CN110403300A - A kind of middle revolving die group, plasma processor and the processing technology of plasma processor - Google Patents
A kind of middle revolving die group, plasma processor and the processing technology of plasma processor Download PDFInfo
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- CN110403300A CN110403300A CN201910785001.4A CN201910785001A CN110403300A CN 110403300 A CN110403300 A CN 110403300A CN 201910785001 A CN201910785001 A CN 201910785001A CN 110403300 A CN110403300 A CN 110403300A
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- revolving die
- die group
- electrode plate
- accommodating chamber
- plasma
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- 238000012545 processing Methods 0.000 title claims description 16
- 238000005516 engineering process Methods 0.000 title description 3
- 238000012546 transfer Methods 0.000 claims abstract description 35
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 claims abstract description 32
- 230000002093 peripheral effect Effects 0.000 claims abstract description 32
- 238000009832 plasma treatment Methods 0.000 claims abstract description 28
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
- 229910052760 oxygen Inorganic materials 0.000 claims description 16
- 239000001301 oxygen Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 11
- 238000010992 reflux Methods 0.000 claims description 8
- 230000003028 elevating effect Effects 0.000 claims description 6
- 239000000463 material Substances 0.000 abstract description 13
- 238000007789 sealing Methods 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000012360 testing method Methods 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 241000208340 Araliaceae Species 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000008450 motivation Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43D—MACHINES, TOOLS, EQUIPMENT OR METHODS FOR MANUFACTURING OR REPAIRING FOOTWEAR
- A43D11/00—Machines for preliminary treatment or assembling of upper-parts, counters, or insoles on their lasts preparatory to the pulling-over or lasting operations; Applying or removing protective coverings
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43D—MACHINES, TOOLS, EQUIPMENT OR METHODS FOR MANUFACTURING OR REPAIRING FOOTWEAR
- A43D111/00—Shoe machines with conveyors for jacked shoes or for shoes or shoe parts
Landscapes
- Chemical Vapour Deposition (AREA)
- Plasma Technology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention belongs to footwear material manufacture fields, disclose a kind of middle revolving die group of plasma processor, accommodating chamber including pedestal, setting surface on the base, equipped with first electrode plate, the transfer component for being used to support the pallet of peripheral hardware and the tray conveying of peripheral hardware being arrived or removed accommodating chamber in the accommodating chamber.The plasma processor of this programme is realized on the basis of middle revolving die group, and the operation of the plasma treatment of footwear material can be realized only by the lifting of middle revolving die group.The maximum advantage of middle revolving die group of the invention is, by the way that first electrode plate and transfer component are arranged in accommodating chamber, it can cooperate the lifting of the lift drive mechanism driving pallet of peripheral hardware, cavity occurs so that the sealing of the electrode plate unit of pedestal and peripheral hardware cooperatively forms plasma, and carries out plasma treatment.
Description
Technical field
The present invention relates to footwear material manufacture field, the middle revolving die group and plasma treatment of especially a kind of plasma processor
Machine.
Background technique
Obligee Electric Co., Ltd. Suzhou Wei Peng has declared a patent of invention in 2013
CN201310081884.3, it discloses a kind of footwear material surface plasma discharge treatment device, including rack, in the rack
Vacuum tank and transmission guide rail are disposed among portion, the vacuum tank side is provided with the first tray rack, and the other side is provided with
Second tray rack, first tray rack and the second tray rack two sides are all provided with pallet idler wheel, first tray rack bottom
It is connect with the first pallet oscilaltion cylinder, and centre is provided with motor, described to there is motor to connect with push rod running part, institute
It states push rod running part to connect with charging push rod, second tray rack bottom is connect with the second pallet oscilaltion cylinder.
It is equipped with the chamber being vacuum-treated, and the pallet by the way that input and output material is arranged in the two sides of vacuum tank at the middle part of rack
Frame realizes input and output material operation, wherein the first tray rack and the equal liftable of the second tray rack, can thus send pallet from low level
To a high position, the second tray rack is sent into after the processing of vacuum chamber.
Above-mentioned design needs that the retractable door for keeping sealing vacuum box is arranged in the two sides of vacuum tank, while needing to make first
Tray rack lifting, the lifting of the second tray rack, structure are extremely complex.
Solve the problems, such as to be required for the application: it is desirable that proposing a kind of plasma processing, this equipment passes through one
The new middle revolving die group of kind realizes that the formation of cavity occurs for plasma can cooperate with equipment, by the lifting of middle revolving die group, and
Pallet can automatically be passed in and out.
Meanwhile on the basis of this middle revolving die group newly, it is further proposed that a kind of new plasma processing is to solve
Technical problem present in certainly above-mentioned technical solution.
Summary of the invention
The object of the present invention is to provide the middle revolving die groups and plasma processor of a kind of plasma processor.This programme
Plasma processor is realized on the basis of middle revolving die group, and footwear material can be realized only by the lifting of middle revolving die group
The operation of plasma treatment.The maximum advantage of middle revolving die group of the invention is, by the way that first electrode is arranged in accommodating chamber
Plate and transfer component, can cooperate the lift drive mechanism of peripheral hardware to drive the lifting of pallet, in favor of the electricity of pedestal and peripheral hardware
The sealing of pole plate unit cooperatively forms plasma and cavity occurs, and carries out plasma treatment.
Technical solution provided by the invention are as follows: a kind of middle revolving die group of plasma processor, including pedestal, setting are in pedestal
The accommodating chamber of upper surface, the accommodating chamber is interior to be equipped with first electrode plate, is used to support the pallet of peripheral hardware and the pallet by peripheral hardware
It is transplanted on or removes the transfer component of accommodating chamber.
In the middle revolving die group of above-mentioned plasma processor, the transfer component includes the conveying of pair of parellel arrangement
Chain, the drive shaft for driving conveyor chain, the driving motor for driving drive shaft turns, the conveyor chain are calm
Receiving the side of chamber extends to the other opposite side of accommodating chamber.
In the middle revolving die group of above-mentioned plasma processor, the driving motor is stepper motor.
In the middle revolving die group of above-mentioned plasma processor, the moving assembly further includes being arranged in conveyor chain two
The middle part of conveyor chain is arranged in the driven shaft at end, the drive shaft.
First bearing support base and the are equipped in the middle revolving die group of above-mentioned plasma processor, in the accommodating chamber
Two bearing support blocks, the driven shaft are connected on first bearing support base by bearing, and the drive shaft passes through bearing
It is connected on second bearing support base;The drive shaft is engaged by gear and conveyor chain.
In the middle revolving die group of above-mentioned plasma processor, the first electrode plate by snakelike arrangement electrode stem
Composition;The upside of the conveyor chain is located in the gap of the serpentine path of first electrode plate.
In the middle revolving die group of above-mentioned plasma processor, the pedestal is equipped with screw rod bushing, the screw rod bushing
Cooperate with the screw rod for driving pedestal to go up and down of peripheral hardware.
In the middle revolving die group of above-mentioned plasma processor, the use positioned at accommodating chamber lower part is additionally provided on the pedestal
Component is transferred in the auxiliary of the pallet of transfer peripheral hardware, the transfer direction for assisting moving assembly and moving assembly is opposite.
Meanwhile the invention also discloses a kind of plasma processor, the charging including being sequentially arranged conveys mould group, plasma
Revolving die group in processing mould group, reflux, the charging conveying mould group is equipped with first conveyer belt, in the reflux in revolving die group
Equipped with the second conveyer belt;Electrode plate unit is equipped in the plasma treatment mould group, be equipped in the electrode plate unit with
The second electrode plate of first electrode plate cooperation, vacuum unit, oxygen supply unit;The first electrode plate and second electrode
Polarity of voltage caused by plate is opposite;
As above any middle revolving die group is arranged in the plasma treatment mould group and passes through lift drive mechanism
Driving lifting;
When revolving die group rises to the first predeterminated position by lift drive mechanism in the middle, the accommodating chamber and electrode plate list
Member sealing cooperatively forms plasma and cavity occurs;
When revolving die group drops to the second predeterminated position by elevating mechanism in the middle, the first conveyer belt, transfer component,
Second conveyer belt is located along the same line;
The first conveyer belt, the second conveyer belt can positive and negative rotations.
In above-mentioned plasma processor, it is additionally provided on the pedestal positioned at accommodating chamber lower part for transferring peripheral hardware
The auxiliary of pallet transfer component, the transfer direction of the described auxiliary moving assembly and moving assembly is opposite;
When revolving die group rises to the first predeterminated position by elevating mechanism in the middle, the first conveyer belt, auxiliary movement
Component, the second conveyer belt are located along the same line.
Finally, the invention also discloses a kind of plasma treatment process of vamp, vamp in plasma treatment mould group with
Voltage 1000V, electric current 10A, time 25S, the parameters of 300ML/Min/2500-2900 square centimeters of tray areas of oxygen flow into
Row processing
The present invention is after adopting the above technical scheme, it has the beneficial effect that
The middle revolving die group of this programme can cooperate the lift drive mechanism of peripheral hardware to drive the lifting of pallet, pass through peripheral hardware
Lift drive mechanism by the electrode plate unit of pedestal and peripheral hardware sealing cooperatively form plasma occur cavity, by accommodating chamber
The electrode plate unit matching of interior setting first electrode plate and peripheral hardware generates plasma atmosphere, by transfer component that pallet is mobile,
And carry out plasma treatment.
The plasma processor of this programme is based on middle revolving die group and proposes, is input on pedestal by first conveyer belt
In accommodating chamber, after pedestal rises, plasma treatment mould group and middle revolving die group form plasma and cavity occur, to footwear material carry out etc. from
Subprocessing, pedestal declines after the completion of processing, carries out other processing by the output of the second conveyer belt.
As the further preferred of this programme, auxiliary transfer component is additionally provided on pedestal, so that pallet is conveyed from second
Band is sent through auxiliary transfer component to first conveyer belt, completes processing.
Detailed description of the invention
Fig. 1 is the main view of the embodiment of the present invention 1;
Fig. 2 is the perspective view of the embodiment of the present invention 1;
Fig. 3 is the main view of the embodiment of the present invention 2;
Fig. 4 is the main view of the embodiment of the present invention 2;
Fig. 5 is the perspective view of the plasma treatment mould group of the embodiment of the present invention 2.
Specific embodiment
With reference to embodiment, technical solution of the present invention is described in further detail, but do not constituted pair
Any restrictions of the invention.
Embodiment 1:
With reference to Fig. 1-2, including pedestal 1, the appearance of 1 upper surface of pedestal is arranged in a kind of middle revolving die group of plasma processor
Receive chamber 2, in the accommodating chamber 2 equipped with first electrode plate 3, be used to support the pallet of peripheral hardware and the tray conveying of peripheral hardware is arrived or
Remove the transfer component 4 of accommodating chamber 2.
In the actual production process, pedestal 1 is driven to go up and down by the lift drive mechanism of peripheral hardware 8, meanwhile, pedestal 1 and outer
If electrode plate unit can seal cooperation, if first electrode plate 3 is anode in the present embodiment, in the electrode plate unit of peripheral hardware
Electrode plate be then cathode, vice versa.
Preferably, in the present embodiment, can be as shown in Fig. 1, it is used in 2 surrounding of the accommodating chamber setting sealing strip of pedestal 1
Cooperated with being sealed with the electrode plate unit of peripheral hardware, can also be arranged on the electrode plate unit of peripheral hardware and match with pedestal 1 and accommodating chamber 2
The sealing strip of conjunction, to realize sealing cooperation.
Pallet is transplanted on the top of first electrode plate 3 by transfer component 4, then elevator drive machine of the pedestal 1 in peripheral hardware
It is the electrode plate unit formation plasma generation cavity of liftable and peripheral hardware under the driving of structure 8.After processing is completed, pedestal 1 is outside
If lift drive mechanism 8 driving under decline, by transfer component 4 pallet is removed.
In the present embodiment, the transfer component 4 includes the conveyor chain 41 of pair of parellel arrangement, for driving conveying
The drive shaft 42 of chain 41, the driving motor 43 for driving drive shaft 42 to rotate, the conveyor chain 41 is from accommodating chamber 2
Side extends to the other opposite side of accommodating chamber 2.In practical applications, moving assembly is not limited to conveyor chain 41,
Such as conveyer belt and can using.
In the present embodiment, in order to improve the transfer accuracy for transferring component 4, the driving motor 43 is stepping electricity
Machine.
In the present embodiment, the moving assembly further includes the driven shaft 44 that 41 both ends of conveyor chain are arranged in, described
Drive shaft 42 middle part of conveyor chain 41 is set.
Preferably, be equipped with first bearing support base 45 and second bearing support base 46 in the accommodating chamber 2, it is described from
Moving axis 44 is connected on first bearing support base 45 by bearing, and the drive shaft 42 is connected to second bearing branch by bearing
It supports on seat 46;The drive shaft 42 is engaged by gear and conveyor chain 41.
In the present embodiment, the first electrode plate 3 is made of the electrode stem of snakelike arrangement;The conveyor chain
41 upside is located in the gap of the serpentine path of first electrode plate 3.Certainly in practical applications, first electrode plate 3 can also be with
Using other any shapes such as such as plate, this present embodiment is not limited excessively.
In the present embodiment, in order to realize that the precision lift of pedestal 1, the pedestal 1 are equipped with the lifting with peripheral hardware and drive
The screw rod for driving pedestal 1 to go up and down of the screw rod bushing 11 that motivation structure 8 cooperates, the screw rod bushing 11 and peripheral hardware cooperates.
In the present embodiment, the pallet for transferring peripheral hardware positioned at 2 lower part of accommodating chamber is additionally provided on the pedestal 1
The transfer direction of auxiliary transfer component 9, the auxiliary moving assembly and moving assembly is opposite.It is specifically described in example 2
Assist the effect of moving assembly.
Embodiment 2
Fig. 3-5, a kind of plasma processor are please referred to, the charging including being sequentially arranged conveys mould group 5, plasma treatment mould
Revolving die group 7 in group 6, reflux, the charging conveying mould group 5 is equipped with first conveyer belt 51, in the reflux in revolving die group 7
Equipped with the second conveyer belt 71;It is equipped with electrode plate unit in the plasma treatment mould group 6, is equipped in the electrode plate unit
Second electrode plate 61, vacuum unit 62, oxygen supply unit 63 with the cooperation of first electrode plate 3;The first electrode plate 3
It is opposite with polarity of voltage caused by second electrode plate 61;
Middle revolving die group is arranged in the plasma treatment mould group 6 and by the driving lifting of lift drive mechanism 8;Transfer
Mould group is as described in Example 1.
When revolving die group rises to the first predeterminated position by lift drive mechanism 8 in the middle, the accommodating chamber 2 and electrode plate
Unit sealing cooperatively forms plasma and cavity occurs;
When revolving die group drops to the second predeterminated position by elevating mechanism in the middle, the first conveyer belt 51, transfer group
Part 4, the second conveyer belt 71 are located along the same line;
The first conveyer belt 51, the second conveyer belt 71 can positive and negative rotations.
Preferably, the auxiliary that the pallet for transferring peripheral hardware positioned at 2 lower part of accommodating chamber is additionally provided on the pedestal 1 is moved
Sending component 9, the auxiliary moving assembly 9 are opposite with the transfer direction of moving assembly 4;
When revolving die group rises to the first predeterminated position by elevating mechanism in the middle, the first conveyer belt 51, auxiliary are moved
Dynamic component 9, the second conveyer belt 71 are located along the same line.Assist moving assembly 9 preferably identical with the transfer structure of component 4.
In vamp plasma treatment process, comprising:
Step 1: footwear material being put into first conveyer belt, then into transfer component 4, lift drive mechanism 8 is driven
Middle revolving die group rises, and footwear material enters processing in plasma treatment mould group 6, and after the completion of processing, lift drive mechanism 8 drives transfer
The decline of mould group transfers the footwear material on component 4 and enters revolving die group 7 in reflux;
Step 2: untreated shoes are put into first conveyer belt, then into transfer component 4 in, lift drive mechanism
Revolving die group rises in 8 drivings, and footwear material enters processing in plasma treatment mould group 6, in the process, in reflux in revolving die group 7
Shoes enter auxiliary moving assembly 9, auxiliary moving assembly 9 shoes are sent to first conveyer belt 51, which completes the process.
Step 3: repetitive cycling step 1 and step 2.
In the plasma treatment process of plasma treatment mould group 6, by testing repeatedly, preferred plasma treatment ginseng
Number are as follows:
Electric current 10A, voltage 1000V, conduction time 25s, oxygen flow 300ml/min.
Specifically, after plasma treatment mould group 6 and the sealing cooperation of accommodating chamber 2, immediately to plasma treatment mould group 6
The seal chamber formed with accommodating chamber 2 vacuumizes, and vacuum degree is passed through oxygen after being lower than 10Pa, and keeping pressure is 30Pa-100Pa left
It is right;It is powered in the process and carries out plasma.
At the process conditions, carried out the test of 11 batches, the 20-30 of every batch of footwear material only, after above-mentioned processing
It is bonded using same binder, tests bonding part pulling force respectively,
In 11 batches, value of thrust minimum 2.7N/mm, up to 4.9N/mm meet acceptance condition 2.4N/mm.
Illustrate the performance parameter difference under different technology conditions below with reference to table:
1, voltage 1000V, electric current 15A, time 20-25S, the test result of oxygen flow 200-300ML/Min are shown in Table 1
Table 1
2, voltage 1000V, electric current 18A, time 25S, the test result of oxygen flow 200-300ML/Min are shown in Table 2
Table 2
3, voltage 1000V, electric current 15A, time 25S, the test result of oxygen flow 300ML/Min are shown in Table 3
Table 3
4, voltage 1000V, electric current 10A, time 25S, the test result of oxygen flow 300ML/Min are shown in Table 4
Table 4
4, voltage 1000V, electric current 7-8A, time 25S, the test result of oxygen flow 300ML/Min are shown in Table 5
Table 5
It is found by above-mentioned test, is satisfied with the technological parameter of production requirement are as follows: voltage 1000V, electric current 10A, time
25S, 300ML/Min/2500-2900 square centimeters of tray areas of oxygen flow.
Voltage, electric current, time do not have the direct relation of detail to the tray area of entire plasma treatment, and voltage is fixed on
1000V, electric current are fixed on 10A, time 25S.
When tray area is 2500-2900 square centimeters, oxygen flow 300ML/Min;Tray area and oxygen flow
It is directly proportional.
For specifically, in test process, two kinds of pallets, long by 63 × wide by 46 × high 7cm of small pallet, oxygen stream have been used
Measure 300ML/Min;Big pallet long by 72 × wide by 70 × high 7cm, 600ml ML/Min.Test result is that all batches pass through survey
Examination.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (8)
1. a kind of middle revolving die group of plasma processor, the accommodating chamber including pedestal, setting surface on the base, feature exists
In: in the accommodating chamber equipped with first electrode plate, be used to support peripheral hardware pallet and by the tray conveying of peripheral hardware to or remove
The transfer component of accommodating chamber.
2. the middle revolving die group of plasma processor according to claim 1, it is characterised in that: the transfer component includes
The conveyor chain of pair of parellel arrangement, the drive shaft for driving conveyor chain, the driving motor for driving drive shaft turns,
The conveyor chain extends to the other opposite side of accommodating chamber from the side of accommodating chamber.
3. the middle revolving die group of plasma processor according to claim 2, it is characterised in that: the first electrode plate by
The electrode stem of snakelike arrangement forms;The upside of the conveyor chain is located in the gap of the serpentine path of first electrode plate.
4. the middle revolving die group of plasma processor according to claim 1, it is characterised in that: the pedestal is equipped with silk
The screw rod cooperation for driving pedestal to go up and down of rod set, the screw rod bushing and peripheral hardware.
5. the middle revolving die group of plasma processor according to claim 1, it is characterised in that: be additionally provided on the pedestal
Auxiliary positioned at the pallet for transferring peripheral hardware of accommodating chamber lower part transfers component, the auxiliary moving assembly and moving assembly
Transfer direction it is opposite.
6. a kind of plasma processor, which is characterized in that including be sequentially arranged charging conveying mould group, plasma treatment mould group,
Revolving die group in reflux, the charging conveying mould group are equipped with first conveyer belt, and revolving die group is equipped with second in the reflux
Conveyer belt;It is equipped with electrode plate unit in the plasma treatment mould group, is equipped in the electrode plate unit and first electrode
The second electrode plate of plate cooperation, vacuum unit, oxygen supply unit;Produced by the first electrode plate and second electrode plate
Polarity of voltage it is opposite;
Middle revolving die group a method as claimed in any one of claims 1 to 5 is arranged in the plasma treatment mould group and by lifting driving
Mechanism driving lifting;
When revolving die group rises to the first predeterminated position by lift drive mechanism in the middle, the accommodating chamber and electrode plate unit are close
Envelope cooperatively forms plasma and cavity occurs;
When revolving die group drops to the second predeterminated position by elevating mechanism in the middle, the first conveyer belt, transfer component, second
Conveyer belt is located along the same line;
The first conveyer belt, the second conveyer belt can positive and negative rotations.
7. plasma processor according to claim 6, which is characterized in that be additionally provided on the pedestal positioned at accommodating chamber
The auxiliary transfer component of the pallet for transferring peripheral hardware of lower part, the transfer direction of the auxiliary moving assembly and moving assembly
On the contrary;
When revolving die group rises to the first predeterminated position by elevating mechanism in the middle, the first conveyer belt, auxiliary moving assembly,
Second conveyer belt is located along the same line.
8. a kind of technique for carrying out vamp processing using plasma processor as claimed in claims 6 or 7, which is characterized in that shoes
With voltage 1000V, electric current 10A, time 25S in plasma treatment mould group, oxygen flow 300ML/Min/2500-2900 is flat in face
Square centimetre of tray area.
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CN110833237A (en) * | 2019-12-27 | 2020-02-25 | 河南先途智能科技有限公司 | Plasma environmental protection shoes material treatment facility |
CN110936596A (en) * | 2019-12-27 | 2020-03-31 | 河南先途智能科技有限公司 | Process for treating surface of shoe material by low-temperature plasma technology |
CN110978571A (en) * | 2019-12-27 | 2020-04-10 | 河南先途智能科技有限公司 | Special mixed gas formula for plasma environment-friendly shoe material treatment equipment |
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CN109968697A (en) * | 2019-05-07 | 2019-07-05 | 深圳市东信高科自动化设备有限公司 | A kind of footwear material surface plasma processor |
CN210809518U (en) * | 2019-08-23 | 2020-06-23 | 万邦(清新)鞋业有限公司 | Transfer module of plasma processor and plasma processor |
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CN110833237A (en) * | 2019-12-27 | 2020-02-25 | 河南先途智能科技有限公司 | Plasma environmental protection shoes material treatment facility |
CN110936596A (en) * | 2019-12-27 | 2020-03-31 | 河南先途智能科技有限公司 | Process for treating surface of shoe material by low-temperature plasma technology |
CN110978571A (en) * | 2019-12-27 | 2020-04-10 | 河南先途智能科技有限公司 | Special mixed gas formula for plasma environment-friendly shoe material treatment equipment |
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