CN110344250A - A kind of conductive fabric for clothes of losing weight, reduce weight - Google Patents
A kind of conductive fabric for clothes of losing weight, reduce weight Download PDFInfo
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- CN110344250A CN110344250A CN201910633244.6A CN201910633244A CN110344250A CN 110344250 A CN110344250 A CN 110344250A CN 201910633244 A CN201910633244 A CN 201910633244A CN 110344250 A CN110344250 A CN 110344250A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/18—Definition of the polymer structure conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
- C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
- C08G2261/3221—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more nitrogen atoms as the only heteroatom, e.g. pyrrole, pyridine or triazole
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/43—Chemical oxidative coupling reactions, e.g. with FeCl3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/90—Applications
- C08G2261/93—Applications in textiles, fabrics and yarns
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Abstract
The present invention provides a kind of conductive fabrics for clothes of losing weight, reduce weight, and the cotton fiber and/or silk thread fabric of conjugation heterocycle polymer film are coated with for surface, belongs to textile field.Present invention employs a kind of new monomers to coat on common fabric, and the more existing conductive chemical & blended fabric of fabric obtained has preferably clothing comfort level.Provided by the invention to be prepared with by two methods of infusion process and sedimentation using conductive fabric, monomer selects diamino nitrogen heterocyclic, and oxide selects isocyanuric acid or derivatives thereof, and dopant selects non-oxidizing proton acid.Minimum reachable 950.6 Ω of final resulting conductive fabric specific surface resistivity.
Description
Technical field
The invention belongs to textile field, especially a kind of conductive fabric for clothes of losing weight, reduce weight.
Background technique
Intelligent textile is a kind of emerging textile, it is that New School is born from the textile fabric class consumer goods,
This kind of textile can make induction to the variation of external condition and according to requiring to make corresponding adjustment.
As the improvement of people's living standards, higher requirements are also raised for function of the people to textile.In recent years, section
Scholars are also more extensive to the research of the Textile material of height stimulation intelligent response.Currently, such as optical fiber,
Intelligent anti-bacterial fibre, chameleon fibre, shape memory fiber, poultry thermal fiber, conductive fiber, are developed and are fabricated to intelligent weaving
Product.
Shellfish company, the U.S. is manufactured that a kind of " the poly- phthalein amine fiber of intelligence " recently, by containing antibacterial agent in fiber
Portion, and ensured durability and the safety of fiber, this fiber be in place of being different from general anti-bacterial fibre, no matter when you are
Light activity or strenuous exercise, it can control the quantity of skin surface bacterium, keep it in normal level.
Earliest conductive fiber is the electric conductivity using metal and manufactured metal class conductive fiber mainly has stainless steel
Silk, copper wire, aluminium wire etc., or with metal spraying in fiber surface, the electric conductivity for making fiber have metal the same.And this kind of conduction
The purposes of fiber is generally dust-proof working clothes, industrial material.The hand woven using this kind of conductive fiber and general fibre
Set, has the function of antistatic, dust protection, is widely used in semi-conductor industry and precise electronic industry.
The most advanced in the prior art is high polymer conductive fiber, it has been found that conduction high polymer have polyacetylene, polyphenyl
Amine, polypyrrole, polythiophene etc. all belong to two π and are total to macromolecule, and conductivity is lower, but to carry out chemical doping or electrochemical doping,
It can be allowed to rapid and reversibly become conduction state.Why conduction high polymer causes great concern, and is since it not only has
Special electric property and optical property, but also have both the processability of high polymer and the semiconductive of flexibility, inorganic material
With the electric conductivity of metal.Currently, prepare conductive fabric uses liquid phase chemical polymerization mostly, using hydrochloric acid be dopant compared with
It is more.
In the prior art, traditional conductive fiber uses metallic fiber, carbon fiber or high polymer fibre, although these fibers
Electric conductivity is relatively good, the extremely discomfort but human body dress is got up.According further to " A study on the electrical
conductivity decay of polypyrrole coated wool textiles》.(Polymer Degradation&
Stability, 2005,89 (1): 125-132.) the literary conductivity decline for reporting the conductive fabric prepared by chemical polymerization
The main reason for be alkali in water-washing process effect.It is oxidized further, since conductive fabric is placed in atmospheric environment for a long time,
Electric conductivity is also declined.When in use, temperature and humidity, illumination, washing, friction can all influence the electric conductivity of fabric.
Summary of the invention
Since drawbacks described above exists in the prior art, the present invention develops a kind of completely new conjugation heterocycle polymer membrane body
System coats on traditional clothing fabric surface, not only can solve comfortableness problem, moreover it is possible to have to the electric conductivity of conductive fabric
Certain promotion, more resistant to alkali cleaning.
Specifically, the present invention is achieved through the following technical solutions:
A kind of conductive fabric for clothes of losing weight, reduce weight is coated with the cotton fiber of conjugation heterocycle polymer film for surface
And/or silk thread fabric.
Preferably, the surface is coated with the cotton fiber of conjugation heterocycle polymer film and/or the preparation method of silk thread fabric
It is as follows:
(1) cotton fiber and/or silk thread fabric are put into lye, boil at 50-70 DEG C 2-5 hours, is washed with water after taking-up
To neutrality, natural air drying, must pre-process fabric A at room temperature；
(2) it is taken out after impregnating pretreatment fabric A 1-2 hours in doping liquid, naturally dry, then in oxidizing agent solution
It is taken out after impregnating 1-2 hours, naturally dry must pre-process fabric B；
(3) fabric C must polymerization reaction: be pre-processed；
(4) rinsing is dry to get the conductive fabric for clothes of losing weight, reduce weight.
Preferably, the step of step (3) polymerization reaction is that will pre-process fabric B to impregnate 12-36 in monomer liquid small
When.
Preferably, the step of step (3) polymerization reaction is that will pre-process fabric B and be put into vapor phase growing apparatus to replace
Device internal gas is inert gas, is decompressed to 100-500mTorr, and heating monomer liquid keeps it heavy in pretreatment fabric B surface
Product, sedimentation time are 12-36 hours.
Preferably, the lye is 5-20wt% sodium hydrate aqueous solution.
Preferably, it is described doping liquid solute be phenylpyruvic acid, pyruvic acid, p-methyl benzenesulfonic acid, dodecyl sodium sulfonate, to hydroxyl
Base benzene sulfonic acid, 2 hydroxy propanoic acid, 4 hydroxybutyric acid, in 2,3 dihydroxybutanedioic acid any one or any two arbitrarily to compare
The mixture of example；
The solvent of the doping liquid is water, ethyl alcohol, methanol, any one in tetrahydrofuran.
Preferably, doping liquid is 0.05-0.50mol/L pyruvic acid aqueous solution, 0.005-0.10mol/L 4 hydroxybutyric acid
Ethanol solution, 0.10-1.0mol/L dodecyl alkyl sulfonic acid aqueous solution in any one.
Preferably, doping liquid is the dodecyl alkane of 0.05-0.50mol/L pyruvic acid aqueous solution and 0.10-1.0mol/L
The isometric mixed solution of sulfonic acid aqueous solution.
Preferably, the solute of the oxidizing agent solution is sodium hypochlorite, sym-closene, dichloroisocyanuric acid, dichloro
Sodium isocyanurate, dibromo sodium isocyanate, dibromo isocyanic acid, chloramines, any one in t-butyl hypochlorate；
The solvent of the oxidizing agent solution is any one in methylene chloride, chloroform, ethyl alcohol or water.
Preferably, in the oxidizing agent solution Solute mass be solvent quality 10-50%.
Preferably, the solute of the monomer liquid is 3,5- diamino-pyridine, 2,5- diamino-pyridine, 2,4- diamino pyrrole
Pyridine, 2,6- diamino-pyridine, 2,3 diamino pyridine, 3,6- diamino radical pyridazine, 2,6- diaminopyrazine, 4,5- diamino radical pyridazine
In any one；
The solvent of the monomer liquid is tetrahydrofuran or acetonitrile.
Preferably, the mass ratio of solute and solution is (0.5-1.5) in the monomer liquid: 1.
The invention has the beneficial effects that: develop a kind of conjugation heterocycle polymer coating different from prior art mechanism
Conductive fabric, selected the compounds such as diamino-pyridine, diamino imidazoles, diaminopyrazine, diamino radical pyridazine, passed through oxidation
Agent coupling, forms polymer.Oxidant and dopant have been screened simultaneously.Finally coating processes are improved.By improving
Conjugated polymer thin films have good coverage and fastness in fabric surface afterwards, and traditional polyaniline compound compares table after Alkaline Elution
Surface resistance can be substantially increased, and ascensional range often reaches 100 times or more or even 1000 times, and conjugated polymer of the invention
Film is more secured in fabric surface, illustrates there is longer service life more resistant to washing.
Specific embodiment
The present invention is further elaborated on combined with specific embodiments below, following embodiments are only used to explain this hair
It is bright, it is not intended to limit the present invention.
Specifically, No. CAS of compound used in following embodiments or raw material sources it is as follows:
Cotton fabric, longitude and latitude yarn density are 96 × 54, grammes per square metre 160g/m2, thickness 0.8mm.
Gas aggradation device, referring to the specific embodiment self-control of the Chinese patent of Authorization Notice No. CN 100351426C.
Sodium hydroxide, No. CAS: 1310-73-2.
Dodecyl sodium sulfate, No. CAS: 2385-53-0.
Pyruvic acid, No. CAS: 127-17-3.
Sodium dichloro cyanurate, No. CAS: 2893-78-9.
3,5- diamino-pyridines, No. CAS: 4318-78-9.
2,5- diamino-pyridines, No. CAS: 4318-76-7.
4,5- diamino radical pyridazines, No. CAS: 28682-70-4.
Tetrahydrofuran, No. CAS: 109-99-9.
Ethyl alcohol, No. CAS: 64-17-5.
Embodiment 1
A kind of conductive fabric for clothes of losing weight, reduce weight is coated with the cotton fiber of conjugation heterocycle polymer film for surface
And/or silk thread fabric, the preparation method is as follows:
(1) cotton fabric is put into the sodium hydroxide solution of 10wt%, is boiled at 60 DEG C 2 hours, it is clear with distilled water after taking-up
It is washed till neutrality, at room temperature natural air drying, fabric A must be pre-processed；
(2) it takes out after impregnating pretreatment fabric A 1 hour in doping liquid, naturally dry, then is soaked in oxidizing agent solution
Bubble takes out after 1 hour, and naturally dry must pre-process fabric B；
The dodecyl sodium sulfonate aqueous solution that the doping liquid is 0.15mol/L；
The 12wt% sodium dichloro cyanurate aqueous solution of the oxidizing agent solution；
(3) polymerization reaction: pretreatment fabric B is impregnated 24 hours in monomer liquid, fabric C must be pre-processed；
The monomer liquid is the tetrahydrofuran solution of 3,5- diamino-pyridine, wherein 3,5- diamino-pyridines and tetrahydrofuran
Mass ratio be 1:1；
(4) drying is rinsed: with dry 4 hours at dehydrated alcohol rinsing pretreatment fabric 5 minutes, 60 DEG C to get for subtracting
The conductive fabric of fertilizer, weight reducing clothes.
Wherein, the cotton fabric, 10wt% sodium hydroxide solution mass ratio be 1:20.
The pretreatment fabric A, the mass ratio for adulterating liquid are 1:50.
It is described pretreatment fabric A, oxidizing agent solution mass ratio be 1:50.
It is described pretreatment fabric B, monomer liquid mass ratio be 1:50.
Embodiment 2
A kind of conductive fabric for clothes of losing weight, reduce weight is coated with the cotton fiber of conjugation heterocycle polymer film for surface
And/or silk thread fabric, the preparation method is as follows:
(1) cotton fabric is put into the sodium hydroxide solution of 10wt%, is boiled at 60 DEG C 2 hours, it is clear with distilled water after taking-up
It is washed till neutrality, at room temperature natural air drying, fabric A must be pre-processed；
(2) it takes out after impregnating pretreatment fabric A 1 hour in doping liquid, naturally dry, then is soaked in oxidizing agent solution
Bubble takes out after 1 hour, and naturally dry must pre-process fabric B；
The pyruvic acid aqueous solution that the doping liquid is 0.15mol/L；
The 12wt% sodium dichloro cyanurate aqueous solution of the oxidizing agent solution；
(3) polymerization reaction: pretreatment fabric B is impregnated 24 hours in monomer liquid, fabric C must be pre-processed；
The monomer liquid is the tetrahydrofuran solution of 3,5- diamino-pyridine, wherein 3,5- diamino-pyridines and tetrahydrofuran
Mass ratio be 1:1；
(4) drying is rinsed: with dry 4 hours at dehydrated alcohol rinsing pretreatment fabric 5 minutes, 60 DEG C to get for subtracting
The conductive fabric of fertilizer, weight reducing clothes.
Wherein, the cotton fabric, 10wt% sodium hydroxide solution mass ratio be 1:20.
The pretreatment fabric A, the mass ratio for adulterating liquid are 1:50.
It is described pretreatment fabric A, oxidizing agent solution mass ratio be 1:50.
It is described pretreatment fabric B, monomer liquid mass ratio be 1:50.
Embodiment 3
A kind of conductive fabric for clothes of losing weight, reduce weight is coated with the cotton fiber of conjugation heterocycle polymer film for surface
And/or silk thread fabric, the preparation method is as follows:
(1) cotton fabric is put into the sodium hydroxide solution of 10wt%, is boiled at 60 DEG C 2 hours, it is clear with distilled water after taking-up
It is washed till neutrality, at room temperature natural air drying, fabric A must be pre-processed；
(2) it takes out after impregnating pretreatment fabric A 1 hour in doping liquid, naturally dry, then is soaked in oxidizing agent solution
Bubble takes out after 1 hour, and naturally dry must pre-process fabric B；
The doping liquid is that the dodecyl alkyl sulfonic acid of 0.15mol/L pyruvic acid aqueous solution and 0.15mol/L are water-soluble
The isometric mixed solution of liquid；
The 12wt% sodium dichloro cyanurate aqueous solution of the oxidizing agent solution；
(3) polymerization reaction: pretreatment fabric B is impregnated 24 hours in monomer liquid, fabric C must be pre-processed；
The monomer liquid is the tetrahydrofuran solution of 3,5- diamino-pyridine, wherein 3,5- diamino-pyridines and tetrahydrofuran
Mass ratio be 1:1；
(4) drying is rinsed: with dry 4 hours at dehydrated alcohol rinsing pretreatment fabric 5 minutes, 60 DEG C to get for subtracting
The conductive fabric of fertilizer, weight reducing clothes.
Wherein, the cotton fabric, 10wt% sodium hydroxide solution mass ratio be 1:20.
The pretreatment fabric A, the mass ratio for adulterating liquid are 1:50.
It is described pretreatment fabric A, oxidizing agent solution mass ratio be 1:50.
It is described pretreatment fabric B, monomer liquid mass ratio be 1:50.
Embodiment 4
A kind of conductive fabric for clothes of losing weight, reduce weight is coated with the cotton fiber of conjugation heterocycle polymer film for surface
And/or silk thread fabric, the preparation method is as follows:
(1) cotton fabric is put into the sodium hydroxide solution of 10wt%, is boiled at 60 DEG C 2 hours, it is clear with distilled water after taking-up
It is washed till neutrality, at room temperature natural air drying, fabric A must be pre-processed；
(2) it takes out after impregnating pretreatment fabric A 1 hour in doping liquid, naturally dry, then is soaked in oxidizing agent solution
Bubble takes out after 1 hour, and naturally dry must pre-process fabric B；
The doping liquid is that the dodecyl alkyl sulfonic acid of 0.15mol/L pyruvic acid aqueous solution and 0.15mol/L are water-soluble
The isometric mixed solution of liquid；
The 12wt% sodium dichloro cyanurate aqueous solution of the oxidizing agent solution；
(3) polymerization reaction: pretreatment fabric B is impregnated 24 hours in monomer liquid, fabric C must be pre-processed；
The monomer liquid is the tetrahydrofuran solution of 2,5- diamino-pyridine, wherein 2,5- diamino-pyridines and tetrahydrofuran
Mass ratio be 1:1；
(4) drying is rinsed: with dry 4 hours at dehydrated alcohol rinsing pretreatment fabric 5 minutes, 60 DEG C to get for subtracting
The conductive fabric of fertilizer, weight reducing clothes.
Wherein, the cotton fabric, 10wt% sodium hydroxide solution mass ratio be 1:20.
The pretreatment fabric A, the mass ratio for adulterating liquid are 1:50.
It is described pretreatment fabric A, oxidizing agent solution mass ratio be 1:50.
It is described pretreatment fabric B, monomer liquid mass ratio be 1:50.
Embodiment 5
A kind of conductive fabric for clothes of losing weight, reduce weight is coated with the cotton fiber of conjugation heterocycle polymer film for surface
And/or silk thread fabric, the preparation method is as follows:
(1) cotton fabric is put into the sodium hydroxide solution of 10wt%, is boiled at 60 DEG C 2 hours, it is clear with distilled water after taking-up
It is washed till neutrality, at room temperature natural air drying, fabric A must be pre-processed；
(2) it takes out after impregnating pretreatment fabric A 1 hour in doping liquid, naturally dry, then is soaked in oxidizing agent solution
Bubble takes out after 1 hour, and naturally dry must pre-process fabric B；
The doping liquid is that the dodecyl alkyl sulfonic acid of 0.15mol/L pyruvic acid aqueous solution and 0.15mol/L are water-soluble
The isometric mixed solution of liquid；
The 12wt% sodium dichloro cyanurate aqueous solution of the oxidizing agent solution；
(3) polymerization reaction: pretreatment fabric B is impregnated 24 hours in monomer liquid, fabric C must be pre-processed；
The monomer liquid is the tetrahydrofuran solution of 4,5- diamino radical pyridazine, wherein 4,5- diamino radical pyridazines and tetrahydrofuran
Mass ratio be 1:1；
(4) drying is rinsed: with dry 4 hours at dehydrated alcohol rinsing pretreatment fabric 5 minutes, 60 DEG C to get for subtracting
The conductive fabric of fertilizer, weight reducing clothes.
Wherein, the cotton fabric, 10wt% sodium hydroxide solution mass ratio be 1:20.
The pretreatment fabric A, the mass ratio for adulterating liquid are 1:50.
It is described pretreatment fabric A, oxidizing agent solution mass ratio be 1:50.
It is described pretreatment fabric B, monomer liquid mass ratio be 1:50.
Embodiment 6
A kind of conductive fabric for clothes of losing weight, reduce weight is coated with the cotton fiber of conjugation heterocycle polymer film for surface
And/or silk thread fabric, the preparation method is as follows:
(1) cotton fabric is put into the sodium hydroxide solution of 10wt%, is boiled at 60 DEG C 2 hours, it is clear with distilled water after taking-up
It is washed till neutrality, at room temperature natural air drying, fabric A must be pre-processed；
(2) it takes out after impregnating pretreatment fabric A 1 hour in doping liquid, naturally dry, then is soaked in oxidizing agent solution
Bubble takes out after 1 hour, and naturally dry must pre-process fabric B；
The doping liquid is that the dodecyl alkyl sulfonic acid of 0.15mol/L pyruvic acid aqueous solution and 0.15mol/L are water-soluble
The isometric mixed solution of liquid；
The 12wt% sodium dichloro cyanurate aqueous solution of the oxidizing agent solution；
(3) polymerization reaction: it is nitrogen that pretreatment fabric B, which is put into displacement apparatus internal gas in vapor phase growing apparatus, is subtracted
It is depressed into 120mTorr, heating monomer liquid makes it in pretreatment fabric B surface deposition to 150 DEG C, and sedimentation time is 24 hours, is obtained pre-
Handle fabric C；
The monomer liquid is the tetrahydrofuran solution of 2,5- diamino-pyridine, wherein 2,5- diamino-pyridines and tetrahydrofuran
Mass ratio be 1:1；
(4) drying is rinsed: with dry 4 hours at dehydrated alcohol rinsing pretreatment fabric 5 minutes, 60 DEG C to get for subtracting
The conductive fabric of fertilizer, weight reducing clothes.
Wherein, the cotton fabric, 10wt% sodium hydroxide solution mass ratio be 1:20.
The pretreatment fabric A, the mass ratio for adulterating liquid are 1:50.
It is described pretreatment fabric A, oxidizing agent solution mass ratio be 1:50.
It is described pretreatment fabric B, monomer liquid mass ratio be 1:50.
Embodiment 7
A kind of conductive fabric for clothes of losing weight, reduce weight is coated with the cotton fiber of conjugation heterocycle polymer film for surface
And/or silk thread fabric, the preparation method is as follows:
(1) cotton fabric is put into the sodium hydroxide solution of 10wt%, is boiled at 60 DEG C 2 hours, it is clear with distilled water after taking-up
It is washed till neutrality, at room temperature natural air drying, fabric A must be pre-processed；
(2) it takes out after impregnating pretreatment fabric A 1 hour in doping liquid, naturally dry, then is soaked in oxidizing agent solution
Bubble takes out after 1 hour, and naturally dry must pre-process fabric B；
The doping liquid is that the dodecyl alkyl sulfonic acid of 0.15mol/L pyruvic acid aqueous solution and 0.15mol/L are water-soluble
The isometric mixed solution of liquid；
The 12wt% sodium dichloro cyanurate aqueous solution of the oxidizing agent solution；
(3) polymerization reaction: it is nitrogen that pretreatment fabric B, which is put into displacement apparatus internal gas in vapor phase growing apparatus, is subtracted
It is depressed into 200mTorr, heating monomer liquid makes it in pretreatment fabric B surface deposition to 150 DEG C, and sedimentation time is 24 hours, is obtained pre-
Handle fabric C；
The monomer liquid is the tetrahydrofuran solution of 2,5- diamino-pyridine, wherein 2,5- diamino-pyridines and tetrahydrofuran
Mass ratio be 1:1；
(4) drying is rinsed: with dry 4 hours at dehydrated alcohol rinsing pretreatment fabric 5 minutes, 60 DEG C to get for subtracting
The conductive fabric of fertilizer, weight reducing clothes.
Wherein, the cotton fabric, 10wt% sodium hydroxide solution mass ratio be 1:20.
The pretreatment fabric A, the mass ratio for adulterating liquid are 1:50.
It is described pretreatment fabric A, oxidizing agent solution mass ratio be 1:50.
It is described pretreatment fabric B, monomer liquid mass ratio be 1:50.
Embodiment 8
A kind of conductive fabric for clothes of losing weight, reduce weight is coated with the cotton fiber of conjugation heterocycle polymer film for surface
And/or silk thread fabric, the preparation method is as follows:
(1) cotton fabric is put into the sodium hydroxide solution of 10wt%, is boiled at 60 DEG C 2 hours, it is clear with distilled water after taking-up
It is washed till neutrality, at room temperature natural air drying, fabric A must be pre-processed；
(2) it takes out after impregnating pretreatment fabric A 1 hour in doping liquid, naturally dry, then is soaked in oxidizing agent solution
Bubble takes out after 1 hour, and naturally dry must pre-process fabric B；
The doping liquid is that the dodecyl alkyl sulfonic acid of 0.15mol/L pyruvic acid aqueous solution and 0.15mol/L are water-soluble
The isometric mixed solution of liquid；
The 12wt% sodium dichloro cyanurate aqueous solution of the oxidizing agent solution；
(3) polymerization reaction: it is nitrogen that pretreatment fabric B, which is put into displacement apparatus internal gas in vapor phase growing apparatus, is subtracted
It is depressed into 350mTorr, heating monomer liquid makes it in pretreatment fabric B surface deposition to 150 DEG C, and sedimentation time is 24 hours, is obtained pre-
Handle fabric C；
The monomer liquid is the tetrahydrofuran solution of 2,5- diamino-pyridine, wherein 2,5- diamino-pyridines and tetrahydrofuran
Mass ratio be 1:1；
(4) drying is rinsed: with dry 4 hours at dehydrated alcohol rinsing pretreatment fabric 5 minutes, 60 DEG C to get for subtracting
The conductive fabric of fertilizer, weight reducing clothes.
Wherein, the cotton fabric, 10wt% sodium hydroxide solution mass ratio be 1:20.
The pretreatment fabric A, the mass ratio for adulterating liquid are 1:50.
It is described pretreatment fabric A, oxidizing agent solution mass ratio be 1:50.
It is described pretreatment fabric B, monomer liquid mass ratio be 1:50.
Test case 1
Specific surface resistivity test
Using commercial surface resistance meter (Changzhou De Du precision instrument Co., Ltd produces, model FY321B) to reality
Apply a 1-8 it is obtained for losing weight, the progress specific surface resistivity test of the conductive fabric for clothes of reduce weight.
Test result is as shown in table 1.
1 specific surface resistivity of table (Ω)
| Specific surface resistivity (Ω) | |
| Embodiment 1 | 1530.4 |
| Embodiment 2 | 1487.2 |
| Embodiment 3 | 1204.8 |
| Embodiment 4 | 1093.4 |
| Embodiment 5 | 1196.7 |
| Embodiment 6 | 968.5 |
| Embodiment 7 | 920.4 |
| Embodiment 8 | 950.6 |
As seen from the above table, there is lower specific surface electricity provided by the present invention for the conductive fabric for clothes of losing weight, reduce weight
Resistance, instruction sheet body effectively can form conjugated polymer thin films on surface, wherein especially suitable sedimentation compares table compared with infusion process
Surface resistance decreases drastically, it was demonstrated that preferably can form conjugated polymer thin films in fabric surface using sedimentation.
Test case 2
Alkaline washing experiment
It will be used to lose weight made from embodiment 1-8, the conductive fabric for clothes of reducing weight carries out alkaline washing experiment, preparation
The commercially available white cat board basic laundry amidin of 0.005g/mL, pH value 9 are washed 50 minutes, and washing methods is referring to GB/T
5A program in 8629-2001 is washed, and is dried at 60 DEG C for 24 hours, tests specific surface resistivity by the method that test case 1 provides.
Test result is as shown in table 2.
Specific surface resistivity (Ω) after 2 alkaline washing of table
| Specific surface resistivity (Ω) | |
| Embodiment 1 | 20718.6 |
| Embodiment 2 | 18451.7 |
| Embodiment 3 | 11967.3 |
| Embodiment 4 | 9919.3 |
| Embodiment 5 | 11766.0 |
| Embodiment 6 | 2375.7 |
| Embodiment 7 | 1763.5 |
| Embodiment 8 | 1905.0 |
As seen from the above table, the conductive fabric provided by the present invention for clothes of losing weight, reduce weight has good fastness, alkali resistance
Washing, it means that have longer service life.Especially in the conductive fabric prepared using sedimentation, after alkaline washing, than
Sheet resistance incrementss are universal less than 3 times, best less than 2 times, far super state of the art.
Claims (9)
1. a kind of conductive fabric for clothes of losing weight, reduce weight, which is characterized in that be coated with conjugation heterocycle polymer film for surface
Cotton fiber and/or silk thread fabric.
2. it is according to claim 1 for losing weight, the conductive fabric for clothes of reduce weight, which is characterized in that the surface coats
Have conjugation heterocycle polymer film cotton fiber and/or silk thread fabric the preparation method is as follows:
(1) cotton fiber and/or silk thread fabric are put into lye, boil at 50-70 DEG C 2-5 hours, washes with water after taking-up into
Property, natural air drying, must pre-process fabric A at room temperature；
(2) it takes out after impregnating pretreatment fabric A 1-2 hours in doping liquid, naturally dry, then is impregnated in oxidizing agent solution
It is taken out after 1-2 hours, naturally dry, fabric B must be pre-processed；
(3) fabric C must polymerization reaction: be pre-processed；
(4) rinsing is dry to get the conductive fabric for clothes of losing weight, reduce weight.
3. it is according to claim 2 for lose weight, the conductive fabric for clothes of reduce weight, which is characterized in that the step (3) gather
The step of closing reaction is impregnated 12-36 hours for that will pre-process fabric B in monomer liquid.
4. it is according to claim 2 for lose weight, the conductive fabric for clothes of reduce weight, which is characterized in that the step (3) gather
The step of closing reaction is put into vapor phase growing apparatus for that will pre-process fabric B, and displacement apparatus internal gas is inert gas, decompression
To 100-500mTorr, heating monomer liquid makes it in pretreatment fabric B surface deposition, and sedimentation time is 12-36 hours.
5. it is according to claim 2 for lose weight, the conductive fabric for clothes of reduce weight, which is characterized in that the lye be 5-
20wt% sodium hydrate aqueous solution.
6. it is according to claim 2 for losing weight, the conductive fabric of clothes of reduce weight, which is characterized in that it is described to adulterate liquid
Solute is phenylpyruvic acid, pyruvic acid, p-methyl benzenesulfonic acid, dodecyl sodium sulfonate, p-hydroxybenzenyl sulfonate, 2 hydroxy propanoic acid, 4- hydroxyl
In butyric acid, 2,3 dihydroxybutanedioic acid any one or any two with the mixture of arbitrary proportion；
The solvent of the doping liquid is water, ethyl alcohol, methanol, any one in tetrahydrofuran.
7. it is according to claim 2 for lose weight, the conductive fabric for clothes of reducing weight, which is characterized in that the oxidant is molten
The solute of liquid is sodium hypochlorite, sym-closene, dichloroisocyanuric acid, sodium dichloro cyanurate, dibromo sodium isocyanate, dibromo
Isocyanic acid, chloramines, any one in t-butyl hypochlorate；
The solvent of the oxidizing agent solution is any one in methylene chloride, chloroform, ethyl alcohol or water.
8. it is according to claim 7 for lose weight, the conductive fabric for clothes of reducing weight, which is characterized in that the oxidant is molten
The quality of solute is the 5-20% of solvent quality in liquid.
9. it is according to claim 3 or 4 for lose weight, the conductive fabric for clothes of reducing weight, which is characterized in that the monomer liquid
Solute be 3,5- diamino-pyridine, 2,5- diamino-pyridine, 2,4- diamino-pyridine, 2,6- diamino-pyridine, 2,3- diamino
Yl pyridines, 3,6- diamino radical pyridazine, 2,6- diaminopyrazine, any one in 4,5- diamino radical pyridazine；
The solvent of the monomer liquid is tetrahydrofuran or acetonitrile.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910633244.6A CN110344250A (en) | 2019-07-15 | 2019-07-15 | A kind of conductive fabric for clothes of losing weight, reduce weight |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910633244.6A CN110344250A (en) | 2019-07-15 | 2019-07-15 | A kind of conductive fabric for clothes of losing weight, reduce weight |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110344250A true CN110344250A (en) | 2019-10-18 |
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ID=68175221
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910633244.6A Withdrawn CN110344250A (en) | 2019-07-15 | 2019-07-15 | A kind of conductive fabric for clothes of losing weight, reduce weight |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110344250A (en) |
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2019
- 2019-07-15 CN CN201910633244.6A patent/CN110344250A/en not_active Withdrawn
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Application publication date: 20191018 |