CN110372163A - A kind of method of sump oil soil harmless biological processing - Google Patents

A kind of method of sump oil soil harmless biological processing Download PDF

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Publication number
CN110372163A
CN110372163A CN201910571736.7A CN201910571736A CN110372163A CN 110372163 A CN110372163 A CN 110372163A CN 201910571736 A CN201910571736 A CN 201910571736A CN 110372163 A CN110372163 A CN 110372163A
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China
Prior art keywords
sump oil
oil soil
soil
biological processing
treatment agent
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CN201910571736.7A
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Chinese (zh)
Inventor
梁庆
贠军贤
卜涛
田兵
张颂红
周婷
万立之
陈蒙
方艺璇
张晓超
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Shaanxi Feide Europe Environmental Technology Co Ltd
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Shaanxi Feide Europe Environmental Technology Co Ltd
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Priority to CN201910571736.7A priority Critical patent/CN110372163A/en
Publication of CN110372163A publication Critical patent/CN110372163A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/32Hydrocarbons, e.g. oil

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Processing Of Solid Wastes (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention discloses a kind of methods of sump oil soil harmless biological processing.This method realizes the harmless treatment of sump oil soil with the Residual petroleum hydrocarbon in nettle and microbiological garbage treatment agent Synergistic degradation sump oil soil.Cell in microbiological garbage treatment agent removes the petroleum hydrocarbon in sump oil soil using petroleum hydrocarbon as substrate, by metabolic degradation;Meanwhile nettle well developed root system, mushrooming out in sump oil soil, sump oil soil oxygen supply microenvironment is improved, the microbial reproduction and metabolic degradation in inorganic agent are promoted.Method provided by the invention is without secondary pollution, and sustainable and environmental safety is good, can be realized the harmless treatment of sump oil soil, and industrialization amplification is easy, has broad application prospects in petroleum pollution and field of environment protection.

Description

A kind of method of sump oil soil harmless biological processing
Technical field
The invention belongs to environmental protection technical fields, and in particular to a kind of method of sump oil soil harmless biological processing.
Background technique
Petroleum sludge is the danger wastes generated in the industrial process such as oil-gas mining, storage and transportation and refining, bulky, Processing is difficult, is current worldwide problem.In recent years, in industrial process using three phase separation, filters pressing and pyrolysis etc. Method carries out minimizing processing to petroleum sludge, reduces the volume of oil sludge.But it is produced in these treatment processes Sump oil soil, wherein the content of petroleum hydrocarbon can not discharge still 5 ~ 10%, it is still desirable to further harmless treatment.
Oil sludge local products amount is big, and harmless treatment is difficult.The petroleum hydrocarbon contained in sump oil soil is discharged into environment can be right Animals and plants, water source, atmosphere and human lives bring serious threat.By sump oil soil by high temperature incineration, it is prepared into other Material, such as building brick are the processing approach that current oil-sludge treatment enterprise uses.But burn and produce secondary pollution, simultaneously Prepared material still has pollutant residual, it is difficult to industrial application.Therefore, the method for exploring the harmless treatment of sump oil soil, It is of great significance.
Summary of the invention
For the above-mentioned problems in the prior art, it is an object of that present invention to provide a kind of sump oil soil harmless biologicals The method of processing.
Present invention provide the technical scheme that
A kind of method of sump oil soil harmless biological processing, the method is made with the collaboration of nettle and microbiological garbage treatment agent With, degrade sump oil soil in Residual petroleum hydrocarbon, keep sump oil soil innoxious.
A kind of method of described sump oil soil harmless biological processing, the method the following steps are included:
1) microbiological garbage treatment agent is uniformly mixed with sump oil soil, and nutritional substrate auxiliary material is added, it is smooth to be made with a thickness of 30cm The mixing sump oil soil of left and right;
2) nettle seed is sprouted, is sowed in gained mixing sump oil soil;
3) it keeps the skin wet, keeps certain illumination condition and ventilation, maintain plant strain growth and microbial reproduction, degrade;
4) plant strain growth and reparation certain time, are turned over, and plant is crushed as the organic biomass in sump oil soil, Repeated recycling utilize.
The step of described sump oil soil harmless biological processing method, which is characterized in that micro- life in the step 1) Object inorganic agent is the graininess CSETIA-BR series microbiological garbage treatment agent of fixed oil degradation microorganism, can complete natural degradation.
The step of described sump oil soil harmless biological processing method, which is characterized in that microorganism in the step 1) The dosage (by mass) of inorganic agent is 1 ~ 4.6 kg/m3Sump oil soil.
The step of described sump oil soil harmless biological processing method, which is characterized in that the nutrition in the step 1) Substrate auxiliary material is the mixture of the 20:1:1:280:17 in mass ratio such as glucose, yeast powder, peptone, compound fertilizer and water configuration, Dosage (by mass) is 1.5 ~ 16 times of microbiological garbage treatment agent quality.
Further, the dosage of nettle seed is 0.01 ~ 0.02 kg/ m in the step 23Mix sump oil soil.
Further, the degradation conditions such as illumination, ventilation, moisturizing in the step 3) are natural conditions.
Further, the repair time in the step 4) is 40 ~ 50 days.
By using above-mentioned technology, the invention has the following beneficial effects:
1) sump oil soil is the solid waste of generation during the processing of oil sludge three phase separation, filters pressing or pyrolysis processing etc., wherein Still contain a large amount of crude oil, harmless treatment is always a problem.The present invention provides a kind of new sump oil soil without Evil metaplasia substance treating method, it is without secondary pollution, there is distinct sustainability.
2) method provided by the invention realizes the innoxious place of sump oil soil using the Synergistic degradation of nettle and microorganism Reason, microorganism remove the petroleum hydrocarbon in sump oil soil using petroleum hydrocarbon as substrate, by metabolic degradation;And nettle well developed root system, Its growth in sump oil soil is rapid, can improve sump oil soil oxygen supply microenvironment well, promote in inorganic agent Microbial reproduction and metabolic degradation can be realized the thorough harmless treatment of sump oil soil.
3) method provided by the invention, process cycle is short, and industrialization amplification is easy, petroleum pollution and ring in inland Border protection field has broad application prospects.
Specific embodiment
The present invention is described further combined with specific embodiments below, but protection scope of the present invention is not limited in This:
Embodiment 1
By the CSETIA-BR series microorganism renovation agent of the fixed oil degradation bacterium of 1 kg, 1.1 m are put into3In oil contaminated soil, It is uniformly mixed, is 6.0%(w/w through gravimetric method detection contaminated soil oil content, similarly hereinafter);16 kg nutritional substrate auxiliary material (Portugals are added The mixture that grape sugar, yeast powder, peptone, compound fertilizer and water 20:1:1:280:17 in mass ratio are configured), it is then smooth to be made With a thickness of the mixing sump oil soil of 30 cm or so;After about 0.022 kg nettle seed is sprouted, it is seeded in mixing sump oil soil In;Moisture of supplement daily, keeps the degradation conditions such as suitable illumination, ventilation, moisturizing, natural temperature about 20 ~ 35oC is maintained Nettle growth and microbial metabolism;After repairing 50 days, by the synergistic effect of plant growth and microbial degradation, examined through gravimetric method Surveying contaminated soil oil content is 1.6%.
Embodiment 2
By the CSETIA-BR series microorganism renovation agent of the fixed oil degradation bacterium of 9.2 kg, 2.3 m are put into3Oil contaminated soil In, it is uniformly mixed, is 0.33%(w/w through gravimetric method detection contaminated soil oil content, similarly hereinafter);It is auxiliary that 13.9 kg nutritional substrates are added Material (mixture of glucose, yeast powder, peptone, compound fertilizer and water 20:1:1:280:17 in mass ratio configuration), it is then smooth The mixing sump oil soil with a thickness of 30 cm or so is made;After about 0.09 kg nettle seed is sprouted, it is seeded in mixing oil sludge In soil;Moisture of supplement daily, keeps the degradation conditions such as suitable illumination, ventilation, moisturizing, natural temperature about 20 ~ 35oC, dimension Hold nettle growth and microbial metabolism;After repairing 42 days, by the synergistic effect of plant growth and microbial degradation, through gravimetric method Detecting contaminated soil oil content is 0.02%.
Embodiment 3
By the CSETIA-BR series microorganism renovation agent of the fixed oil degradation bacterium of 7.82 kg, 1.7 m are put into3Oil contaminated soil In, it is uniformly mixed, is 0.53%(w/w through gravimetric method detection contaminated soil oil content, similarly hereinafter);17 kg nutritional substrate auxiliary materials are added The mixture of configuration (glucose, yeast powder, peptone, compound fertilizer and water 20:1:1:280:17 in mass ratio), then smooth system At the mixing sump oil soil with a thickness of 30 cm or so;After about 0.08 kg nettle seed is sprouted, it is seeded in mixing sump oil soil In;Moisture of supplement daily, keeps the degradation conditions such as suitable illumination, ventilation, moisturizing, natural temperature about 20 ~ 35oC is maintained Nettle growth and microbial metabolism;After repairing 40 days, by the synergistic effect of plant growth and microbial degradation, examined through gravimetric method Contaminated soil oil content is surveyed less than 0.001%.
Content described in this specification is only to enumerate to inventive concept way of realization, and protection scope of the present invention is not answered When the concrete form for being seen as limited by embodiment and being stated.

Claims (5)

1. a kind of method of sump oil soil harmless biological processing, which is characterized in that the method is with nettle and microorganism The synergistic effect of inorganic agent, degrade sump oil soil in Residual petroleum hydrocarbon, keep sump oil soil innoxious.
2. a kind of method of sump oil soil harmless biological processing according to claim 1, which is characterized in that the side Method is smooth to be made the following steps are included: 1) be uniformly mixed microbiological garbage treatment agent with sump oil soil, and nutritional substrate auxiliary material is added With a thickness of the mixing sump oil soil of 30cm or so;2) nettle seed is sprouted, is sowed in gained mixing sump oil soil;3) it supplements Moisture keeps certain illumination condition and ventilation, maintains plant strain growth and microbial reproduction, degrades;4) plant strain growth and Certain time is repaired, is turned over, and plant is crushed as the organic biomass in sump oil soil, repeated recycling utilize.
3. the step of sump oil soil harmless biological processing method according to claim 2, which is characterized in that the step 1) microbiological garbage treatment agent in is the graininess CSETIA-BR series microbiological garbage treatment agent of fixed oil degradation microorganism.
4. the step of sump oil soil harmless biological processing method according to claim 2, which is characterized in that the step 1) dosage of microbiological garbage treatment agent in is by mass 1 ~ 4.6 kg/m3Sump oil soil.
5. the step of sump oil soil harmless biological processing method according to claim 2, which is characterized in that the step 1) the nutritional substrate auxiliary material in is that the 20:1:1:280:17 in mass ratio such as glucose, yeast powder, peptone, compound fertilizer and water match The mixture set, dosage are 1.5 ~ 16 times of microbiological garbage treatment agent quality by mass;
Processing realizes microorganism using petroleum hydrocarbon as substrate, removes the petroleum hydrocarbon in sump oil soil by metabolic degradation;Meanwhile nettle Well developed root system, mushrooming out in sump oil soil improve sump oil soil oxygen supply microenvironment, promote micro- in inorganic agent Biological self reproducing and metabolic degradation, this realization have and are interconnected and aperture is from sub-micron and micron dimension with pelleted substrate Super large hole is embedded with the microbial cell of degradable petroleum pollution in carrier.
CN201910571736.7A 2019-06-28 2019-06-28 A kind of method of sump oil soil harmless biological processing Pending CN110372163A (en)

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CN201910571736.7A CN110372163A (en) 2019-06-28 2019-06-28 A kind of method of sump oil soil harmless biological processing

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CN110372163A true CN110372163A (en) 2019-10-25

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101890426A (en) * 2010-07-19 2010-11-24 南开大学 Method for restoring petroleum-polluted saline alkali soil by ryegrass and high efficiency microbes
CN103480644A (en) * 2013-10-12 2014-01-01 南开大学 Plant-microorganism combined method for enhanced repairing of petroleum-contaminated spetroleum
CN103664340A (en) * 2013-11-15 2014-03-26 青岛天人环境股份有限公司 Soil culture medium applicable to petroleum hydrocarbon pollution
CN104001712A (en) * 2014-02-28 2014-08-27 天津科技大学 Method for repairing petroleum-contaminated soil through combination of alkali grass and microbes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101890426A (en) * 2010-07-19 2010-11-24 南开大学 Method for restoring petroleum-polluted saline alkali soil by ryegrass and high efficiency microbes
CN103480644A (en) * 2013-10-12 2014-01-01 南开大学 Plant-microorganism combined method for enhanced repairing of petroleum-contaminated spetroleum
CN103664340A (en) * 2013-11-15 2014-03-26 青岛天人环境股份有限公司 Soil culture medium applicable to petroleum hydrocarbon pollution
CN104001712A (en) * 2014-02-28 2014-08-27 天津科技大学 Method for repairing petroleum-contaminated soil through combination of alkali grass and microbes

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