CN110354655A - A kind of flue gas desulfurization takes off white treatment process - Google Patents
A kind of flue gas desulfurization takes off white treatment process Download PDFInfo
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- CN110354655A CN110354655A CN201910384720.5A CN201910384720A CN110354655A CN 110354655 A CN110354655 A CN 110354655A CN 201910384720 A CN201910384720 A CN 201910384720A CN 110354655 A CN110354655 A CN 110354655A
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/40—Acidic components
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- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/42—Basic components
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- B01D53/502—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/304—Alkali metal compounds of sodium
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- B01D2251/306—Alkali metal compounds of potassium
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- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/408—Alkaline earth metal or magnesium compounds of barium
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2251/604—Hydroxides
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- B01D2251/606—Carbonates
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Abstract
The invention belongs to fume treatment technical fields, in particular a kind of flue gas desulfurization takes off white treatment process, it is inconsistent for the reaction environment temperature between the different parts and flue gas on absorption tower in existing flue gas treating process, so that the problem that gas cleaning rate is slow and not thorough enough, now propose following scheme, it is the following steps are included: S1: preparing an absorption tower, layered shaping is carried out to absorption tower, absorption tower is divided into multiple reaction compartments from the bottom to top, and it is interconnected between multiple reaction compartments, multiple spaces are reacted from the bottom to top is successively denoted as first chamber, second chamber, third chamber, 4th chamber, 5th chamber and the 6th chamber.The present invention has rational design, the temperature that various absorbing liquids are increased using the heat that flue gas itself contains can be come into full contact with after being atomized absorbing liquid with flue gas, can effectively improve reaction rate after increasing the environment temperature of reaction, absorption processing quickly can be carried out to flue gas, realize that desulfurization takes off white purpose.
Description
Technical field
The present invention relates to fume treatment technical fields more particularly to a kind of flue gas desulfurization to take off white treatment process.
Background technique
Atmosphere pollution is one of most important environmental problem of our times, and pollutant kind is various, mainly includes particle
Object, oxysulfide, carbon monoxide, nitrogen oxidation agent, photochemical oxidant etc..To human health, industrial and agricultural production, implements material,
Animal and plant growth, social property and global environment etc. can all cause very big injury.Through retrieving, application No. is
201810583391.2 patent document discloses a kind of method that compound flue gas desulfurization and denitrification takes off white minimum discharge processing, tool
Body step is dedusting, flue gas activated, flue gas oxidation, desulphurization denitration processing, takes off white processing, the flue gas emission of smoke discharging pipe discharge
Standard be sulfur dioxide less than 35 milligrams/cubic metre, nitrogen oxides less than 50 milligrams/cubic metre, water mist less than 10 milligrams/it is vertical
Square rice is invisible to the naked eye and visualizes cigarette band；Simple process and low cost, it is white ultralow that high efficiency realizes that furnace flue gas desulphurization denitration takes off
Draining technology, operating cost is cheap, can handle the furnace flue gas of various concentration heterogeneity, and high-efficient, system can be in positive pressure
Or run under negative pressure, minimum discharge flue gas, the cigarette of exclusion are reached by dedusting, activation, oxidation, desulphurization denitration, de- butter dirt etc.
Gas is not visible cigarette band.
But existing flue gas treating process is when absorbing the harmful substance in flue gas using absorbing liquid, initially and flue gas
Reaction environment temperature when contact is influenced to can be realized preferable assimilation effect, but inhale so relatively high by flue-gas temperature
The upward position of tower is received since temperature is lower so absorption rate is low, absorbing reaction is relatively slow and not thorough enough, the flue gas of discharge
It is easy to retain a small amount of harmful substance, therefore we have proposed a kind of flue gas desulfurizations to take off white treatment process for solving above-mentioned ask
Topic.
Summary of the invention
The purpose of the present invention is to solve existing flue gas treating process in purifying smoke, the different parts on absorption tower
Reaction environment temperature between flue gas is inconsistent, so that the disadvantage that gas cleaning rate is slow and not thorough enough, and one proposed
Kind flue gas desulfurization takes off white treatment process.
To achieve the goals above, present invention employs following technical solutions:
A kind of flue gas desulfurization takes off white treatment process, comprising the following steps:
S1: preparing an absorption tower, carries out layered shaping to absorption tower, and absorption tower is divided into from the bottom to top multiple anti-
Space is answered, and is interconnected between multiple reaction compartments, multiple spaces are reacted from the bottom to top is successively denoted as first chamber, second
Chamber, third chamber, the 4th chamber, the 5th chamber and the 6th chamber；
S2: being arranged cycle heat exchange mechanism in absorption tower, and the cycle heat exchange mechanism sequentially passes through first chamber, second
Chamber, third chamber, the 4th chamber and the 5th chamber, and in second chamber, third chamber, the 4th chamber, the 5th chamber and
Atomising mechanism is set in six chambers；
The cycle heat exchange mechanism is used to absorb the heat of flue gas and conducts to other chambers；
The atomising mechanism is used to the indoor liquid of corresponding chamber carrying out atomization process；
S3: it is successively set in first chamber, second chamber, third chamber, the 4th chamber, the 5th chamber and the 6th chamber
Set oxygenation machanism, a lye absorbing mechanism, secondary lye absorbing mechanism, acid solution absorbing mechanism, neutralizer absorbing mechanism and cold
But defogging mechanism；
The oxygenation machanism is used to the substance of complete oxidation non-in flue gas being oxidized into stable oxide；
Lye absorbing mechanism is for the acidic materials in initial absorption flue gas；
The secondary lye absorbing mechanism is for the acidic materials in double absorption flue gas；
The acid solution absorbing mechanism is used to absorb the alkaline matter in flue gas；
The neutralizer absorbing mechanism is for flue gas to be adjusted to neutrality；
The cooling defogging mechanism is for reducing flue-gas temperature and removes the steam in flue gas；
S4: flue gas to be processed, the circulating picture-changing heat engine in flue gas and first chamber are passed through into the first chamber on absorption tower
Structure and oxygenation machanism come into full contact with, and the cycle heat exchange mechanism absorbs the heat of flue gas and conducts to second chamber, third chamber
Room, the 4th chamber and the 5th chamber, the oxygenation machanism carry out oxidation processes to full oxide non-in flue gas；
S5: the flue gas that oxidation processes in S4 are finished imports in second chamber, and the lye absorption in the second chamber follows
The heat of ring heat exchange mechanisms conduction carries out warming temperature, and the atomising mechanism with smoke contacts and is tentatively inhaled after being atomized lye
Receive the acidic materials in flue gas；
S6: the flue gas after basification preliminary in S5 is imported in third chamber, and the indoor lye of third chamber absorbs
The heat of cycle heat exchange transfer mechanism carries out warming temperature, the atomising mechanism lye is atomized after with smoke contacts and again
Absorb the acidic materials in flue gas；
S7: by the flue gas after basification imports in the 4th chamber again in S6, the indoor acid solution of the 4th chamber absorbs
The heat of cycle heat exchange transfer mechanism carries out warming temperature, the atomising mechanism by after acid liquor atomization with smoke contacts and absorb
Alkaline matter in flue gas；
S8: the flue gas after S7 neutral and alkali is absorbed imports in the 5th chamber, and the indoor neutralizer of the 5th chamber follows
The heat of ring heat exchange mechanisms conduction carries out warming temperature, the atomising mechanism neutralizer is atomized after with smoke contacts and absorb
Remaining acidity and alkaline matter in flue gas；
S9: the flue gas after neutralizing in S8 is imported in the 6th chamber, and the cooling defogging mechanism carries out cooling drop to flue gas
Mild demisting processing；
S10: detecting the flue gas being disposed in S9, is discharged after complying with standard.
Preferably, multiple stomatas are equipped between adjacent two chambers, the diameter of stomata is 2~5 centimetres, and flue gas is not necessarily to
Other external force just step by step and can flow slowly into next chamber.
Preferably, cycle heat exchange heat exchange liquid within the organization is one of water, kerosene and machine oil, uses specific heat capacity
Biggish liquid improves heat transfer effect as heat exchange liquid.
Preferably, the lye in a lye absorbing mechanism is sodium hydroxide solution, potassium hydroxide solution and hydrogen-oxygen
Change one of barium solution, a large amount of acid positions in flue gas are absorbed using aqueous alkali.
Preferably, the lye in the secondary lye absorbing mechanism is one of ammonium hydroxide and sodium bicarbonate solution, is used
Weak lye absorbs remaining acid position in flue gas.
Preferably, the acid solution in the acid solution absorbing mechanism is one of sulfuric acid, hydrochloric acid, nitric acid and hydrosulphuric acid, is utilized
Acid solution absorbs the less alkaline matter of the ratio in flue gas.
Preferably, the neutralizer in the neutralizer absorbing mechanism is sodium acetate, sodium carbonate, phosphoric acid, acetic acid and hypochlorous acid
One of, neutralizer adjusts the soda acid degree of flue gas to neutrality.
Preferably, in the S9, by flue gas cool-down to discharging after 15-45 degrees Celsius, so that will not when flue gas emission
Flying creature is damaged.
In the present invention, a kind of flue gas desulfurization takes off white treatment process, straight in first chamber by cycle heat exchange mechanism
The heat for absorbing flue gas is connect, other chambers except the 6th chamber are then conducted heat to, flue gas overheat is avoided to cause absorption tower
Heat is excessively high, and efficiently uses the heat of flue gas to increase the indoor liquid of other chambers in addition to the 6th chamber；
The liquid such as aqueous alkali, weak lye, acid solution and neutralizer are increased using flue gas heat by cycle heat exchange mechanism,
So that the partially liq be atomized mechanism heating after can shape temperature it is higher spraying, flue gas is filled by spraying with this
Tap is touched and is reacted, and reaction rate is improved；
The substance contained in flue gas can be subjected to complete oxidation by oxygenation machanism, avoid the incomplete oxygen in flue gas
Compound, which directly discharges, damages surrounding biologic, big in flue gas to absorb by the way that aqueous alkali is arranged in second chamber
It measures sour gas and, to absorb remaining sour gas in flue gas, passes through the 4th by the way that weak lye is arranged in third chamber
The indoor acid solution of chamber absorbs a small amount of alkaline matter contained in flue gas, by neutralizer makes slant acidity and meta-alkali in flue gas
Property substance sufficiently neutralized, finally utilize various soot dust granule objects, the aerosol and super in cooling defogging mechanism removal flue gas
The substances such as fine crystallization salt particle object；
The present invention has rational design, and the temperature of various absorbing liquids is increased using the heat that flue gas itself contains, makes absorbing liquid
It can be come into full contact with flue gas after being atomized, reaction rate can be effectively improved after increasing the environment temperature of reaction, it can be quickly right
Flue gas carries out absorption processing, realizes that desulfurization takes off white purpose.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.
A kind of flue gas desulfurization takes off white treatment process, comprising the following steps:
S1: preparing an absorption tower, carries out layered shaping to absorption tower, and absorption tower is divided into from the bottom to top multiple anti-
Space is answered, and is interconnected between multiple reaction compartments, multiple spaces are reacted from the bottom to top is successively denoted as first chamber, second
Chamber, third chamber, the 4th chamber, the 5th chamber and the 6th chamber；
S2: being arranged cycle heat exchange mechanism in absorption tower, and the cycle heat exchange mechanism sequentially passes through first chamber, second
Chamber, third chamber, the 4th chamber and the 5th chamber, and in second chamber, third chamber, the 4th chamber, the 5th chamber and
Atomising mechanism is set in six chambers；
The cycle heat exchange mechanism is used to absorb the heat of flue gas and conducts to other chambers；
The atomising mechanism is used to the indoor liquid of corresponding chamber carrying out atomization process；
S3: it is successively set in first chamber, second chamber, third chamber, the 4th chamber, the 5th chamber and the 6th chamber
Set oxygenation machanism, a lye absorbing mechanism, secondary lye absorbing mechanism, acid solution absorbing mechanism, neutralizer absorbing mechanism and cold
But defogging mechanism；
The oxygenation machanism is used to the substance of complete oxidation non-in flue gas being oxidized into stable oxide；
Lye absorbing mechanism is for the acidic materials in initial absorption flue gas；
The secondary lye absorbing mechanism is for the acidic materials in double absorption flue gas；
The acid solution absorbing mechanism is used to absorb the alkaline matter in flue gas；
The neutralizer absorbing mechanism is for flue gas to be adjusted to neutrality；
The cooling defogging mechanism is for reducing flue-gas temperature and removes the steam in flue gas；
S4: flue gas to be processed, the circulating picture-changing heat engine in flue gas and first chamber are passed through into the first chamber on absorption tower
Structure and oxygenation machanism come into full contact with, and the cycle heat exchange mechanism absorbs the heat of flue gas and conducts to second chamber, third chamber
Room, the 4th chamber and the 5th chamber, the oxygenation machanism carry out oxidation processes to full oxide non-in flue gas；
S5: the flue gas that oxidation processes in S4 are finished imports in second chamber, and the lye absorption in the second chamber follows
The heat of ring heat exchange mechanisms conduction carries out warming temperature, and the atomising mechanism with smoke contacts and is tentatively inhaled after being atomized lye
Receive the acidic materials in flue gas；
S6: the flue gas after basification preliminary in S5 is imported in third chamber, and the indoor lye of third chamber absorbs
The heat of cycle heat exchange transfer mechanism carries out warming temperature, the atomising mechanism lye is atomized after with smoke contacts and again
Absorb the acidic materials in flue gas；
S7: by the flue gas after basification imports in the 4th chamber again in S6, the indoor acid solution of the 4th chamber absorbs
The heat of cycle heat exchange transfer mechanism carries out warming temperature, the atomising mechanism by after acid liquor atomization with smoke contacts and absorb
Alkaline matter in flue gas；
S8: the flue gas after S7 neutral and alkali is absorbed imports in the 5th chamber, and the indoor neutralizer of the 5th chamber follows
The heat of ring heat exchange mechanisms conduction carries out warming temperature, the atomising mechanism neutralizer is atomized after with smoke contacts and absorb
Remaining acidity and alkaline matter in flue gas；
S9: the flue gas after neutralizing in S8 is imported in the 6th chamber, and the cooling defogging mechanism carries out cooling drop to flue gas
Mild demisting processing；
S10: detecting the flue gas being disposed in S9, is discharged after complying with standard.
In the present embodiment, multiple stomatas are equipped between adjacent two chambers, the diameter of stomata is 2~5 centimetres, flue gas
Step by step and next chamber just can be flowed slowly into without other external force.
In the present embodiment, cycle heat exchange heat exchange liquid within the organization is one of water, kerosene and machine oil, uses specific heat capacity
Biggish liquid improves heat transfer effect as heat exchange liquid.
In the present embodiment, the lye in a lye absorbing mechanism is sodium hydroxide solution, potassium hydroxide solution and hydrogen-oxygen
Change one of barium solution, a large amount of acid positions in flue gas are absorbed using aqueous alkali.
In the present embodiment, the lye in secondary lye absorbing mechanism is one of ammonium hydroxide and sodium bicarbonate solution, is used
Weak lye absorbs remaining acid position in flue gas.
In the present embodiment, the acid solution in acid solution absorbing mechanism is one of sulfuric acid, hydrochloric acid, nitric acid and hydrosulphuric acid, is utilized
Acid solution absorbs the less alkaline matter of the ratio in flue gas.
In the present embodiment, the neutralizer in neutralizer absorbing mechanism is sodium acetate, sodium carbonate, phosphoric acid, acetic acid and hypochlorous acid
One of, neutralizer adjusts the soda acid degree of flue gas to neutrality.
In the present embodiment, in S9, by flue gas cool-down to discharging after 15-45 degrees Celsius, so that will not when flue gas emission
Flying creature is damaged.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited to
This, anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention
And its inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of flue gas desulfurization takes off white treatment process, which comprises the following steps:
S1: preparing an absorption tower, carries out layered shaping to absorption tower, and absorption tower is divided into the sky of multiple reactions from the bottom to top
Between, and between multiple reaction compartments be interconnected, multiple spaces react from the bottom to top be successively denoted as first chamber, second chamber,
Third chamber, the 4th chamber, the 5th chamber and the 6th chamber；
S2: in absorption tower be arranged cycle heat exchange mechanism, the cycle heat exchange mechanism sequentially pass through first chamber, second chamber,
Third chamber, the 4th chamber and the 5th chamber, and in second chamber, third chamber, the 4th chamber, the 5th chamber and the 6th chamber
Interior setting atomising mechanism；
The cycle heat exchange mechanism is used to absorb the heat of flue gas and conducts to other chambers；
The atomising mechanism is used to the indoor liquid of corresponding chamber carrying out atomization process；
S3: oxidation is set gradually in first chamber, second chamber, third chamber, the 4th chamber, the 5th chamber and the 6th chamber
Mechanism, a lye absorbing mechanism, secondary lye absorbing mechanism, acid solution absorbing mechanism, neutralizer absorbing mechanism and cooling demisting
Mechanism；
The oxygenation machanism is used to the substance of complete oxidation non-in flue gas being oxidized into stable oxide；
Lye absorbing mechanism is for the acidic materials in initial absorption flue gas；
The secondary lye absorbing mechanism is for the acidic materials in double absorption flue gas；
The acid solution absorbing mechanism is used to absorb the alkaline matter in flue gas；
The neutralizer absorbing mechanism is for flue gas to be adjusted to neutrality；
The cooling defogging mechanism is for reducing flue-gas temperature and removes the steam in flue gas；
S4: being passed through flue gas to be processed into the first chamber on absorption tower, cycle heat exchange mechanism in flue gas and first chamber and
Oxygenation machanism comes into full contact with, and the cycle heat exchange mechanism absorbs the heat of flue gas and conducts to second chamber, third chamber, the 4th
Chamber and the 5th chamber, the oxygenation machanism carry out oxidation processes to full oxide non-in flue gas；
S5: the flue gas that oxidation processes in S4 are finished imports in second chamber, and the lye absorption cycle in the second chamber changes
The heat of hot transfer mechanism carries out warming temperature, the atomising mechanism lye is atomized after with smoke contacts and initial absorption flue gas
In acidic materials；
S6: the flue gas after basification preliminary in S5 is imported in third chamber, the indoor lye absorption cycle of third chamber
The heat of heat exchange mechanisms conduction carries out warming temperature, and the atomising mechanism absorbs cigarette after being atomized lye with smoke contacts and again
Acidic materials in gas；
S7: by the flue gas after basification imports in the 4th chamber again in S6, the indoor acid solution absorption cycle of the 4th chamber
The heat of heat exchange mechanisms conduction carries out warming temperature, the atomising mechanism by after acid liquor atomization with smoke contacts and absorb in flue gas
Alkaline matter；
S8: the flue gas after S7 neutral and alkali is absorbed imports in the 5th chamber, the indoor neutralizer circulating picture-changing of the 5th chamber
The heat of hot transfer mechanism carries out warming temperature, the atomising mechanism neutralizer is atomized after with smoke contacts and absorb in flue gas
Remaining acidity and alkaline matter；
S9: the flue gas after neutralizing in S8 is imported in the 6th chamber, the cooling defogging mechanism flue gas is cooled down and
Demisting processing；
S10: detecting the flue gas being disposed in S9, is discharged after complying with standard.
2. a kind of flue gas desulfurization according to claim 1 takes off white treatment process, which is characterized in that adjacent two chambers it
Between be equipped with multiple stomatas, the diameter of stomata is 2~5 centimetres.
3. a kind of flue gas desulfurization according to claim 1 takes off white treatment process, which is characterized in that the cycle heat exchange mechanism
Interior heat exchange liquid is one of water, kerosene and machine oil.
4. a kind of flue gas desulfurization according to claim 1 takes off white treatment process, which is characterized in that a lye absorbs
Lye in mechanism is one of sodium hydroxide solution, potassium hydroxide solution and barium hydroxide solution.
5. a kind of flue gas desulfurization according to claim 1 takes off white treatment process, which is characterized in that the secondary lye absorbs
Lye in mechanism is one of ammonium hydroxide and sodium bicarbonate solution.
6. a kind of flue gas desulfurization according to claim 1 takes off white treatment process, which is characterized in that the acid solution absorbing mechanism
In acid solution be one of sulfuric acid, hydrochloric acid, nitric acid and hydrosulphuric acid.
7. a kind of flue gas desulfurization according to claim 1 takes off white treatment process, which is characterized in that the neutralizer absorbs machine
Neutralizer in structure is one of sodium acetate, sodium carbonate, phosphoric acid, acetic acid and hypochlorous acid.
8. a kind of flue gas desulfurization according to claim 1 takes off white treatment process, which is characterized in that in the S9, by flue gas
It is discharged after being cooled to 15-45 degrees Celsius.
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102716652A (en) * | 2012-07-09 | 2012-10-10 | 常州大学 | Comprehensive complicated waste gas treatment system |
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Application publication date: 20191022 |