CN110342627A - Ozone catalytic oxidation advanced treatment method for biochemical effluent of chemical wastewater - Google Patents
Ozone catalytic oxidation advanced treatment method for biochemical effluent of chemical wastewater Download PDFInfo
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- CN110342627A CN110342627A CN201910494576.0A CN201910494576A CN110342627A CN 110342627 A CN110342627 A CN 110342627A CN 201910494576 A CN201910494576 A CN 201910494576A CN 110342627 A CN110342627 A CN 110342627A
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- catalyst
- ozone
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- 239000002351 wastewater Substances 0.000 title claims abstract description 54
- 239000000126 substance Substances 0.000 title claims abstract description 39
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 24
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 13
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 12
- 230000003647 oxidation Effects 0.000 title abstract description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003054 catalyst Substances 0.000 claims abstract description 21
- 238000006385 ozonation reaction Methods 0.000 claims abstract description 10
- 239000000571 coke Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 238000007210 heterogeneous catalysis Methods 0.000 claims description 6
- 229910017163 MnFe2O4 Inorganic materials 0.000 claims description 5
- 239000002905 metal composite material Substances 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 241000233855 Orchidaceae Species 0.000 claims 1
- 239000003610 charcoal Substances 0.000 claims 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical group [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims 1
- 239000003344 environmental pollutant Substances 0.000 abstract description 8
- 231100000719 pollutant Toxicity 0.000 abstract description 8
- 238000004939 coking Methods 0.000 abstract description 7
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 239000002957 persistent organic pollutant Substances 0.000 abstract description 2
- 230000001988 toxicity Effects 0.000 abstract description 2
- 231100000419 toxicity Toxicity 0.000 abstract description 2
- 238000004064 recycling Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000007059 acute toxicity Effects 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 238000009303 advanced oxidation process reaction Methods 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 238000007172 homogeneous catalysis Methods 0.000 description 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The invention relates to an ozone catalytic oxidation advanced treatment method for biochemical effluent of chemical wastewater. And (3) feeding biochemical effluent of the chemical wastewater into a reactor, adding a catalyst and hydrogen peroxide, and introducing ozone to perform heterogeneous catalytic ozonation reaction. The method can effectively remove organic pollutants with difficult toxicity degradation in the chemical wastewater biochemical effluent, reaches the discharge standard of coking chemical industry pollutants (GB 16171-2012), has no secondary pollution, realizes the recycling of the catalyst, and has wide application prospect.
Description
Technical field
The present invention relates to a kind of processing method of chemical wastewater biochemical water outlet more particularly to a kind of water outlets of chemical wastewater biochemical
Catalytic ozonation deep treatment method.
Background technique
Semi-coke wastewater is one kind of wastewater from chemical industry also referred to as semicoke waste water, is using coal as raw material, in, low temperature
(500 DEG C~900 DEG C) destructive distillation, a series of industrial wastewaters that production semi-coke etc. generates in the process.Semi-coke wastewater is during generation
Discharge amount is larger, and waste water quality is influenced by enterprise's coal chemical industry production technology.From the point of view of the comparison of conventional coking wastewater, in semi-coke wastewater
The primary categories of pollutant are similar, wherein containing a large amount of phenolic compound, benzene compounds, heterocyclic compound, also contain one
Part inorganic compound.But the concentration of pollutant will much be higher by conventional coking wastewater in semi-coke wastewater, be a kind of typical difficulty
Biological treatment waste water.
At this stage, it is useless mainly to handle semi-coke using the method for " pretreatment+biological treatment " for the semi-coke manufacturing enterprise in China
Water, such as Gas biological filter (BAF) and membrane bioreactor (MBR) etc..But since in process of production, semi-coke is useless
Water water is more, water-quality constituents is complicated, variation water quality amplitude is violent, and bio-treatment Feasibility is poor, therefore bio-chemical effluent water quality is difficult
Meet the standards such as discharge and reuse, therefore it is imperative to carry out advanced treating to the bio-chemical effluent of semi-coke wastewater.
Heterogeneous catalysis ozonation technology belongs to one kind of advanced oxidation processes, in recent years to be used to advanced treating coal more
The biochemical tail water of chemical industry.This method is based on traditional Ozonation, and using the catalysis efficiency of catalyst, generates more
The OH with strong oxidizing property, will effectively can solve the problems, such as that pollutant process is halfway at normal temperatures and pressures, mention simultaneously
The utilization rate to ozone in the reaction is risen, the power consumption of production ozone devices is reduced, there is easy to operate, energy fast degradation pollution
It object and does not cause the advantages that secondary pollution.
Summary of the invention
A kind of the smelly of chemical wastewater biochemical water outlet is provided the purpose of the invention is to improve the deficiencies in the prior art
Oxygen catalysis oxidation deep treatment method.
The technical solution of the present invention is as follows: a kind of catalytic ozonation deep treatment method of chemical wastewater biochemical water outlet,
Specific step is as follows: chemical wastewater biochemical being discharged and is sent into reactor, catalyst and hydrogen peroxide are added, it is non-to be passed through ozone progress
Homogeneous catalysis ozone oxidation reaction.
It is preferred that the add quality and the volume ratio of chemical wastewater biochemical water outlet of the catalyst are 0.5~3.0g/L；Often
The dosage of ozone is 30~60mg in the waste water COD of 100mg/L；The dosage of hydrogen peroxide in the waste water COD of every 1000mg/L
For 1~3ml；Reaction time is 30~90min.
It is preferred that the wastewater from chemical industry is semi-coke wastewater, the COD of the bio-chemical effluent of semi-coke wastewater is 300~500mg/L；Volatilization
Phenol is 10~30mg/L；Initial pH=4~9 of solution.
It is preferred that the catalyst is ferrimanganic metal composite oxide type catalyst MnFe2O4。
The utility model has the advantages that
The present invention uses heterogeneous catalysis ozone oxidation advanced treating wastewater from chemical industry --- the bio-chemical effluent of semi-coke wastewater, benefit
With the synergistic effect of ozone, catalyst and hydrogen peroxide, more hydroxyl radical free radicals are generated, oxidation-reduction potential 2.80eV,
The toxicity persistent organic pollutants in semi-coke wastewater bio-chemical effluent can be effectively removed, CO is mineralized into2And H2O is reduced acute
Toxicity, and do not cause secondary pollution.The semi-coke wastewater bio-chemical effluent of present invention process processing, COD removal rate volatilize up to 83.5%
Phenol removal rate is up to 98.9%.Semi-coke wastewater bio-chemical effluent indices after processed by the invention reach " coking chemistry industry
Pollutant emission standard " (GB 16171-2012).
Specific embodiment
Embodiment 1:
The semi-coke wastewater bio-chemical effluent of certain chemical company, specific water quality are shown in Table 1.The bio-chemical effluent of semi-coke wastewater is sent into anti-
It answers in device, adds catalyst and hydrogen peroxide, be passed through ozone and carry out heterogeneous catalysis ozone oxidation reaction.Wherein catalyst adds
Amount is 0.5g/L, is 30mg according to the dosage of ozone in the waste water COD of every 100mg/L, then ozone dosage is in this example
150mg, reaction time 30min, the dosage according to hydrogen peroxide in the waste water COD of every 1000mg/L are 1ml, then double in this example
The dosage of oxygen water is about 0.3ml, the initial pH=4 of solution.Ferrimanganic metal composite oxide type catalyst MnFe2O4It is solidifying by colloidal sol
The preparation of glue method, wherein calcining time is 4h, and maturing temperature is 400 DEG C.Final process water outlet reaches " coking chemistry industrial pollutants
Discharge standard " (GB 16171-2012).The O3 catalytic oxidation effect of 1 waste water of embodiment is as shown in table 1.
Table 1
Embodiment 2:
The semi-coke wastewater bio-chemical effluent of certain chemical company, specific water quality are shown in Table 2.The bio-chemical effluent of semi-coke wastewater is sent into anti-
It answers in device, adds catalyst and hydrogen peroxide, be passed through ozone and carry out heterogeneous catalysis ozone oxidation reaction.Wherein catalyst adds
Amount is 2.0g/L, is 40mg according to the dosage of ozone in the waste water COD of every 100mg/L, then ozone dosage is in this example
200mg, reaction time 60min, the dosage according to hydrogen peroxide in the waste water COD of every 1000mg/L are 2ml, then double in this example
The dosage of oxygen water is 0.8ml, the initial pH=7 of solution.Ferrimanganic metal composite oxide type catalyst MnFe2O4By collosol and gel
Method preparation, wherein calcining time is 6h, and maturing temperature is 600 DEG C.Final process water outlet reaches " coking chemistry industrial pollutants row
Put standard " (GB 16171-2012).The O3 catalytic oxidation effect of 2 waste water of embodiment is as shown in table 2.
Table 2
Embodiment 3:
The semi-coke wastewater bio-chemical effluent of certain chemical company, specific water quality are shown in Table 3.The bio-chemical effluent of semi-coke wastewater is sent into anti-
It answers in device, adds catalyst and hydrogen peroxide, be passed through ozone and carry out heterogeneous catalysis ozone oxidation reaction.Wherein catalyst adds
Amount is 3.0g/L, is 50mg according to the dosage of ozone in the waste water COD of every 100mg/L, then ozone dosage is in this example
300mg, reaction time 90min, the dosage according to hydrogen peroxide in the waste water COD of every 1000mg/L are 3ml, then double in this example
The dosage of oxygen water is 1.5ml, the initial pH=9 of solution.Ferrimanganic metal composite oxide type catalyst MnFe2O4By collosol and gel
Method preparation, wherein calcining time is 8h, and maturing temperature is 800 DEG C.Final process water outlet reaches " coking chemistry industrial pollutants row
Put standard " (GB 16171-2012).The O3 catalytic oxidation effect of 3 waste water of embodiment is as shown in table 3.
Table 3
Claims (4)
1. a kind of catalytic ozonation deep treatment method of chemical wastewater biochemical water outlet, the specific steps of which are as follows: chemical industry is given up
Water bio-chemical effluent is sent into reactor, and catalyst and hydrogen peroxide are added, and is passed through ozone and is carried out heterogeneous catalysis ozone oxidation reaction.
2. catalytic ozonation deep treatment method according to claim 1, it is characterised in that the throwing of the catalyst
The volume ratio for adding quality and chemical wastewater biochemical to be discharged is 0.5~3.0g/L；Ozone adds in the waste water COD of every 100mg/L
Amount is 30~60mg；The dosage of hydrogen peroxide is 1~3ml in the waste water COD of every 1000mg/L；Reaction time is 30~90min.
3. catalytic ozonation deep treatment method according to claim 1, it is characterised in that the wastewater from chemical industry is orchid
Charcoal waste water, the COD of the bio-chemical effluent of semi-coke wastewater are 300~500mg/L；Volatile phenol is 10~30mg/L；The initial pH=4 of solution
~9.
4. catalytic ozonation deep treatment method according to claim 1, it is characterised in that the catalyst is iron
Manganese metal composite oxide type catalyst MnFe2O4。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910494576.0A CN110342627A (en) | 2019-06-10 | 2019-06-10 | Ozone catalytic oxidation advanced treatment method for biochemical effluent of chemical wastewater |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910494576.0A CN110342627A (en) | 2019-06-10 | 2019-06-10 | Ozone catalytic oxidation advanced treatment method for biochemical effluent of chemical wastewater |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116510782A (en) * | 2023-04-28 | 2023-08-01 | 浙江工业大学 | ZIFs-derived core-shell magnetic nano ozone catalyst, preparation method and application |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5376285A (en) * | 1993-02-11 | 1994-12-27 | Uop | Oxidative removal of aqueous metal-complexed cyanide under acidic conditions |
| US20030102269A1 (en) * | 2001-11-30 | 2003-06-05 | Jim Bender | Pulsed blackbody radiation flux enhancement |
| CN102151567A (en) * | 2011-02-25 | 2011-08-17 | 哈尔滨工业大学 | Catalyst for oxidation and decomposition of organic pollutants in water with ozone and method thereof for catalyzing sewage treatment with ozone |
| CN102161537A (en) * | 2010-07-27 | 2011-08-24 | 王兵 | Deep purification method of coking wastewater based on advanced ozone oxidation |
| CN104773930A (en) * | 2015-04-30 | 2015-07-15 | 中国华电工程(集团)有限公司 | Semi-coke waste water treatment system and technology |
| KR20170056155A (en) * | 2015-11-13 | 2017-05-23 | 주식회사 코벡 | Method of treating phenol-containing water |
| CN106882866A (en) * | 2017-02-24 | 2017-06-23 | 河北科技大学 | The method that hydrogen peroxide synergy ozone heterogeneous catalytic oxidation processes waste water |
| CN108928890A (en) * | 2018-08-20 | 2018-12-04 | 四川大学 | A kind of method of three-diemsnional electrode coupling oxidizer treatment used water difficult to degradate |
-
2019
- 2019-06-10 CN CN201910494576.0A patent/CN110342627A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5376285A (en) * | 1993-02-11 | 1994-12-27 | Uop | Oxidative removal of aqueous metal-complexed cyanide under acidic conditions |
| US20030102269A1 (en) * | 2001-11-30 | 2003-06-05 | Jim Bender | Pulsed blackbody radiation flux enhancement |
| CN102161537A (en) * | 2010-07-27 | 2011-08-24 | 王兵 | Deep purification method of coking wastewater based on advanced ozone oxidation |
| CN102151567A (en) * | 2011-02-25 | 2011-08-17 | 哈尔滨工业大学 | Catalyst for oxidation and decomposition of organic pollutants in water with ozone and method thereof for catalyzing sewage treatment with ozone |
| CN104773930A (en) * | 2015-04-30 | 2015-07-15 | 中国华电工程(集团)有限公司 | Semi-coke waste water treatment system and technology |
| KR20170056155A (en) * | 2015-11-13 | 2017-05-23 | 주식회사 코벡 | Method of treating phenol-containing water |
| CN106882866A (en) * | 2017-02-24 | 2017-06-23 | 河北科技大学 | The method that hydrogen peroxide synergy ozone heterogeneous catalytic oxidation processes waste water |
| CN108928890A (en) * | 2018-08-20 | 2018-12-04 | 四川大学 | A kind of method of three-diemsnional electrode coupling oxidizer treatment used water difficult to degradate |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116510782A (en) * | 2023-04-28 | 2023-08-01 | 浙江工业大学 | ZIFs-derived core-shell magnetic nano ozone catalyst, preparation method and application |
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