CN110350099A - Display device, the method for manufacturing display device and glass stack - Google Patents

Display device, the method for manufacturing display device and glass stack Download PDF

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Publication number
CN110350099A
CN110350099A CN201910270204.XA CN201910270204A CN110350099A CN 110350099 A CN110350099 A CN 110350099A CN 201910270204 A CN201910270204 A CN 201910270204A CN 110350099 A CN110350099 A CN 110350099A
Authority
CN
China
Prior art keywords
coating
frit
package substrate
display device
light transmissive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910270204.XA
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Chinese (zh)
Inventor
廉宗勳
姜高云
金伦湖
金正洙
李允钒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Samsung Display Co Ltd
Original Assignee
Samsung Display Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samsung Display Co Ltd filed Critical Samsung Display Co Ltd
Publication of CN110350099A publication Critical patent/CN110350099A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/84Passivation; Containers; Encapsulations
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09GARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G3/00Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes
    • G09G3/20Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters
    • G09G3/22Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • C03C27/10Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/08Copolymers of ethene
    • C09D123/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • G06F3/0412Digitisers structurally integrated in a display
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/84Passivation; Containers; Encapsulations
    • H10K50/842Containers
    • H10K50/8426Peripheral sealing arrangements, e.g. adhesives, sealants
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass

Abstract

This application involves display device, the method for manufacture display device and glass to stack.Display device includes light transmissive substrate, package substrate, frit and first coating, wherein, light transmissive substrate includes base portion and the light-emitting component that is arranged on base portion, package substrate is arranged on light transmissive substrate, frit is around light-emitting component and is arranged between light transmissive substrate and package substrate, and first coating is arranged between package substrate and frit, and first coating includes having intramolecular *-(OCH2CH2)-OH structure compound, and first coating is at least partly contacted with frit.

Description

Display device, the method for manufacturing display device and glass stack
Cross reference to related applications
This application claims be submitted to the 10-2018-0039066 South Korea of Korean Intellectual Property Office on April 4th, 2018 The disclosure of the equity of patent application, the South Korea patent application is totally integrating herein by reference with it.
Technical field
This disclosure relates to which display device, the method for manufacturing display device and glass stack.
Background technique
With multimedia development, display device is become more and more important.Correspondingly, such as liquid crystal display is being developed With the various display devices of organic light emitting diode display.
For example, organic light emitting display includes base portion and the organic illuminating element that is arranged on base portion.Organic illuminating element The organic luminous layer that may include two comparative electrodes and be plugged between two comparative electrodes.From two electrodes provide electronics and Hole can be recombined in organic luminous layer to generate exciton, and exciton generated can be transitted at them from excitation state It shines when ground state.Damage of the organic luminous layer of organic illuminating element vulnerable to moisture or air.
As a kind of mode for the damage for inhibiting the organic luminous layer as caused by outside moisture or air, can include will be sealed Fitted lining bottom is placed on the light transmissive substrate including light-emitting component and then uses frit material by light transmissive substrate and package substrate Combined method.
There is limitations in terms of improving the bond strength between package substrate and frit.For example, working as from display device It is external when applying impact, the mating surface between package substrate and frit may be damaged.If package substrate and frit Between mating surface it is impaired, then moisture, air etc. may be allowed from external penetration, to reduce the durable of organic illuminating element Property.
Summary of the invention
The display dress with the improved bond strength between package substrate and frit is provided in terms of the disclosure It sets.
The method of manufacture display device is additionally provided in terms of the disclosure, uses this method to improve package substrate and glass Bond strength between material.
The glass with improved bond strength is additionally provided in terms of the disclosure to stack.
However, the unlimited aspect documented in this article of the aspect of the disclosure.By referring to the disclosure given below Detailed description, above and other aspect of the disclosure will become more disclosure person of an ordinary skill in the technical field Obviously.
The embodiment of display device includes light transmissive substrate, package substrate, frit and first coating, wherein shine lining Bottom includes base portion and the light-emitting component that is arranged on base portion, and package substrate is arranged on light transmissive substrate, and frit is around the member that shines Part and it is arranged between light transmissive substrate and package substrate, first coating is arranged between package substrate and frit, and the One coating includes having intramolecular *-(OCH2CH2)-OH structure compound, and first coating and frit are at least partly Contact.
The embodiment that glass stacks includes the first glass workpiece, the second glass workpiece and coating, wherein the setting of the second glass workpiece On the first glass workpiece, coating is plugged between the first glass workpiece and the second glass workpiece, coating and the first glass workpiece and the second glass The contact of glass part, and coating includes having intramolecular *-(OCH2CH2)-OH structure compound.
The embodiment of method for manufacturing display device includes: to prepare light transmissive substrate, wherein light transmissive substrate include base portion and Light-emitting component on base portion is set;Prepare package substrate, wherein painting is formed in at least part on the surface of package substrate Layer, coating include having intramolecular *-(OCH2CH2)-OH structure compound;Glass is formed between light transmissive substrate and package substrate Glass material, at least partly to contact with the coating of formation on the package substrate, frit is used for light transmissive substrate and package substrate It is combined together.
Detailed description of the invention
Embodiment is described below in conjunction with the accompanying drawings, these and/or other aspects will become clear and more It is readily appreciated that, in the accompanying drawings:
Fig. 1 is the perspective view according to the display device of embodiment;
Fig. 2 is the viewing area of the display device of Fig. 1 and the cross-sectional view of non-display area;
Fig. 3 is the enlarged cross-sectional view of the non-display area of the display device of Fig. 2;
Fig. 4 is the cross-sectional view according to the display device of embodiment;
Fig. 5 is the enlarged cross-sectional view of the non-display area of the display device of Fig. 4;
Fig. 6 is the cross-sectional view according to the display device of embodiment;
Fig. 7 is the enlarged cross-sectional view of the non-display area of the display device of Fig. 6;
Fig. 8 is the cross-sectional view according to the display device of embodiment;
Fig. 9 is the enlarged cross-sectional view of the non-display area of the display device of Fig. 8;
Figure 10 is the cross-sectional view according to the display device of embodiment;
Figure 11 is the enlarged cross-sectional view of the non-display area of the display device of Figure 10;
Figure 12 is the cross-sectional view according to the display device of embodiment;
Figure 13 is the enlarged cross-sectional view of the non-display area of the display device of Figure 12;And
Figure 14 to Figure 23 is the cross-sectional view for showing the method for the manufacture display device according to embodiment.
Specific embodiment
By referring to the features as discussed above of embodiment, can be more easily to understand the feature of present inventive concept with And the method for realizing present inventive concept.However, present inventive concept can be embodied in many different forms, and should not be construed To be limited to embodiment set forth herein.More precisely, thesing embodiments are provided so that the disclosure will be comprehensive With concept that is complete, and will fully communicating present inventive concept to those skilled in the art, and present inventive concept will only It is limited by the accompanying claims.Specification in the whole text, identical appended drawing reference refers to identical element.
Term used herein is the purpose merely for description particular implementation, and is not intended to structure of the present invention The limitation of think of.Unless the context clearly dictates otherwise, otherwise as used herein singular " one (a) ", " one (an) " it is also intended to " being somebody's turn to do (the) " including plural form.It should also be understood that when used in this manual, term " including (comprise) " and/or " including (comprising) " indicate stated feature, entirety, step, operation, element and/or The presence of component, but it is not excluded for one or more of the other feature, entirety, step, operation, element, component and/or its cluster In the presence of or addition.
It should be understood that when element or layer be referred in another element or layer "upper", " being connected to " or " being attached to " another element Or when layer, the element or layer can directly on another element or layer, be connected to or coupled to another element, or Jie may be present In intermediate element or layer.On the contrary, when element is referred to as " direct " in another element or layer "upper", " being connected directly to " or " straight Connect and be attached to " another element or when layer, then there is no elements or layer between.As used herein, term " and/ Or " include one or more of related listed item any and all combinations.
It should be understood that although term first, second etc. can be used to describe various elements herein, component, region, layer and/ Or part, but these elements, component, regions, layers, and/or portions should not be limited by these terms.These terms are only used to will One element, component, region, layer or part are distinguished with another element, component, region, layer or part.Therefore, without departing substantially from In the case where the introduction of present inventive concept, first element discussed below, first assembly, first area, first layer or first Divide and is referred to alternatively as second element, the second component, second area, the second layer or second part.
As used in this article, first direction X indicates any one direction in plane, and second direction Y indicates plane In the direction intersected with first direction X, and third direction Z indicates the direction vertical with the plane.Unless otherwise defined, Otherwise " plane " refers to plane belonging to first direction X and second direction Y.
Hereinafter, embodiment is described with reference to the accompanying drawings.
Fig. 1 is the perspective view according to the display device 1 of embodiment.
It referring to Fig.1, may include viewing area DA and non-display area NA according to the display device of current embodiment 1.
Viewing area DA can be for by facilitating the region that substantial image is shown including multiple pixel PX.Such as institute herein It uses, " pixel " refers to makes viewing area DA be divided into the single region shown for color, and a picture in the plan view Element can be the single region for being limited to express the minimum unit of color independently of other pixels.That is, in pixel PX Each of can uniquely show one of predetermined primary colors to realize that color is shown.The example of primary colors include red, green and Blue.In the plan view, viewing area DA can be surrounded by non-display area NA.Non-display area NA is displayed without contribution to image, and Element needed for the operation of display device 1 can be located in non-display area NA.
It now will be by carrying out more detailed retouch to according to the display device 1 of current embodiment referring additionally to Fig. 2 It states.Fig. 2 is the cross-sectional view of the viewing area DA and non-display area NA of the display device 1 of Fig. 1, shows and is provided with light-emitting component 150 Region and be provided with the region of frit 310.
Referring to Figures 1 and 2, display device 1 may include light transmissive substrate 100, package substrate 200 and by light transmissive substrate 100 With the combined frit 310 of package substrate 200, and it may also include and the surface of package substrate 200 is set at least Lower coating 411 and upper coating 412 in a part.
Light transmissive substrate 100 may include base portion 110 and light-emitting component 150.Light transmissive substrate 100 may include can itself shine with The light-emitting component 150 of light needed for image is shown is provided.For example, light transmissive substrate 100 can be to include being arranged in each pixel PX Light-emitting component 150 display substrate.The light-emitting component 150 being separately positioned in pixel PX can shine independently of one another, thus Realize that image is shown and color is shown.
Base portion 110 can be transparent or opaque insulating substrate or film.For example, base portion 110 may include glass material or stone English material, or may include polymer material, such as polyimides, polycarbonate, polyethylene terephthalate or poly- third Olefin(e) acid ester.
It may be provided with buffer layer 115 on the surface (upper surface in Fig. 2) of base portion 110.Buffer layer 115 can protect base portion It 110 and prevents the dopants penetration of such as moisture or air and damages light-emitting component 150.In addition, buffer layer 115 can prevent base portion 110 is impaired during forming active layer 121 that will be explained hereinafter.Buffer layer 115 may be provided at viewing area DA and On non-display area NA.Buffer layer 115 may include inorganic material, such as silicon nitride (SiNx), silica (SiOx) or silicon oxynitride (SiNxOy、SiOxNy).In embodiments, buffer layer 115 can be omitted.
Thin film transistor (TFT) 120 and the first insulating layer 131 and second insulating layer 133 may be provided on buffer layer 115.
Thin film transistor (TFT) 120 can be driving transistor, be configured to by according to the signal control stream for being transferred to control terminal The magnitude of current through the channel region in active layer 121 come control the light-emitting component 150 from specific pixel PX transmitting light quantity.Example Such as, thin film transistor (TFT) 120 may include the active layer 121 to form channel, as the grid 123 of control terminal, as the leakage of input terminal Pole 125 and source electrode 127 as output end.
Active layer 121 may be provided on buffer layer 115.Active layer 121 may include semiconductor material.For example, active layer 121 It may include polysilicon.In embodiments, active layer 121 may include monocrystalline silicon or amorphous silicon, or may include such as oxide The non-silicon base semiconductor material of semiconductor.Active layer 121 can be partially electronically conductive.For example, active layer 121 may include drain region The source region and, wherein drain region and source region pass through the channel region that is plugged between drain region and source region It is separated from each other, and each of drain region and source region can have the electric conductivity bigger than channel region.
Grid 123 may be provided on active layer 121.Grid 123 can at least partly be weighed with the channel region of active layer 121 It is folded.Grid 123 may include the alloy of aluminium (Al), molybdenum (Mo), copper (Cu) or these materials.Though being not shown, grid 123 may be electrically connected to the output electrode of the switching transistor (not shown) of the ON/OFF of control specific pixel PX.
First insulating layer 131 can be plugged between active layer 121 and grid 123 so that active layer 121 and grid 123 that This insulation.That is, the first insulating layer 131 can be gate insulating layer.First insulating layer 131 may be provided at viewing area DA and non- On the NA of viewing area.First insulating layer 131 may include inorganic insulating material, such as silicon nitride, silica or silicon oxynitride.
Second insulating layer 133 may be provided on grid 123.Second insulating layer 133 can make grid 123 and be arranged in grid Element insulating on 123.Second insulating layer 133 may be provided on viewing area DA and non-display area NA.In some embodiments, Second insulating layer 133 can be the stepped construction of multiple insulating layers.Second insulating layer 133 may include inorganic insulating material, such as nitrogen SiClx, silica or silicon oxynitride.
The through-hole at least partly exposing active layer 121 can be formed in first insulating layer 131 and second insulating layer 133. For example, through-hole may pass through the first insulating layer 131 and second insulating layer 133, at least partly to expose the drain region of active layer 121 Domain and source region.
Drain electrode 125 and source electrode 127 may be provided in second insulating layer 133.Drain electrode 125 and source electrode 127 can be inserted respectively into To be contacted with active layer 121 in through-hole.Although being not shown, drain electrode 125 may be electrically connected to drive voltage line and (not show Out) to receive driving voltage, and source electrode 127 may be electrically connected to light-emitting component 150.
It may be provided with step difference compensation layer 140 on drain electrode 125 and source electrode 127.Step difference compensation layer 140 can be minimized by all Such as thin film transistor (TFT) 120, switching transistor (not shown), the element of auxiliary electrode (not shown) and/or such as scan line, data The step that line and the wiring (not shown) of drive voltage line are formed.That is, step difference compensation layer 140 can be planarization layer, Planarization layer provides the space being steadily arranged for light-emitting component 150.The material of step difference compensation layer 140 is not limited especially System, as long as it is with insulating property (properties) and planarization property.For example, step difference compensation layer 140 may include organic material or nothing Machine material, such as acrylic resin, epoxy resin, imide resin, the more resins of card or ester resin.
Light-emitting component 150 may be provided on step difference compensation layer 140.Light-emitting component 150 may be provided in each pixel PX. Include anode 151 and cathode 153 facing with each other and be plugged on anode 151 and cathode 153 for example, light-emitting component 150 can be Between organic luminous layer 155 organic illuminating element.Light-emitting component 150 can material according to organic luminous layer 155 or stacking Structure and emit blue and green light, feux rouges or white light.
Anode 151 may be provided on step difference compensation layer 140.Anode 151 can be via penetrating the logical of step difference compensation layer 140 Hole is electrically connected to source electrode 127.In Fig. 2 etc., the source electrode 127 of anode 151 and thin film transistor (TFT) 120 (that is, driving transistor) that This is directly contacted, and is therefore connected to each other directly.However, the present disclosure is not limited to such case, and anode 151 and source electrode 127 It can be electrically connected by one or more thin film transistor (TFT) (not shown) or connection electrode (not shown).Anode 151 can exist for setting There is the pixel electrode of independent driving signal in each pixel PX in the DA of viewing area and by transmission.Anode 151 can be transparent The stepped construction of electrode, opaque electrode or transparent electrode and opaque electrode.The example of material for forming transparent electrode includes Tin indium oxide (ITO), indium zinc oxide (IZO), zinc oxide and indium oxide.The example for forming the material of opaque electrode includes lithium (Li), aluminium (Al), magnesium (Mg), silver-colored (Ag), nickel (Ni) and chromium (Cr).
Cathode 153 may be provided on anode 151.Cathode 153 can be in the case where not to distinguishing between pixel PX Public electrode on multiple pixel PX or across multiple pixel PX is set.That is, being arranged in different pixel PX A plurality of light-emitting elements 150 can share cathode 153 each other.As anode 151, cathode 153 can be transparent electrode, opaque electrode Or the stepped construction of transparent electrode and opaque electrode.
Organic luminous layer 155 can be plugged between anode 151 and cathode 153.Organic luminous layer 155 can be by from anode 151 and the hole that receives of cathode 153 recombined with electronics to shine.For example, electrons and holes can be in organic light emission It recombines in layer 155 to generate exciton, and exciton generated can shine when they transit to ground state from excitation state.
Organic luminous layer 155 may include the peak wavelength that can emit Ju You in the range of about 430nm to about 470nm The material of blue phosphorescent or fluorescence can emit the green phosphorus with peak wavelength in the range of about 530nm to about 570nm The material of light or fluorescence or can emit red phosphorescent with peak wavelength in the range of about 610nm to about 650nm or The material of fluorescence.In Fig. 2 etc., organic luminous layer 155 is arranged in each pixel PX.However, the present disclosure is not limited to this feelings Condition.In embodiments, organic luminous layer 155 may be provided on multiple pixel PX.That is, different pixel PX is arranged in In at least some of a plurality of light-emitting elements 150 can share organic luminous layer 155 each other.
Although being not shown, between organic luminous layer 155 and anode 151 or organic luminous layer 155 and cathode It may also be formed with such as hole of hole injection layer, hole transmission layer and hole blocking layer control auxiliary layer between 153 (not show Out), the electronic control auxiliary layer (not shown) or charge of such as electron injecting layer, electron transfer layer and electronic barrier layer generate Auxiliary layer (not shown), to improve the luminous efficiency of light-emitting component 150.
In some embodiments, it may be provided with pixel confining layer 160 on anode 151.Pixel confining layer 160 can shown Each pixel PX is limited in area DA.Pixel confining layer 160 can have the opening on the surface of partially exposed anode 151.Namely It says, in the plan view, at least part for the anode 151 that pixel confining layer 160 can have exposure to be arranged in each pixel PX Opening.Above-mentioned organic luminous layer 155 and cathode 153 may be provided in pixel confining layer 160.Pixel confining layer 160 can wrap Include organic material, such as acrylic resin, epoxy resin, imide resin or ester resin.
Light transmissive substrate 100 may also include the protective layer 170 being arranged on light-emitting component 150.Protective layer 170 can be directly arranged On light-emitting component 150.For example, protective layer 170 can be set up directly on the cathode 153 of light-emitting component 150.Protective layer 170 can Prevent dopants penetration and the damage of such as moisture or air together with the package substrate 200 and frit 310 that will be described later Light-emitting component 150 prevents light-emitting component 150 to be damaged because of filler 510 containing organic material.That is, protective layer 170 can execute additional encapsulation function to light-emitting component 150.Protective layer 170 may be provided on multiple pixel PX.Protective layer 170 It may include inorganic material, such as silicon nitride, silica or silicon oxynitride.
Next, package substrate 200 will be described.Package substrate 200 may be provided on light transmissive substrate 100.Encapsulation Substrate 200 may include the material that light-emitting component 150 can be prevented impaired because of the infiltration of moisture or air.For example, package substrate 200 may include glass material or quartz material.
In embodiments, the surface of package substrate 200 can be handled at least partially with fluorine.That is, fluorin radical (- F) may be present on the surface of package substrate 200, specifically, fluorin radical (- F) may be present in package substrate 200 with will be rear On the surface that the lower coating 411 and upper coating 412 of face description contact.In a non-limiting example, when package substrate 200 includes silicon When base glass material, the fluorin radical for being bonded to silicon atom be may be present on the surface of package substrate 200.The table of package substrate 200 Fluorin radical on face can form secondary or physical bond/chemical bond with the compound in lower coating 411 and upper coating 412, to help to improve Bond strength between package substrate 200 and frit 310.
Now by by referring additionally to Fig. 3 to according to the frit 310 of the display device 1 of current embodiment and under Coating 411 and upper coating 412 are described in detail.As used in this article, term " frit " refers not only to powder shape The glass material containing additive of formula, but also refer to by melting the glass material containing additive with curing powder form The glass structure expected and formed.
Referring to figs. 1 to Fig. 3, frit 310 be may be provided between light transmissive substrate 100 and package substrate 200.Frit 310 It can be for for by light transmissive substrate 100 and the combined containment member of package substrate 200.Frit 310 can be to include glass The glass frit of material.The transmissivity of frit 310 is smaller than the transmissivity of package substrate 200.
Frit 310 may be provided in non-display area NA and around a plurality of light-emitting elements 150.In the plan view, glass It is similar but be not limited to the band of substantially quadrangle that material 310, which can shape,.Frit 310 can be configured to package substrate 200 together Fully enclosed light-emitting component 150.Correspondingly, it can prevent light-emitting component 150 from damaging because of the infiltration of moisture or air.
In some embodiments, frit 310 can have inclined side surface.The lower width W of frit 3101(example Such as, width W of the frit 310 on 100 side of light transmissive substrate1) the upper width W of frit 310 can be greater than2(for example, frit The 310 width W on 200 side of package substrate2).Optionally, the lower width W1 of frit 310 is smaller than the upper of frit 310 The side surface of portion width W2 or frit 310 can not tilt, but can be substantially vertical.
The lower surface of frit 310 can connect with the first insulating layer 131 and/or second insulating layer 133 of light transmissive substrate 100 Touching.In figure 2 and figure 3, both frit 310 and the first insulating layer 131 of light transmissive substrate 100 and second insulating layer 133 connect Touching.However, the present disclosure is not limited to such cases.In embodiments, frit 310 can not be contacted with the first insulating layer 131, can It does not contact, or can be contacted with buffer layer 115 or base portion 110 with second insulating layer 133.In addition, the upper surface of frit 310 can be with Lower coating 411 contacts.Lower coating 411 will be described later.
Frit 310 can be formed by fusing and curing glass feed composition or frit paste.For example, frit 310 It may include vanadium oxide, such as vanadic anhydride (V2O5).The content of vanadium oxide in frit 310 can be but be not limited to about 30mol% To about 50mol%.In some embodiments, frit 310 may also include ceramic fillers.In embodiments, in addition to oxygen Change other than vanadium, frit 310 may include barium monoxide, bismuth oxide, antimony oxide, borate, phosphate or borosilicate.
Lower coating 411 may be provided between frit 310 and package substrate 200.For example, lower coating 411 can be directly arranged On the back surface of package substrate 200.Lower coating 411 can be contacted with frit 310 and package substrate 200.Lower coating 411 can have Help improve the bond strength between frit 310 and package substrate 200.
Lower coating 411 can be the coating formed by the unimolecule with autoregistration property or self-assembly property.That is, Lower coating 411 can be self-aligned layer.For example, lower coating 411 may be based on the self-aligned layer of the compound of polyethylene glycol.
In embodiments, lower coating 411 may include with intramolecular *-(OCH2CH2)nThe compound of-* structure is (wherein, N is 1 to 200 natural number), and the coating that can be formed for the autoregistration by the above compound.For example, lower coating 411 In compound can have intramolecular *-(OCH2CH2)n- OH structure or intramolecular *-(OCH2CH2)-OH structure.More specific In example, the compound in lower coating 411 can have R- (OCH2CH2)n- OH structure, wherein R can be with one or more hydroxyls The C that group replaces1-C50Groups.Autoregistration compound with hydroxyl groups can be with the fluorin radical on the back surface of package substrate 200 Form secondary or physical bond/chemical bond.Lower coating 411 can have alkalinity.As used in this article, " alkalinity " indicates to have more than 7 PH.
Lower coating 411 may be provided on viewing area DA and non-display area NA.For example, lower coating 411 can be on third direction Z It is Chong Die with the frit 310 in the light-emitting component 150 and non-display area NA in the DA of viewing area.In embodiments, lower coating 411 Thickness can be for approaches uniformity.The maximum gauge T of lower coating 4111It can be about 10 μm or smaller.Instantly the maximum of coating 411 Thickness T1It is about 10 μm or more hour, the compound in lower coating 411 can be stably maintained at autoregistration state.
In addition, upper coating 412 may be provided in the front surface of package substrate 200.For example, upper coating 412 can be directly arranged In package substrate 200.Upper coating 412 can help to the first binder course 530 that improves package substrate 200 with will be described later Between bond strength.Upper coating 412 may include compound identical with lower coating 411.For example, upper coating 412 can be to pass through With intramolecular *-(OCH2CH2)n- OH structure or intramolecular *-(OCH2CH2)-OH structure above-mentioned compound autoregistration and The self-aligned layer of formation.Autoregistration compound with hydroxyl groups can be formed with the fluorin radical in the front surface of package substrate 200 Secondary or physical bond/chemical bond.
Like that, upper coating 412 can have alkalinity to following coating 411.In addition, upper coating 412 may be provided at viewing area DA and On non-display area NA, and can be Chong Die with light-emitting component 150 and frit 310 on third direction Z.The maximum of upper coating 412 Thickness can be but be not limited to about 10 μm or smaller.
In embodiments, filler 510 may be provided between package substrate 200 and light-emitting component 150.Filler 510 The step formed by light-emitting component 150 can be minimized, for example, the step formed by pixel confining layer 160.In addition, filler 510 Space between fillable package substrate 200 and light transmissive substrate 100.Since filler 510 minimizes package substrate 200 and shines Step difference between substrate 100 and the space between package substrate 200 and light transmissive substrate 100 is filled, therefore display can be improved The mechanical strength or durability of device 1.Filler 510 can at least partly with protective layer 170, lower coating 411 and frit 310 Contact.The material of filler 510 is not particularly limited, as long as it is the material with planarization property.For example, filler 510 may include organic material, such as acrylic resin, epoxy resin, imide resin or acrylate.
In embodiments, filler 510 can be not used or not be included in package substrate 200 and light-emitting component 150 it Between, and package substrate 200 and light-emitting component 150 can be separated from each other.Sky between package substrate 200 and light-emitting component 150 Between can be by such as nitrogen (N2) inert gas filling.
In some embodiments, display device 1 may include the building blocks of function 600 being arranged in package substrate 200, setting The shell 800 of cover glass 700, receiving light transmissive substrate 100 and package substrate 200 on building blocks of function 600 and setting are encapsulating Pad component 900 on the side surface of substrate 200.
Building blocks of function 600 may be provided in the front surface of package substrate 200.Building blocks of function 600 can have polarization function or Touch-sensing function.That is, building blocks of function 600 may include polarizer or touch sensitive elements.
Polarizer can be facilitated by stopping the transmission of the reflected light of exterior light or at least partly absorb reflected light Outdoor visibility.Polarizer can be to convert incident light into the linear polarization of linearly polarized photon or convert incident light into circle The circuit polarizer of polarised light.
In addition, touch sensitive elements, which can be sensed, is input to display device 1 by touch operation by the user of display device 1 Information.A part, writing pencil of user's body etc. can be used to execute touch operation.For example, touch sensitive elements can sense In information input by user about whether have been carried out touch information, about touch location information, about touch press The information of the size of power and about execute touch function at least one of the information of shape of object.
In some embodiments, building blocks of function 600 can be multiple layers of stepped construction.
First binder course 530 can be plugged between building blocks of function 600 and upper coating 412.First binder course 530 can be with function The lower surface of component 600 and upper coating 412 contact.First binder course 530 may include as double faced adhesive tape optically clear adhesive, The optical clear resin or contact adhesive of such as light-cured resin or thermosetting resin.Package substrate 200 and the first binder course Upper coating 412 between 530 can help to improve the bond strength between package substrate 200 and the first binder course 530.
Cover glass 700 may be provided on building blocks of function 600.Cover glass 700 can form the upper surface of display device 1.Lid glass Glass 700 can protect the element in display device 1, and form display device 1 makes the display surface that image is formed thereon, and can Form the outside of display device 1.In some embodiments that building blocks of function 600 is touch sensitive elements, cover glass 700 can shape At the touch-surface for the touch operation (that is, touch operation performed by the user) for carrying out user on it.Cover glass 700 may include Material with high transparency and excellent in strength, such as glass material, sapphire material or polymer material.
Second binder course 550 can be plugged between cover glass 700 and building blocks of function 600.Second binder course 550 can be with lid glass The lower surface of glass 700 and the upper surface contact of building blocks of function 600.As the first binder course 530, the second binder course 550 can be wrapped Include the optical clear resin or pressure-sensitive viscous of the optically clear adhesive such as double faced adhesive tape, such as light-cured resin or thermosetting resin Mixture.Second binder course 550 may include the material identical or different with the first binder course 530.
Shell 800 may be provided on the back surface of light transmissive substrate 100.Shell 800 can have inner space, light transmissive substrate 100 and/or package substrate 200 can store or be contained in the inner space.That is, shell 800 can for back-cover, backrest or Bracket.For example, shell 800 may include cover light transmissive substrate 100 back surface bottom part 810 and from bottom part 810 to Upper side section 830 outstanding, to cover the side surface of light transmissive substrate 100 and/or package substrate 200.The side section of shell 800 830 can protect the base portion of light transmissive substrate 100 by the base portion 110 and the side surface of package substrate 200 for covering light transmissive substrate 100 110 and package substrate 200.The side section 830 of shell 800 can pass through at least partly covering function component 600 and cover glass 700 Side surface come defencive function component 600 and cover glass 700.The bottom part 810 of shell 800 can be spaced apart with base portion 110, and And the side section 830 of shell 800 can be spaced apart with the base portion 110 of light transmissive substrate 100, package substrate 200 and cover glass 700.So And the present disclosure is not limited to such cases.The material of shell 800 is not particularly limited, as long as it is with excellent in strength and rigidity Material.For example, shell 800 may include such as the polymer material of carbonate resin or such as aluminium, nickel or these metals The metal material of alloy.
Pad component 900 may be provided on the side surface of package substrate 200.Pad component 900 may be provided at package substrate 200 with Between the side section 830 of shell 800, to prevent package substrate 200 to be damaged because of shell 800.For example, when package substrate 200 becomes When shape or external impact are applied to display device 1, pad component 900 can remain potted the distance between substrate 200 and shell 800 simultaneously And absorb and at least partly impact, to minimize impaired.
Pad component 900 can cover the side surface of package substrate 200, and can be shaped like substantially four in the plan view The band of side shape.Padding component 900 can be with package substrate 200, the first binder course 530, building blocks of function 600, the second binder course 550, lid The contact of the side section 830 of glass 700 and/or shell 800.For example, pad component 900 may be coupled to package substrate 200, but can be with Shell 800 separates.
Alignment package substrate 200, the side surface of building blocks of function 600 and cover glass 700 and guarantor are come by using pad component 900 The distance between package substrate 200 and shell 800 are held, light transmissive substrate 100, package substrate 200 and frit 310 can be protected to exempt from It is influenced by external impact, and minimizes the width of the non-display area NA of display device 1.The material of component 900 is padded not by spy It does not limit, is at least partly impacted as long as it can be absorbed.For example, pad component 900 may include organic material, such as acrylic acid Resin, epoxy resin, imide resin or acrylate.
As described above, may include being arranged on the surface of package substrate 200 according to the display device 1 of current embodiment Lower coating 411 and upper coating 412.
Specifically, the package substrate 200 including glass material, frit 310 and package substrate 200 and frit are plugged on Lower coating 411 between 310 can form glass stacking.That is, being capable of providing according to the disclosure with the first glass workpiece The glass of improved adhesiveness stacks between (for example, package substrate) and the second glass workpiece (for example, frit).Including having Intramolecular *-(OCH2CH2)n- OH structure or intramolecular *-(OCH2CH2) the lower coating 411 of compound of-OH structure can help to Improve the bond strength between the first glass workpiece (for example, package substrate) and the second glass workpiece (for example, frit).Therefore, root Stacking according to the glass of current embodiment can express excellent bond strength.
In addition, including the package substrate 200 of glass material, the first binder course 530 including organic material and being plugged on envelope Upper coating 412 between fitted lining bottom 200 and the first binder course 530 can form glass/resin stacking.That is, according to this public affairs It opens, is capable of providing the glass/resin with the improved adhesiveness between glass and resin and stacks.Including with intramolecular *- (OCH2CH2)n- OH structure or intramolecular *-(OCH2CH2)-OH structure compound upper coating 412 can help to improve encapsulation Bond strength between substrate 200 and the first binder course 530.Therefore, glass/resin according to the present embodiment, which stacks, can express Excellent bond strength out.
Hereinafter, other embodiment will be described.For the sake of simplicity, it will omit and according to above embodiment Display device 1 the identical element of element description, and those skilled in the art will be expressly understood from attached drawing it is identical Element.
Fig. 4 is to show the light-emitting component for being provided with display device 2 according to the cross-sectional view of the display device 2 of embodiment 150 viewing area and the non-display area for being provided with frit 310.Fig. 5 is that the amplification of the non-display area of the display device 2 of Fig. 4 is cutd open View.
Referring to Fig. 4 and Fig. 5, filled according to the display device 2 of current embodiment and the display of the embodiment waited according to fig. 2 Set 1 the difference is that, further include the side coating 413 being arranged on the side surface of package substrate 200.
In embodiments, side coating 413 may be provided between package substrate 200 and pad component 900.For example, side coating 413 can be set up directly on the side surface of package substrate 200.Side coating 413 can help to improve package substrate 200 and pad component Bond strength between 900.Side coating 413 may include compound identical with lower coating 411 and upper coating 412.For example, side applies Layer 413 can be for by with intramolecular *-(OCH2CH2)n- OH structure or intramolecular *-(OCH2CH2)-OH structure above-mentioned chemical combination The autoregistration of object and the self-aligned layer formed.Autoregistration compound with hydroxyl groups can on the side surface of package substrate 200 Fluorin radical formed secondary or physical bond/chemical bond.Between side coating 413 and lower coating 411 and side coating 413 and upper coating 412 Between macroscopic physical boundary can be substantially absent.
Like that, side coating 413 can have alkalinity for following coating 411 and upper coating 412.The maximum gauge of side coating 413 can For but be not limited to about 10 μm or smaller.
In embodiments, side coating 413 may include the compound different from lower coating 411 and upper coating 412.
Pad component 900 may be provided on side coating 413.Padding component 900 can be with side coating 413, the first binder course 530, function The contact of side section 830 of energy component 600, the second binder course 550, cover glass 700 and/or shell 800.
In the display device 2 according to current embodiment, package substrate 200 including organic material including glass material The pad component 900 of material and the side coating 413 for being plugged on package substrate 200 and padding between component 900 can form glass/resin heap It is folded.
Fig. 6 is to show the light-emitting component for being provided with display device 3 according to the cross-sectional view of the display device 3 of embodiment 150 viewing area and the non-display area for being provided with frit 330.Fig. 7 is that the amplification of the non-display area of the display device 3 of Fig. 6 is cutd open View.
Referring to figure 6 and figure 7, it is filled according to the display device of current embodiment 3 and the display of the embodiment according to Fig. 4 etc. 2 are set the difference is that lower coating 431 is with partially different thickness.
Lower coating 431 can on third direction Z with the light-emitting component 150 in viewing area and the frit in non-display area 330 overlappings.In embodiments, the average thickness of the lower coating 431 Chong Die with light-emitting component 150 can be greater than and frit 330 The average thickness of the lower coating 431 of overlapping.For example, the first of the lower coating 431 Chong Die with the light-emitting component 150 in viewing area is thick Spend T2It can be substantially homogeneous.First thickness T2It can be about 10 μm or smaller.
On the other hand, the thickness of the lower coating 431 Chong Die with the frit 330 in non-display area can be uneven for part 's.For example, the part Chong Die with frit 330 of lower coating 431 can have less than first thickness T2Second thickness T3.More In specific example, the part of lower coating 431 contacted with frit 330 can have second thickness T3.Second thickness T3The upper limit It can be about 5.0 μm, about 4.0 μm, about 3.0 μm, about 2.0 μm or about 1.0 μm.Therefore, inclined surface may be formed at lower coating 431 In a part on surface.
There can be part uneven according to the lower coating 431 of current embodiment contacted with the frit 330 of display device 3 Even thickness.Specifically, the lower coating 431 contacted with frit 330 can form relatively thin, so that lower coating 431 can be formed The inclined surface in part, while there is intramolecular *-(OCH2CH2)n- OH structure or intramolecular *-(OCH2CH2)-OH structure change Object is closed to be stably maintained in autoregistration state.The inclined surface of lower coating 431 can increase frit 330 and lower coating 431 it Between combination interface area, to further improve the bond strength formed by frit 330.
In addition, the inclined surface of lower coating 431 can increase the road of the combination interface between frit 330 and lower coating 431 Electrical path length, to increase the length of the permeation pathway of the impurity of such as moisture or air.
In embodiments, side coating 413 can be omitted, and pads component 900 and can contact with package substrate 200.
Fig. 8 is to show the light-emitting component for being provided with display device 4 according to the cross-sectional view of the display device 4 of embodiment 150 viewing area and the non-display area for being provided with frit 340.Fig. 9 is that the amplification of the non-display area of the display device 4 of Fig. 8 is cutd open View.
Referring to Fig. 8 and Fig. 9, filled according to the display device 4 of current embodiment and the display of the embodiment according to Fig. 4 etc. 2 are set the difference is that at least part of frit 340 is contacted with package substrate 200.
In embodiments, lower coating 441 can have the opening for the back surface at least partly exposing package substrate 200 441p.The opening 441p of lower coating 441 can form frit 340 by fusing and curing glass feed composition or frit paste During formed, but the present disclosure is not limited to such cases.In irradiation laser to be formed in the embodiment of frit 340, The opening 441p of lower coating 441 can pass through the type of laser, the position of laser spot, laser irradiation intensity or laser irradiation time To control.
In addition, frit 340 can at least partly contact with lower coating 441 and can also be with the envelope by opening 441p exposure Fitted lining bottom 200 contacts.For example, the substantial middle part of the upper surface of frit 340 can connect with package substrate 200 in the plan view Touching.
On the other hand, the inner edge portion that is formed by the upper surface of frit 340 and inner surface 340a and by frit Each of the outer edge part that 340 upper surface and outer surface 340b are formed can be contacted with lower coating 441.In plan view In, when frit 340 is formed about light-emitting component 150, the inner surface 340a of frit 340 can be light-emitting component 150 Side surface on side, and the outer surface 340b of frit 340 can be the side surface opposite with inner surface 340a.
When from the external application impact of display device 4, stress can concentrate on the mating surface formed by frit 340 On, to damage mating surface.Specifically, because stress caused by external impact can mainly be transferred to the inward flange of frit 340 Part and outer edge part.However, the inner edge portion for being easiest to stress and damaging and peripheral portion due to frit 340 Divide and be formed as contacting with lower coating 441, therefore bond strength can be improved.In addition, due to 200 shape of frit 340 and package substrate As partly contacting each other, therefore combination interface can be formed between frit 340 and package substrate 200, and can be effectively Prevent the impurity of such as moisture or air from passing through the combination being formed between the frit 340 being in contact with each other and package substrate 200 The infiltration at interface.
In embodiments, side coating 413 can be omitted, and pads component 900 and can contact with package substrate 200.
Figure 10 is to show the light-emitting component for being provided with display device 5 according to the cross-sectional view of the display device 5 of embodiment 150 viewing area and the non-display area for being provided with frit 350.Figure 11 is the amplification of the non-display area of the display device 5 of Figure 10 Cross-sectional view.
0 and Figure 11 referring to Fig.1, the display of the embodiment according to the display device 5 of current embodiment and according to Fig. 4 etc. Device 2 is the difference is that the outer edge part of frit 350 is contacted with package substrate 200.
In embodiments, in the plan view, lower coating 451 may be provided on the back surface of package substrate 200, but can It is not arranged in the fringe region of the back surface of package substrate 200.Can during forming frit 350 to being not provided under The region of coating 451 is controlled, but the present disclosure is not limited to such cases.The reality of frit 350 is formed in irradiation laser It applies in mode, the region for being not provided with the lower coating 451 of frit 350 can be controlled for example, by laser irradiating position.
Frit 350 can at least partly contact with lower coating 451 and can also be with the encapsulation that is not covered by lower coating 451 Substrate 200 contacts.
The inner edge portion formed by the upper surface and inner surface 350a of frit 350 can be contacted with lower coating 451.Separately On the one hand, by the outside table of the substantial middle part of the upper surface of frit 350, the upper surface of frit 350 and frit 350 The outer edge part that face 350b is formed can be contacted with package substrate 200.
When from the external application impact of display device 5, stress can concentrate on the mating surface formed by frit 350 On, to damage mating surface.Specifically, compared near the outer edge part of frit 350, mating surface is in frit 350 inner edge portion nearby opposite can be easier to be damaged.However, due in the display device 5 according to current embodiment Inner edge portion is formed as contacting with lower coating 451, therefore can improve bond strength.In addition, due to frit 350 and encapsulation lining Bottom 200 is formed as partly contacting each other, specifically, due to the outer edge part of frit 350 and the upper surface of frit 350 Center portion be formed as contacting with package substrate 200, therefore can be formed between frit 350 and package substrate 200 in conjunction with boundary Face, and the impurity that such as moisture or air can be effectively prevented passes through the frit 350 for being formed in and being in contact with each other and serves as a contrast with encapsulation The infiltration of combination interface between bottom 200.
In some embodiments, the average tilt angle θ of the inner surface 350a of frit 3501With frit 350 The average tilt angle θ of outer surface 350b2It can be different.For example, the average tilt of the inner surface 350a of frit 350 Angle, θ1With the average tilt angle θ of the outer surface 350b of frit 3502It can be 90 degree or smaller, but frit 350 Inner surface 350a average tilt angle θ1It is smaller than the average tilt angle θ of the outer surface 350b of frit 3502.? In more specific example, the average tilt angle θ of the inner surface 350a of frit 3501It can be about 60 degree to about 80 degree, and The average tilt angle θ of the outer surface 350b of frit 3502It can be about 65 degree to about 88 degree.The inner surface of frit 350 The tilt angle theta of 350a and outer surface 350b1And θ2It can be during fusing and curing glass feed composition or frit paste It is controlled, but the present disclosure is not limited to such cases.In irradiation laser to be formed in the embodiment of frit 350, glass The tilt angle theta of the inner surface 350a and outer surface 350b of material 3501And θ2It can be controlled for example, by laser irradiating position.
In embodiments, side coating 413 can be omitted, and pads component 900 and can contact with package substrate 200.
Figure 12 is to show the light-emitting component for being provided with display device 6 according to the cross-sectional view of the display device 6 of embodiment 150 viewing area and the non-display area for being provided with frit 360.Figure 13 is the amplification of the non-display area of the display device 6 of Figure 12 Cross-sectional view.
2 and Figure 13 referring to Fig.1, according to the display device 6 of current embodiment with according to the aobvious of the embodiment of Figure 10 etc. Showing device 5 is the difference is that frit 360 has inclined surface, and the lower width W of frit 3601(for example, glass Width W of the material 360 on 100 side of light transmissive substrate1) it is less than the upper width W of frit 3602(for example, frit 360 is served as a contrast in encapsulation Width W on 200 side of bottom2)。
In embodiments, the average tilt angle θ of the inner surface 360a of frit 3601With the outside of frit 360 The average tilt angle θ of surface 360b2It can be different.For example, the average tilt angle of the inner surface 360a of frit 360 θ1With the average tilt angle θ of the outer surface 360b of frit 3602It can be 90 degree or bigger, but frit 360 is interior The average tilt angle θ of side surface 360a1The average tilt angle θ of the outer surface 360b of frit 360 can be greater than2.Frit The tilt angle theta of 360 inner surface 360a and outer surface 360b1And θ2It can be in fusing and curing glass feed composition or glass Glass material is controlled during pasting, but the present disclosure is not limited to such cases.
In embodiments, side coating 413 can be omitted, and pads component 900 and can contact with package substrate 200.
Hereinafter, the method for the manufacture display device according to the disclosure will be described.Figure 14 is to show to Figure 23 According to the cross-sectional view of the method for the manufacture display device of embodiment.
Firstly, referring to Fig.1 4, preparation includes base portion 110, thin film transistor (TFT) 120, light-emitting component 150 and protective layer 170 Light transmissive substrate 100.Since the element of light transmissive substrate 100 is described above, its redundancy description is omitted.
Then, referring to Fig.1 5, it is handled with surface of the fluorine to package substrate 200.With fluorine to the first of package substrate 200 Surface (lower surface in Figure 15) and second surface (upper surface in Figure 15) are handled in the first table of package substrate 200 Fluorin radical (- F) is formed on face and second surface.In some embodiments, also can be used fluorine to the side surface of package substrate 200 into Row processing.
Then, referring to Fig.1 6, preparing has the lower coating 411 and upper coating formed on at least a part of the surface thereof 412 package substrate 200.
In embodiments, preparation has the package substrate 200 of lower coating 411 and upper coating 412 can include: serves as a contrast in encapsulation Lower coating 411 is formed on the first surface (lower surface in Figure 15) of the fluoro-containing group at bottom 200;In the fluorine-containing of package substrate 200 Upper coating 412 is formed on the second surface (upper surface in Figure 15) of group;And to lower coating 411 and upper coating 412 Package substrate 200 washed and dried.
Form lower coating 411 can include: autoregistration has autoregistration property or self assembly directly in package substrate 200 The individual molecule of matter.In embodiments, lower coating 411 can be for by with intramolecular *-(OCH2CH2)n- OH structure or molecule Interior *-(OCH2CH2)-OH structure compound autoregistration and the coating that is formed.Since above compound is described above, because This omits its redundancy description.
In addition, forming upper coating 412 can include: directly in package substrate 200 autoregistration have autoregistration property or from Assemble the individual molecule of property.Upper coating 412 may include compound identical with lower coating 411, and therefore omit its redundancy Description.In some embodiments, lower coating 411 and upper coating 412 can be synchronously imposed by single technique.
Washing and the dry package substrate 200 with lower coating 411 and upper coating 412 can include: using distilled water or go Ionized water wash and washed package substrate 200 is dried using air knife to package substrate 200.Passing through water During medium is washed, the lower coating 411 being substantially insoluble in and upper coating 412 can be made to stablize.That is, by It is washed after coating 411 and upper coating 412 under in package substrate 200 being formed in package substrate 200, therefore under can making Coating 411 and upper coating 412 are firmer.
Then, referring to Fig.1 7, glass frit compositions 310' and filler compositions 510' is set simultaneously on light transmissive substrate 100 It is heat-treated.
It can be the operation being applied to glass frit compositions 310' on light transmissive substrate 100 that glass frit compositions 310', which is arranged,. Method of application is not particularly limited, still, for example, silk-screen printing can be used.Glass frit compositions 310' can be along light transmissive substrate 100 edge is arranged to the belt shape of substantially quadrangle.Glass frit compositions 310' may include vanadium oxide and further include pottery Porcelain filler or organic material, and can be paste state or gel state.
The heat treatment of glass frit compositions 310' can be for by toasting with by paste state glass frit compositions 310' Or the glass frit compositions 310' precuring of gel state is at the operation of solid state.Pass through the glass of heat treatment precuring or baking Glass feed composition 310' can be temporarily fixed on light transmissive substrate 100 with substantially solid state.In this operation, frit group The organic material closed in object 310' can be removed by deterioration, but the present disclosure is not limited to such cases.In addition, filler group The heat treatment for closing object 510' can be for the cured operation of filler compositions 510' progress.Glass frit compositions 310' and filler The heat treatment temperature of composition 510' can be about 300 DEG C to about 500 DEG C or about 350 DEG C to about 450 DEG C.In addition, can be in nitrogen atmosphere Lower execution heat treatment operation.
In Figure 17, glass frit compositions 310' and filler compositions 510' are arranged on light transmissive substrate 100 and with hot It is handled.However, the present disclosure is not limited to such cases.In embodiments, glass frit compositions 310' and/or filler group Closing object 510' may be provided on package substrate (not shown).
In embodiments, the setting of filler compositions 510', and available such as nitrogen (N can be omitted2) inertia Gas fills the space surrounded by light transmissive substrate 100, package substrate 200 and the frit 310 that will be described later.
Then, referring to Fig.1 8, frit 310 is formed between light transmissive substrate 100 and package substrate 200, is served as a contrast luminous Bottom 100 is combined together with package substrate 200.In embodiments, frit 310 is formed can include: alignment light transmissive substrate 100 With package substrate 200;And frit 310 is formed by melting and solidifying thermally treated glass frit compositions 310'.
Light transmissive substrate 100 and package substrate 200 to will definitely be to be aligned to light transmissive substrate 100 and package substrate 200 So that the behaviour Chong Die with lower coating 411 and upper coating 412 by the glass frit compositions 310' of heat treatment precuring or baking Make.
In addition, melting and solidifying thermally treated glass frit compositions 310' can include: being irradiated to laser L by heat Manage the glass frit compositions 310' of precuring or baking.The laser L for being irradiated to thermally treated glass frit compositions 310' is fusible Change glass frit compositions 310'.After with laser L irradiation the glass frit compositions 310' that melts can be cured or resolidification with Form frit 310.Laser L sequentially can be irradiated to frit group via upper coating 412, package substrate 200 and lower coating 411 Close object 310'.
Frit 310 can connect with the first insulating layer 131 and second insulating layer 133 and lower coating 411 of light transmissive substrate 100 Touching is to form combination interface.As described above, the lower coating 411 between package substrate 200 and frit 310 can help to improve envelope Bond strength between fitted lining bottom 200 and frit 310.
Laser L can have the wavelength of about 760nm to about 860nm or about 780nm to about 830nm.In glass frit compositions 310' is arranged in the substantially embodiment of the belt shape of quadrangle, and laser L can be faced along because of precuring or baking When fixed glass frit compositions 310' shape it is mobile while be irradiated.The Energy distribution of laser L can have pancake Shape, rather than Gaussian Profile, but the present disclosure is not limited to such cases.
In some embodiments, after light transmissive substrate 100 and package substrate 200 are combined together, encapsulation can be made to serve as a contrast The side surface exposure at bottom 200.
Then, referring to Fig.1 9, side coating 413 is formed on the side surface of package substrate 200.Forming side coating 413 can wrap Include: autoregistration has the individual molecule of autoregistration property or self-assembly property directly on the side surface of package substrate 200.Side applies Layer 413 may include compound identical with lower coating 411 and upper coating 412, that is, have intramolecular *-(OCH2CH2)n- OH structure Or intramolecular *-(OCH2CH2)-OH structure compound.Therefore, the redundancy description of the compound of side coating 413 is omitted.
In some embodiments, after forming side coating 413, the method for manufacturing display device may also include that part Ground washing and dry combined light transmissive substrate 100 and package substrate 200.Washing and dry light transmissive substrate 100 and encapsulation Substrate 200 can include: light transmissive substrate 100 and package substrate 200 are washed using distilled water or deionized water, and used Light transmissive substrate 100 and package substrate 200 is dried in air knife.
Then, referring to Figure 20, building blocks of function 600 is formed in package substrate 200, and serve as a contrast in building blocks of function 600 and encapsulation The first binder course 530 is planted between bottom 200.Since the first binder course 530 and building blocks of function 600 is described above, save Slightly its redundancy description.
Then, referring to Figure 21, cover glass 700 is formed on building blocks of function 600, and in cover glass 700 and building blocks of function 600 Between plant the second binder course 550.Since the second binder course 550 and cover glass 700 is described above, its redundancy is omitted Description.
Referring to Figure 22, pad component 900 is formed.Pad component 900 may be provided on the side surface of package substrate 200.For example, pad Component 900 can be with side coating 413, the first binder course 530, building blocks of function 600, the second binder course 550 and at least portion of cover glass 700 Divide ground contact.Since pad component 900 is described above, its redundancy description is omitted.
Referring to Figure 23, light transmissive substrate 100 and package substrate 200 are inserted into shell 800.Since shell is described above Body 800, therefore omit its redundancy description.
According to embodiment, the coating that can improve bond strength is plugged between package substrate or glass and frit, To improve the bond strength between package substrate or glass and frit.Therefore, it is possible to provide with improved durability and can By the display device of property.
However, the unlimited effect documented in this article of the effect of embodiment.By referring to claims, embodiment party Above and other effect of formula will become more fully apparent embodiment person of an ordinary skill in the technical field.

Claims (20)

1. display device, comprising:
Light transmissive substrate, the light transmissive substrate include the light-emitting component of base portion and setting on the base portion;
Package substrate, the package substrate are arranged on the light transmissive substrate;
Frit, the frit around the light-emitting component and be arranged the light transmissive substrate and the package substrate it Between;And
First coating, the first coating are arranged between the package substrate and the frit, and including with molecule Interior *-(OCH2CH2)-OH structure compound, and at least partly contacted with the frit.
2. display device as described in claim 1, wherein the first coating be set up directly on the package substrate towards On the first surface of the light transmissive substrate, and on the first surface of the package substrate contacted with the first coating There are fluorin radical (- F).
3. display device as described in claim 1, wherein the first coating has alkalinity.
4. display device as described in claim 1, wherein the first coating is the self-aligned layer of the compound, and The maximum gauge of the first coating is 10 μm or smaller.
5. display device as described in claim 1, wherein the first coating and the light-emitting component and the frit weight It is folded.
6. display device as claimed in claim 5, wherein the average thickness of the first coating Chong Die with the light-emitting component Degree is greater than the average thickness of the first coating Chong Die with the frit.
7. display device as described in claim 1, wherein at least part of the frit connects with the package substrate Touching.
8. display device as claimed in claim 7, wherein in the plan view, the center portion of the upper surface of the frit It is contacted with the package substrate.
9. display device as claimed in claim 8, wherein the frit has the side being located at where the light-emitting component On inner surface and the outer surface opposite with the inner surface, wherein the upper surface and institute by the frit The inner edge portion for stating inner surface formation is contacted with the first coating, and by the upper surface of the frit and institute The outer edge part for stating outer surface formation is contacted with the package substrate.
10. display device as claimed in claim 9, wherein the frit is on the side where the light transmissive substrate Width is of different size on the side where the package substrate with the frit, and the inside of the frit The average tilt angle on surface and the average tilt angle of the outer surface of the frit are different.
11. display device as described in claim 1, further includes:
Second coating, the second coating are arranged on the second surface of the package substrate and are self-aligned layer, and described Two surfaces deviate from the light transmissive substrate.
12. display device as claimed in claim 11, wherein the second coating is set up directly on the institute of the package substrate It states on second surface, it is Chong Die with the light-emitting component and the frit, and including chemical combination identical with the first coating Object.
13. display device as claimed in claim 11, further includes:
Building blocks of function, the building blocks of function are arranged in the second coating and including polarizer or touch sensitive elements; And
Binder course, the binder course be arranged between the second coating and the building blocks of function and with the second coating and The building blocks of function contact.
14. display device as claimed in claim 13, further includes:
Third coating, the third coating are set up directly on the side surface of the package substrate and are with intramolecular *- (OCH2CH2)-OH structure compound self-aligned layer.
15. display device as claimed in claim 14, further includes:
Cover glass, the cover glass are arranged on the building blocks of function;
Shell, the shell, which accommodates the light transmissive substrate and the package substrate and has, covers the described of the package substrate The sidewall sections of side surface;And
Component is padded, the pad component is arranged between the third coating and the sidewall sections of the shell and includes Machine material,
Wherein, the pad component is contacted with the third coating, the binder course, the building blocks of function and the cover glass.
16. glass stacks, comprising:
First glass workpiece;
Second glass workpiece, second glass workpiece are arranged on first glass workpiece;And
Coating, the coating are plugged between first glass workpiece and second glass workpiece, with first glass workpiece and The second glass workpiece contact, and including with intramolecular *-(OCH2CH2)-OH structure compound.
17. the method for manufacturing display device, which comprises
Light transmissive substrate is prepared, the light transmissive substrate includes the light-emitting component of base portion and setting on the base portion;
Package substrate is prepared, coating is formed in at least part on the surface of the package substrate, the coating includes having Intramolecular *-(OCH2CH2)-OH structure compound;
Between the light transmissive substrate and the package substrate formed for by the light transmissive substrate in conjunction with the package substrate Frit together, at least partly to be contacted with the coating being formed in the package substrate.
18. method as claimed in claim 17, wherein the coating includes:
First coating, the first coating are arranged on the first surface towards the light transmissive substrate of the package substrate;With And
Second coating, the second coating be arranged in the package substrate on the second surface of the light transmissive substrate, with And
Preparing the package substrate with the coating includes:
The first surface of the package substrate and the second surface are handled with fluorine;
By directly on the first surface of the package substrate compound described in autoregistration form the first coating;
By directly on the second surface of the package substrate compound described in autoregistration form the second coating; And
The package substrate with the first coating and the second coating is washed and dried.
19. method as claimed in claim 17, wherein forming the frit includes:
Glass frit compositions are set on the light transmissive substrate;
The glass frit compositions are handled with heat;
It is directed at the package substrate, so that the thermally treated glass frit compositions overlap each other with the coating;And
The thermally treated frit is melted and solidified by irradiating laser to the thermally treated glass frit compositions Composition,
Wherein, the coating includes:
First coating, the first coating are formed on the first surface towards the light transmissive substrate of the package substrate;With And
Second coating, the second coating are formed on the second surface of the package substrate, and the second surface is away from described Light transmissive substrate, and
Irradiating the laser includes:
The laser is irradiated so that the laser is sequentially applied through the second coating, the package substrate and described first Layer.
20. method as claimed in claim 17, after forming the frit, further includes:
Third coating is formed on the side surface of the package substrate, wherein the third coating includes having intramolecular *- (OCH2CH2)-OH structure compound;
Building blocks of function including polarizer or touch sensitive elements is placed on the lining of the encapsulation with the third coating On bottom;
Cover glass is placed on the building blocks of function;And
On the third coating by include organic material pad component be positioned to the third coating, the building blocks of function and The cover glass contact.
CN201910270204.XA 2018-04-04 2019-04-04 Display device, the method for manufacturing display device and glass stack Pending CN110350099A (en)

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US20190311671A1 (en) 2019-10-10
EP3550628B1 (en) 2022-03-09

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