CN110368791A - A kind of industrial waste gas purifying technique - Google Patents

A kind of industrial waste gas purifying technique Download PDF

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Publication number
CN110368791A
CN110368791A CN201910721678.1A CN201910721678A CN110368791A CN 110368791 A CN110368791 A CN 110368791A CN 201910721678 A CN201910721678 A CN 201910721678A CN 110368791 A CN110368791 A CN 110368791A
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partition
exhaust gas
framework
sodium hydroxide
waste gas
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王亚威
沈恒祥
林继承
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/44Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Catalysts (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention belongs to technical field of waste gas treatment, specifically a kind of industrial waste gas purifying technique, used waste gas purification apparatus includes framework, electric pushrod and controller;It is fixed with first partition in the framework, and is equipped with second partition below first partition;The second partition is slidably connected to framework inner wall;Space between the first partition and second partition is equipped with sodium hydroxide solution;First tracheae is arranged across first partition, and first intratracheally slidably connects the second tracheae;Second tracheae lower end is located at the liquid level of sodium hydroxide solution or less;The framework outer wall is fixed with storing ring;Floating block is slidably connected in the storing ring;The present invention passes through the ejection of sodium hydroxide solution and photocatalyst, purifies to exhaust gas, while can purify to the smell in exhaust gas, and can realize the recycling and reusing of sodium hydroxide solution and photocatalyst.

Description

A kind of industrial waste gas purifying technique
Technical field
The invention belongs to technical field of waste gas treatment, specifically a kind of industrial waste gas purifying technique.
Background technique
Industrial waste gas refers to that generate in plant area, enterprise fuel combustion and production process various are discharged into containing for air The general name of contaminant gases.
These exhaust gas have: carbon dioxide, carbon disulfide, hydrogen sulfide, fluoride, nitrogen oxides, chlorine, hydrogen chloride, an oxidation Carbon, sulfuric acid (mist) lead mercury, beryllide, flue dust and industrial dust, are discharged into atmosphere, can pollute air.These substances pass through difference Approach respiratory tract enter the internal of people, some directly generates harm, and some is there are also cumulative effect, harm people that can be more serious Health, wherein in exhaust gas content at most be sulphur class compound.
Photocatalyst is a kind of using Nano titanium dioxide as the total of the photosemiconductor material with photo-catalysis function of representative Claim, it is coated on substrate surface, under the action of ultraviolet light and visible light, generates strong catalytic degradation function: can effectively drop Solve toxic and harmful gas in air;It can effectively kill various bacteria, and the toxin that bacterium or fungi release can be decomposed and nothing Evilization processing;It is also equipped with simultaneously except functions such as formaldehyde, deodorization, anti-pollution, purification air;Photocatalyst material mainly have nano TiO 2, ZnO, CdS, WO3, Fe2O3, PbS, SnO2, ZnS, SrTiO3, SiO2 etc.;Light irradiation titanium dioxide electrodes can carry out the electrolysis of water Reaction;I.e. by air water or oxygen catalytic at oxidability hydroxyl radical free radical and ultra-oxygen anion free radical, active oxygen Deng the photoproduction active group with oxidability.
Industrial waste gas is handled in the prior art, and processing method is single, generally carries out simple filtering again using filter screen Discharge, and some uses spray filtering, when carrying out spray filtering, the water body after spray is also to carry out direct emission, not only unrestrained Water wasting resource, and certain pollution is caused to underground water, and after industrial waste gas processing, though without compared with multi-pollutant in exhaust gas, The smell of exhaust gas is still pungent, is emitted into atmosphere and has seriously affected people's lives, can exhaust gas carry out the dress of high-precision purification Set also has with method in the prior art, but resource is unable to get effective recycling during to waste gas purification, causes Purification cost is excessively high, and small business can not undertake the investment for managing this.
Summary of the invention
In order to make up for the deficiencies of the prior art, it is single to solve exhaust gas purifying method, it is direct for purifying the substance after exhaust gas After discharge causes secondary pollution, waste gas purification, the non-synchronous purification of exhaust gas moderate stimulation smell and waste gas purification higher cost are asked Topic, a kind of industrial waste gas purifying technique proposed by the present invention.
The technical solution adopted by the present invention to solve the technical problems is: a kind of industrial waste gas purifying work of the present invention Skill, the technique the following steps are included:
S1: by the exhaust gas of industrial discharge by filter screen, by relatively large particle filtering, and will be led to by the exhaust gas of filter screen Plasma electric stratum reticulare is crossed, the heavy metal in exhaust gas is removed;The exhaust gas after primary filtration is passed through in waste gas purification apparatus again, and Exhaust gas starts waste gas purification apparatus before being passed through, and can effectively be carried out to exhaust gas by the double filtration of filter screen and plasmasphere preliminary Processing, reduces the workload of waste gas purification apparatus, to effectively improve the service life of waste gas purification apparatus, while improving useless The purification efficiency and degree of gas;
S2: the gas discharged in waste gas purification apparatus in S1 is passed through after anaerobic pond and is passed through in aerobic tank again, in anaerobic pond Anaerobic bacteria the organic matter in exhaust gas is just decomposed, the aerobic bacteria in aerobic tank by the organic matter in exhaust gas further into Row decomposes, and effectively improves exhaust purification efficiency and degree of purification;
S3: the exhaust gas discharged in aerobic tank will be passed through in S2 and be passed through in alkaline solution, can be arranged by the exhaust gas of alkaline solution It puts into atmosphere, remaining sulphur in exhaust gas is further dispelled by alkaline solution, is emitted into atmosphere and pollutes atmosphere;
Wherein, waste gas purification apparatus used in S1 includes framework, electric pushrod and controller;The controller is used for Control electric pushrod work;It is fixed with first partition in the framework, and is equipped with second partition below first partition;Described second Partition is slidably connected to framework inner wall;The electric pushrod quantity is two, is fixed on framework bottom interior wall, and electric pushrod Extension end is fixed on second partition lower surface;Space between the first partition and second partition is molten equipped with sodium hydroxide Liquid;Be connected between the first partition and second partition there are two retractable sack, retractable sack bottom be connected to first partition and second every Space between plate, connectivity part are equipped with check valve;The first partition upper surface is connected, and there are two atomizers;The atomization spray Head is connected to corresponding retractable sack respectively, and connectivity part is equipped with check valve;The first partition upper surface is connected, and there are two the first gas Pipe;First tracheae is arranged across first partition, and first intratracheally slidably connects the second tracheae;Under second tracheae End is located at the liquid level of sodium hydroxide solution or less;The framework is externally provided with escape pipe, and escape pipe is in the upper table of the intracorporal one end of frame Face and first partition lower surface are horizontal;When work, before exhaust gas will be passed through, keep electric pushrod intermittence flexible by controller, To push second partition to move up and down, during second partition moves up, cooperation first partition squeezes retractable sack, makes in retractable sack Sodium hydroxide solution is sprayed by atomizer, after exhaust gas enters in device, can directly be connect with the sodium hydroxide solution after atomization Touching, when second partition moves down, pulls retractable sack, makes between first partition and second partition to purify to exhaust gas Sodium hydroxide solution enters in retractable sack, supplements the consumption of sodium hydroxide solution in retractable sack, and continuous due to exhaust gas is passed through, the One partition upper space air pressure rises, and since sulfur-bearing class exhaust gas is larger compared with air quality in exhaust gas, makes the exhaust gas after tentatively evolving It floats, enters the gas after tentatively evolving in sodium hydroxide solution by the first tracheae and the second tracheae, by sodium hydroxide The double purification of solution, improves the purification efficiency of exhaust gas, and purified exhaust gas is discharged by escape pipe, is purified, mentioned by multilayer The purification efficiency of high exhaust gas, and structure is simple, is applicable to back yard industry factory.
Preferably, air bag is equipped between two retractable sacks;The air bag is fixed on first partition lower surface and second Partition upper surface;The first partition upper surface middle part is fixed with conduit, and catheter surface is uniformly fixed with spray gun;Described first every The first cavity is offered in plate;Stripper plate is slidably connected in first cavity;The first cavity below the stripper plate is empty Between communicated air bags;Storage tank is fixed with outside the framework;The storage tank is provided with photocatalyst, offers charging at the top of storage tank Mouthful;The first void space is connected to storage tank above the stripper plate, and connectivity part is equipped with check valve;The frame side wall is equipped with ultraviolet Line fluorescent tube;When work, when the second stripper plate moves up, extruding gasbag makes the first cavity above stripper plate so that stripper plate be made to move up Interior photocatalyst enters in conduit, and is sprayed by spray gun, photocatalyst can be made to come into full contact with exhaust gas since spray gun is evenly arranged, purple Outside line lamp is starting simultaneously with electric pushrod, irradiates photocatalyst by ultraviolet light and generates strong catalytic degradation effect, cooperates hydrogen-oxygen Change purification efficiency and degree of purification that sodium solution improves exhaust gas, while the water in photocatalyst and sodium hydroxide solution reacts production Raw hydroxyl radical free radical, cooperation sodium hydroxide solution improve the purification to sulphur in exhaust gas, and clean-up effect is stronger, more thoroughly, the same to time Catalyst can effectively purify the smell in exhaust gas.
Preferably, the framework outer wall is fixed with storing ring;The storing ring is respectively communicated with by the hole opened up in framework First partition upper space and first partition lower space are connected to the hole of first partition lower space close to the intracorporal side position of frame More than sodium hydroxide solution liquid level, the other end is equipped with check valve in the bottom of storing ring in hole;In the first partition Surface arches design;The storing ring is located at below storage tank;When work, it is molten that atomizer and spray gun spray sodium hydroxide respectively After liquid and photocatalyst, exhaust gas is purified, due to first partition upper surface arch design, extra sodium hydroxide solution and photocatalyst are logical Via hole flows into storing ring, and through hole enters the space between first partition and second partition, mixes with sodium hydroxide solution, Photocatalyst reacts the hydroxyl radical free radical generated with water and is supplemented in sodium hydroxide solution, increases hydroxyl free in sodium hydroxide solution The content of base can economize on resources to improve the efficiency of waste gas purification, while substance recycles, and avoid the waste of resource, from And save the cost, it is more suitable for small business.
Preferably, floating block is slidably connected in the storing ring;The floating block light material is made, and can be suspended in molten Liquid surface;The floating block surface offers the filter hole being evenly arranged, can be by particle filtering in exhaust gas;The thickness of the floating block is big Diameter in hole, and floating block annular design are close to the setting of storing ring inner wall, can prevent sodium hydroxide solution from flowing back;The storing Ring surface offers material taking mouth;When work, after first partition surface sodium hydroxide solution and photocatalyst inflow storing ring, on floating block It is floating, after sodium hydroxide solution and photocatalyst are by floating block filtering, into space between first partition and second partition, pass through floating block Filtering effectively the particulate matter in exhaust gas can be filtered, while can by material taking mouth will the lower particulate matter taking-up of filtering, avoid Grain object precipitating is more to be caused to filter hole plug, by the filter hole of floating block that the particulate matter in sodium hydroxide solution and photocatalyst is miscellaneous Matter filtering can be improved the efficiency that sodium hydroxide solution and photocatalyst recycle, excessive impurity avoided to enter sodium hydroxide solution In, sodium hydroxide is polluted, to guarantee that save the cost consumes while the purification efficiency of exhaust gas.
Preferably, filter plate is fixed in the framework, filter plate is located above first partition;The filter plate water-absorption material Material is made, and filter surface offers the stomata being evenly arranged;First tracheae upper end is arranged across filter plate, extends to Above filter plate;When work, sodium hydroxide solution by atomizer spray and photocatalyst by spray gun ejection after, to first every Exhaust gas in plate upper space is purified, and part sodium hydroxide solution and photocatalyst are attached to filter surface, passes through filtering Plate can be further to will enter the first tracheae and the second endotracheal exhaust gas further purifies, and the first tracheae passes through filtering Plate, it is ensured that pass through multiple purifying into the first endotracheal gas, and prevent particulate matter from entering first intratracheally, improve useless The degree of purification of gas, while filter plate lower surface can form water droplet, increase the contact surface of sodium hydroxide, photocatalyst and exhaust gas Product, to improve the purification efficiency of exhaust gas.
Preferably, water suction cotton is fixed in the stomata;Described water suction cotton one end is fixed on stomata inner wall, another End extends downwardly venthole setting, and is fixed with spring between stomata inner wall in the middle part of the cotton that absorbs water;When work, sodium hydroxide is molten When liquid and photocatalyst pass through atomizer and spray gun ejection respectively, water suction cotton absorbs sodium hydroxide solution and photocatalyst, cooperation Filter plate further increases the contact area of exhaust gas Yu sodium hydroxide solution and photocatalyst, improves exhaust purification efficiency, gives up simultaneously During gas passes through venthole, water suction cotton shake is driven, filter plate is hit by the shake for the cotton that absorbs water, trembles filter plate It is dynamic, while cooperation absorbent wool cloth prevents that particulate matter blocks venthole in exhaust gas, by filter plate lower surface sodium hydroxide solution and The water droplet that photocatalyst is formed is shaken off, particulate matter posterior synechia in the water droplet combination exhaust gas for preventing sodium hydroxide solution and photocatalyst from being formed Filter plate lower surface causes sodium hydroxide solution and photocatalyst to recycle difficult, to improve sodium hydroxide solution and photocatalyst The purification efficiency of exhaust gas is improved while recovery efficiency.
Beneficial effects of the present invention are as follows:
1. a kind of industrial waste gas purifying technique of the present invention, by setting electric pushrod, first partition, second every Plate, sodium hydroxide solution, photocatalyst, atomizer, spray gun, air bag and retractable sack squeeze second partition by electric pushrod With loosen air bag and retractable sack, so that sodium hydroxide solution and photocatalyst be made to spray, exhaust gas is purified, while can be to exhaust gas In smell purified, degree of purification is high.
2. a kind of industrial waste gas purifying technique of the present invention passes through setting storing ring and floating block, sodium hydroxide solution Enter in storing ring after being sprayed with photocatalyst, and filter granule foreign by floating block, make filtered sodium hydroxide solution with Photocatalyst reenters in the space between first partition and second partition, and the recycling of realization sodium hydroxide solution and photocatalyst is again It utilizes, and photocatalyst reacts the hydroxyl radical free radical generated with water, can supplement the consumption of sodium hydroxide solution.
3. a kind of industrial waste gas purifying technique of the present invention passes through filtering by setting filter plate and water suction cotton Plate can will enter the first endotracheal exhaust gas and pass through multiple purifying, while can make the cotton shake drive filter plate vibration that absorbs water, and add The recycling of fast sodium hydroxide solution and photocatalyst.
Detailed description of the invention
The present invention will be further explained below with reference to the attached drawings.
Fig. 1 is process flow chart of the invention;
Fig. 2 is the main view of waste gas purification apparatus used herein;
Fig. 3 is partial enlarged view at A in Fig. 2;
Fig. 4 is partial enlarged view at B in Fig. 2;
In figure: framework 1, electric pushrod 11, first partition 12, second partition 13, retractable sack 14, atomizer 15, first Tracheae 16, the second tracheae 17, escape pipe 18, air bag 2, conduit 21, the first cavity 22, stripper plate 23, storage tank 24, storing ring 3, Floating block 31, filter plate 4, stomata 41, water suction cotton 42.
Specific embodiment
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below Specific embodiment is closed, the present invention is further explained.
As shown in Figures 1 to 4, a kind of industrial waste gas purifying technique of the present invention, the technique the following steps are included:
S1: by the exhaust gas of industrial discharge by filter screen, by relatively large particle filtering, and will be led to by the exhaust gas of filter screen Plasma electric stratum reticulare is crossed, the heavy metal in exhaust gas is removed;The exhaust gas after primary filtration is passed through in waste gas purification apparatus again, and Exhaust gas starts waste gas purification apparatus before being passed through, and can effectively be carried out to exhaust gas by the double filtration of filter screen and plasmasphere preliminary Processing, reduces the workload of waste gas purification apparatus, to effectively improve the service life of waste gas purification apparatus, while improving useless The purification efficiency and degree of gas;
S2: the gas discharged in waste gas purification apparatus in S1 is passed through after anaerobic pond and is passed through in aerobic tank again, in anaerobic pond Anaerobic bacteria the organic matter in exhaust gas is just decomposed, the aerobic bacteria in aerobic tank by the organic matter in exhaust gas further into Row decomposes, and effectively improves exhaust purification efficiency and degree of purification;
S3: the exhaust gas discharged in aerobic tank will be passed through in S2 and be passed through in alkaline solution, can be arranged by the exhaust gas of alkaline solution It puts into atmosphere, remaining sulphur in exhaust gas is further dispelled by alkaline solution, is emitted into atmosphere and pollutes atmosphere;
Wherein, waste gas purification apparatus used in S1 includes framework 1, electric pushrod 11 and controller;The controller It works for controlling electric pushrod 11;First partition 12 is fixed in the framework 1, and below first partition 12 be equipped with second every Plate 13;The second partition 13 is slidably connected to 1 inner wall of framework;11 quantity of electric pushrod is two, is fixed on 1 bottom of framework Portion's inner wall, and the extension end of electric pushrod 11 is fixed on 13 lower surface of second partition;The first partition 12 and second partition Space between 13 is equipped with sodium hydroxide solution;Being connected between the first partition 12 and second partition 13, there are two retractable sacks 14,14 bottom of retractable sack is connected to the space between first partition 12 and second partition 13, and connectivity part is equipped with check valve;Described first 12 upper surface of partition is connected, and there are two atomizers 15;The atomizer 15 is connected to corresponding retractable sack 14 respectively, connection Place is equipped with check valve;12 upper surface of first partition is connected, and there are two the first tracheaes 16;First tracheae 16 passes through first Partition 12 is arranged, and the second tracheae 17 is slidably connected in the first tracheae 16;Second tracheae, 17 lower end is located at sodium hydroxide Below the liquid level of solution;The framework 1 is externally provided with escape pipe 18, and escape pipe 18 is in the upper surface and first of one end in framework 1 12 lower surface of partition is horizontal;When work, before exhaust gas will be passed through, keep electric pushrod 11 intermittent flexible by controller, thus Second partition 13 is pushed to move up and down, during second partition 13 moves up, cooperation first partition 12 squeezes retractable sack 14, makes to stretch Sodium hydroxide solution is sprayed by atomizer 15 in capsule 14, after exhaust gas enters in device, can directly with the hydroxide after atomization Sodium solution contact, when second partition 13 moves down, pulls retractable sack 14, makes 12 He of first partition to purify to exhaust gas Sodium hydroxide solution between second partition 13 enters in retractable sack 14, supplements the consumption of sodium hydroxide solution in retractable sack 14, Due to exhaust gas constantly be passed through, 12 upper space air pressure of first partition rise, due in exhaust gas sulfur-bearing class exhaust gas compared with air quality It is larger, so that the exhaust gas after tentatively evolving is floated, enters the gas after tentatively evolving by the first tracheae 16 and the second tracheae 17 In sodium hydroxide solution, by the double purification of sodium hydroxide solution, the purification efficiency of exhaust gas is improved, purified exhaust gas passes through Escape pipe 18 is discharged, and is purified by multilayer, improves the purification efficiency of exhaust gas, and structure is simple, is applicable to back yard industry factory.
As one embodiment of the present invention, air bag 2 is equipped between two retractable sacks 14;The air bag 2 is connected In 13 upper surface of 12 lower surface of first partition and second partition;12 upper surface middle part of first partition is fixed with conduit 21, leads 21 surface of pipe is uniformly fixed with spray gun;The first cavity 22 is offered in the first partition 12;Sliding in first cavity 22 It is connected with stripper plate 23;The 22 space communicated air bags 2 of the first cavity of 23 lower section of stripper plate;Storage is fixed with outside the framework 1 Object case 24;The storage tank 24 is provided with photocatalyst, offers feed opening at the top of storage tank 24;23 top first of stripper plate 22 space of cavity is connected to storage tank 24, and connectivity part is equipped with check valve;1 side wall of framework is equipped with quartz burner;When work, the When two partitions 13 move up, extruding gasbag 2 makes photocatalyst in 23 the first cavity 22 of top of stripper plate so that stripper plate 23 be made to move up It is sprayed into conduit 21, and through spray gun, photocatalyst can be made to come into full contact with exhaust gas since spray gun is evenly arranged, ultraviolet radiator Start simultaneously with electric pushrod 11, photocatalyst is irradiated by ultraviolet light and generates strong catalytic degradation effect, cooperates sodium hydroxide Solution improves the purification efficiency and degree of purification of exhaust gas, while the water in photocatalyst and sodium hydroxide solution reacts and generates hydroxyl Base free radical, cooperation sodium hydroxide solution improve the purification to sulphur in exhaust gas, and clean-up effect is stronger, more thoroughly, while photocatalyst Smell in exhaust gas can effectively be purified.
As one embodiment of the present invention, 1 outer wall of framework is fixed with storing ring 3;The storing ring 3 passes through frame The hole opened up in body 1 is respectively communicated with 12 lower space of 12 upper space of first partition and first partition, is connected under first partition 12 Side of the hole of side space in framework 1 is located at sodium hydroxide solution liquid level or more, the other end in the bottom of storing ring 3, and Check valve is equipped in hole;The 12 upper surface arch design of first partition;The storing ring 3 is located at 24 lower section of storage tank;Work When making, after atomizer 15 and spray gun spray sodium hydroxide solution and photocatalyst respectively, exhaust gas is purified, due in first partition 12 Surface arches design, extra sodium hydroxide solution and photocatalyst through hole flow into storing ring 3, and through hole enter first every Space between plate 12 and second partition 13, mixes with sodium hydroxide solution, and photocatalyst reacts the hydroxyl radical free radical generated with water It is supplemented in sodium hydroxide solution, increases the content of hydroxyl radical free radical in sodium hydroxide solution, to improve the effect of waste gas purification Rate, while substance recycles, and can economize on resources, and avoids the waste of resource, so that save the cost, is more suitable for small business.
As one embodiment of the present invention, floating block 31 is slidably connected in the storing ring 3;The floating block 31 Light material is made, and can be suspended in solution surface;31 surface of floating block offers the filter hole being evenly arranged, can will be in exhaust gas Particle filtering;The thickness of the floating block 31 is greater than the diameter in hole, and 31 annular design of floating block, is close to the setting of 3 inner wall of storing ring, can Prevent sodium hydroxide solution from flowing back;3 surface of storing ring offers material taking mouth;When work, 12 surface hydroxide of first partition After sodium solution and photocatalyst flow into storing ring 3, floating block 31 floats, after sodium hydroxide solution and photocatalyst are filtered by floating block 31, It, can be effectively by the particulate contaminant in exhaust gas by the filtering of floating block 31 into space between first partition 12 and second partition 13 Filtering, while can be taken out the particulate matter under filtering by material taking mouth, it avoids particulate matter precipitating is more from causing to filter hole plug, leads to The filter hole of floating block 31 is crossed to filter the particulate contaminant in sodium hydroxide solution and photocatalyst, can be improved sodium hydroxide solution and The efficiency that photocatalyst recycles, avoids excessive impurity from entering in sodium hydroxide solution, sodium hydroxide is polluted, to guarantee exhaust gas Purification efficiency while save the cost consume.
As one embodiment of the present invention, filter plate 4 is fixed in the framework 1, filter plate 4 is located at first partition 12 tops;4 water-absorbent material of filter plate is made, and 4 surface of filter plate offers the stomata 41 being evenly arranged;First gas 16 upper end of pipe is arranged across filter plate 4, is extended to the over 4 top of filter plate;When work, sodium hydroxide solution is sprayed by atomizer 15 Out and photocatalyst by spray gun spray after, the exhaust gas in 12 upper space of first partition is purified, part sodium hydroxide is molten Liquid and photocatalyst are attached to 4 surface of filter plate, can be further to will enter the first tracheae 16 and the second tracheae by filter plate 4 Exhaust gas in 17 further purifies, and the first tracheae 16 passes through filter plate 4, it is ensured that passes through into the gas in the first tracheae 16 Multiple purifying is crossed, and prevents particulate matter from entering in the first tracheae 16, improves the degree of purification of exhaust gas, while 4 lower surface of filter plate Water droplet can be formed, the contact area of sodium hydroxide, photocatalyst and exhaust gas is increased, to improve the purification efficiency of exhaust gas.
As one embodiment of the present invention, water suction cotton 42 is fixed in the stomata 41;The water suction cotton 42 one end are fixed on 41 inner wall of stomata, and the other end extends downwardly the setting of venthole 41, and absorb water in 42 middle part of cotton and stomata 41 Spring is fixed between wall;When work, when sodium hydroxide solution and photocatalyst pass through atomizer 15 and spray gun ejection respectively, inhale Water cotton 42 absorbs sodium hydroxide solution and photocatalyst, complement filter plate 4 further increase exhaust gas and sodium hydroxide solution and light The contact area of catalyst improves exhaust purification efficiency, while exhaust gas is by during venthole 41, driving water suction cotton 42 to tremble It is dynamic, filter plate 4 is hit by the shake for the cotton 42 that absorbs water, shakes filter plate 4, cooperation water suction cotton 42 prevents particle in exhaust gas While object blocks venthole 41, the water droplet that 4 lower surface sodium hydroxide solution of filter plate and photocatalyst are formed is shaken off, hydrogen is prevented 4 lower surface of particulate matter posterior synechia filter plate in the water droplet combination exhaust gas that sodium hydroxide solution and photocatalyst are formed, causes sodium hydroxide Solution and photocatalyst recycling are difficult, improve the net of exhaust gas while to improve the recovery efficiency of sodium hydroxide solution and photocatalyst Change efficiency.
When work, by the exhaust gas of industrial discharge by filter screen, by relatively large particle filtering, and the useless of filter screen will be passed through Gas removes the heavy metal in exhaust gas by plasma electric stratum reticulare;The exhaust gas after primary filtration is passed through in waste gas purification apparatus again, And start waste gas purification apparatus before exhaust gas is passed through;Before exhaust gas will be passed through, stretch 11 intermittence of electric pushrod by controller Contracting, so that second partition 13 be pushed to move up and down, during second partition 13 moves up, cooperation first partition 12 squeezes retractable sack 14, spray sodium hydroxide solution in retractable sack 14 by atomizer 15, it, can be directly and after atomization after exhaust gas enters in device Sodium hydroxide solution contact when second partition 13 moves down, pull retractable sack 14, make first to be purified to exhaust gas Sodium hydroxide solution between partition 12 and second partition 13 enters in retractable sack 14, supplements sodium hydroxide solution in retractable sack 14 Consumption, due to exhaust gas constantly be passed through, 12 upper space air pressure of first partition rise, since sulfur-bearing class exhaust gas is more empty in exhaust gas Makings amount is larger, and the exhaust gas after tentatively evolving is made to float, and the gas after tentatively evolving is made to pass through the first tracheae 16 and the second tracheae 17 enter in sodium hydroxide solution, and purified exhaust gas is discharged by escape pipe 18, when second partition 13 moves up, extruding gasbag 2, To make stripper plate 23 move up, enter photocatalyst in 23 the first cavity 22 of top of stripper plate in conduit 21, and spray by spray gun Out, ultraviolet radiator starts simultaneously with electric pushrod 11, and atomizer 15 and spray gun spray sodium hydroxide solution and light touching respectively After matchmaker, exhaust gas, due to 12 upper surface arch design of first partition, extra sodium hydroxide solution and photocatalyst through hole stream are purified Enter in storing ring 3, and through hole enters the space between first partition 12 and second partition 13, mixes with sodium hydroxide solution, After 12 surface sodium hydroxide solution of first partition and photocatalyst flow into storing ring 3, floating block 31 floats, sodium hydroxide solution and light touching It, can be effective by the filtering of floating block 31 into space between first partition 12 and second partition 13 after matchmaker is filtered by floating block 31 By the particulate contaminant filtering in exhaust gas, while the particulate matter under filtering can be taken out by material taking mouth, sodium hydroxide solution is logical After the ejection of atomizer 15 and photocatalyst are crossed by spray gun ejection, the exhaust gas in 12 upper space of first partition is purified, Part sodium hydroxide solution and photocatalyst are attached to 4 surface of filter plate, can be further to will enter the first gas by filter plate 4 Exhaust gas in pipe 16 and the second tracheae 17 further purifies, and the first tracheae 16 passes through filter plate 4, it is ensured that enters the first tracheae Gas in 16 passes through multiple purifying, and prevents particulate matter from entering in the first tracheae 16, sodium hydroxide solution and photocatalyst point Not Tong Guo atomizer 15 and spray gun when spraying, water suction cotton 42 absorbs sodium hydroxide solution and photocatalyst, exhaust gas pass through outlet During hole 41, water suction cotton 42 is driven to shake, filter plate 4 is hit by the shake for the cotton 42 that absorbs water, shakes filter plate 4, The gas discharged in waste gas purification apparatus is passed through in aerobic tank again after being passed through anaerobic pond, and the anaerobic bacteria in anaerobic pond will be in exhaust gas Organic matter just decompose, the aerobic bacteria in aerobic tank by exhaust gas organic matter further progress decompose;It will pass through aerobic The exhaust gas discharged in pond is passed through in alkaline solution, can be emitted into atmosphere by the exhaust gas of alkaline solution.
The basic principles, main features and advantages of the invention have been shown and described above.The technical staff of the industry should Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe originals of the invention Reason, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes and improvements It all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appended claims and its equivalent circle It is fixed.

Claims (6)

1. a kind of industrial waste gas purifying technique, it is characterised in that: the technique the following steps are included:
S1: by the exhaust gas of industrial discharge by filter screen, by relatively large particle filtering, and will be passed through by the exhaust gas of filter screen Ion-conductance stratum reticulare removes the heavy metal in exhaust gas;The exhaust gas after primary filtration is passed through in waste gas purification apparatus again, and in exhaust gas Start waste gas purification apparatus before being passed through;
S2: the gas discharged in waste gas purification apparatus in S1 being passed through after anaerobic pond and is passed through in aerobic tank again, detesting in anaerobic pond Oxygen bacterium just decomposes the organic matter in exhaust gas, and the aerobic bacteria in aerobic tank divides the organic matter further progress in exhaust gas Solution;
S3: the exhaust gas discharged in aerobic tank will be passed through in S2 and be passed through in alkaline solution, can be emitted by the exhaust gas of alkaline solution In atmosphere;
Wherein, waste gas purification apparatus used in S1 includes framework (1), electric pushrod (11) and controller;The controller For controlling electric pushrod (11) work;It is fixed with first partition (12) in the framework (1), and is set below first partition (12) There are second partition (13);The second partition (13) is slidably connected to framework (1) inner wall;Electric pushrod (11) quantity is Two, it is fixed on framework (1) bottom interior wall, and the extension end of electric pushrod (11) is fixed on second partition (13) lower surface; Space between the first partition (12) and second partition (13) is equipped with sodium hydroxide solution;The first partition (12) and It is connected between two partitions (13) there are two retractable sack (14), retractable sack (14) bottom is connected to first partition (12) and second partition (13) space between, connectivity part are equipped with check valve;First partition (12) upper surface is connected, and there are two atomizer (15); The atomizer (15) is connected to corresponding retractable sack (14) respectively, and connectivity part is equipped with check valve;The first partition (12) Upper surface is connected, and there are two the first tracheae (16);First tracheae (16) is arranged across first partition (12), and the first tracheae (16) the second tracheae (17) are slidably connected in;Second tracheae (17) lower end is located at the liquid level of sodium hydroxide solution or less; The framework (1) is externally provided with escape pipe (18), and escape pipe (18) is in the upper surface and first partition (12) of one end in framework (1) Lower surface is horizontal.
2. a kind of industrial waste gas purifying technique according to claim 1, it is characterised in that: two retractable sacks (14) it Between be equipped with air bag (2);The air bag (2) is fixed on first partition (12) lower surface and second partition (13) upper surface;Described One partition (12) upper surface middle part is fixed with conduit (21), and conduit (21) surface is uniformly fixed with spray gun;The first partition (12) the first cavity (22) are offered in;Stripper plate (23) are slidably connected in first cavity (22);The stripper plate (23) the first cavity (22) space communicated air bags (2) below;Storage tank (24) are fixed with outside the framework (1);The storing Case (24) is provided with photocatalyst, offers feed opening at the top of storage tank (24);First cavity (22) above the stripper plate (23) Space is connected to storage tank (24), and connectivity part is equipped with check valve;Framework (1) side wall is equipped with quartz burner.
3. a kind of industrial waste gas purifying technique according to claim 2, it is characterised in that: framework (1) outer wall is connected There are storing ring (3);The storing ring (3) by the hole opened up in framework (1) be respectively communicated with first partition (12) upper space and First partition (12) lower space is connected to side of the hole of first partition (12) lower space in framework (1) and is located at hydrogen-oxygen Change sodium solution liquid level or more, the other end is equipped with check valve in the bottom of storing ring (3) in hole;The first partition (12) Upper surface arch design;The storing ring (3) is located at below storage tank (24).
4. a kind of industrial waste gas purifying technique according to claim 3, it is characterised in that: in the storing ring (3) Slidably connect floating block (31);Floating block (31) light material is made, and can be suspended in solution surface;Floating block (31) surface The filter hole being evenly arranged is offered, it can be by particle filtering in exhaust gas;The thickness of the floating block (31) is greater than the diameter in hole, and floating Block (31) annular design is close to the setting of storing ring (3) inner wall;Storing ring (3) surface offers material taking mouth.
5. a kind of industrial waste gas purifying technique according to claim 1, it is characterised in that: be fixed in the framework (1) Filter plate (4), filter plate (4) are located above first partition (12);Filter plate (4) water-absorbent material is made, and filter plate (4) Surface offers the stomata (41) being evenly arranged;First tracheae (16) upper end is arranged across filter plate (4), extends to filtering Above plate (4).
6. a kind of industrial waste gas purifying technique according to claim 5, it is characterised in that: be connected in the stomata (41) There are water suction cotton (42);Described water suction cotton (42) one end is fixed on stomata (41) inner wall, and the other end extends downwardly venthole (41) it is arranged, and absorbs water and be fixed with spring between cotton (42) middle part and stomata (41) inner wall.
CN201910721678.1A 2019-08-06 2019-08-06 A kind of industrial waste gas purifying technique Withdrawn CN110368791A (en)

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CN112604479A (en) * 2020-11-25 2021-04-06 卢振杰 Chemical processing waste gas purification method
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CN106237835A (en) * 2016-08-12 2016-12-21 广州市净水有限公司 Urban wastewater treatment firm high concentration organic odoriferous emission-control equipment and process technique
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