CN110354772A - A kind of flue gas directly draws denitration urea pyrolysis device and method - Google Patents

A kind of flue gas directly draws denitration urea pyrolysis device and method Download PDF

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Publication number
CN110354772A
CN110354772A CN201910722647.8A CN201910722647A CN110354772A CN 110354772 A CN110354772 A CN 110354772A CN 201910722647 A CN201910722647 A CN 201910722647A CN 110354772 A CN110354772 A CN 110354772A
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flue gas
urea pyrolysis
pyrolysis
urea
furnace
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唐亮
张朋
周福伟
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Kunshan 31 Environmental Protection Technology Co Ltd
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Kunshan 31 Environmental Protection Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D45/00Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/12Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces
    • B01D45/16Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces generated by the winding course of the gas stream, the centrifugal forces being generated solely or partly by mechanical means, e.g. fixed swirl vanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8634Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/0013Controlling the temperature of the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00121Controlling the temperature by direct heating or cooling
    • B01J2219/00123Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00132Controlling the temperature using electric heating or cooling elements
    • B01J2219/00135Electric resistance heaters

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of flue gases directly to draw denitration urea pyrolysis device and method, belongs to thermal power generation technical field of environment protection equipment.Include: boiler, smoke taking mouth is offered on the furnace wall of boiler, smoke taking mouth is connected to one end of gas inlet pipeline;Cyclone separator, cyclone separator are arranged on gas inlet pipeline;Deduster, deduster are arranged on gas inlet pipeline, and the side that cyclone separator deviates from smoke taking mouth is arranged in deduster;Cold air duct, cold air duct is connected to by cold wind electric butterfly valve with gas inlet pipeline, and cold air duct is between smoke taking mouth and cyclone separator;The entrance of urea pyrolysis furnace, urea pyrolysis furnace is connected to the other end of gas inlet pipeline, and the outlet of urea pyrolysis furnace has several pyrolysis oven outlet conduits, and each pyrolysis oven outlet conduit is provided with blower.A kind of flue gas provided by the invention directly draws denitration urea pyrolysis device and method, energy-saving, can guarantee system stable operation.

Description

A kind of flue gas directly draws denitration urea pyrolysis device and method
Technical field
The present invention relates to thermal power generation technical field of environment protection equipment, it is specifically related to a kind of flue gas and directly draws denitration urea pyrolysis Device and method.
Background technique
Contain a large amount of nitrogen oxides (NOx) in the flue gas that thermal power plant coal unit generates at present, for by nitrogen oxidation Object (NOx) concentration is reduced to national security discharge standard, and domestic thermal power plant mainstream technology prepares ammonia conduct using urea pyrolysis Reducing agent, selective catalytic reduction (SCR) flue-gas denitration process.Heat source uses air preheater outlet heat primary air (~300 DEG C) enter urea pyrolysis furnace after electric heater is heated to (~580 DEG C), the urea liquid sprayed by spray gun is pyrolyzed, heat The ammonia (as reducing agent) that solution generates is transported to SCR reactor and is reacted.In former hot-air system, electric heater conduct The core equipment of this system, power is big, power consumption is high, high failure rate, and heating tube leakage easy to wear, overtemperature tripping etc. lead to denitration system It unites out of service, discharge is exceeded, and equipment dependability is low.
Summary of the invention
For the above-mentioned problems in the prior art, it is desirable to provide a kind of flue gas directly draws denitration urea pyrolysis device and side High temperature flue-gas from boiler is introduced directly into urea pyrolysis furnace as the technology of heat source by method, replaces electric heater to prepare heat source with this, It can guarantee system stable operation while reaching energy-saving again, manufacture and easy for installation practical.
Specific technical solution is as follows:
A kind of flue gas directly draws in denitration urea pyrolysis device, including
Boiler offers smoke taking mouth on the furnace wall of boiler, and smoke taking mouth is connected to one end of gas inlet pipeline;
Cyclone separator, cyclone separator are arranged on gas inlet pipeline;
Deduster, deduster are arranged on gas inlet pipeline, and deduster setting deviates from smoke taking mouth in cyclone separator Side;
Cold air duct, cold air duct are connected to by cold wind electric butterfly valve with gas inlet pipeline, and cold air duct is positioned at taking Between mouth and cyclone separator;
The entrance of urea pyrolysis furnace, urea pyrolysis furnace is connected to the other end of gas inlet pipeline, and urea pyrolysis furnace goes out Mouth is communicated with several pyrolysis oven outlet conduits, and each pyrolysis oven outlet conduit is provided with blower;
Former hot-air system, the electric heater in former hot-air system are connected by the entrance of heat primary air pipeline and urea pyrolysis furnace It is logical.
A kind of above-mentioned flue gas directly draws in denitration urea pyrolysis device, also has the feature that, further includes cryogenic overheating The horizontal flue region in boiler is arranged in device, low temperature superheater, and the furnace wall of low temperature superheater rear end is arranged in smoke taking mouth.
A kind of above-mentioned flue gas directly draws in denitration urea pyrolysis device, also has the feature that, the height of smoke taking mouth output Warm flue-gas temperature is not less than 580 DEG C.
A kind of above-mentioned flue gas directly draws in denitration urea pyrolysis device, also has the feature that, further includes electric gate valve One and electric gate valve two, cyclone separator the side of smoke taking mouth is provided with electric gate valve one, furthermore deduster deviate from whirlwind The side of separator is provided with electric gate valve two.
A kind of above-mentioned flue gas directly draws in denitration urea pyrolysis device, also has the feature that, further includes electric gate valve Three, electric gate valve three is additionally provided on heat primary air pipeline.
A kind of above-mentioned flue gas directly draws in denitration urea pyrolysis device, also has the feature that, pyrolysis oven outlet conduit Two are provided with, one is normally opened pyrolysis oven outlet conduit, and another is spare pyrolysis oven outlet conduit.
A kind of above-mentioned flue gas directly draws in denitration urea pyrolysis device, also has the feature that, normally opened pyrolysis outlet of still It is provided with blower one on pipeline, is provided with electric gate valve four and electric gate valve on the normally opened pyrolysis oven outlet conduit of one two sides of blower Five;It is provided with blower two on spare pyrolysis oven outlet conduit, is provided with electricity on the spare pyrolysis oven outlet conduit of two two sides of blower Dynamic gate valve six and electric gate valve seven.
A kind of above-mentioned flue gas directly draws in denitration urea pyrolysis device, also has the feature that, blower one and blower two Interior impeller surface carries out sprayed ceramic processing.
A kind of above-mentioned flue gas directly draws in denitration urea pyrolysis device, also has the feature that, normally opened pyrolysis outlet of still Pipeline and spare pyrolysis oven outlet conduit are connected to away from one end of urea pyrolysis furnace with SCR reactor.
A kind of flue gas directly draws the method for denitration urea pyrolysis, comprising:
Step 1: by the high-temperature flue gas that is generated in boiler by first separating, after after the two-stage adsorbed removes dust technique Into urea pyrolysis furnace;Or after using air preheater outlet heat primary air (300 DEG C) to be heated to 580 DEG C using electric heater Into urea pyrolysis furnace;
Step 2: urea liquid is decomposed in urea pyrolysis furnace and generates ammonia;
Step 3: the ammonia (as reducing agent) for being pyrolyzed generation is transported to SCR reactor and is reacted.
The good effect of above-mentioned technical proposal is:
A kind of flue gas provided by the invention directly draws denitration urea pyrolysis device and method, and high temperature flue-gas from boiler is introduced directly into Urea pyrolysis furnace is as main heating source, and using former hot-air system as standby heat source, two systems select a carry out heat supply, using boiler height Warm flue gas be able to achieve when heat supply energy-saving, the stable operation of guarantee system entirety, and manufacture installation is simple;It additionally can be with Carry out the replacement of new and old heat source system, former hot-air system is as spare, and furthermore pyrolysis oven outlet conduit is also equipped with twice, together Another road is commonly used as spare, the reliability of guarantee system entirety.
Detailed description of the invention
Fig. 1 is the system principle for the embodiment one that a kind of flue gas of the invention directly draws denitration urea pyrolysis device and method Figure.
In attached drawing: 1, boiler;2, low temperature superheater;3, cold wind electric butterfly valve;4, cold air duct;5, gas inlet pipeline; 61, electric gate valve one;62, electric gate valve two;63, electric gate valve three;64, electric gate valve four;65, electric gate valve five;66, electronic Gate valve six;67, electric gate valve seven;7, cyclone separator;8, deduster;9, former hot-air system;91, electric heater;10, heat is primary Air piping;11, urea pyrolysis furnace;12, normally opened pyrolysis oven outlet conduit;13, spare pyrolysis oven outlet conduit;141, blower one; 142, blower two.
Specific embodiment
It is real below in order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention It applies example combination attached drawing 1 denitration urea pyrolysis device is directly drawn to a kind of flue gas provided by the invention and be specifically addressed.
Fig. 1 is the structural schematic diagram for the embodiment one that a kind of flue gas of the invention directly draws denitration urea pyrolysis device, at this In embodiment, the flue gas directly draw denitration urea pyrolysis device mainly include boiler 1, it is low temperature superheater 2, cold wind electric butterfly valve 3, cold Air piping 4, gas inlet pipeline 5, electric gate valve 1, electric gate valve 2 62, electric gate valve 3 63, electric gate valve 4 64, electricity Dynamic gate valve 5 65, electric gate valve 6 66, electric gate valve 7 67, cyclone separator 7, deduster 8, former hot-air system 9, electric heater 91, heat primary air pipeline 10, urea pyrolysis furnace 11, normally opened pyrolysis oven outlet conduit 12, spare pyrolysis oven outlet conduit 13, blower One 141, blower 2 142.
A kind of flue gas directly draws in denitration urea pyrolysis device, and smoke taking mouth is offered on the furnace wall of boiler 1, smoke taking mouth position Selection has particular requirement, it is desirable that the temperature of the high-temperature flue gas at the position is not less than 580 DEG C, smoke taking mouth and gas inlet pipeline 5 One end connection, high-temperature flue gas enters gas inlet pipeline 5.Cyclone separator 7 is arranged on gas inlet pipeline 5, whirlwind Separator 7 is for separating the dust in high-temperature flue gas.Deduster 8 is arranged on gas inlet pipeline 5, and deduster 8 The side that cyclone separator 7 deviates from smoke taking mouth is set, and dust of the deduster 8 in high-temperature flue gas is adsorbed, Neng Gouti Removal efficiency dusty, to be lowered into the dust concentration of subsequent workshop section.Cold air duct 4 passes through cold wind electric butterfly valve 3 and cigarette Gas inlet pipe road 5 is connected to, and cold air duct 4 is between smoke taking mouth and cyclone separator 7, if the temperature of high-temperature flue gas is excessively high, May by open cold wind electric butterfly valve 3, the cold wind in cold air duct 4 be passed through in gas inlet pipeline 5, to high-temperature flue gas into Row cooling.The entrance of urea pyrolysis furnace 11 is connected to the other end of gas inlet pipeline 5, and high-temperature flue gas passes through gas inlet pipeline 5 enter one of the heat source in urea pyrolysis furnace 11 as pyrolysis, and the outlet of urea pyrolysis furnace 11 has several pyrolysis outlet of stills Pipeline, each pyrolysis oven outlet conduit are provided with blower, and the ammonia generated in urea pyrolysis furnace 11 passes through a wherein pyrolysis oven Outlet conduit is delivered to SCR reactor.Electric heater 91 in former hot-air system 9 passes through heat primary air pipeline and urea pyrolysis furnace 11 entrance connection, former hot-air system 9 is also as one of the pyrolysis heat source in urea pyrolysis furnace 11.
In a preferred embodiment, as shown in Figure 1, further including low temperature superheater 2, the setting of low temperature superheater 2 exists Horizontal flue region in boiler 1, smoke taking mouth are preferably provided at the furnace wall of 2 rear end of low temperature superheater, 2 rear end of low temperature superheater Flue-gas temperature fluctuating range stablize, and the region high-temperature flue-gas be higher than 580 DEG C.
In a preferred embodiment, as shown in Figure 1, the high-temperature flue-gas of smoke taking mouth output is not less than 580 DEG C, Flue-gas temperature is excessively high can to carry out temperature adjusting by the cold wind in cold air duct 4.
In a preferred embodiment, as shown in Figure 1, further including electric gate valve 1 and electric gate valve 2 62, rotation Wind separator 7 is provided with electric gate valve 1 close to the side of smoke taking mouth, and furthermore deduster 8 deviates from the side of cyclone separator 7 Be provided with electric gate valve 2 62, the on-off of electric gate valve 1 and electric gate valve 2 62 come control the high-temperature flue gas in boiler 1 into Enter in urea pyrolysis furnace 11.
In a preferred embodiment, it as shown in Figure 1, further including electric gate valve 3 63, is gone back on heat primary air pipeline It is provided with electric gate valve 3 63, the on-off of electric gate valve 3 63 enters urea pyrolysis furnace to control the hot wind in former hot-air system 9 In 11.
In a preferred embodiment, as shown in Figure 1, pyrolysis oven outlet conduit is provided with two, one is normally opened Pyrolysis oven outlet conduit 12, another is spare pyrolysis oven outlet conduit 13, wherein when a pyrolysis oven outlet conduit is opened, separately One pyrolysis oven outlet conduit is closed.
In a preferred embodiment, as shown in Figure 1, being provided with blower one on normally opened pyrolysis oven outlet conduit 12 141, electric gate valve 4 64 and electric gate valve 5 65 are provided on the normally opened pyrolysis oven outlet conduit 12 of one 141 two sides of blower;It is standby With blower 2 142 is provided on pyrolysis oven outlet conduit 13, it is arranged on the spare pyrolysis oven outlet conduit 13 of 2 142 two sides of blower There are electric gate valve 6 66 and electric gate valve 7 67, blower 141, blower 142 are placed on the lower urea pyrolysis furnace 11 of temperature and gone out It is placed on the high gas inlet pipeline 5 of temperature on mouth pipeline without selecting, it in this way can be to avoid blower 141, blower 142 in high temperature Long-play under the bad working environments of abrasion dusty.
In a preferred embodiment, as shown in Figure 1, the impeller surface in blower 1 and blower 2 142 carries out Sprayed ceramic processing.Though high-temperature flue gas has fraction dust by the bipolar dedusting of cyclone separator 7 and deduster 8, special Sprayed ceramic processing can improve the abrasionproof performance of impeller surface, prolong the service life.
In a preferred embodiment, as shown in Figure 1, normally opened pyrolysis oven outlet conduit 12 and spare pyrolysis outlet of still Pipeline 13 is connected to away from one end of urea pyrolysis furnace 11 with SCR reactor, and it is anti-that the ammonia generated in urea pyrolysis furnace 11 passes to SCR It answers in device, as the reduction to nitrogen oxides.
Hereinafter, being illustrated with a kind of specific embodiment, it should be pointed out that described in following implementation it Structure, technique, selection are only to illustrate the feasibility of embodiment, the intention of there is no restriction the scope of the present invention.
The flue gas directly draws the working principle of denitration urea pyrolysis device, has two sets of independent heat source systems in the device, High temperature flue-gas from boiler heat source is as common heat source, and former hot-air system is as standby heat source, and the high-temperature flue gas in boiler successively passes through Cyclone separator and deduster are crossed, the flue dust in high-temperature flue gas is adsorbed, if the temperature of high-temperature flue gas is excessively high to lead to It crosses cold air duct to be adjusted temperature, high-temperature flue gas enters urea pyrolysis furnace as heat source, there is spray gun spray in urea pyrolysis furnace The urea liquid entered, high-temperature flue gas carry out thermal decomposition to urea liquid to generate ammonia, and the ammonia of generation passes through wherein one heat Solution outlet of still pipeline enters SCR reactor, to contain a large amount of nitrogen oxygen in the flue gas generated to thermal power plant coal unit Compound carries out reduction treatment.
The above is only preferred embodiments of the present invention, are not intended to limit the implementation manners and the protection scope of the present invention, right For those skilled in the art, it should can appreciate that and all replace with being equal made by description of the invention and diagramatic content It changes and obviously changes obtained scheme, should all be included within the scope of the present invention.

Claims (10)

1. a kind of flue gas directly draws denitration urea pyrolysis device characterized by comprising
Boiler offers smoke taking mouth on the furnace wall of the boiler, and the smoke taking mouth is connected to one end of gas inlet pipeline;
Cyclone separator, the cyclone separator are arranged on the gas inlet pipeline;
Deduster, the deduster are arranged on the gas inlet pipeline, and the deduster is arranged in the cyclonic separation Device deviates from the side of the smoke taking mouth;
Cold air duct, the cold air duct is connected to by cold wind electric butterfly valve with the gas inlet pipeline, and the cool air hose Road is between the smoke taking mouth and the cyclone separator;
Urea pyrolysis furnace, the entrance of the urea pyrolysis furnace are connected to the other end of the gas inlet pipeline, the urea heat The outlet of solution furnace has several pyrolysis oven outlet conduits, and each pyrolysis oven outlet conduit is provided with blower;
Former hot-air system, electric heater the entering by heat primary air pipeline and the urea pyrolysis furnace in the original hot-air system Mouth connection.
2. a kind of flue gas according to claim 1 directly draws denitration urea pyrolysis device, which is characterized in that further include low temperature mistake The horizontal flue region in the boiler is arranged in hot device, the low temperature superheater, and the smoke taking mouth is arranged in the low temperature mistake The furnace wall of hot device rear end.
3. a kind of flue gas according to claim 1 directly draws denitration urea pyrolysis device, which is characterized in that the smoke taking mouth is defeated High-temperature flue-gas out is not less than 580 DEG C.
4. a kind of flue gas according to claim 1 directly draws denitration urea pyrolysis device, which is characterized in that further include electric brake Valve one and electric gate valve two, the cyclone separator are provided with the electric gate valve one close to the side of the smoke taking mouth, furthermore The deduster is provided with the electric gate valve two away from the side of the cyclone separator.
5. a kind of flue gas according to claim 1 directly draws denitration urea pyrolysis device, which is characterized in that further include electric brake Valve three is additionally provided with the electric gate valve three on the heat primary air pipeline.
6. a kind of flue gas according to claim 1 directly draws denitration urea pyrolysis device, which is characterized in that the pyrolysis oven goes out Mouth pipeline is provided with two, and one is normally opened pyrolysis oven outlet conduit, and another is spare pyrolysis oven outlet conduit.
7. a kind of flue gas according to claim 1 directly draws denitration urea pyrolysis device, which is characterized in that the normally opened pyrolysis It is provided with blower one on outlet of still pipeline, is provided with electric brake on the normally opened pyrolysis oven outlet conduit of one two sides of blower Valve four and electric gate valve five;Be provided with blower two on the spare pyrolysis oven outlet conduit, two two sides of blower it is described standby With being provided with electric gate valve six and electric gate valve seven on pyrolysis oven outlet conduit.
8. a kind of flue gas according to claim 7 directly draws denitration urea pyrolysis device, which is characterized in that one He of blower Impeller surface in the blower two carries out sprayed ceramic processing.
9. a kind of flue gas according to claim 7 directly draws denitration urea pyrolysis device, which is characterized in that the normally opened pyrolysis Outlet of still pipeline and the spare pyrolysis oven outlet conduit are connected to away from one end of the urea pyrolysis furnace with SCR reactor.
10. a kind of flue gas directly draws the method for denitration urea pyrolysis, directly draw including flue gas described in claim 1-9 any one de- Nitre urea pyrolysis device, which is characterized in that
Step 1: by the high-temperature flue gas that is generated in the boiler by first separating, after after the two-stage adsorbed removes dust technique Into the urea pyrolysis furnace;Or 580 are heated to using electric heater using air preheater outlet heat primary air (300 DEG C) Enter the urea pyrolysis furnace after DEG C;
Step 2: urea liquid is decomposed in the urea pyrolysis furnace and generates ammonia;
Step 3: the ammonia (as reducing agent) for being pyrolyzed generation is transported to the SCR reactor and is reacted.
CN201910722647.8A 2019-08-06 2019-08-06 A kind of flue gas directly draws denitration urea pyrolysis device and method Pending CN110354772A (en)

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CN111847489A (en) * 2020-08-20 2020-10-30 沈阳工业大学 Magnesium nitrate pyrolysis furnace device with high-temperature dust removal function and method
CN112007509A (en) * 2020-08-27 2020-12-01 中航超能(北京)科技有限公司 Treatment process for dedusting and denitration of tail gas of rotary kiln
CN113368805A (en) * 2021-06-07 2021-09-10 北京未来明能科技有限公司 System and method for preparing ammonia by decomposing urea

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