CN110343490A - A kind of preparation method of high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture - Google Patents
A kind of preparation method of high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture Download PDFInfo
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- CN110343490A CN110343490A CN201910640805.5A CN201910640805A CN110343490A CN 110343490 A CN110343490 A CN 110343490A CN 201910640805 A CN201910640805 A CN 201910640805A CN 110343490 A CN110343490 A CN 110343490A
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- hot melt
- melt adhesive
- furniture
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- resistant thermoplastic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention proposes a kind of preparation methods of high-temperature-resistant thermoplastic edge sealing hot melt adhesive for furniture, belong to hot melt adhesive for edge bonding of furniture field.A kind of high temperature resistant hot melt adhesive for edge bonding of furniture is made by reasonably designing ethylene-vinyl acetate copolymer (EVA), amorphous state alpha olefin copolymer (APAO) polymer and resin, filler and antioxidant each group distribution ratio in this method.High temperature resistant hot melt adhesive for edge bonding of furniture of the invention, with not wire drawing, higher initial bonding strength, low smell, preferable adhesive property, the edge banding requirements of ordinary particle board, density board and core-board etc. can be met: the hot melt adhesive for edge bonding of furniture has preferable high temperature resistance, storage and transport suitable for the edge sealing finished product of (70-90 DEG C) under higher temperature conditions, and common EVA edge sealing can only be used with hot melt adhesive at 50-70 DEG C, solve the problems, such as that common EVA edge sealing can not be used under the high temperature conditions with hot melt adhesive.
Description
Technical field
The invention belongs to hot melt adhesive for edge bonding of furniture fields, and in particular to a kind of high-temperature-resistant thermoplastic edge sealing of furniture hot melt
Glue and preparation method thereof
Background technique
Hot melt adhesive is a kind of thermoplastic adhesive, and in certain temperature range, the Macroscopic physical state of hot melt adhesive is with temperature
Degree changes and changes, and had chemical characteristic is constant.This glue very solid content, nontoxic, quick-drying, simple production process,
High financial profit, equipment investment is few when client uses, easy to use, high production efficiency.
Hot melt adhesive is widely used in all trades and professions, especially prevalent in the application of edge sealing of furniture field, when hot melt adhesive uses
It is required that institute the problem of cannot having wire drawing using edge sealing hot melt adhesive and plate is caused to pollute, after the edge sealing of furniture of part in post-processing and
Storage is with will appear higher temperature (70-80 DEG C) in transportational process, this requires hot melt adhesive has not wire drawing and has higher
Heat-resisting ability, in addition, the consumer group is higher and higher to the appearance requirement of product, therefore also to edge sealing in edge sealing of furniture field
The dirty plate problem of wire drawing and tree lace more stringent requirements are proposed, Thermoplastic hot melt rubber-surfaced roll that EVA of the invention is blended with APAO applies
Less glue amount can reach with common EVA Edge strength and without the pure dirty plate problem of APAO wire drawing.Existing common EVA edge sealing hot melt
Glue, although can satisfy the edge sealing bonding of common wealth furniture, on to core-board edge sealing, heat-resisting ability and spread, also
Up for improving.
Summary of the invention
The object of the present invention is to be directed to the deficiency of existing common EVA edge sealing hot melt adhesive, a kind of high temperature resistant, bonding are provided
The hot melt adhesive for edge bonding of furniture that ability is strong, applicability is wide;The basic components of heat resistance are provided by selecting suitable APAO, are led to
It crosses suitable EVA model and the problem of ratio makes original APAO wire drawing dirty plate is improved solution.
Present invention provide the technical scheme that a kind of preparation method of high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture, institute
State preparation method the following steps are included:
(1) by 20-60 parts by weight of ethylene-acetate ethylene copolymer (EVA), 5-25 parts by weight amorphous state alpha olefin copolymer
(APAO) it and in 0.3-1 parts by weight antioxidant investment kneader, beginning to warm up and mediates uniformly, kneading frequency is 15-25Hz,
The control of material temperature degree is heated to material and all melts at 150-180 DEG C in reaction kettle;
(2) 5-15 parts by weight Petropols and 0-5 parts by weight rosin resin are put into the material melted into step 1 and are pinched
It closes uniformly, kneading frequency is 27-40Hz, mediates to material and all melts, and reduces temperature of charge to 130-150 DEG C;
(3) it is reduced into step 2 and slowly puts into 15-40 parts of filler material by weight in the material of temperature, kneading frequency is 20-
30Hz is mediated uniformly, stops heating to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder is arrived;
(4) the high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder 200-400 mesh plate filter for obtaining step 3
Discharging is granulated, dehydration and drying, packs to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture.
Further, the antioxidant is 2,6- di-tert-butyl-4-methy phenol, three [2.4- di-tert-butyl-phenyls] Asia
One or both of phosphate, four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters.
Further, the filler is one or both of calcium carbonate, barium sulfate.
The beneficial effects of the present invention are: high-temperature-resistant thermoplastic edge sealing hot melt adhesive for furniture of the invention, have lower cost, compared with
Good cementitiousness, material applicability is wide, can expire the edge sealing demand of particieboard, filled board and core-board.The EVA and APAO is total
Mixed hot melt adhesive for edge bonding of furniture has preferable high temperature resistance, and rosin resin can be improved to the wellability of substrate to improve
Adhesive property, but it is bad with APAO compatibility, so that selecting EVA to be that APAO is compatible with EVA for cosolvent provides condition,
Compatibility is adjusted by the ratio of APAO, EVA and rosin resin three in the system, come control bonding, heat resistance and
Improve and solve wire drawing phenomenon in product use process, prevents pollution plate.The finished product is suitable for depositing for higher temperature (70-90 DEG C)
Storage and transport, and common EVA hot melt adhesive for edge bonding of furniture can only use at 50-70 DEG C, solve common EVA edge sealing of furniture and use
The problem of hot melt adhesive can not use under the high temperature conditions.
Specific embodiment
The present invention is further illustrated combined with specific embodiments below.
Embodiment 1
A kind of high-temperature-resistant thermoplastic edge sealing hot melt adhesive for furniture, it includes the component of following parts by weight:
The antioxidant is four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters.
A kind of preparation method of high-temperature-resistant thermoplastic edge sealing hot melt adhesive for furniture, the preparation method the following steps are included:
(1) EVA, APAO and four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters investment are mediated
It in machine, begins to warm up and mediates uniformly, kneading frequency is 22Hz, and it is complete to be heated to material at 160 DEG C for the control of material temperature degree in reaction kettle
Portion's fusing;
(2) in the melting materialss of step 1 put into regulated proportion Petropols and rosin resin and mediate uniformly, mediate
Frequency is 33Hz, mediates to material and all melts, and reduces temperature of charge to 140 DEG C;
(3) it is reduced into step 2 in the material of temperature and slowly puts into calcium carbonate, mediated uniformly, kneading frequency is 27Hz, is stopped
It only heats to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder is arrived;
(4) the high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder 200-400 mesh plate filter for obtaining step 3
Discharging is granulated, and dehydration and drying is packed to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture.
High-temperature-resistant thermoplastic hot melt adhesive end properties made from embodiment 1 is shown in Table 1.
Embodiment 2
A kind of high-temperature-resistant thermoplastic edge sealing hot melt adhesive for furniture, it includes the component of following parts by weight:
The antioxidant is for 2,6 di tert butyl 4 methyl phenol and three [2.4- di-tert-butyl-phenyl] phosphite esters
Mixture.
A kind of preparation method of high-temperature-resistant thermoplastic edge sealing hot melt adhesive for furniture, the preparation method the following steps are included:
(1) EVA, APAO and 2,6 di tert butyl 4 methyl phenol and three [2.4- di-tert-butyl-phenyl] phosphite esters are mixed
It closes in object investment kneader, begin to warm up and mediates uniformly, kneading frequency is 15Hz, and material temperature degree is controlled at 150 DEG C in reaction kettle,
Material is heated to all to melt;
(2) to step 1 melt material in put into regulated proportion Petropols and rosin resin and mediate uniformly, mediate
Frequency is 27Hz, mediates to material and all melts, and reduces temperature of charge to 130 DEG C;
(3) it is reduced into step 2 in the material of temperature and slowly puts into calcium carbonate, mediated uniformly, kneading frequency is 20Hz, is stopped
It only heats to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder is arrived;
(4) the high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder 200-400 mesh plate filter for obtaining step 3
Discharging is granulated, and dehydration and drying is packed to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture.
High-temperature-resistant thermoplastic hot melt adhesive end properties made from embodiment 2 is shown in Table 1.
Embodiment 3
A kind of high-temperature-resistant thermoplastic edge sealing hot melt adhesive for furniture, it includes the component of following parts by weight:
The antioxidant is three [2.4- di-tert-butyl-phenyl] phosphite esters.
A kind of preparation method of high-temperature-resistant thermoplastic edge sealing hot melt adhesive for furniture, the preparation method the following steps are included:
(1) EVA, APAO and three [2.4- di-tert-butyl-phenyl] phosphite esters are put into kneader, are begun to warm up and are mediated
Uniformly, mediating frequency is 25Hz, and the control of material temperature degree is heated to material and all melts at 180 DEG C in reaction kettle;
(2) in the material melted into step 1 put into regulated proportion Petropols and rosin resin and mediate uniformly, pinch
Sum of fundamental frequencies rate is 40Hz, mediates to material and all melts, and reduces temperature of charge to 150 DEG C;
(3) it is reduced into step 2 in the material of temperature and slowly puts into barium sulfate, mediated uniformly, kneading frequency is 30Hz, is stopped
It only heats to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder is arrived;
(4) the high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder 200-400 mesh plate filter for obtaining step 3
Discharging is granulated, and dehydration and drying is packed to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture.
High-temperature-resistant thermoplastic hot melt adhesive end properties made from embodiment 3 is shown in Table 1.
Embodiment 4
A kind of high-temperature-resistant thermoplastic edge sealing hot melt adhesive for furniture, it includes the component of following parts by weight:
The antioxidant is 2,6 di tert butyl 4 methyl phenol.
A kind of preparation method of high-temperature-resistant thermoplastic edge sealing hot melt adhesive for furniture, the preparation method the following steps are included:
(1) by EVA, APAO and 2,6- di-tert-butyl-4-methy phenol is put into kneader, is begun to warm up and is mediated
Even, kneading frequency is 22Hz, and the control of material temperature degree is heated to material and all melts at 160 DEG C in reaction kettle;
(2) in the melting materialss of step 1 put into regulated proportion Petropols and rosin resin and mediate uniformly, mediate
Frequency is 30Hz, mediates to material and all melts, and reduces temperature of charge to 140 DEG C;
(3) it is reduced into step 2 in the material of temperature and slowly puts into calcium carbonate and barium sulfate, mediated uniformly, mediate frequency
For 27Hz, stop heating to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder is arrived;
(4) the high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder 200-400 mesh plate filter for obtaining step 3
Discharging is granulated, and dehydration and drying is packed to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture.
High-temperature-resistant thermoplastic hot melt adhesive end properties made from embodiment 4 is shown in Table 1.
Comparative example 1
A kind of common EVA hot melt adhesive for edge bonding of furniture, it includes the component of following parts by weight:
The antioxidant is four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters
A kind of preparation method of common EVA hot melt adhesive for edge bonding of furniture, the preparation method the following steps are included:
(1) it in EVA and four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters investment kneader, opens
Begin to heat and mediate uniformly, mediates speed control material temperature degree control in 25Hz, reaction kettle and be heated to material whole at 170 DEG C
Fusing;
(2) into step 1 melting materialss put into regulated proportion Petropols and rosin resin and mediate uniformly, mediate frequency
Rate is 35Hz, mediates to material and all melts, and reduces temperature of charge to 140 DEG C;
(3) it is reduced to step 2 in the material of temperature and slowly puts into calcium carbonate, mediated uniformly, kneading frequency is 27Hz, is stopped
It heats to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder is arrived;
(4) the high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder 200-400 mesh plate filter for obtaining step 3
Discharging is granulated, and dehydration and drying is packed to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture.
Common EVA hot melt adhesive for edge bonding of furniture end properties made from comparative example 1 is shown in Table 1.
Comparative example 2
A kind of APAO hot melt adhesive for edge bonding of furniture, it includes the component of following parts by weight:
The antioxidant is four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters.
A kind of preparation method of common EVA hot melt adhesive for edge bonding of furniture, the preparation method the following steps are included:
(1) it by EVA, four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters investment kneader, opens
Begin to heat and mediate uniformly, kneading frequency is 22Hz, and the control of material temperature degree is heated to material and all melts at 170 DEG C in reaction kettle;
(2) to step 1 melt material in put into regulated proportion Petropols and rosin resin and mediate uniformly, mediate
Frequency is 35Hz, mediates to material and all melts, and reduces temperature of charge to 140 DEG C;
(3) it is reduced to step 2 in the material of temperature and slowly puts into calcium carbonate, mediated uniformly, kneading frequency is 27Hz, is stopped
It heats to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder is arrived;
(4) the high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder 200-400 mesh plate filter for obtaining step 3
Discharging is granulated, and dehydration and drying is packed to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture.
APAO hot melt adhesive for edge bonding of furniture end properties made from comparative example 2 is shown in Table 1.
As shown in table 1, the high-temperature-resistant thermoplastic fixture edge sealing heat being prepared for embodiment 1-4 and comparative example 1-2
The thermoplastic property testing result of melten gel, the high-temperature-resistant thermoplastic that embodiment 1-4 is prepared it can be seen from adhesive strength test
Adhesive strength of the hot melt adhesive on particieboard and core-board is similar to the adhesive strength of comparative example 1-2, illustrates prepared by this programme
Obtained High-temp.-resistant hot-melt adhesive has stronger adhesive strength.It is small to after different substrate materials progress edge sealing 24 by full automatic edge bander
The test of Shi Jinhang heatproof.For core-board is with respect to particieboard, edge sealing face structure is more fine and close, and the permeability of glue can reduce,
It causes adhesive strength too low, at high temperature since molecule segment motility increases high polymer at high temperature, is also easy to produce alice or phase
To sliding.
Embodiment 1-4 is offset as the cohesive force high energy of high polymer and is displaced caused by most of movement as molecule segment,
Therefore, even if under 90 DEG C of high temperature, furniture will not generate alice during edge sealing.Comparative example 1 due to cohesion not enough therefore
High-temperature resistant result is poor, and alice occurs at high temperature or produces relative sliding that will cause quality of finished not up to standard for finished product.Secondly exist
It is contaminated if generating wire drawing during edge sealing and will cause plate, influences exterior quality, generate rejected product, APAO in comparative example 2
Since itself α-amorphous structure and cohesive force height cause wire drawing situation serious, and with rosin resin compatibility is lower causes to base
Material wellability is insufficient, and causes the dirty plate of wire drawing and temperature tolerance not up to standard.
The performance test results of the furniture edge sealing glue of table 1 embodiment 1-4 and comparative example 1-2
Claims (3)
1. a kind of preparation method of high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture, which is characterized in that the preparation method includes
Following steps:
(1) by 20-60 parts by weight of ethylene-acetate ethylene copolymer (EVA), 5-25 parts by weight amorphous state alpha olefin copolymer
(APAO) it and in 0.3-1 parts by weight antioxidant investment kneader, beginning to warm up and mediates uniformly, kneading frequency is 15-25Hz,
The control of material temperature degree is heated to material and all melts at 150-180 DEG C in reaction kettle;
(2) 5-15 parts by weight Petropols and 0-5 parts by weight rosin resin are put into the material melted into step 1 and are mediated equal
Even, kneading frequency is 27-40Hz, mediates to material and all melts, and reduces temperature of charge to 130-150 DEG C;
(3) it is reduced into step 2 and slowly puts into 15-40 parts of filler material by weight in the material of temperature, kneading frequency is 20-30Hz, is pinched
It closes uniformly, stops heating to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder is arrived;
(4) the high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture coarse fodder 200-400 mesh plate filter that step 3 obtains is gone out
Material is granulated, dehydration and drying, packs to get high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture.
2. preparation method according to claim 1, which is characterized in that the antioxidant is 2,6- di-t-butyl -4- first
Base phenol, three [2.4- di-tert-butyl-phenyl] phosphite esters, four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] Ji Wusi
One or both of alcohol ester.
3. preparation method according to claim 1, which is characterized in that the filler is one of calcium carbonate, barium sulfate
Or two kinds.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111073552A (en) * | 2020-01-02 | 2020-04-28 | 佛山市同人粘胶有限公司 | Hot melt adhesive for coating wood section with decorative veneer and production process thereof |
CN112266744A (en) * | 2020-11-06 | 2021-01-26 | 福建省昌德胶业科技有限公司 | Hot melt adhesive for independent cylinder mattress and preparation method thereof |
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CN1687280A (en) * | 2005-06-03 | 2005-10-26 | 江苏工业学院 | New type hot-melt adhesive and preparation method thereof |
CN101928530A (en) * | 2010-09-02 | 2010-12-29 | 上海天洋热熔胶有限公司 | Edge sealing hot melt adhesive for furniture and preparation method thereof |
CN104745122A (en) * | 2015-04-13 | 2015-07-01 | 长城崛起(福建)新材料科技股份公司 | Hot melt adhesive and preparation process thereof |
WO2016139345A1 (en) * | 2015-03-04 | 2016-09-09 | Sika Technology Ag | Hotmelt adhesive with enhanced uv stability and use for producing a multilayer polymeric sheet |
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2019
- 2019-07-16 CN CN201910640805.5A patent/CN110343490A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1687280A (en) * | 2005-06-03 | 2005-10-26 | 江苏工业学院 | New type hot-melt adhesive and preparation method thereof |
CN101928530A (en) * | 2010-09-02 | 2010-12-29 | 上海天洋热熔胶有限公司 | Edge sealing hot melt adhesive for furniture and preparation method thereof |
WO2016139345A1 (en) * | 2015-03-04 | 2016-09-09 | Sika Technology Ag | Hotmelt adhesive with enhanced uv stability and use for producing a multilayer polymeric sheet |
CN104745122A (en) * | 2015-04-13 | 2015-07-01 | 长城崛起(福建)新材料科技股份公司 | Hot melt adhesive and preparation process thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111073552A (en) * | 2020-01-02 | 2020-04-28 | 佛山市同人粘胶有限公司 | Hot melt adhesive for coating wood section with decorative veneer and production process thereof |
CN112266744A (en) * | 2020-11-06 | 2021-01-26 | 福建省昌德胶业科技有限公司 | Hot melt adhesive for independent cylinder mattress and preparation method thereof |
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Application publication date: 20191018 |