CN110386594B - Preparation method of nano porous iron phosphide cube - Google Patents
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- CN110386594B CN110386594B CN201910273089.1A CN201910273089A CN110386594B CN 110386594 B CN110386594 B CN 110386594B CN 201910273089 A CN201910273089 A CN 201910273089A CN 110386594 B CN110386594 B CN 110386594B
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- VAKIVKMUBMZANL-UHFFFAOYSA-N iron phosphide Chemical compound P.[Fe].[Fe].[Fe] VAKIVKMUBMZANL-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 18
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000004070 electrodeposition Methods 0.000 claims abstract description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 12
- 239000001257 hydrogen Substances 0.000 claims abstract description 12
- 239000002243 precursor Substances 0.000 claims abstract description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 9
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 8
- 239000011574 phosphorus Substances 0.000 claims abstract description 8
- 239000002253 acid Substances 0.000 claims abstract description 7
- DPTATFGPDCLUTF-UHFFFAOYSA-N phosphanylidyneiron Chemical compound [Fe]#P DPTATFGPDCLUTF-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003792 electrolyte Substances 0.000 claims abstract description 6
- 238000005530 etching Methods 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims abstract description 5
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 claims description 7
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical group FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 5
- 239000008151 electrolyte solution Substances 0.000 claims description 5
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 5
- 238000000970 chrono-amperometry Methods 0.000 claims description 3
- 229960002089 ferrous chloride Drugs 0.000 claims description 3
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical group Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 3
- SUOTZEJYYPISIE-UHFFFAOYSA-N iron(2+);dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O SUOTZEJYYPISIE-UHFFFAOYSA-N 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 238000009210 therapy by ultrasound Methods 0.000 claims description 3
- 239000007809 chemical reaction catalyst Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 9
- 238000011161 development Methods 0.000 abstract description 5
- 239000011259 mixed solution Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 238000003786 synthesis reaction Methods 0.000 abstract description 3
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000007789 gas Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000000151 deposition Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000010411 electrocatalyst Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000002484 cyclic voltammetry Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005713 exacerbation Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- -1 nickel and cobalt) Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000004098 selected area electron diffraction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
- B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
-
- B01J35/33—
-
- B01J35/60—
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/08—Other phosphides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
- C01B3/042—Decomposition of water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Abstract
The invention provides a preparation method of a nano porous ferric phosphide cube. The nano porous iron phosphide cubic material is prepared by adopting a simple and effective method of electrodeposition before acid etching: taking a mixed solution of an iron source and a phosphorus source precursor as an electrolyte, taking carbon paper as a working electrode, arranging a reference electrode and a counter electrode in an electrolytic cell, transferring the electrolyte into the electrolytic cell for electrochemical deposition, and removing non-iron phosphide substances by using a sulfuric acid solution. The method has the advantages of simple process, low synthesis temperature, uniform size, high repeatability, high acid stability and the like, and particularly can avoid the generation of a large amount of PH in the traditional heat treatment phosphating process3The problem of gas. The nano porous iron phosphide cubic material prepared by the method has excellent performance in the aspect of electrochemical water decomposition hydrogen production, and is a material with great development prospect.
Description
Technical Field
The invention belongs to the field of functional material synthesis, and particularly relates to a preparation method of a three-dimensional nano porous iron phosphide cube.
Background
The reduction of fossil fuels and the exacerbation of environmental crisis have attracted public attention over the last several decades. To solve these problems, the development and utilization of renewable energy have been imminent, and hydrogen energy becomes a very promising renewable energy source because of its high energy storage density and zero carbon emission. Electrochemical water splitting currently provides an efficient method for large-scale production of high-purity hydrogen, but requires an efficient and stable electrocatalyst to reduce the overpotential of the hydrogen evolution reaction. Currently, noble metals Pt, Ru and Pd are the most excellent electrocatalysts for hydrogen evolution reaction (angelw. chem. int. ed.2013,125,3192), but their wide application is severely limited by their low content and high cost in nature. For this reason, rational development of effective noble metal-free HER catalysts is of great importance for large-scale commercialization.
Transition metal phosphide materials can provide high current density at low overpotentials and faster reaction kinetics in hydrogen evolution reactions due to having phosphorus and metal as proton acceptor and hydride acceptor sites (j.am. chem. soc.2013,135, 9267). Meanwhile, iron is one of the most abundant (about 5% of the earth's crust) metals on earth, and is at least 2 orders of magnitude cheaper than the same class of transition metals (such as nickel and cobalt), which is beneficial for commercial mass production. In addition, the iron phosphide material with the three-dimensional porous nanostructure is designed and synthesized, so that the specific surface area of charge transfer is increased, and the efficiency of hydrogen evolution reaction is improved. Therefore, the development of the iron phosphide material with the porous structure has very important theoretical significance and practical value for the hydrogen evolution reaction.
Disclosure of Invention
The invention aims to provide a preparation method of a nano porous iron phosphide cube.
The nano porous iron phosphide cubic material is obtained by taking carbon paper as a substrate at room temperature and performing electrochemical deposition and acid etching in a mixed solution of an iron source and a phosphorus source precursor, and specifically comprises the following steps:
(1) preparing an electrolyte: adding a soluble iron source precursor and a phosphorus source precursor into water, and performing ultrasonic treatment to obtain an electrolyte solution;
(2) preparing an electrolytic cell: taking carbon paper as a working electrode, arranging a reference electrode and a counter electrode in an electrolytic cell at the same time, and transferring the electrolyte solution prepared in the step (1) into the electrolytic cell for electrochemical deposition;
(3) carrying out electrochemical deposition: in the electrolytic cell prepared in the step (2), a chronoamperometry method is selected, and electrochemical deposition is continuously carried out under the condition that the initial potential parameter is-0.95V;
(4) acid etching is used: and (4) soaking the carbon paper deposited in the step (3) in a sulfuric acid solution, and standing to obtain the nano porous ferric phosphide cube.
The iron source precursor in the step (1) is ferrous chloride tetrahydrate, ferrous nitrate hexahydrate or ferrous sulfate heptahydrate; the phosphorus source precursor is sodium hypophosphite.
The concentration of the iron source precursor in the mixed solution in the step (1) is 0.015-0.035M.
The concentration of the phosphorus source precursor in the mixed solution in the step (1) is 0.4-0.6M.
And (4) the electrochemical deposition time in the step (3) is 20-40 minutes.
The concentration of sulfuric acid in the sulfuric acid solution in the step (4) is 0.3-0.7M.
The nano porous iron phosphide cube prepared by the method can be used as a catalyst to participate in hydrogen evolution reaction.
The invention has the beneficial effects that: (1) the non-noble metal iron used in the preparation method is cheap and easy to obtain; (2) the preparation method has the advantages of simplicity, low synthesis temperature, uniform size, high repeatability, high acid stability and the like, avoids a phosphorization method of heat treatment, and greatly avoids the generation of toxic gas phosphine; (3) the prepared nano porous iron phosphide cubic material has a nano porous structure and a larger specific surface area, is rich in resources, low in cost and simple and convenient to prepare, has very excellent performance in the aspect of electrochemical water decomposition hydrogen production, and is a catalyst with a great development prospect.
Drawings
FIG. 1 is a scanning electron micrograph of a nanoporous iron phosphide cube obtained in example 1 of the present invention.
FIG. 2 is a transmission electron micrograph of a nanoporous iron phosphide cube obtained in example 1 of the present invention.
FIG. 3 is a high-resolution projection electron micrograph and a selected area electron diffraction pattern of a nanoporous iron phosphide cube obtained in example 1 of the present invention.
FIG. 4 is the element mapping and EDS energy spectra of the nanoporous iron phosphide cubes obtained in example 1 of the present invention.
FIG. 5 is a powder X-ray diffraction pattern of a nanoporous iron phosphide cube obtained in example 1 of the present invention.
FIG. 6 is a test chart of the performance of the nano-porous iron phosphide cube obtained in the example 1 of the invention in hydrogen production by electrolysis of water under acidic conditions and cyclic voltammetry stability.
Detailed Description
The present description will be further explained with reference to the drawings and specific examples.
Example 1:
(1) preparing an electrolyte: preparing a mixed solution of 0.025M ferrous sulfate heptahydrate and 0.5M sodium hypophosphite by taking 30mL of water as a solvent, and performing ultrasonic treatment for 5 minutes to obtain an electrolyte solution;
(2) preparing an electrolytic cell for the step (1): the carbon paper is used as a working electrode, a reference electrode and a counter electrode are arranged in an electrolytic cell at the same time, and the electrolyte is transferred to the electrolytic cell for electrochemical deposition;
(3) performing electrochemical deposition to the step (2): under the condition of 25 ℃, a chronoamperometry method is selected, the initial potential parameter is that electrochemical deposition is continuously carried out under minus 0.95V, and the deposition time is 30 minutes;
(4) acid etching is used for the step (3): and soaking the carbon paper after deposition in a 0.5M sulfuric acid solution, and standing for 5 minutes to obtain the nano porous ferric phosphide cube.
Example 2:
the ferrous sulfate heptahydrate obtained in the step (1) in the example 1 is changed into ferrous chloride tetrahydrate, and other steps are the same as those in the example 1, so that the nano-porous ferric phosphide cube is obtained.
Example 3:
the ferrous sulfate heptahydrate obtained in the step (1) in the example 1 is changed into ferrous nitrate hexahydrate, and other steps are the same as those in the example 1, so that the nano-porous ferric phosphide cube is obtained.
Example 4:
the concentration of ferrous sulfate heptahydrate in the step (1) in the example 1 was changed to 0.015M, and the other steps were the same as in the example 1, to obtain a nanoporous ferric phosphide cube.
Example 5:
the concentration of ferrous sulfate heptahydrate in the step (1) in the example 1 was changed to 0.035M, and the other steps were the same as in the example 1, to obtain a cubic nanoporous iron phosphide.
Example 6:
the concentration of sodium hypophosphite obtained in step (1) in example 1 was changed to 0.40M, and the other steps were the same as in example 1, to obtain a nanoporous iron phosphide cube.
Example 7:
the concentration of sodium hypophosphite obtained in step (1) in example 1 was changed to 0.60M, and the other steps were performed in the same manner as in example 1, to obtain a nanoporous iron phosphide cube.
Example 8:
the deposition time in the step (3) in the example 1 was changed to 20 minutes, and the other steps were the same as in the example 1, to obtain a nanoporous iron phosphide cube.
Example 9:
the deposition time in the step (3) in the example 1 was changed to 40 minutes, and the other steps were the same as in the example 1, to obtain a nanoporous iron phosphide cube.
Example 10:
the sulfuric acid concentration in the step (4) in example 1 was changed to 0.3M, and the other steps were the same as in example 1, to obtain a nanoporous iron phosphide cube.
Example 11:
the sulfuric acid concentration in the step (4) in example 1 was changed to 0.7M, and the other steps were the same as in example 1, to obtain a nanoporous iron phosphide cube.
Claims (3)
1. A preparation method of a nano-porous iron phosphide cube comprises the following steps:
(1) preparing an electrolyte: adding a soluble iron source precursor with the concentration of 0.015-0.035M and a phosphorus source precursor with the concentration of 0.4-0.6M into water, and performing ultrasonic treatment to obtain an electrolyte solution, wherein the iron source precursor is ferrous chloride tetrahydrate, ferrous nitrate hexahydrate or ferrous sulfate heptahydrate, and the phosphorus source precursor is sodium hypophosphite;
(2) preparing an electrolytic cell: taking carbon paper as a working electrode, arranging a reference electrode and a counter electrode in an electrolytic cell at the same time, and transferring the electrolyte solution prepared in the step (1) into the electrolytic cell for electrochemical deposition;
(3) carrying out electrochemical deposition: in the electrolytic cell prepared in the step (2), a chronoamperometry method is selected, and electrochemical deposition is continuously carried out for 20-40 minutes under the condition that the initial potential parameter is-0.95V;
(4) acid etching is used: and (4) soaking the carbon paper deposited in the step (3) in a sulfuric acid solution with the concentration of 0.3-0.7M, and standing to obtain the nano porous ferric phosphide cube.
2. A nanoporous iron phosphide cube produced by the method of claim 1.
3. Use of the nanoporous iron phosphide cube of claim 2 as a hydrogen evolution reaction catalyst.
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| CN108807941A (en) * | 2018-07-18 | 2018-11-13 | 江苏科技大学 | The preparation method and application of iron phosphide nanometer sheet and biomass carbon composite material |
| CN109136983A (en) * | 2018-09-26 | 2019-01-04 | 太原理工大学 | A kind of Mo/Ni/Co/P/C composite material and preparation method and application |
| CN109261177A (en) * | 2018-09-30 | 2019-01-25 | 温州大学 | Nanoscale nickel phosphide/carbon cloth composite material and preparation method thereof and the application in elctro-catalyst |
| CN109267094A (en) * | 2018-10-19 | 2019-01-25 | 温州大学 | A kind of Heteroatom doping porous carbon/phosphatization iron composite material |
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| US8343327B2 (en) * | 2010-05-25 | 2013-01-01 | Reel Solar, Inc. | Apparatus and methods for fast chemical electrodeposition for fabrication of solar cells |
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|---|---|---|---|---|
| CN108807941A (en) * | 2018-07-18 | 2018-11-13 | 江苏科技大学 | The preparation method and application of iron phosphide nanometer sheet and biomass carbon composite material |
| CN109136983A (en) * | 2018-09-26 | 2019-01-04 | 太原理工大学 | A kind of Mo/Ni/Co/P/C composite material and preparation method and application |
| CN109261177A (en) * | 2018-09-30 | 2019-01-25 | 温州大学 | Nanoscale nickel phosphide/carbon cloth composite material and preparation method thereof and the application in elctro-catalyst |
| CN109267094A (en) * | 2018-10-19 | 2019-01-25 | 温州大学 | A kind of Heteroatom doping porous carbon/phosphatization iron composite material |
Non-Patent Citations (2)
| Title |
|---|
| "Toward High-Performance and Low-Cost Hydrogen Evolution Reaction Electrocatalysts: Nanostructuring Cobalt Phosphide (CoP) Particles on Carbon Fiber Paper";Shu Hearn Yu et al.;《ACS APPLIED MATERIALS & INTERFACES 》;20180410;第10卷(第17期);第14777-14785页 * |
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