CN1103420A - Effective liquefied ceramic and its preparing method - Google Patents
Effective liquefied ceramic and its preparing method Download PDFInfo
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- CN1103420A CN1103420A CN 93114919 CN93114919A CN1103420A CN 1103420 A CN1103420 A CN 1103420A CN 93114919 CN93114919 CN 93114919 CN 93114919 A CN93114919 A CN 93114919A CN 1103420 A CN1103420 A CN 1103420A
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Abstract
The effective liquid ceramic used as external paint of cement, metal, wood, plastics, plaster, etc. includes basic material A and curing agent B and may be used by mixing A with B. The basic material A is prepared with epoxy resin, polyurethane resin, 2,4,6-tribromophenol, precipitated baryte, rutile powder, xylene, cyclohexanone, amino resin and talc powder through dissolving, grinding, filtering and colouring. The liquid ceramic features high hardness and toughness, resisting water, rubbing, flame, acid and alkali, strong adhesion and good finishness.
Description
The invention belongs to a kind of coating and preparation method thereof, particularly a kind of effective liquefied ceramic and preparation method thereof.
The coating that uses on cement, timber, plastics, gypsum, glass reinforced plastic and metal at present mainly is paint and some other coating.As disclosed coating in CN1034943A, J01-201370, VS4835225, the DE3818162 patent document.Though these coating are all made raw material with Resins, epoxy, other compositions are different fully with the present invention.And after paint and some coating use, poor with base material avidity, thereby intensity is not high, wear resistance and antiacid, basicity is poor, smooth finish is also bad.Sometimes use ceramic tile or mosaic etc. as ornament, these materials can not use on all base materials, and snappiness is poor, and are easily broken.
One of purpose of the present invention provides a kind of effective liquefied ceramic prescription.
Two of purpose of the present invention provides a kind of preparation method who prepares the used A material of effective liquefied ceramic.
Purpose of the present invention can realize by following measure:
Effective liquefied ceramic is to be mixed by A material and solidifying agent B material, and its prescription is as follows: (weight %)
A material: Resins, epoxy 601E-20 10～25%
Resins, epoxy 604E-12 10～30%
Linear loop epoxy resins 621 4.5～13%
Urethane resin 7110J
42～6%
2,4,6 tribromophenols 4.5～12%
Process white (technical grade) 2～6%
Rutile Cornstarch R930 20～46%
Dimethylbenzene 8～36%
Cyclohexanone 7～25%
Aminoresin 590-3 2～6%
Talcum powder 325 orders 2～8%
B material: T
31It is 30～60% of A material.
T
32It is 0～30% of A material
The preparation technology of A material in turn includes the following steps:
(1) dissolving: in reactor, add Resins, epoxy and dimethylbenzene, add cyclohexanone solvent again, warming while stirring to 110 ℃～125 ℃, constant temperature 2～3 hours is to all dissolvings.Be cooled to 35 ℃～50 ℃ then, can from reactor, take out, put into container;
(2) filter: the liquid resin in the container is filtered;
(3) grind: the liquid resin after will filtering is introduced shredder, add urethane resin, rutile Cornstarch and 2,4,6 tribromophenols, process white, aminoresin, talcum powder simultaneously, after the mixing, ground at normal temperatures 2～4 hours, can meet the requirements of fineness;
(4) filter: with above-mentioned ground material with 180 orders～240 purpose strainer filterings;
(5) painted: 1～5% pigment of the material after the filtration and material adds in the jar rolling machine simultaneously and mixes, and at normal temperatures through 1～2 hour, can finish paintedly, just makes finished product A material.
The B material is to adopt commercially available prod T
31Or T
32Epoxy curing agent.This solidifying agent is the fatty amine modified compound that contains phenyl ring.The reactive hydrogen that contains fatty amine in the molecular structure has the group of nucleophilic addition(Adn) or catalyzed reaction.So speed of response is fast, can at room temperature solidify.Because molecular weight is not high, viscosity is low, and is good with the compatibility of Resins, epoxy.Presetting period can be regulated with different solvents, and processing performance is good.Owing to introduced benzene ring structure in the molecule, good stability, the heat-drawn wire height is so it is little at room temperature to volatilize, thereby greatly reduce the possibility that the solidifying agent nuisance directly enters human body by respiratory tract, also avoided the solidifying agent steam to enter the approach of human body by skin pore.Because T
31Introduced aromatic group in the solidifying agent molecule, generally be dissolved in organic solvent and water insoluble, thereby construction environment has been required not tight, adaptability is strong, and anti ageing property is good.
During use, can use after A material and B material be mixed in proportion, fast dried as not needing, can not add T
32Material.
According to different purposes, can adjust the consumption of each composition, make special role, effective liquefied ceramic series product independently, as flame retardant type, anti-corrosive type, best bright finish, high hardness type, high-flexibility wear-resistant type or the like.
After tested, the physics of liquefied ceramic, chemical property are as follows:
Time of drying: 25 ℃ of surface dryings of normal temperature 1～3 hour, did solid work 12～48 hours;
Hardness: 〉=0.7(pendulum-rocker hardness meter);
Gloss: % 〉=100(photoelectricity glossometer);
Sticking power: 1～2 grade (drawing the circle method);
Fineness :≤30 μ m;
Wear resistance wearing and tearing :≤0.0003 gram;
Resistance to acids and bases: 25% solution, 24 hours no changes;
Stain resistance: after 30% pollution, whiteness value falls 15%;
Temperature difference test: more than 5 times-30 ℃ do not ftracture ,+100 ℃ softening.
The present invention compared with prior art has following advantage:
Effective liquefied ceramic is nontoxic, unleaded; Existing good snappiness has suitable hardness again; Waterproof, fire-retardant; Wear-resisting, shock-resistant; Antiacid, caustic corrosion; Also has the smooth finish as the ceramic tile.With cement, metal, timber, plastics, gypsum, glass reinforced plastic, solid fiberboard, wax fabulous avidity is arranged all, coverage and conjugation are fabulous.Therefore, can replace paint, coating, ceramic tile, mosaic etc.During use, spontaneous curing need not be toasted.Environment for use temperature, high temperature coating in the time of 100 ℃ is not softening, and low temperature coating in the time of subzero 30 ℃ does not ftracture.
The invention will be further described below in conjunction with specific embodiment:
Embodiment 1
1. preparation A expects
(1) dissolving: the Resins, epoxy 601E-20 that in reactor, adds 5000 grams, the dimethylbenzene of the linear loop epoxy resins 621 of the Resins, epoxy 604E-12 of 6500 grams, 3250 grams and 6000 grams, the cyclohexanone solvent that adds 7500 grams again, warming while stirring to 110 ℃, constant temperature 3 hours is to all dissolvings.Be cooled to 40 ℃ then, from reactor, take out, put into container;
(2) filter: the liquid resin strainer filtering in the container;
(3) grind: the liquid resin after will filtering is introduced shredder, adds the urethane resin 7110J of 3000 grams simultaneously
4, 10000 the gram rutile Cornstarch R930,3250 the gram 2,4,6 tribromophenols, 2000 the gram process whites (technical grade), 1500 the gram aminoresin 590-3,2000 the gram talcum powder (325 order), after it is mixed, ground at normal temperatures 2.5 hours, and can meet the requirements of fineness;
(4) filter: with above-mentioned ground material with 190 purpose strainer filterings;
(5) painted: the material after the filtration adds in the jar rolling machine simultaneously and mixes with the middle network yellow dyess of 850 grams, at normal temperatures through 1 hour, can finish paintedly, just makes 48 kilograms A material.
2. preparation liquefied ceramic
Get 1 kilogram of A material, with 0.3 kilogram T
31B expects to mix, and stirs evenly, and promptly makes the yellow liquefied ceramic of network in 1.3 kilograms.
After measured, its result is as follows:
Fineness: 25 μ m hardness: 0.7 snappiness: 1mm
Gloss: 110 sticking power: 2 grades of shock strength: 50kg/cm
2
Surface drying: did solid work in 2 hours: 24 hours
Acid, alkali corrode no considerable change in 24 hours respectively.
Embodiment 2
1. preparation A expects
(1) dissolving: in reactor, add the Resins, epoxy 601E-20 of 7500 grams, the Resins, epoxy 604E-12 of 5000 grams, the linear loop epoxy resins 621 of 5500 grams and the dimethylbenzene of 5500 grams, the cyclohexanone solvent that adds 5500 grams again, warming while stirring to 120 ℃, constant temperature 2.5 hours is to all dissolvings.Be cooled to 35 ℃ then, from reactor, take out, put into container;
(2) filter: the liquid resin strainer filtering in the container;
(3) grind: the liquid resin after will filtering is introduced shredder, adds the urethane resin 7110J of 2000 grams simultaneously
4, 10000 the gram rutile Cornstarch R930,3000 the gram 2,4,6 tribromophenols, 3000 the gram process whites (technical grade), 1000 the gram aminoresin 590-3,2000 the gram talcum powder (325 order), after it is mixed, ground at normal temperatures 3 hours, and can meet the requirements of fineness;
(4) filter: with above-mentioned ground material with 200 purpose strainer filterings;
(5) painted: the material after the filtration adds in the jar rolling machine simultaneously and mixes with the ultramarine dyestuffs of 1500 grams, at normal temperatures through 1.5 hours, can finish paintedly, just makes 50 kilograms of ultramarine blue A material.
2. preparation liquefied ceramic
Get 1 kilogram of A material, with 0.6 kilogram T
31B expects to mix, and stirs evenly, and promptly makes 1.6 kilograms of ultramarine blue liquefied ceramics.
After measured, its result is as follows:
Fineness: 20 μ m hardness: 0.85 snappiness: 1mm
Gloss: 107 sticking power: 2 grades of shock strength: 50kg/cm
2
Surface drying: did solid work in 2 hours: 18 hours
Acid, alkali corrode no considerable change in 48 hours respectively.
Embodiment 3
1. preparation A expects
(1) dissolving: in reactor, add the Resins, epoxy 601E-20 of 10000 grams, the Resins, epoxy 604E-12 of 7500 grams, the linear loop epoxy resins 621 of 4000 grams and the dimethylbenzene of 4000 grams, the cyclohexanone solvent that adds 3500 grams again, warming while stirring to 125 ℃, constant temperature 2 hours is to all dissolvings.Be cooled to 45 ℃ then, from reactor, take out, put into container;
(2) filter: the liquid resin strainer filtering in the container;
(3) grind: the liquid resin after will filtering is introduced shredder, adds the urethane resin 7110J of 1000 grams simultaneously
4, 10000 the gram rutile Cornstarch R930,3500 the gram 2,4,6 tribromophenols, 1000 the gram process whites (technical grade), 2500 the gram aminoresin 590-3,3000 the gram talcum powder (325), after it is mixed, ground at normal temperatures 4 hours, and can meet the requirements of fineness;
(4) filter: with above-mentioned ground material with 240 purpose strainer filterings;
(5) painted: the material after the filtration adds in the jar rolling machine simultaneously and mixes with the pea green dyestuffs of 2500 grams, at normal temperatures through 2 hours, can finish paintedly, just makes 50 kilograms of pea green A material.
2. preparation liquefied ceramic
Get 1 kilogram of A material, with 0.3 kilogram T
32B expects to mix, and stirs evenly, and promptly makes 1.3 kilograms of pea green liquefied ceramics.
After measured, its result is as follows:
Fineness: 20 μ m hardness: 0.8 snappiness: 1mm
Gloss: 120 sticking power: 2 grades of shock strength: 50kg/cm
2
Surface drying: did solid work in 1 hour: 12 hours
Acid, alkali corrode no considerable change in 30 hours respectively.
Claims (2)
1, a kind of effective liquefied ceramic is characterized in that: it is to be mixed by A material and solidifying agent B material, and its prescription is as follows: (weight %)
A material: Resins, epoxy 601E-20 10～25%
Resins, epoxy 604E-12 10～30%
Linear loop epoxy resins 621 4.5～13%
Urethane resin 7110J
42～6%
2,4,6 tribromophenols 4.5～12%
Process white (technical grade) 2～6%
Rutile Cornstarch R 930 20～46%
Dimethylbenzene 8～36%
Cyclohexanone 7～25%
Aminoresin 590--3 2～6%
Talcum powder 325 orders 2～8%
B material: T
31It is 30～60% of A material.
T
32It is 0～30% of A material.
2, as the preparation method of the said liquefied ceramic of claim 1, it is characterized in that: the step of preparation process of A material is as follows successively:
(1) dissolving: in reactor, add Resins, epoxy and dimethylbenzene, add cyclohexanone solvent again, warming while stirring to 110 ℃～125 ℃, constant temperature 2～3 hours is to all dissolvings.Be cooled to 35 ℃～50 ℃ then, can from reactor, take out, put into container;
(2) filter: the liquid resin in the container is filtered;
(3) grind: the liquid resin after will filtering is introduced shredder, add urethane resin, rutile Cornstarch and 2,4,6 tribromophenols, process white, aminoresin, talcum powder simultaneously, after the mixing, ground at normal temperatures 2～4 hours, can meet the requirements of fineness;
(4) filter: with above-mentioned ground material with 180 orders～240 purpose strainer filterings;
(5) painted: the material after the filtration adds in the jar rolling machine simultaneously with pigment and mixes, and at normal temperatures through 1～2 hour, can finish paintedly, just makes finished product A material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93114919 CN1103420A (en) | 1993-12-02 | 1993-12-02 | Effective liquefied ceramic and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93114919 CN1103420A (en) | 1993-12-02 | 1993-12-02 | Effective liquefied ceramic and its preparing method |
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| Publication Number | Publication Date |
|---|---|
| CN1103420A true CN1103420A (en) | 1995-06-07 |
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ID=4990698
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93114919 Pending CN1103420A (en) | 1993-12-02 | 1993-12-02 | Effective liquefied ceramic and its preparing method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103773089A (en) * | 2014-01-15 | 2014-05-07 | 芜湖市宝艺游乐科技设备有限公司 | Environmental-friendly glass fiber reinforced plastic coating material and preparation method thereof |
| CN104710896A (en) * | 2015-02-15 | 2015-06-17 | 淄博世纪联合新型建筑材料有限公司 | Liquid ceramic tile preparation and site construction process |
| CN104945845A (en) * | 2015-05-10 | 2015-09-30 | 江苏兴盛化工有限公司 | Double-component brominated epoxy resin artificial stone board, and granules and preparation method thereof |
| CN110948976A (en) * | 2019-12-11 | 2020-04-03 | 光之科技(北京)有限公司 | Heating integrated plate and preparation method thereof |
-
1993
- 1993-12-02 CN CN 93114919 patent/CN1103420A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103773089A (en) * | 2014-01-15 | 2014-05-07 | 芜湖市宝艺游乐科技设备有限公司 | Environmental-friendly glass fiber reinforced plastic coating material and preparation method thereof |
| CN104710896A (en) * | 2015-02-15 | 2015-06-17 | 淄博世纪联合新型建筑材料有限公司 | Liquid ceramic tile preparation and site construction process |
| CN104945845A (en) * | 2015-05-10 | 2015-09-30 | 江苏兴盛化工有限公司 | Double-component brominated epoxy resin artificial stone board, and granules and preparation method thereof |
| CN104945845B (en) * | 2015-05-10 | 2018-01-09 | 江苏兴盛化工有限公司 | Two-component brominated epoxy resin artificial slabstone and its particle and preparation method |
| CN110948976A (en) * | 2019-12-11 | 2020-04-03 | 光之科技(北京)有限公司 | Heating integrated plate and preparation method thereof |
| CN110948976B (en) * | 2019-12-11 | 2023-05-16 | 光之科技(北京)有限公司 | Heating integrated plate and preparation method thereof |
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| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |