluminium ash Multiple components separation, release the property that its danger removes waste, go back the due value of primary aluminum ash.
Technical solution of the present invention:
This recovery process is:
1. the hydrolysis of aluminium ash, Ammonia recovery
1.1 aluminium ash ball millings: aluminium ash, which is carried out repeatedly ball milling, makes its fineness reach 200 mesh or more;
1.1.1 this process separating sieve can largely separate remaining primary aluminum in aluminium ash;
1.1.2 the aluminium ash for reaching fineness is transported in hydrolytic decomposition pot;
1.2. aluminium ash hydrolyzes:
1.2.1 aluminium ash is added in hydrolytic decomposition pot according to solid-liquid mass ratio 1:7-10 and is hydrolyzed, while by catalyst and aluminium ash Sodium carbonate catalyst is added in mass ratio 1:5-9, and controls the temperature 60-90 degree of material in tank, is steadily carried out using hydrolytic process;
1.2.2 sulfate of ammoniac is made in the ammonia of hydrolysis forward and backward phase, 50% or less low concentration of content, does chemical fertilizer or conduct Raw material is in market sale.Hydrolysis mid-term, ammonia purity is high yield is big, can be directly prepared into use or market inside liquid ammonia Sale;
2. recycling aluminium oxide:
The 2.1 aluminium ashes for completing hydrolysis carry out 300 meshes point;
2.1.1 ball milling is repeated in the material that 300 mesh are not achieved;
2.1.2 remaining primary aluminum in aluminium ash can be separated and be recycled again by this process separating sieve;
Fineves (aluminium hydroxide) more than 2.2300 mesh is separated by solid-liquid separation:
2.2.1 aluminium hydroxide is through filter press filters pressing;
2.2.2 the aluminium hydroxide washing after filters pressing;
Aluminium hydroxide calcining after 2.3 washings, produces aluminium oxide;
3. Sewage treatment:
3.1 aluminium hydroxides are separated by solid-liquid separation water, washing water returns to technique storage tank respectively;
3.2 wastewater treatments: nanofiltration, reverse osmosis, electrodialysis and diffusion dialysis Combined Treatment waste water are utilized;
3.2.1 it is recycled in sodium carbonate catalyst system;
3.2.2 mixed salt concentration, evaporation, salt low temperature are precipitated;
3.2.2.1 condensed water recycles in system;
3.2.2.2 it is salted out using the temperature difference, drying is used to make founding additive;
3.2.2.3 the water after salting out enters technique storage tank, circulating and evaporating.
System and device of the invention is:
Feed bin is connected to ball mill inlet, the premenstrual separating sieve of ball mill outlet with hydrolytic decomposition pot is closed is connected to, technique storage tank with The closed connection of hydrolytic decomposition pot, hydrolytic decomposition pot ammonia outlet with Ammonia recovery tank is closed is connected to, the aluminium ash outlet after the completion of hydrolytic decomposition pot hydrolysis With after separating sieve be connected to filter press;
Filter press filters out washing pipe and is connected to technique storage tank, technique outlet and nanofiltration, reverse osmosis, electrodialysis and diffusion The connection of dialysis combined unit entrance, nanofiltration, reverse osmosis, electrodialysis and diffusion dialysis combined unit water outlet and technique storage tank connect Logical, nanofiltration, reverse osmosis, electrodialysis and the outlet of diffusion dialysis combined unit concentrated water are connected to evaporator.
The beneficial effects of the present invention are: the various compositions in aluminium ash are separately recovered by class, itself of various compositions is restored Value, removal process zero-emission;Equipment used 80% is traditional chemical industry equipment and solid-liquid separating equipment, equipment maturity It is high, price is low, good operation stability, processing capacity are big.
Detailed description of the invention
Fig. 1 is process flow chart of the invention;
Fig. 2 is present system equipment flowsheet.
Specific embodiment
Embodiment 1
The present invention is described further with reference to the accompanying drawing:
As shown in Figure 2, wherein 11 be feed bin, 12 be preceding ball mill, 13 be preceding primary aluminum collecting cart, 14 be hydrolytic decomposition pot, 15 be Ammonia recycling device, 21 be rear separating sieve, 22 be rear ball mill, 23 be rear primary aluminum collecting cart, 25 be rotary kiln, 26 be transmission Machine, 31 be technique storage tank, 32 be reverse osmosis, electrodialysis and diffusion dialysis combined unit, 33 be evaporator, 34 be salt collecting cart.
First part: hydrolysis of aluminium nitride, Ammonia recovery in aluminium ash.
1, aluminium ash is added into feed bin 11;
2, ball mill 12 is run, hydrolytic decomposition pot 14 is entered by the aluminium ash of separating sieve, the ball milling repeatedly that can't pass, until all Pass through.The primary aluminum sorted out enters primary aluminum collecting cart 13, concentrates and returns to founding workshop;
3, suitable water is added into hydrolytic decomposition pot 14 from technique storage tank 31 by pipeline, while is heated to hydrolytic decomposition pot, make aluminium Ash is hydrolyzed;
4, ammonia recycling device 15, the Ammonia recovery that will be generated in hydrolytic decomposition pot 14 are opened;
Second part: recycling aluminium oxide
1, sorted 21 sorting of sieve of the aluminium ash that hydrolysis is completed.Enter filter press 24 by the aluminium ash of separating sieve and carries out solid-liquid point From, the aluminium ash that can't pass through the ball milling repeatedly of ball mill 22, pass through until all.The primary aluminum sorted out enters primary aluminum collecting cart 23, it concentrates and returns to founding workshop;
2, the aluminium ash main ingredient in filter press is aluminium hydroxide, enters rotary kiln 25 through conveyer and is sintered into oxidation Aluminium is sold after the packaging of conveyer 26;
Part III: recycling is salted out
1, filter press 24 is separated by solid-liquid separation water, washing water returns to technique storage tank 31 respectively;
2, the water in technique storage tank 31 through nanofiltration mould, reverse osmosis mould, electrodialysis and diffusion dialysis combined unit 32 processing after, Fresh water is returned in technique storage tank 31 and is recycled, and concentrated water will be salted out through the evaporation of evaporator 33, and salt is collected in 34 salt collecting carts Packing and selling.

Claims (2)

1. a kind of aluminium ash recovery process, technique is:
A. the hydrolysis of aluminium ash, Ammonia recovery
1.1 aluminium ash ball millings: aluminium ash, which is carried out repeatedly ball milling, makes its fineness reach 200 mesh or more;
1.1.1 this process separating sieve can largely separate remaining primary aluminum in aluminium ash;
1.1.2 the aluminium ash for reaching fineness is transported in hydrolytic decomposition pot;
1.2. aluminium ash hydrolyzes:
1.2.1 aluminium ash is added in hydrolytic decomposition pot according to solid-liquid mass ratio 1:7-10 and is hydrolyzed, while by catalyst and aluminium ash quality Sodium carbonate catalyst is added than 1:5-9, and controls the temperature 60-90 degree of material in tank, is steadily carried out using hydrolytic process;
1.2.2 sulfate of ammoniac is made in the ammonia of hydrolysis forward and backward phase, 50% or less low concentration of content, makees chemical fertilizer or as raw material In market sale;Hydrolysis mid-term, ammonia purity is high yield is big, can be directly prepared into use or market inside liquid ammonia and sell It sells;
B. aluminium oxide is recycled
The 2.1 aluminium ashes for completing hydrolysis carry out 300 meshes point;
2.1.1 ball milling is repeated in the material that 300 mesh are not achieved;
2.1.2 remaining primary aluminum in aluminium ash can be separated and be recycled again by this process separating sieve;
Fineves more than 2.2300 mesh is separated by solid-liquid separation:
2.2.1 aluminium hydroxide is through filter press filters pressing;
2.2.2 the aluminium hydroxide washing after filters pressing;
Aluminium hydroxide calcining after 2.3 washings, produces aluminium oxide;
C. Sewage treatment
3.1 aluminium hydroxides are separated by solid-liquid separation water, washing water returns to technique storage tank respectively;
3.2 wastewater treatments: nanofiltration, reverse osmosis, electrodialysis and diffusion dialysis Combined Treatment waste water are utilized;
3.2.1 it is recycled in sodium carbonate catalyst system;
3.2.2 mixed salt concentration, evaporation, salt low temperature are precipitated;
3.2.2.1 condensed water recycles in system;
3.2.2.2 it is salted out using the temperature difference, drying is used to make founding additive;
3.2.2.3 the water after salting out enters technique storage tank, circulating and evaporating.
2. a kind of aluminium ash recovery system: it is characterized in that: feed bin is connected to ball mill inlet, the premenstrual separating sieve of ball mill outlet and water Solve the closed connection of tank, technique storage tank with hydrolytic decomposition pot is closed is connected to, hydrolytic decomposition pot ammonia outlet with Ammonia recovery tank is closed is connected to, hydrolysis Aluminium ash outlet after the completion of tank hydrolysis with after separating sieve be connected to filter press;
Filter press filters out washing pipe and is connected to technique storage tank, technique outlet and nanofiltration, reverse osmosis, electrodialysis and diffusion dialysis The connection of combined unit entrance, nanofiltration, reverse osmosis, electrodialysis and diffusion dialysis combined unit water outlet are connected to technique storage tank, Nanofiltration, reverse osmosis, electrodialysis and the outlet of diffusion dialysis combined unit concentrated water are connected to evaporator.
CN201910774006.7A 2019-08-21 2019-08-21 Aluminium ash recovery process and system Pending CN110407233A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910774006.7A CN110407233A (en) 2019-08-21 2019-08-21 Aluminium ash recovery process and system

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Application Number Priority Date Filing Date Title
CN201910774006.7A CN110407233A (en) 2019-08-21 2019-08-21 Aluminium ash recovery process and system

Publications (1)

Publication Number Publication Date
CN110407233A true CN110407233A (en) 2019-11-05

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CN201910774006.7A Pending CN110407233A (en) 2019-08-21 2019-08-21 Aluminium ash recovery process and system

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111394585A (en) * 2020-04-22 2020-07-10 北京中冶设备研究设计总院有限公司 Gradient utilization treatment process for casting aluminum slag
CN111874931A (en) * 2020-07-23 2020-11-03 辽宁忠旺集团有限公司 Harmless treatment process for secondary aluminum ash
CN112194159A (en) * 2020-09-28 2021-01-08 江西省科学院应用物理研究所 Harmless recycling treatment process for secondary aluminum ash
CN112813275A (en) * 2020-12-23 2021-05-18 洛阳天瑞环保科技有限公司 Method for inhibiting reaction loss of metal aluminum in aluminum ash wet-process aluminum extraction process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106629774A (en) * 2016-12-31 2017-05-10 佛山市吉力达铝材科技有限公司 Method for harmlessly treating aluminum ash
CN109678180A (en) * 2019-02-14 2019-04-26 平罗县中兴碳素有限公司 A kind of method of mixed type Quadratic aluminum dust comprehensive reutilization
CN211035258U (en) * 2019-08-21 2020-07-17 于沛洲 Aluminum ash recovery system

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106629774A (en) * 2016-12-31 2017-05-10 佛山市吉力达铝材科技有限公司 Method for harmlessly treating aluminum ash
CN109678180A (en) * 2019-02-14 2019-04-26 平罗县中兴碳素有限公司 A kind of method of mixed type Quadratic aluminum dust comprehensive reutilization
CN211035258U (en) * 2019-08-21 2020-07-17 于沛洲 Aluminum ash recovery system

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111394585A (en) * 2020-04-22 2020-07-10 北京中冶设备研究设计总院有限公司 Gradient utilization treatment process for casting aluminum slag
CN111874931A (en) * 2020-07-23 2020-11-03 辽宁忠旺集团有限公司 Harmless treatment process for secondary aluminum ash
CN112194159A (en) * 2020-09-28 2021-01-08 江西省科学院应用物理研究所 Harmless recycling treatment process for secondary aluminum ash
CN112813275A (en) * 2020-12-23 2021-05-18 洛阳天瑞环保科技有限公司 Method for inhibiting reaction loss of metal aluminum in aluminum ash wet-process aluminum extraction process
CN112813275B (en) * 2020-12-23 2023-04-07 洛阳天瑞环保科技有限公司 Method for inhibiting reaction loss of metal aluminum in aluminum ash wet-process aluminum extraction process

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