CN110331464A - A kind of dissolvant type nanofiber with very high performance - Google Patents

A kind of dissolvant type nanofiber with very high performance Download PDF

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Publication number
CN110331464A
CN110331464A CN201910571155.3A CN201910571155A CN110331464A CN 110331464 A CN110331464 A CN 110331464A CN 201910571155 A CN201910571155 A CN 201910571155A CN 110331464 A CN110331464 A CN 110331464A
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parts
high performance
type nanofiber
dissolvant type
nanofiber
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CN201910571155.3A
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Inventor
崔建中
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Shanghai Jianhu Hongda Technology Co Ltd
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Shanghai Jianhu Hongda Technology Co Ltd
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Priority to CN201910571155.3A priority Critical patent/CN110331464A/en
Publication of CN110331464A publication Critical patent/CN110331464A/en
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00Treatment of filament-forming or like material
    • D01D1/02Preparation of spinning solutions
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/10Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/16Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent

Abstract

The invention discloses a kind of dissolvant type nanofiber with very high performance, formula includes: Kynoar, solute, polyethersulfone resin, polyurethane, biological agent, antioxidant, diluent, solvent, antibacterial additives, catalyst;Manufacture craft is the following steps are included: step 1, raw material are chosen;Step 2, raw material mixing;Step 3 makes stoste;Step 4, lance ejection;Step 5, fiber process;Step 6, dry filter;Step 7 examines storage;The invention, securely and reliably, manufacture craft is simple, dissolvant type nanofiber performance is greatly promoted, simultaneously added with antibacterial additives, promotes the dissolvant type nanofiber antibacterial ability, be conducive to number of users use, and biological agent is added, inhibits harm when fiber carrier degradation, make fiber carrier complete biodegradable, it has no toxic side effect, is conducive to user's health, the invented technology is simply rigorous, raw material is cheaply low in cost, is conducive to produce.

Description

A kind of dissolvant type nanofiber with very high performance
Technical field
The present invention relates to nanofiber technology field, specially a kind of dissolvant type nanofiber with very high performance.
Background technique
Nanofiber refers to that diameter is nanoscale and the biggish filamentary material with certain draw ratio of length, in addition, Nano particle is filled into general fibre, nanofiber is also referred to as to the fiber that it is modified, said in the narrow sense, nanofiber Diameter between 1nm to 100nm, but in a broad sense, fiber of the fibre diameter lower than 1000nm is referred to as nanofiber, Nanofiber is generally dissolvant type or non-solvent formula;Conventional solvent formula nanofiber complex manufacturing technology, performance is low, is not able to satisfy User uses, while fiber carrier degradation of the conventional solvent formula nanofiber in production can generate toxic side effect, be unfavorable for making User's health, for these defects, it is necessary for designing a kind of dissolvant type nanofiber with very high performance.
Summary of the invention
The purpose of the present invention is to provide a kind of dissolvant type nanofiber with very high performance, to solve above-mentioned background skill The problem of being proposed in art.
In order to solve the above technical problem, the present invention provides following technical solutions: a kind of dissolvant type with very high performance Nanofiber, formula include: Kynoar, solute, polyethersulfone resin, polyurethane, biological agent, antioxidant, diluent, The mass percentage of solvent, antibacterial additives, catalyst, each component is respectively: 15-25 parts of Kynoar, 20-30 parts Solute, 15-25 parts of polyethersulfone resin, 10-20 parts of polyurethane, 2-4 parts of biological agent, 10-20 parts anti-oxidant Agent, 1-3 parts of diluent, 5-10 parts of solvent, 1-2 parts of antibacterial additives and 2-4 parts of catalyst.
According to the above technical scheme, the antibacterial additives are waterborne antibacterial additive.
According to the above technical scheme, the catalyst is aluminium oxide or other oxidation catalysts.
According to the above technical scheme, the solute is polyamide, diphenyl methane -4, chitosan, polytetrahydrofuran ether two It is mixed in alcohol and polyvinyl alcohol according to 5: 3: 2: 1: 3 ratio.
According to the above technical scheme, the solvent is dimethylformamide, dimethyl acetamide, ionized water, acetic acid and second One of acid is a variety of.
According to the above technical scheme, one of the diluent acetone, dimethylbenzene and styrene or a variety of.
According to the above technical scheme, the biological agent is adriamycin, polyvinyl alcohol, biological enzyme and polylactic acid according to 3: 3: 2: 1 ratio mixes.
According to the above technical scheme, the antioxidant tea polyphenols, butylated hydroxy anisole, dibutyl hydroxy toluene and uncle One of butylhydroquinone is a variety of.
According to the above technical scheme, the polyethersulfone resin is liquid shape polyethersulfone resin.
According to the above technical scheme, the manufacture craft of the dissolvant type nanofiber with very high performance includes following step Rapid: step 1, raw material are chosen;Step 2, raw material mixing;Step 3 makes stoste;Step 4, lance ejection;Step 5, it is fine Dimension processing;Step 6, dry filter;Step 7 examines storage;
Wherein in the above step 1, it carries out weighing required raw material according to the parts by weight of each component;
Wherein in above-mentioned steps two, reaction kettle is cleaned up, pours into solute and solvent, is slowly stirred 1-2, temperature is protected It holds at 60-70 DEG C, adds antibacterial additives, catalyst, react 1-2h;
Wherein in above-mentioned steps three, reaction kettle in step 2 is blended into Kynoar, is converted after persistently stirring 20min Enter polyethersulfone resin, polyurethane, heat 1-2h, adds biological agent, antioxidant and diluent, confined reaction 2- again 4h obtains macromolecule stoste;
Wherein in above-mentioned steps four, manually macromolecule stoste is poured into spray gun, opens spray gun, using spray gun by high score Sub- stoste is sprayed from nozzle enters wire drawing chamber, reheats wire drawing chamber, so that wire drawing chamber is reached a high temperature high pressure, by macromolecule stoste wire drawing At nanofiber;
Wherein in above-mentioned steps five, using getter device by nanofiber, then rice fiber made by the artificial wind It scatters, forms nanometer fiber net;
Wherein in above-mentioned steps six, nanometer fiber net is placed in dryer and is dried, then is filtered, Dissolvant type nanofiber can be obtained;
Wherein in above-mentioned steps seven, dissolvant type nanofiber is subjected to the examination and test of products, is stored in sets material after the assay was approved In bucket, storage is in the cool.
Compared with prior art, the beneficial effects obtained by the present invention are as follows being: the invention, securely and reliably, manufacture craft is simple, It reacts to each other to obtain macromolecule stoste using Kynoar, solute and solvent, recycles spray gun processing, being formed has dissolvant type Nanofiber greatly promotes dissolvant type nanofiber performance, simultaneously added with antibacterial additives, promotes the dissolvant type nanofiber Antibacterial ability is conducive to number of users use, and biological agent is added, and inhibits harm when fiber carrier degradation, makes fiber carrier Complete own biological degradation is conducive to user's health, the invented technology is simply rigorous, can replace it without toxic side effect His dissolvant type nanofiber costly, performance is high, and raw material is cheaply low in cost, easy to process, and production is greatly saved Cost is conducive to processing and production.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
The present invention provides a kind of technical solution:
Embodiment 1:
A kind of dissolvant type nanofiber with very high performance, formula include: Kynoar, solute, polyethersulfone resin, Polyurethane, biological agent, antioxidant, diluent, solvent, antibacterial additives, catalyst, the mass percentage point of each component Be not: 20 parts of Kynoar, 20 parts of solute, 25 parts of polyethersulfone resin, 10 parts of polyurethane, 3 parts of biological agent, 15 parts of antioxidant, 2 parts of diluent, 6 parts of solvent, 2 parts of antibacterial additives and 4 parts of catalyst.
Wherein, antibacterial additives are waterborne antibacterial additive;Catalyst is aluminium oxide or other oxidation catalysts;Solute is It is mixed according to 5: 3: 2: 1: 3 ratio in polyamide, diphenyl methane -4, chitosan, polytetrahydrofuran ether glycol and polyvinyl alcohol It closes;Solvent is one of dimethylformamide, dimethyl acetamide, ionized water, acetic acid and acetic acid or a variety of;Diluent One of acetone, dimethylbenzene and styrene are a variety of;Biological agent is that adriamycin, polyvinyl alcohol, biological enzyme and polylactic acid are pressed It is mixed according to 3: 3: 2: 1 ratio;Antioxidant tea polyphenols, butylated hydroxy anisole, dibutyl hydroxy toluene and tert-butyl One of hydroquinone is a variety of;Polyethersulfone resin is liquid shape polyethersulfone resin.
The manufacture craft of the dissolvant type nanofiber of the very high performance is the following steps are included: step 1, raw material are chosen;Step Two, raw material mixing;Step 3 makes stoste;Step 4, lance ejection;Step 5, fiber process;Step 6, dry filter; Step 7 examines storage;
Wherein in the above step 1, it carries out weighing required raw material according to the parts by weight of each component;
Wherein in above-mentioned steps two, reaction kettle is cleaned up, pours into solute and solvent, is slowly stirred 1-2, temperature is protected It holds at 60-70 DEG C, adds antibacterial additives, catalyst, react 1-2h;
Wherein in above-mentioned steps three, reaction kettle in step 2 is blended into Kynoar, is converted after persistently stirring 20min Enter polyethersulfone resin, polyurethane, heat 1-2h, adds biological agent, antioxidant and diluent, confined reaction 2- again 4h obtains macromolecule stoste;
Wherein in above-mentioned steps four, manually macromolecule stoste is poured into spray gun, opens spray gun, using spray gun by high score Sub- stoste is sprayed from nozzle enters wire drawing chamber, reheats wire drawing chamber, so that wire drawing chamber is reached a high temperature high pressure, by macromolecule stoste wire drawing At nanofiber;
Wherein in above-mentioned steps five, using getter device by nanofiber, then rice fiber made by the artificial wind It scatters, forms nanometer fiber net;
Wherein in above-mentioned steps six, nanometer fiber net is placed in dryer and is dried, then is filtered, Dissolvant type nanofiber can be obtained;
Wherein in above-mentioned steps seven, dissolvant type nanofiber is subjected to the examination and test of products, is stored in sets material after the assay was approved In bucket, storage is in the cool.
Embodiment 2:
A kind of dissolvant type nanofiber with very high performance, formula include: Kynoar, solute, polyethersulfone resin, Polyurethane, biological agent, antioxidant, diluent, solvent, antibacterial additives, catalyst, the mass percentage point of each component Be not: 20 parts of Kynoar, 25 parts of solute, 20 parts of polyethersulfone resin, 10 parts of polyurethane, 3 parts of biological agent, 15 parts of antioxidant, 2 parts of diluent, 6 parts of solvent, 2 parts of antibacterial additives and 4 parts of catalyst.
Wherein, antibacterial additives are waterborne antibacterial additive;Catalyst is aluminium oxide or other oxidation catalysts;Solute is It is mixed according to 5: 3: 2: 1: 3 ratio in polyamide, diphenyl methane -4, chitosan, polytetrahydrofuran ether glycol and polyvinyl alcohol It closes;Solvent is one of dimethylformamide, dimethyl acetamide, ionized water, acetic acid and acetic acid or a variety of;Diluent One of acetone, dimethylbenzene and styrene are a variety of;Biological agent is that adriamycin, polyvinyl alcohol, biological enzyme and polylactic acid are pressed It is mixed according to 3: 3: 2: 1 ratio;Antioxidant tea polyphenols, butylated hydroxy anisole, dibutyl hydroxy toluene and tert-butyl One of hydroquinone is a variety of;Polyethersulfone resin is liquid shape polyethersulfone resin.
The manufacture craft of the dissolvant type nanofiber of the very high performance is the following steps are included: step 1, raw material are chosen;Step Two, raw material mixing;Step 3 makes stoste;Step 4, lance ejection;Step 5, fiber process;Step 6, dry filter; Step 7 examines storage;
Wherein in the above step 1, it carries out weighing required raw material according to the parts by weight of each component;
Wherein in above-mentioned steps two, reaction kettle is cleaned up, pours into solute and solvent, is slowly stirred 1-2, temperature is protected It holds at 60-70 DEG C, adds antibacterial additives, catalyst, react 1-2h;
Wherein in above-mentioned steps three, reaction kettle in step 2 is blended into Kynoar, is converted after persistently stirring 20min Enter polyethersulfone resin, polyurethane, heat 1-2h, adds biological agent, antioxidant and diluent, confined reaction 2- again 4h obtains macromolecule stoste;
Wherein in above-mentioned steps four, manually macromolecule stoste is poured into spray gun, opens spray gun, using spray gun by high score Sub- stoste is sprayed from nozzle enters wire drawing chamber, reheats wire drawing chamber, so that wire drawing chamber is reached a high temperature high pressure, by macromolecule stoste wire drawing At nanofiber;
Wherein in above-mentioned steps five, using getter device by nanofiber, then rice fiber made by the artificial wind It scatters, forms nanometer fiber net;
Wherein in above-mentioned steps six, nanometer fiber net is placed in dryer and is dried, then is filtered, Dissolvant type nanofiber can be obtained;
Wherein in above-mentioned steps seven, dissolvant type nanofiber is subjected to the examination and test of products, is stored in sets material after the assay was approved In bucket, storage is in the cool.
Embodiment 3:
A kind of dissolvant type nanofiber with very high performance, formula include: Kynoar, solute, polyethersulfone resin, Polyurethane, biological agent, antioxidant, diluent, solvent, antibacterial additives, catalyst, the mass percentage point of each component Be not: 20 parts of Kynoar, 30 parts of solute, 15 parts of polyethersulfone resin, 10 parts of polyurethane, 3 parts of biological agent, 15 parts of antioxidant, 2 parts of diluent, 6 parts of solvent, 2 parts of antibacterial additives and 4 parts of catalyst.
Wherein, antibacterial additives are waterborne antibacterial additive;Catalyst is aluminium oxide or other oxidation catalysts;Solute is It is mixed according to 5: 3: 2: 1: 3 ratio in polyamide, diphenyl methane -4, chitosan, polytetrahydrofuran ether glycol and polyvinyl alcohol It closes;Solvent is one of dimethylformamide, dimethyl acetamide, ionized water, acetic acid and acetic acid or a variety of;Diluent One of acetone, dimethylbenzene and styrene are a variety of;Biological agent is that adriamycin, polyvinyl alcohol, biological enzyme and polylactic acid are pressed It is mixed according to 3: 3: 2: 1 ratio;Antioxidant tea polyphenols, butylated hydroxy anisole, dibutyl hydroxy toluene and tert-butyl One of hydroquinone is a variety of;Polyethersulfone resin is liquid shape polyethersulfone resin.
The manufacture craft of the dissolvant type nanofiber of the very high performance is the following steps are included: step 1, raw material are chosen;Step Two, raw material mixing;Step 3 makes stoste;Step 4, lance ejection;Step 5, fiber process;Step 6, dry filter; Step 7 examines storage;
Wherein in the above step 1, it carries out weighing required raw material according to the parts by weight of each component;
Wherein in above-mentioned steps two, reaction kettle is cleaned up, pours into solute and solvent, is slowly stirred 1-2, temperature is protected It holds at 60-70 DEG C, adds antibacterial additives, catalyst, react 1-2h;
Wherein in above-mentioned steps three, reaction kettle in step 2 is blended into Kynoar, is converted after persistently stirring 20min Enter polyethersulfone resin, polyurethane, heat 1-2h, adds biological agent, antioxidant and diluent, confined reaction 2- again 4h obtains macromolecule stoste;
Wherein in above-mentioned steps four, manually macromolecule stoste is poured into spray gun, opens spray gun, using spray gun by high score Sub- stoste is sprayed from nozzle enters wire drawing chamber, reheats wire drawing chamber, so that wire drawing chamber is reached a high temperature high pressure, by macromolecule stoste wire drawing At nanofiber;
Wherein in above-mentioned steps five, using getter device by nanofiber, then rice fiber made by the artificial wind It scatters, forms nanometer fiber net;
Wherein in above-mentioned steps six, nanometer fiber net is placed in dryer and is dried, then is filtered, Dissolvant type nanofiber can be obtained;
Wherein in above-mentioned steps seven, dissolvant type nanofiber is subjected to the examination and test of products, is stored in sets material after the assay was approved In bucket, storage is in the cool.
Embodiment 4:
A kind of dissolvant type nanofiber with very high performance, formula include: Kynoar, solute, polyethersulfone resin, Polyurethane, biological agent, antioxidant, diluent, solvent, antibacterial additives, catalyst, the mass percentage point of each component Be not: 20 parts of Kynoar, 20 parts of solute, 15 parts of polyethersulfone resin, 10 parts of polyurethane, 3 parts of biological agent, 15 parts of antioxidant, 2 parts of diluent, 6 parts of solvent, 2 parts of antibacterial additives and 4 parts of catalyst.
Wherein, antibacterial additives are waterborne antibacterial additive;Catalyst is aluminium oxide or other oxidation catalysts;Solute is It is mixed according to 5: 3: 2: 1: 3 ratio in polyamide, diphenyl methane -4, chitosan, polytetrahydrofuran ether glycol and polyvinyl alcohol It closes;Solvent is one of dimethylformamide, dimethyl acetamide, ionized water, acetic acid and acetic acid or a variety of;Diluent One of acetone, dimethylbenzene and styrene are a variety of;Biological agent is that adriamycin, polyvinyl alcohol, biological enzyme and polylactic acid are pressed It is mixed according to 3: 3: 2: 1 ratio;Antioxidant tea polyphenols, butylated hydroxy anisole, dibutyl hydroxy toluene and tert-butyl One of hydroquinone is a variety of;Polyethersulfone resin is liquid shape polyethersulfone resin.
The manufacture craft of the dissolvant type nanofiber of the very high performance is the following steps are included: step 1, raw material are chosen;Step Two, raw material mixing;Step 3 makes stoste;Step 4, lance ejection;Step 5, fiber process;Step 6, dry filter; Step 7 examines storage;
Wherein in the above step 1, it carries out weighing required raw material according to the parts by weight of each component;
Wherein in above-mentioned steps two, reaction kettle is cleaned up, pours into solute and solvent, is slowly stirred 1-2, temperature is protected It holds at 60-70 DEG C, adds antibacterial additives, catalyst, react 1-2h;
Wherein in above-mentioned steps three, reaction kettle in step 2 is blended into Kynoar, is converted after persistently stirring 20min Enter polyethersulfone resin, polyurethane, heat 1-2h, adds biological agent, antioxidant and diluent, confined reaction 2- again 4h obtains macromolecule stoste;
Wherein in above-mentioned steps four, manually macromolecule stoste is poured into spray gun, opens spray gun, using spray gun by high score Sub- stoste is sprayed from nozzle enters wire drawing chamber, reheats wire drawing chamber, so that wire drawing chamber is reached a high temperature high pressure, by macromolecule stoste wire drawing At nanofiber;
Wherein in above-mentioned steps five, using getter device by nanofiber, then rice fiber made by the artificial wind It scatters, forms nanometer fiber net;
Wherein in above-mentioned steps six, nanometer fiber net is placed in dryer and is dried, then is filtered, Dissolvant type nanofiber can be obtained;
Wherein in above-mentioned steps seven, dissolvant type nanofiber is subjected to the examination and test of products, is stored in sets material after the assay was approved In bucket, storage is in the cool.
Each embodiment property comparison is as follows:
Based on above-mentioned, it is an advantage of the current invention that the invention, securely and reliably, manufacture craft is simple, using polyvinylidene fluoride Alkene, solute and solvent react to each other to obtain macromolecule stoste, recycle spray gun processing, and being formed has dissolvant type nanofiber, greatly The big dissolvant type nanofiber performance that promoted promotes the dissolvant type nanofiber antibacterial ability, has simultaneously added with antibacterial additives Conducive to number of users use, and biological agent is added, inhibits harm when fiber carrier degradation, make the complete own biological of fiber carrier Degradation, without toxic side effect.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features. All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (9)

1. a kind of dissolvant type nanofiber with very high performance, formula includes: Kynoar, solute, polyethersulfone resin, gathers Urethane, biological agent, antioxidant, diluent, solvent, antibacterial additives, catalyst, it is characterised in that: the quality of each component Percentage composition is respectively: 15-25 parts of Kynoar, 20-30 parts of solute, 15-25 parts of polyethersulfone resin, 10-20 parts Polyurethane, 2-4 parts of biological agent, 10-20 parts of antioxidant, 1-3 parts of diluent, 5-10 parts of solvent, 1-2 parts Antibacterial additives and 2-4 parts of catalyst.
2. a kind of dissolvant type nanofiber with very high performance according to claim 1, it is characterised in that: the antibacterial Additive is waterborne antibacterial additive.
3. a kind of dissolvant type nanofiber with very high performance according to claim 1, it is characterised in that: the catalysis Agent is aluminium oxide or other oxidation catalysts.
4. a kind of dissolvant type nanofiber with very high performance according to claim 1, it is characterised in that: the solute For the ratio in polyamide, diphenyl methane -4, chitosan, polytetrahydrofuran ether glycol and polyvinyl alcohol according to 5: 3: 2: 1: 3 It mixes.
5. a kind of dissolvant type nanofiber with very high performance according to claim 1, it is characterised in that: the solvent For one of dimethylformamide, dimethyl acetamide, ionized water, acetic acid and acetic acid or a variety of.
6. a kind of dissolvant type nanofiber with very high performance according to claim 1, it is characterised in that: the dilution One of agent acetone, dimethylbenzene and styrene are a variety of.
7. a kind of dissolvant type nanofiber with very high performance according to claim 1, it is characterised in that: the biology Preparation is that adriamycin, polyvinyl alcohol, biological enzyme and polylactic acid are mixed according to 3: 3: 2: 1 ratio.
8. a kind of dissolvant type nanofiber with very high performance according to claim 1, it is characterised in that: the antioxygen One of agent tea polyphenols, butylated hydroxy anisole, dibutyl hydroxy toluene and tert-butyl hydroquinone are a variety of.
9. a kind of dissolvant type nanofiber with very high performance according to claim 1, it is characterised in that: the polyethers Sulphone resin is liquid shape polyethersulfone resin.
CN201910571155.3A 2019-06-28 2019-06-28 A kind of dissolvant type nanofiber with very high performance Pending CN110331464A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1593734A (en) * 2003-09-12 2005-03-16 浙江欧美环境工程有限公司 Formula of preparation liquid for hollow-fibre membrane and products thereof
CN101954250A (en) * 2010-10-13 2011-01-26 东华大学 Method for preparing polyvinylidene fluoride-phenolphthalein polyethersulfone blending membrane
CN102219969A (en) * 2010-04-13 2011-10-19 广州美能材料科技有限公司 Polyvinylidene fluoride-polyether sulfone blended hollow fiber membrane and thermally induced phase separation preparation method
CN104014197A (en) * 2014-06-11 2014-09-03 中鸿纳米纤维技术丹阳有限公司 Solvent-type nanofiber contained filtering membrane and preparation method thereof
CN104313724A (en) * 2014-09-25 2015-01-28 中鸿纳米纤维技术丹阳有限公司 Large scale production method of solvent type nanofibers

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1593734A (en) * 2003-09-12 2005-03-16 浙江欧美环境工程有限公司 Formula of preparation liquid for hollow-fibre membrane and products thereof
CN102219969A (en) * 2010-04-13 2011-10-19 广州美能材料科技有限公司 Polyvinylidene fluoride-polyether sulfone blended hollow fiber membrane and thermally induced phase separation preparation method
CN101954250A (en) * 2010-10-13 2011-01-26 东华大学 Method for preparing polyvinylidene fluoride-phenolphthalein polyethersulfone blending membrane
CN104014197A (en) * 2014-06-11 2014-09-03 中鸿纳米纤维技术丹阳有限公司 Solvent-type nanofiber contained filtering membrane and preparation method thereof
CN104313724A (en) * 2014-09-25 2015-01-28 中鸿纳米纤维技术丹阳有限公司 Large scale production method of solvent type nanofibers

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Application publication date: 20191015