CN110340341A - One kind being used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper - Google Patents

One kind being used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper Download PDF

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Publication number
CN110340341A
CN110340341A CN201910601884.9A CN201910601884A CN110340341A CN 110340341 A CN110340341 A CN 110340341A CN 201910601884 A CN201910601884 A CN 201910601884A CN 110340341 A CN110340341 A CN 110340341A
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CN
China
Prior art keywords
wooden dipper
slag
resistant
fire
niobium alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910601884.9A
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Chinese (zh)
Inventor
毕建荣
尹剑
高四峰
郑树康
陆继伟
车立志
可金川
赵钢
周飞
李佳
苏李城
田家东
夏天强
张正东
李素玲
王劲涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Heqing Yixin Aluminum Co Ltd
Original Assignee
Heqing Yixin Aluminum Co Ltd
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Filing date
Publication date
Application filed by Heqing Yixin Aluminum Co Ltd filed Critical Heqing Yixin Aluminum Co Ltd
Priority to CN201910601884.9A priority Critical patent/CN110340341A/en
Publication of CN110340341A publication Critical patent/CN110340341A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D43/00Mechanical cleaning, e.g. skimming of molten metals
    • B22D43/005Removing slag from a molten metal surface
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

One kind being used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper, and the slag wooden dipper is spoon shape structure, including (2) are offered leak hole (3) in wooden dipper body bottom by wooden dipper body (1) and wooden dipper;Being made of fire-resistant oxidation resistant niobium alloy, the fire-resistant oxidation resistant niobium alloy is Nb-1Zr for the wooden dipper body and wooden dipper;Surface is sprayed MoSi in wooden dipper body and wooden dipper2Fire-resistant oxidation resistant coating material.The present invention is not easy to melt, long service life, can be recycled for multiple times, and reduces tool consumption and production and maintenance cost, and can avoid the iron after fusing and be mixed into reduction aluminium product quality in molten aluminum, and it is high-efficient to remove the gred.

Description

One kind being used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper
Technical field
The invention belongs to non-ferrous metal metallurgy specific purpose tool technical fields, and in particular to one kind is used for electrolytic cell, intermediate frequency furnace Smelt the fire-resistant oxidation resistant slag wooden dipper of slag hitting.
Background technique
Slag wooden dipper is the important slagging-off tool of slag hitting operation in nonferrous metallurgical process, at present the electrolytic cell of aluminium industry, It is widely used in intermediate frequency furnace production work.The slag wooden dipper that the prior art uses is the plane slag shovel board made of Q235 material, Q235 material is carbon containing moderate, and comprehensive comparison is good, and intensity, plasticity and welding performance are preferably cooperated, and fusing point is 1495 DEG C or more.At 950 DEG C -970 DEG C, the two poles of the earth are chemically reacted in electrolytic cell, that is, are electrolysed, and Q235 material slag wooden dipper can generate at this time Quickly oxidation and part are melted, and slag wooden dipper consumption is huge, and tool use cost increases.Meanwhile the iron after thawing is mixed into molten aluminum, Cause molten aluminum iron content to increase (key index that iron content is aluminium grade), directly reduces the quality of aluminium product.Intermediate frequency For furnace smelting molten iron temperature at 1450 DEG C or more, slag wooden dipper scaling loss is larger, and melting one furnace molten steel consumption, 2 pieces of slag shovel boards lead to Work tool Consuming cost is high, and operator needs to constantly change slag wooden dipper, and the production of slag wooden dipper and maintenance cost are higher.In addition, flat Face shovel slag plate slagging-off effect is bad, and slagging-off efficiency is lower.
Summary of the invention
Present invention aims to solve the deficiencies of the prior art, and provides a kind of one kind to be not easy to melt, long service life, can repeatedly follow Ring uses, and reduces tool consumption and production and maintenance cost, and can avoid the iron after fusing and be mixed into reduction aluminium product matter in molten aluminum It measures and what slagging-off was high-efficient is used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper.
The purpose of the present invention is achieved through the following technical solutions:
One kind being used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper, and the slag wooden dipper is spoon shape structure, Including wooden dipper body and wooden dipper handle, leak hole is offered in wooden dipper body bottom;The wooden dipper body and wooden dipper handle are made of fire-resistant oxidation resistant niobium alloy, The fire-resistant oxidation resistant niobium alloy is Nb-1Zr;Surface is sprayed fire-resistant oxidation resistant coating material in wooden dipper body and wooden dipper, it is described Fire-resistant oxidation resistant coating material is MoSi2
The present invention is machined with outer end in wooden dipper can the external mounting hole for lengthening wooden dipper handle.Multiple leakages are offered in wooden dipper body bottom Hole, including the multiple leak holes for being located at the center leak hole of wooden dipper bottom center minimum point and being uniformly arranged around center leak hole.
The fusing point of fire-resistant oxidation resistant niobium alloy of the present invention is 2467 DEG C, in 1093 DEG C of -1427 DEG C of temperature ranges It is able to maintain higher-strength, plasticity is good, and processing performance is excellent.But since niobium alloy is in 600 DEG C or so meeting accelerated oxidations, this hair It is bright to spray MoSi on slag wooden dipper surface2Fire-resistant oxidation resistant coating material can make oxidizing temperature be promoted to 1450 DEG C -1600 DEG C, keep away Exempt from effectively to be solved prior art slag wooden dipper by severe oxidation and fusing and easily melted the deficiency of loss, and avoid prior art fusing Iron afterwards is mixed into molten aluminum the problem of reducing aluminium product quality.
Slag wooden dipper of the present invention is using spoon shape structure rather than the grafter structure of the prior art, wooden dipper body can more scoop up slag, Molten metal can be leaked down by improving slagging-off ability and efficiency, the leak hole of wooden dipper body bottom, prevented from taking molten metal out of when slagging-off and caused wave Take.The wooden dipper outer end be machined with can external lengthening handle mounting hole, be conveniently replaceable, avoid existing shovel slag plate and shovel and use The production of welding structure bring is troublesome and wastes big drawback.
Detailed description of the invention
Fig. 1 is the structural schematic diagram that slag wooden dipper of the present invention is overlooked;
Fig. 2 is the Section A-A figure of Fig. 1.
Specific embodiment
Below in conjunction with attached drawing, the present invention is further described.
As shown in Figure 1 and Figure 2, a kind of to be used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper, the slag Wooden dipper is spoon shape structure, including wooden dipper body 1 and wooden dipper offer leak hole 3 in wooden dipper body bottom 2, and outer end is machined with and external can be added in wooden dipper The mounting hole 4 of long wooden dipper handle is replaced in order to slag wooden dipper and is used, saves welding sequence.The present embodiment wooden dipper is 200mm design length, Contact molten metal liquid level in operating process is avoided to be burnt fusing, outer end is offered 3 11 mounting holes of Φ by wooden dipper, is connected for bolt It connects and lengthens wooden dipper handle.Multiple leak holes 3 are offered in wooden dipper body bottom, including being located at the center leak hole of wooden dipper bottom center minimum point and in Multiple leak holes that heart leak hole is uniformly arranged, the present embodiment has opened up 7 14 leak holes of Φ, convenient for the filtering of carbon metal in the dreg liquid, wooden dipper Negative camber inclination angle is conducive to slag and faster separates with molten iron, reduces cost of material.The present invention makes wooden dipper body 1 and wooden dipper, and 2 plate is thick Degree only needs 6mm, and the shovel slag plate that plate thickness compared with prior art is 8mm reduces tool weight, saves material, can subtract Light labor intensity of workers, raises labour productivity.
Being made of fire-resistant oxidation resistant niobium alloy, the fire-resistant oxidation resistant niobium alloy is for wooden dipper body of the invention and wooden dipper Nb-1Zr.Surface is sprayed fire-resistant oxidation resistant coating material in wooden dipper body and wooden dipper, the fire-resistant oxidation resistant coating material is MoSi2.Nb-1Zr and MoSi2It is prior art material.

Claims (3)

1. one kind is used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper, which is characterized in that the slag wooden dipper is (2) are offered leak hole (3) in wooden dipper body bottom by spoon shape structure, including wooden dipper body (1) and wooden dipper;The wooden dipper body and wooden dipper are using resistance to height The anti-oxidant niobium alloy production of temperature, the fire-resistant oxidation resistant niobium alloy is Nb-1Zr;Surface is sprayed high temperature resistant in wooden dipper body and wooden dipper Antioxidant coating material, the fire-resistant oxidation resistant coating material are MoSi2
2. one kind according to claim 1 is used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper, It is characterized in that, outer end is machined in wooden dipper can the external mounting hole (4) for lengthening wooden dipper handle.
3. one kind according to claim 1 or 2 is used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper, It is characterized in that, multiple leak holes (3) are offered in wooden dipper body bottom, including being located at the center leak hole of wooden dipper bottom center minimum point and surrounding Multiple leak holes that center leak hole is uniformly arranged.
CN201910601884.9A 2019-07-05 2019-07-05 One kind being used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper Pending CN110340341A (en)

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CN201910601884.9A CN110340341A (en) 2019-07-05 2019-07-05 One kind being used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper

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CN201910601884.9A CN110340341A (en) 2019-07-05 2019-07-05 One kind being used for non-ferrous metal metallurgy slag hitting fire-resistant oxidation resistant niobium alloy slag wooden dipper

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112570701A (en) * 2020-12-30 2021-03-30 湖北楠田工模具科技有限公司 Quick ladle slag device of ladle molten steel

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2699933A (en) * 1952-10-28 1955-01-18 Northrop Aircraft Inc Dross remover
JPH063068A (en) * 1992-06-17 1994-01-11 Orii:Kk Melted slag removal apparatus
EP1745873A1 (en) * 2005-07-22 2007-01-24 Sanki Dengyo Co., Ltd. Method and device for removing slag
CN103406531A (en) * 2013-08-29 2013-11-27 南通华东油压科技有限公司 Slag scoop manufacturing process
CN203917907U (en) * 2014-02-27 2014-11-05 西南铝业(集团)有限责任公司 A kind of scarfing cinder spoon
CN204234724U (en) * 2014-10-25 2015-04-01 重庆孟池机械制造有限公司 Molten iron oxide on surface scavenge unit
CN205008571U (en) * 2015-10-15 2016-02-03 闵金忠 Drag for sediment wooden dipper
CN205165859U (en) * 2015-10-13 2016-04-20 武汉钢铁(集团)公司 Prevent novel molten iron of slag backward flow and take off slag plate

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2699933A (en) * 1952-10-28 1955-01-18 Northrop Aircraft Inc Dross remover
JPH063068A (en) * 1992-06-17 1994-01-11 Orii:Kk Melted slag removal apparatus
EP1745873A1 (en) * 2005-07-22 2007-01-24 Sanki Dengyo Co., Ltd. Method and device for removing slag
CN103406531A (en) * 2013-08-29 2013-11-27 南通华东油压科技有限公司 Slag scoop manufacturing process
CN203917907U (en) * 2014-02-27 2014-11-05 西南铝业(集团)有限责任公司 A kind of scarfing cinder spoon
CN204234724U (en) * 2014-10-25 2015-04-01 重庆孟池机械制造有限公司 Molten iron oxide on surface scavenge unit
CN205165859U (en) * 2015-10-13 2016-04-20 武汉钢铁(集团)公司 Prevent novel molten iron of slag backward flow and take off slag plate
CN205008571U (en) * 2015-10-15 2016-02-03 闵金忠 Drag for sediment wooden dipper

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
(俄)А.В.叶留金(А.В.ЕЛЮТИН)等: "《铌与钽》", 31 October 1997, 中南大学出版社 *
周瑞发等: "《高温结构材料》", 30 April 2006, 国防工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112570701A (en) * 2020-12-30 2021-03-30 湖北楠田工模具科技有限公司 Quick ladle slag device of ladle molten steel

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Application publication date: 20191018