CN110343440A - A kind of metal surface coating easy to clean and preparation method - Google Patents
A kind of metal surface coating easy to clean and preparation method Download PDFInfo
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- CN110343440A CN110343440A CN201910459054.7A CN201910459054A CN110343440A CN 110343440 A CN110343440 A CN 110343440A CN 201910459054 A CN201910459054 A CN 201910459054A CN 110343440 A CN110343440 A CN 110343440A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Engineering & Computer Science (AREA)
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Abstract
The invention discloses a kind of metal surface coating easy to clean and preparation method thereof, it is desirable to provide material surface adaptability is good, and coating adhesion is strong and hardness is high, the good metal surface of wearability coating easy to clean；Its technical solution includes following weight parts component: 100-120 parts of modified epoxy resin emulsion, 10-13 parts of lithium metasilicate, and 0.9-1.2 parts of KH-560 silane coupling agent, 12-15 parts of diluent, 1-2 parts of coalescing agent, modified Nano CaCO31-2 parts, 1-3 parts of advection agent, 1.2-2.5 parts of defoaming agent, 0.2-0.5 parts of wetting agent, 1-2 parts of wax emulsion；Belong to technical field of coatings.
Description
Technical field
The invention discloses a kind of coating, specifically, be a kind of metal surface coating easy to clean, invention additionally discloses
The preparation method of the coating, belongs to technical field of coatings.
Background technique
Corrosion of metal is the significant wastage to limited resources on the earth and the energy, currently, often phosphatization, chromating etc.
Technique is that widely applied metal surface treatment technology, protecting effect are significant in industrial production.But these techniques seriously pollute
Environment, application are gradually restricted, by coating environment friendly anti-corrosive paint in metal surface, it has also become the hot spot of research.
A kind of metallic paint of Chinese patent CN201210340308.1 and its preparation method and application, technical solution are institutes
It states metallic paint and is mainly made of component A and component B and mixed according to volume ratio 1:1；Wherein, the component A, according to weight
Percentages, mainly consist of the following components: epoxy amino copolymer resins 40-60%, amino resins 20-30%, epoxy resin
5-10%, organic solvent 8-20%, levelling agent 0.1-0.5%；The component B, in percentage by weight, mainly by with the following group
It is grouped as: nitrocotton 30-50%, organic solvent 50-70%.Not only chemical resistance is excellent for metallic paint provided by the present invention
Show, and resistance to aqueous enzyme is washed.Moreover, the method for its coating metal workpiece is succinctly quick, small, obtained metal works are polluted
The paint film on surface is smooth, and gloss is high, and resistance to enzyme liquid is good.
Summary of the invention
In order to solve the above technical problems, use material surface adaptability good the object of the present invention is to provide a kind of, antiseptic property
Excellent and hardness is high, the good metal surface of wearability coating easy to clean.
Second technical solution provided by the invention is to provide the preparation method of above-mentioned coating.
For this purpose, first technical solution provided by the invention is such that
A kind of metal surface coating easy to clean, including following weight parts component: modified epoxy resin emulsion 100-120
Part, 10-13 parts of lithium metasilicate, 0.9-1.2 parts of KH-560 silane coupling agent, 12-15 parts of diluent, 1-2 parts of coalescing agent, modification is received
Rice CaCO31-2 parts, 1-3 parts of advection agent, 1.2-2.5 parts of defoaming agent, 0.2-0.5 parts of wetting agent, 1-2 parts of wax emulsion.
As present invention further optimization, above-mentioned metal surface coating easy to clean, the modified epoxy cream
Liquid is as made from following step:
1) 10 parts of epoxy resin are weighed, mixed solvent is added, stirring is warming up to 110-120 DEG C, and 0.2-0.3 parts of phosphorus are added
Acid, control add for 3 minutes, and the reaction was continued,
2) 0.3-0.5 parts of styrene, 0.4 part of acrylic acid, 0.3-0.5 parts of butyl acrylate, benzoyl peroxide first are slowly added to
0.2-0.3 parts of tert-butyl acrylate, in 105-115 DEG C of reaction 5-6h, and intermediate supplement peroxidized t-butyl perbenzoate is twice, every time
0.1 part；
3) removed under reduced pressure solvent；Then, revolving speed is adjusted to 500-700r/min, and suitable go is slowly added to by minim pipette
Ionized water is emulsified
As present invention further optimization, above-mentioned metal surface coating easy to clean, the diluent is the U.S. DOW
324 reactive diluent of Tao Shi DER.
As present invention further optimization, above-mentioned metal surface coating easy to clean, the coalescing agent is dipropyl
One of glycol methyl ether, alcohol ester 12 or any mixing.
As present invention further optimization, above-mentioned metal surface coating easy to clean, the advection agent is that Germany finishes
Gram BYK-325.
As present invention further optimization, above-mentioned metal surface coating easy to clean, the defoaming agent is Germany
BASF aqueous defoamer FoamStarST2292.
As present invention further optimization, above-mentioned metal surface coating easy to clean, the wetting agent is Tao Shi
Chemical NP-10 water paint wetting agent.
As present invention further optimization, above-mentioned metal surface coating easy to clean, the wax emulsion is Germany
Bi Ke BYK-AQUACER-1547.
As present invention further optimization, above-mentioned metal surface coating easy to clean, the mixed solvent is chaff
What aldehyde and n-butanol were mixed according to volume ratio 1:1.
Second technical solution provided by the invention is such that
The preparation method of metal surface coating easy to clean, by modified epoxy resin emulsion, lithium metasilicate, KH-560 silane
Coupling agent, diluent are added to reaction kettle, and 100-120 DEG C of stirring 2-5h is cooled to room temperature, and surplus stock, which is added, to be uniformly mixed.
Compared with prior art, technical solution provided by the invention has following technological merit:
1, technical solution provided by the invention is good to material surface adaptability, coating adhesion is strong, coating adhesive force can
Up to 1 grade, salt fog resistance is excellent；
2, after technical solution provided by the invention is coated in frosting, antibacterial, long service life, high temperature resistant and resistance to low
Temperature has a wide range of application.
3, technical solution operation provided by the invention is also simple, can reduce difficulty of construction, save cost of labor, saving color
Use cost.
Specific embodiment
Claim of the invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1
A kind of metal surface provided by the invention coating easy to clean, is grouped as by following following weight arrays: modified ring
324 reactive diluent of oxygen resin emulsion 100g, lithium metasilicate 13g, KH-560 silane coupling agent 0.9g, DOW Dow DER
15g, alcohol ester 12 1g, modified Nano CaCO31g, German Bi Ke BYK-325 3g, German BASF aqueous defoamer
FoamStarST2292 1.2g, DOW Chemical NP-10 water paint wetting agent 0.5g, German Bi Ke BYK-AQUACER-1547
1g。
The modified epoxy resin emulsion is as made from following step:
1) 10g epoxy resin is weighed, mixed solvent is added, stirring is warming up to 110 DEG C, and 0.3g phosphoric acid is added, and controls 3 minutes
It adds, the reaction was continued；
The mixed solvent is that furfural and n-butanol are mixed according to volume ratio 1:1
2) styrene 0.5g, acrylic acid 0.4g, butyl acrylate 0.3g, peroxidized t-butyl perbenzoate are slowly added to
0.3g, in 105 DEG C of reaction 6h, and intermediate supplement peroxidized t-butyl perbenzoate is twice, each 0.1g.
3) removed under reduced pressure solvent；Then, revolving speed is adjusted to 700r/min, and suitable deionization is slowly added to by minim pipette
Water is emulsified.
Embodiment 2
A kind of metal surface provided by the invention coating easy to clean, is grouped as by following following weight arrays: modified ring
324 reactive diluent of oxygen resin emulsion 120g, lithium metasilicate 10g, KH-560 silane coupling agent 1.2g, DOW Dow DER
12g, dipropylene glycol methyl ether 2g, modified Nano CaCO32g, German Bi Ke BYK-325 1g, German BASF aqueous defoamer
FoamStarST2292 2.5g, DOW Chemical NP-10 water paint wetting agent 0.5g, German Bi Ke BYK-AQUACER-1547
1。
The modified epoxy resin emulsion is as made from following step:
1) 10g epoxy resin is weighed, mixed solvent is added, stirring is warming up to 120 DEG C, and 0.2g phosphoric acid is added, and controls 3 minutes
It adds, the reaction was continued；
The mixed solvent is that furfural and n-butanol are mixed according to volume ratio 1:1
2) styrene 0.3g, acrylic acid 0.4g, butyl acrylate 0.3g, peroxidized t-butyl perbenzoate are slowly added to
0.3g, in 115 DEG C of reaction 5h, and intermediate supplement peroxidized t-butyl perbenzoate is twice, each 0.1g.
3) removed under reduced pressure solvent；Then, revolving speed is adjusted to 700r/min, and suitable deionization is slowly added to by minim pipette
Water is emulsified.
Embodiment 3
A kind of metal surface provided by the invention coating easy to clean, is grouped as by following following weight arrays: modified ring
324 reactive diluent 13g of oxygen resin emulsion 115g, lithium metasilicate 12g, KH-560 silane coupling agent 1g, DOW Dow DER,
Dipropylene glycol methyl ether 1.5g, modified Nano CaCO31.2g, German Bi Ke BYK-325 2g, German BASF aqueous defoamer
FoamStarST2292 1.8g, DOW Chemical NP-10 water paint wetting agent 0.4g, German Bi Ke BYK-AQUACER-1547
1.2g。
The modified epoxy resin emulsion is as made from following step:
1) 10g epoxy resin is weighed, mixed solvent is added, stirring is warming up to 115 DEG C, and 0.25g phosphoric acid is added, and controls 3 points
Clock adds, and the reaction was continued；
The mixed solvent is that furfural and n-butanol are mixed according to volume ratio 1:1
2) styrene 0.4g, acrylic acid 0.4g, butyl acrylate 0.4g, peroxidized t-butyl perbenzoate are slowly added to
0.25g, in 110 DEG C of reaction 5.5h, and intermediate supplement peroxidized t-butyl perbenzoate is twice, each 0.1g.
3) removed under reduced pressure solvent；Then, revolving speed is adjusted to 600r/min, and suitable deionization is slowly added to by minim pipette
Water is emulsified
Embodiment 4
A kind of metal surface disclosed by the invention coating easy to clean, is grouped as by following following weight arrays: modified ring
324 reactive diluent of oxygen resin emulsion 115g, lithium metasilicate 12g, KH-560 silane coupling agent 1.1g, DOW Dow DER
14g, dipropylene glycol methyl ether 1.2g, modified Nano CaCO31.5g, German Bi Ke BYK-325 2.8g, German BASF are aqueous
Defoaming agent FoamStarST2292 1.8g, DOW Chemical NP-10 water paint wetting agent 0.4g, German Bi Ke BYK-
AQUACER-1547 1.6g。
The modified epoxy resin emulsion is as made from following step:
1) 10g epoxy resin is weighed, mixed solvent is added, stirring is warming up to 116 DEG C, and 0.24g phosphoric acid is added, and controls 3 points
Clock adds, and the reaction was continued；
The mixed solvent is that furfural and n-butanol are mixed according to volume ratio 1:1.
2) styrene 0.36g, acrylic acid 0.4g, butyl acrylate 0.44g, peroxidized t-butyl perbenzoate are slowly added to
0.25g, in 110 DEG C of reaction 6h, and intermediate supplement peroxidized t-butyl perbenzoate is twice, each 0.1g.
3) removed under reduced pressure solvent；Then, revolving speed is adjusted to 500-700r/min, and suitable go is slowly added to by minim pipette
Ionized water is emulsified
The preparation method of metal surface coating easy to clean, by modified epoxy resin emulsion, lithium metasilicate, KH-560 silane
Coupling agent, diluent are added to reaction kettle, and 100-120 DEG C (preferably 105 DEG C) stirring 2-5h is cooled to room temperature, surplus stock adds
Enter uniformly mixed.
The preparation method of the above-mentioned metal surface of any one in embodiment 1 to 4 coating easy to clean, by modified epoxy tree
Fat liquor, lithium metasilicate, KH-560 silane coupling agent, diluent are added to reaction kettle, 100-120 DEG C (preferably 105 DEG C) stirring 2-
5h is cooled to room temperature, and surplus stock, which is added, to be uniformly mixed.It the advantages of in order to illustrate technical solution provided by the present application, gives below
The experimental example of technical solution provided by the present application out.
The formula of embodiment 1- embodiment 4 is prepared into coating, prepare resulting coating using spraying method 100mm ×
Coating is made on the plastics of 100mm；The detection performance of embodiment 1-4 is shown in Table 1
Table 1
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of metal surface coating easy to clean, which is characterized in that including following weight parts component: modified epoxy resin emulsion
100-120 parts, 10-13 parts of lithium metasilicate, 0.9-1.2 parts of KH-560 silane coupling agent, 12-15 parts of diluent, coalescing agent 1-2
Part, modified Nano CaCO31-2 parts, 1-3 parts of levelling agent, 1.2-2.5 parts of defoaming agent, 0.2-0.5 parts of wetting agent, wax emulsion 1-2
Part.
2. metal surface according to claim 1 coating easy to clean, which is characterized in that the modified epoxy resin emulsion
As made from following step:
1) 10 parts of epoxy resin are weighed, mixed solvent is added, stirring is warming up to 110-120 DEG C, and 0.2-0.3 parts of phosphoric acid, control is added
System adds for 3 minutes, and the reaction was continued；
2) 0.3-0.5 parts of styrene, 0.4 part of acrylic acid, 0.3-0.5 parts of butyl acrylate, perbenzoic acid uncle are slowly added to
0.2-0.3 parts of butyl ester, in 105-115 DEG C of reaction 5-6h, and intermediate supplement peroxidized t-butyl perbenzoate is twice, and every time 0.1
Part；
3) removed under reduced pressure solvent；Then, revolving speed is adjusted to 500-700r/min, and suitable deionization is slowly added to by minim pipette
Water is emulsified.
3. metal surface according to claim 1 coating easy to clean, which is characterized in that the diluent is the U.S. DOW
Tao Shi DER324 reactive diluent.
4. metal surface according to claim 1 coating easy to clean, which is characterized in that the coalescing agent is dipropyl two
One of alcohol methyl ether, alcohol ester 12 or any mixing.
5. metal surface according to claim 1 coating easy to clean, which is characterized in that the advection agent is Germany Bi Ke
BYK-325。
6. metal surface according to claim 1 coating easy to clean, which is characterized in that the defoaming agent is Germany bar
This husband's aqueous defoamer FoamStarST2292.
7. metal surface according to claim 1 coating easy to clean, which is characterized in that the wetting agent is Tao Shiization
Learn NP-10 water paint wetting agent.
8. metal surface according to claim 1 coating easy to clean, which is characterized in that the wax emulsion is that Germany finishes
Gram BYK-AQUACER-1547.
9. metal surface according to claim 2 coating easy to clean, which is characterized in that the mixed solvent is furfural
It is mixed with n-butanol according to volume ratio 1:1.
10. the metal surface described in claim 1 preparation method of coating easy to clean, which is characterized in that by modified epoxy tree
Fat liquor, lithium metasilicate, KH-560 silane coupling agent, diluent are added to reaction kettle, and 100-120 DEG C of stirring 2-5h is cooled to room
Temperature, surplus stock, which is added, to be uniformly mixed.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910459054.7A CN110343440A (en) | 2019-05-29 | 2019-05-29 | A kind of metal surface coating easy to clean and preparation method |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113278312A (en) * | 2021-04-26 | 2021-08-20 | 绵阳麦思威尔科技有限公司 | Organic-inorganic hybrid water-based emulsion, preparation method thereof and super-anticorrosion coating |
| CN113604128A (en) * | 2021-07-09 | 2021-11-05 | 湖北金天叶科技有限公司 | Binding agent for easy-to-clean coating on surface of food machinery |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921373A (en) * | 2010-08-17 | 2010-12-22 | 华南理工大学 | Acrylic modified epoxy resin emulsion and preparation method thereof |
| CN105802429A (en) * | 2016-04-18 | 2016-07-27 | 芜湖县双宝建材有限公司 | Anti-ultraviolet coating |
| CN107709483A (en) * | 2015-05-29 | 2018-02-16 | Prc-迪索托国际公司 | Metal base containing lithium metasilicate as the curable film-forming composition and multiple coating of corrosion inhibitor |
| CN109251575A (en) * | 2018-09-17 | 2019-01-22 | 佛山市禅城区诺高环保科技有限公司 | A kind of preparation method of the water-fast aqueous enamel paint of high adhesion force |
| CN109796848A (en) * | 2019-01-24 | 2019-05-24 | 河北汇君新材料制造有限公司 | A kind of water corrosion-resistant epoxy paint and preparation method thereof |
-
2019
- 2019-05-29 CN CN201910459054.7A patent/CN110343440A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921373A (en) * | 2010-08-17 | 2010-12-22 | 华南理工大学 | Acrylic modified epoxy resin emulsion and preparation method thereof |
| CN107709483A (en) * | 2015-05-29 | 2018-02-16 | Prc-迪索托国际公司 | Metal base containing lithium metasilicate as the curable film-forming composition and multiple coating of corrosion inhibitor |
| CN105802429A (en) * | 2016-04-18 | 2016-07-27 | 芜湖县双宝建材有限公司 | Anti-ultraviolet coating |
| CN109251575A (en) * | 2018-09-17 | 2019-01-22 | 佛山市禅城区诺高环保科技有限公司 | A kind of preparation method of the water-fast aqueous enamel paint of high adhesion force |
| CN109796848A (en) * | 2019-01-24 | 2019-05-24 | 河北汇君新材料制造有限公司 | A kind of water corrosion-resistant epoxy paint and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113278312A (en) * | 2021-04-26 | 2021-08-20 | 绵阳麦思威尔科技有限公司 | Organic-inorganic hybrid water-based emulsion, preparation method thereof and super-anticorrosion coating |
| CN113604128A (en) * | 2021-07-09 | 2021-11-05 | 湖北金天叶科技有限公司 | Binding agent for easy-to-clean coating on surface of food machinery |
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