CN110359879A - A kind of abandoned well method for blocking - Google Patents

A kind of abandoned well method for blocking Download PDF

Info

Publication number
CN110359879A
CN110359879A CN201810252783.0A CN201810252783A CN110359879A CN 110359879 A CN110359879 A CN 110359879A CN 201810252783 A CN201810252783 A CN 201810252783A CN 110359879 A CN110359879 A CN 110359879A
Authority
CN
China
Prior art keywords
abandoned well
parts
slurry
weight
well
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810252783.0A
Other languages
Chinese (zh)
Other versions
CN110359879B (en
Inventor
张亚明
范红喜
王海军
高振涛
张裔
王培森
杨晶
柳灵艳
李昊辰
李磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Natural Gas Co Ltd
Original Assignee
China Petroleum and Natural Gas Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Natural Gas Co Ltd filed Critical China Petroleum and Natural Gas Co Ltd
Priority to CN201810252783.0A priority Critical patent/CN110359879B/en
Publication of CN110359879A publication Critical patent/CN110359879A/en
Application granted granted Critical
Publication of CN110359879B publication Critical patent/CN110359879B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B33/00Sealing or packing boreholes or wells
    • E21B33/10Sealing or packing boreholes or wells in the borehole
    • E21B33/13Methods or devices for cementing, for plugging holes, crevices, or the like
    • E21B33/134Bridging plugs
    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21FSAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
    • E21F17/00Methods or devices for use in mines or tunnels, not covered elsewhere
    • E21F17/16Modification of mine passages or chambers for storage purposes, especially for liquids or gases

Landscapes

  • Engineering & Computer Science (AREA)
  • Mining & Mineral Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of abandoned well method for blocking, belong to well workover field.The method for blocking includes: will be in oil pipe tripping in abandoned well at predetermined depth.By oil pipe to the protection plug slurry of injection predetermined amount above the cement plug of the abandoned well, and protection plug slurry is staticly settled, obtains protection plug, complete the closure to abandoned well.Protection plug slurry is prepared by the following method: the blanc fixe of the water of 980-1020 parts by weight, the bentonite of 40-60 parts by weight, the sodium carbonate of 2-3 parts by weight, 1000-1050 parts by weight is mixed; and stir the first preset time; hydration swelling after mixing bentonite, sodium carbonate, blanc fixe with water forms mixture slurry.The diluent of 10-20 parts by weight is added into mixture slurry and stirs the second preset time, forms protection plug slurry.Even if producing gap between abandoned well method for blocking cement plug provided by the invention and the borehole wall of abandoned well, it can also be leaked to avoid the natural gas in abandoned well, improve the plugging effect to abandoned well.

Description

A kind of abandoned well method for blocking
Technical field
The present invention relates to well workover technology field, in particular to a kind of abandoned well method for blocking.
Background technique
Gas storage is a kind of artificial oil gas that the next natural gas of long distance pipeline conveying is refilled the underground space and is formed Hiding, in order to avoid natural gas leaking occurs for abandoned well unserviceable in gas storage, to influence the safety work of gas storage, palpus Abandoned well is permanently blocked.
The relevant technologies block abandoned well unserviceable in gas storage using cement plug.Specifically, to wait block Abandoned well in inject predetermined amount cement slurry can form cement plug after the cement slurry solidify in exhaust gas well, with realization Closure to abandoned well.
Inventor find the relevant technologies the prior art has at least the following problems:
Cement plug plugged and abandoned well for a period of time after, be easy under the action of strata pressure between the borehole wall of abandoned well Gap is generated, to cause natural gas leaking, leaves hidden danger for the subsequent safety work of gas storage.
Summary of the invention
The embodiment of the invention provides a kind of abandoned well method for blocking, can solve above-mentioned technical problem.Specific technical solution It is as follows:
The embodiment of the invention provides a kind of abandoned well method for blocking, the method for blocking includes: to discard oil pipe tripping in In well at predetermined depth;
By the oil pipe to the protection plug slurry of injection predetermined amount above the cement plug of the abandoned well, and make the guarantor Shield plug slurry staticly settles, and obtains protection plug, completes the closure to the abandoned well;
The protection plug slurry is prepared by the following method:
By the water of 980-1020 parts by weight, the bentonite of 40-60 parts by weight, the sodium carbonate of 2-3 parts by weight, 1000-1050 The blanc fixe of parts by weight mixes, and stirs the first preset time, makes the bentonite, the sodium carbonate, the blanc fixe Hydration swelling after mixing with the water forms mixture slurry;
The diluent of 10-20 parts by weight is added into the mixture slurry and stirs the second preset time, forms the guarantor Shield plug slurry.
In a kind of possible design, first preset time is 25min-35min.
In a kind of possible design, second preset time is 10min-15min.
In a kind of possible design, the predetermined depth is 8m-15m above the cement plug.
In a kind of possible design, in by abandoned well described in the oil pipe tripping at predetermined depth after, to described useless Abandoned well carries out well-flushing.
In a kind of possible design, in the protection plug for injecting predetermined amount into the abandoned well by the oil pipe After slurry, the simple to install well head on the abandoned well.
Technical solution provided in an embodiment of the present invention has the benefit that
Abandoned well method for blocking provided in an embodiment of the present invention protects plug slurry by preparation, and by the protection plug slurry It is injected into above the cement plug of abandoned well and staticly settles, obtain protection plug, to realize the closure to abandoned well.In preparation protection plug During slurry, by using sodium carbonate, bentonite, blanc fixe and the mixed hydration swelling ability of water can be improved. By using diluent, bentonite and blanc fixe in mixture slurry can be made to precipitate, and as the growth of time exists It is constantly compacted in abandoned well, forms protection plug, the abandoned well above cement plug is blocked completely.As it can be seen that the embodiment of the present invention mentions The abandoned well method for blocking of confession is to be blocked again on the basis of cement plug to abandoned well, even if cement plug and discarded Gap is produced between the borehole wall of well, also be can use protection and is filled in plugged and abandoned well, the natural gas in abandoned well is avoided to let out Leakage, improves the plugging effect to abandoned well, ensure that the subsequent safety work of gas storage.
Specific embodiment
Unless otherwise defined, all technical terms used in the embodiment of the present invention all have usual with those skilled in the art The identical meaning understood.It to make the object, technical solutions and advantages of the present invention clearer, below will be to embodiment party of the present invention Formula is described in further detail.
The embodiment of the invention provides a kind of abandoned well method for blocking, which includes: by oil pipe tripping in abandoned well At interior predetermined depth.
By oil pipe to the protection plug slurry of injection predetermined amount above the cement plug of abandoned well, and stand protection plug slurry Precipitating obtains protection plug, completes the closure to abandoned well.
Protection plug slurry is prepared by the following method:
By the water of 980-1020 parts by weight, the bentonite of 40-60 parts by weight, the sodium carbonate of 2-3 parts by weight, 1000-1050 The blanc fixe of parts by weight mixes, and stirs the first preset time, water after mixing bentonite, sodium carbonate, blanc fixe with water Change expansion, forms mixture slurry.
The diluent of 10-20 parts by weight is added into mixture slurry and stirs the second preset time, forms protection plug slurry.
In " staticly settling protection plug slurry, to obtain protection plug ", bentonite and blanc fixe in protection plug slurry It can be separated from water, and precipitate, and be constantly compacted with the extension of time of repose under the action of diluent, and then be formed Protection plug.
Abandoned well method for blocking provided in an embodiment of the present invention protects plug slurry by preparation, and by the protection plug slurry It is injected into above the cement plug of abandoned well and staticly settles, obtain protection plug, to realize the closure to abandoned well.In preparation protection plug During slurry, by using sodium carbonate, bentonite, blanc fixe and the mixed hydration swelling ability of water can be improved. By using diluent, bentonite and blanc fixe in mixture slurry can be made to precipitate, and as the growth of time exists It is constantly compacted in abandoned well, forms protection plug, the abandoned well above cement plug is blocked completely.As it can be seen that the embodiment of the present invention mentions The abandoned well method for blocking of confession is to be blocked again on the basis of cement plug to abandoned well, even if cement plug and discarded Gap is produced between the borehole wall of well, also be can use protection and is filled in plugged and abandoned well, the natural gas in abandoned well is avoided to let out Leakage, improves the plugging effect to abandoned well, ensure that the subsequent safety work of gas storage.
Wherein, " predetermined amount " is it is to be understood that abandoned well is filled required amount by protection plug slurry.
Bentonitic parts by weight are 40-60 parts, such as 41 parts, 43 parts, 45 parts, 47 parts, 50 parts;The parts by weight of sodium carbonate are 2-3 parts, such as 2 parts, 3 parts;The parts by weight of blanc fixe be 1000-1050, such as 1005 parts, 1010 parts, 1015 parts, 1020 parts, 1025 parts etc.;The parts by weight of diluent are 10-20 parts, such as 11 parts, 13 parts, 15 parts, 17 parts, 19 parts;The parts by weight of water are 980-1020 parts, such as 990 parts, 1000 parts, 1010 parts.By bentonite, sodium carbonate, barite that above-mentioned parts by weight are arranged Powder, diluent, water, it is ensured that finally formed protection plug is finer and close compared to cement plug, to the plugging effect of abandoned well More preferably.
Water, bentonite, sodium carbonate, blanc fixe, diluent mixing process can be with carrying out in liquid pool, this is matched The structure of liquid pool can be a variety of, for example, it can be cylindrical structure, square structure etc., as long as guaranteeing that it can hold Receive above-mentioned water, bentonite, sodium carbonate, blanc fixe, diluent.
In addition, protection plug slurry can be injected into abandoned well by way of direct circulation, i.e., protection plug slurry is from oil Pipe is injected into abandoned well.Also, in order to improve the preparation speed of protection plug, it can use blender and above-mentioned stir twice Mix operation.
In order to guarantee after bentonite, sodium carbonate, blanc fixe and water are mixed and stirred for can abundant hydration swelling, can will First preset time is set as 25min-35min (such as 28min, 30min, 32min).
In order to which the mixture slurry for guaranteeing that diluent can be formed with water, bentonite, sodium carbonate, blanc fixe stirs evenly, It can set the second preset time to 10min-15min (such as 10min, 11min, 12min).
Further, in order to guarantee that protection plug slurry can smoothly inject in the abandoned well above cement plug, while will not Cement plug is damaged, above-mentioned predetermined depth can be set to 8m-15m (such as 8m, 10m, 12m) above cement plug, is i.e. oil pipe Bottom end is located at 8m-15m above cement plug.
In order to realize the cleaning to sundries in abandoned well, protection plug is improved to the plugging effect of abandoned well, will be under oil pipe After entering in abandoned well at predetermined depth, well-flushing is carried out to abandoned well.
The well-flushing it is understood that above-mentioned clean-out service can be positive, or anti-flushing well, as long as ensuring in abandoned well Sundries can be smoothly discharged to well outer.And in order to guarantee well washing effect, it can be 2-4 weeks (such as 2 to abandoned well circulation well cleanup Week, 3 weeks etc.).
Sundries is fallen into abandoned well in order to prevent, while the protection plug in abandoned well being avoided to be destroyed, natural gas is caused to be let out Leakage.After injecting the protection plug slurry of predetermined amount into abandoned well by oil pipe, the simple to install well head on abandoned well.
Wherein, simple wellhead is common for this field, and those skilled in the art can be obtained by commercially available, and citing comes It says, can be the simple wellhead that the petrolem machinery factory Funing Zhen Ya produces and sells.
Hereinafter the present invention will be further described through by specific embodiment.
In following specific embodiments, condition person is not specified in related operation, according to normal conditions or manufacturer It is recommended that condition carry out.It is raw materials used production firm is not specified and specification person be can be with conventional products that are commercially available.
Embodiment 1
A kind of abandoned well method for blocking is present embodiments provided, which includes: by the water of oil pipe tripping in abandoned well Above the bod at 8m.
It uses clear water circulation well cleanup 2 weeks.
By the water of 980 parts by weight, the bentonite of 40 parts by weight, the sodium carbonate of 2 parts by weight, 1000 parts by weight blanc fixe Mixing, and 25min is stirred, hydration swelling after mixing bentonite, sodium carbonate, blanc fixe with water forms mixture slurry.
The diluent of 10 parts by weight is added into the mixture slurry and stirs 10min, forms protection plug slurry.
Protection plug slurry is filled to the cement plug top of abandoned well by oil pipe, and staticly settles protection plug slurry, is obtained It is filled in protection, completes the closure to abandoned well.
The abandoned well method for blocking that the embodiment 1 provides can block the abandoned well above cement plug completely.As it can be seen that this Inventive embodiments provide abandoned well method for blocking be abandoned well is blocked again on the basis of cement plug, even if Gap is produced between cement plug and the borehole wall of abandoned well, also be can use protection and is filled in plugged and abandoned well, avoids in abandoned well Natural gas leaks, and improves the plugging effect to abandoned well, ensure that the subsequent safety work of gas storage.
Embodiment 2
A kind of abandoned well method for blocking is present embodiments provided, which includes: by the water of oil pipe tripping in abandoned well Above the bod at 10m.
It uses clear water circulation well cleanup 2 weeks.
The weight of the water of 1000 parts by weight, the bentonite of 50 parts by weight, the sodium carbonate of 2.5 parts by weight, 1025 parts by weight is brilliant Mountain flour mixing, and 30min is stirred, hydration swelling after mixing bentonite, sodium carbonate, blanc fixe with water forms mixture slurry.
The diluent of 15 parts by weight is added into the mixture slurry and stirs 12min, forms protection plug slurry.
Protection plug slurry is filled to the cement plug top of abandoned well by oil pipe, and staticly settles protection plug slurry, is obtained It is filled in protection, completes the closure to abandoned well.
The abandoned well method for blocking that the embodiment 2 provides can block the abandoned well above cement plug completely.As it can be seen that this Inventive embodiments provide abandoned well method for blocking be abandoned well is blocked again on the basis of cement plug, even if Gap is produced between cement plug and the borehole wall of abandoned well, also be can use protection and is filled in plugged and abandoned well, avoids in abandoned well Natural gas leaks, and improves the plugging effect to abandoned well, ensure that the subsequent safety work of gas storage.
Embodiment 3
A kind of abandoned well method for blocking is present embodiments provided, which includes: by the water of oil pipe tripping in abandoned well Above the bod at 12m.
It uses clear water circulation well cleanup 2 weeks.
By the water of 1020 parts by weight, the bentonite of 60 parts by weight, the sodium carbonate of 3 parts by weight, 1050 parts by weight barite Powder mixing, and 35min is stirred, hydration swelling after mixing bentonite, sodium carbonate, blanc fixe with water forms mixture slurry.
The diluent of 20 parts by weight is added into the mixture slurry and stirs 15min, forms protection plug slurry.
Protection plug slurry is filled to the cement plug top of abandoned well by oil pipe, and staticly settles protection plug slurry, is obtained It is filled in protection, completes the closure to abandoned well.
The abandoned well method for blocking that the embodiment 3 provides can block the abandoned well above cement plug completely.As it can be seen that this Inventive embodiments provide abandoned well method for blocking be abandoned well is blocked again on the basis of cement plug, even if Gap is produced between cement plug and the borehole wall of abandoned well, also be can use protection and is filled in plugged and abandoned well, avoids in abandoned well Natural gas leaks, and improves the plugging effect to abandoned well, ensure that the subsequent safety work of gas storage.
The foregoing is merely presently preferred embodiments of the present invention, the protection scope being not intended to limit the invention, all in this hair Within bright spirit and principle, any modification, equivalent replacement, improvement and so on should be included in protection scope of the present invention Within.

Claims (6)

1. a kind of abandoned well method for blocking, which is characterized in that the method for blocking includes: that will preset deeply in oil pipe tripping in abandoned well At degree;
By the oil pipe to the protection plug slurry of injection predetermined amount above the cement plug of the abandoned well, and fill in the protection Slurry staticly settles, and obtains protection plug, completes the closure to the abandoned well;
The protection plug slurry is prepared by the following method:
By the water of 980-1020 parts by weight, the bentonite of 40-60 parts by weight, the sodium carbonate of 2-3 parts by weight, 1000-1050 weight The blanc fixe mixing of part, and the first preset time is stirred, make the bentonite, the sodium carbonate, the blanc fixe and institute Hydration swelling after water mixes is stated, mixture slurry is formed;
The diluent of 10-20 parts by weight is added into the mixture slurry and stirs the second preset time, forms the protection plug Slurry.
2. method for blocking according to claim 1, which is characterized in that first preset time is 25min-35min.
3. method for blocking according to claim 1, which is characterized in that second preset time is 10min-15min.
4. method for blocking according to claim 1, which is characterized in that the predetermined depth is 8m- above the cement plug 15m。
5. method for blocking according to claim 1, which is characterized in that will preset in abandoned well described in the oil pipe tripping in After depth, well-flushing is carried out to the abandoned well.
6. method for blocking according to claim 1, which is characterized in that passing through cement of the oil pipe to the abandoned well After the protection plug slurry of the predetermined amount of side's injection beyond the Great Wall, the simple to install well head on the abandoned well.
CN201810252783.0A 2018-03-26 2018-03-26 Abandoned well plugging method Active CN110359879B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810252783.0A CN110359879B (en) 2018-03-26 2018-03-26 Abandoned well plugging method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810252783.0A CN110359879B (en) 2018-03-26 2018-03-26 Abandoned well plugging method

Publications (2)

Publication Number Publication Date
CN110359879A true CN110359879A (en) 2019-10-22
CN110359879B CN110359879B (en) 2021-11-02

Family

ID=68212203

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810252783.0A Active CN110359879B (en) 2018-03-26 2018-03-26 Abandoned well plugging method

Country Status (1)

Country Link
CN (1) CN110359879B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113586004A (en) * 2020-04-30 2021-11-02 中国石油天然气股份有限公司 Method for plugging waste well of gas storage

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4429746A (en) * 1981-07-29 1984-02-07 Allard Gerald D Method and apparatus for disposing of drilling muds and wastes generated during well drilling operations and for plugging and abandoning the well
CN1126486A (en) * 1993-05-28 1996-07-10 挪威国家石油公司 Plugging liquid for plugging a subterranean formation zone
CN1292059A (en) * 1998-02-26 2001-04-18 国际壳牌研究有限公司 Compositions for use in well construction, repair and/or abandonment
US6715543B1 (en) * 1999-10-04 2004-04-06 Sandaband, Inc. Particulate matter plug for plugging a well
CN103089195A (en) * 2011-11-03 2013-05-08 大港油田集团有限责任公司 Old well plugging method for constructing underground gas storage by depleted oil-gas reservoir
CN103244071A (en) * 2012-02-09 2013-08-14 中国石油天然气股份有限公司 Method for plugging old underground gas storage well
CN106930722A (en) * 2015-12-31 2017-07-07 中国石油天然气股份有限公司 The permanent shut-in well method of the natural gas well
CN107722954A (en) * 2017-11-01 2018-02-23 中石化石油工程技术服务有限公司 A kind of sealing agent, leak stopping slurries and leak-blocking construction method for borehole wall fractures leakage

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4429746A (en) * 1981-07-29 1984-02-07 Allard Gerald D Method and apparatus for disposing of drilling muds and wastes generated during well drilling operations and for plugging and abandoning the well
CN1126486A (en) * 1993-05-28 1996-07-10 挪威国家石油公司 Plugging liquid for plugging a subterranean formation zone
CN1292059A (en) * 1998-02-26 2001-04-18 国际壳牌研究有限公司 Compositions for use in well construction, repair and/or abandonment
US6715543B1 (en) * 1999-10-04 2004-04-06 Sandaband, Inc. Particulate matter plug for plugging a well
CN103089195A (en) * 2011-11-03 2013-05-08 大港油田集团有限责任公司 Old well plugging method for constructing underground gas storage by depleted oil-gas reservoir
CN103244071A (en) * 2012-02-09 2013-08-14 中国石油天然气股份有限公司 Method for plugging old underground gas storage well
CN106930722A (en) * 2015-12-31 2017-07-07 中国石油天然气股份有限公司 The permanent shut-in well method of the natural gas well
CN107722954A (en) * 2017-11-01 2018-02-23 中石化石油工程技术服务有限公司 A kind of sealing agent, leak stopping slurries and leak-blocking construction method for borehole wall fractures leakage

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李国韬等: "油气藏型储气库废弃井封堵技术浅析", 《油气井测试》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113586004A (en) * 2020-04-30 2021-11-02 中国石油天然气股份有限公司 Method for plugging waste well of gas storage

Also Published As

Publication number Publication date
CN110359879B (en) 2021-11-02

Similar Documents

Publication Publication Date Title
US20100006288A1 (en) Sorel cements and methods of making and using same
CN104726078B (en) A kind of GEL USED FOR PLUGGING WELL LOST CIRCULATION and preparation method thereof
CN101693827B (en) Coagulation composite sealing agent
CN107382208B (en) Quick-setting early strength mixed slurry
CN103485345A (en) Construction method for covering layer closed porthole high-pressure curtain grouting
CN103304194B (en) A kind of grout material for bag type paste injection hole sealing device
CN103666439B (en) Seawater-based instant fracturing fluid and preparation method thereof
CN106995686B (en) Controllable gelling plugging agent
CN108166535A (en) A kind of construction method of bellows leak stopping
CN111663948B (en) Water-rich sand-gravel stratum shield muck improvement additive and preparation method thereof
CN109749748A (en) A kind of rich water round gravel stratum shield sediment improvement method and sediment improvement agent
CN110359879A (en) A kind of abandoned well method for blocking
CN111763058A (en) Preparation method of building gypsum based on modified phosphogypsum
WO2019095420A1 (en) Method for enlarging safety density window of well drilling borehole formation
CN111793482A (en) Plugging slurry for program plugging and method for plugging drilling loss of oil and gas well
RU2116432C1 (en) Method for restoring tightness of production strings
CN105114032B (en) A kind of method that use cross-linked polymer gel sealing agent carries out middle-deep well leak stopping
CN107325799A (en) A kind of oil-well cement acrylic compounds fluid loss agent and its preparation method and application
CN104045271A (en) Plugging agent for oil field or natural gas extraction and preparation method thereof
JP2008088040A (en) Cement composition for fixing bolt and continuous construction method for the same
CN111793484A (en) Leakage stopping slurry and method for controlling leakage loss and stopping leakage of drilling fluid of oil and gas well
CN101948679A (en) Intelligent reservoir drilling completion fluid system and preparation method thereof
CN204783051U (en) Thick liquid blender
CN104529339B (en) A kind of polypropylene cross-linked copolymer fiber concrete leak stopping slurry
US2795508A (en) Sulfoalkyl cellulose ethers and their salts as hydraulic natural cement set retarders

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant