CN110330835A - The freeze proof table printing ink of grease resistance and its processing method, process equipment - Google Patents
The freeze proof table printing ink of grease resistance and its processing method, process equipment Download PDFInfo
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- CN110330835A CN110330835A CN201910741172.7A CN201910741172A CN110330835A CN 110330835 A CN110330835 A CN 110330835A CN 201910741172 A CN201910741172 A CN 201910741172A CN 110330835 A CN110330835 A CN 110330835A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
This application discloses a kind of freeze proof table printing ink of grease resistance and its processing methods, process equipment, according to the mass fraction, the freeze proof table printing ink of the grease resistance includes following component: 25 ~ 40 parts of water-based acrylic resin, 5 ~ 10 parts of aqueous binding resin, 2 ~ 4 parts of aqueous dispersion, 30 ~ 50 parts of aqueous color paste, 0.5 ~ 1.0 part and 10 ~ 20 parts of water of levelling agent have the advantages that improve frost resistance.
Description
Technical field
The present invention relates to the freeze proof table printing ink of grease resistance and its processing methods, process equipment.
Background technique
Ink is important materials used for printing packaging materials, it is expressed the pattern and text on stock by printing
It include main component and auxiliary element in ink, they equably mix and form a kind of sticky colloidal fluid through repeat-rolling.
In latter stage the 70's of eighties of last century, with the exploitation and commercialization of aqueous high molecular lotion, the states such as America and Europe have produced industry in succession
It is required that water-based ink, abbreviation ink the production of this pollution-free, nonhazardous novel ink and answers for environmental angle
With being the primary huge revolution in ink process industry.Water-based ink is a kind of environment-friendlyink ink using water as solvent, by
In not containing volatile organic solvent, the discharge of organic volatile (VOC) is greatly reduced, to alleviate atmosphere pollution, is changed
It has been apt to printing operation environment, has been conducive to the health of worker.It can be with certain poisonous and harmful substances in elimination solvent type ink
Harm to human body and the pollution to packaged commodity improve overall environmental quality, in addition, it can not only be reduced due to electrostatic
With fire hazard caused by flammable solvent and hidden danger, printing toxicity remained on surface, and printing easy to clean can also be reduced
Equipment, thus answered extensively in packages printings industries such as food packaging, tobacco and wine packaging, medical packaging and toy for children packagings
With ink also starts to be applied to clothes printing industry in recent years.
However since the solvent of water-based ink is mainly water, temperature is too low to will affect its use.
Summary of the invention
The first object of the present invention is to provide a kind of freeze proof table printing ink of grease resistance, has the advantages that improve frost resistance.
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of freeze proof table printing ink of grease resistance, according to the mass fraction, including following component: 25 ~ 40 parts of water-based acrylic resin, water
Property 5 ~ 10 parts of binding resin, 2 ~ 4 parts of aqueous dispersion, 30 ~ 50 parts of aqueous color paste, 0.5 ~ 1.0 part of levelling agent and 10 ~ 20 parts of water.
By adopting the above technical scheme, by the combination of water-based acrylic resin and aqueous binding resin, improve system intensity,
The surface tension and surface energy for reducing aqueous systems, so that the expansive force that system generates when freezing is eased, to improve
Frost resistance.
Preferably, the water-based acrylic resin select acrylamide and acrylic acid-metering system ammonium chloride copolymer and
The weight of acrylamide, acrylic acid and metering system ammonium chloride in acrylamide and acrylic acid-metering system ammonium chloride copolymer
For amount than being 1.4 ~ 1.6:1:3.4 ~ 3.6, the aqueous dispersion includes the PEO-PPO-PEO tri- that molar ratio is 0.45 ~ 0.55:1
Block copolymer and neopelex, the aqueous color paste are selected from the dyestuff of azo structure or the pigment of azo structure,
The levelling agent includes the dimethyl silicone polymer and esters of acrylic acid that mass ratio is 0.30 ~ 0.35:1；The aqueous coupling tree
Rouge is prepared by the following method to obtain: mixing and is passed through nitrogen for 30 ~ 40g water and 1 ~ 2g emulsifier, stir and be warming up to 58 ~ 62
DEG C, 24 ~ 26g butyl acrylate is added and 29 ~ 31g methyl methacrylate is stirred, 0.1 ~ 0.2g initiator is then added
Cause polymerization, form seed emulsion, be added dropwise after stable reaction 24 ~ 26g butyl acrylate, 29 ~ 31g methyl methacrylate and 5 ~
6g silane coupling agent, after dripping off keep the temperature 1 ~ 2hr, be then cooled to 38 ~ 42 DEG C, adjust pH to 8 ~ 9 after discharge.
Including following component preferably, according to the mass fraction: 32 parts of water-based acrylic resin, 8 parts of aqueous binding resin,
3 parts of aqueous dispersion, 40 parts of aqueous color paste, 0.8 part of levelling agent and 16 parts of water；The water-based acrylic resin selects acryloyl
Third in amine-acrylic acid-metering system ammonium chloride copolymer and acrylamide and acrylic acid-metering system ammonium chloride copolymer
The weight ratio of acrylamide, acrylic acid and metering system ammonium chloride is 1.5:1:3.5, and the aqueous dispersion includes that molar ratio is
The PEO-PPO-PEO triblock copolymer and neopelex of 0.50:1, the aqueous color paste are selected from C.I. acid black
191, the levelling agent includes the dimethyl silicone polymer and esters of acrylic acid that mass ratio is 0.33:1；The aqueous binding resin
It is prepared by the following method to obtain: 35g water and 1.2g emulsifier is mixed and are passed through nitrogen, stir and be warming up to 60 DEG C, addition
25g butyl acrylate and 30g methyl methacrylate are stirred, and 0.14g benzoyl peroxide is then added and causes polymerization, shape
At seed emulsion, 25g butyl acrylate, 30g methyl methacrylate and 5.2g vinyl triethoxyl is added dropwise after stable reaction
Silane, keeps the temperature 1.5hr after dripping off, be then cooled to 40 DEG C, adjust pH to 8.5 after discharge.
Preferably, according to the mass fraction, the freeze proof table printing ink of the grease resistance further include 0.05 ~ 0.08 part of maleic anhydride,
0.18 ~ 0.21 part and 0.10 ~ 0.20 part of phosphoethanolamine of sodium cocoyl glycinate.
By adopting the above technical scheme, improving stromal surface makes ink be easier to penetrate into, and accelerates seepage velocity, improves attached
Fastness；After these three components are quantitatively adding in the application ink simultaneously, ink is each in PET, PA, BOPP, PE and paper
(error is ± 5%), the product stable homogeneous of acquisition in the error range for being distributed in the application ink formulations of component.
Preferably, according to the mass fraction, the freeze proof table printing ink of the grease resistance further includes 0.06 part of maleic anhydride, cocounut oil acyl
0.20 part and 0.12 part of phosphoethanolamine of Sodium Glycinate.
The second object of the present invention is to provide a kind of processing method of freeze proof table printing ink of grease resistance.
Above-mentioned technical purpose of the invention has the technical scheme that
The processing method of the freeze proof table printing ink of grease resistance, comprising the following steps: by water-based acrylic resin, aqueous dispersion and water
Mixing, is stirred to being uniformly dispersed, and aqueous color paste and levelling agent are added thereto and stirs to being uniformly dispersed, is added thereto aqueous
Binding resin, stirring is to being uniformly dispersed.
Preferably, comprising the following steps: by water-based acrylic resin, aqueous dispersion, maleic anhydride, cocounut oil acyl glycine
Sodium, phosphoethanolamine and water mixing, are stirred to being uniformly dispersed, and aqueous color paste and levelling agent are added thereto and stirs equal to dispersing
It is even, it is added aqueous binding resin thereto, stirring is to being uniformly dispersed.
The third object of the present invention is to provide a kind of process equipment of freeze proof table printing ink of grease resistance.
Above-mentioned technical purpose of the invention has the technical scheme that
The process equipment of the freeze proof table printing ink of grease resistance, including the reaction kettle with temperature control device and for anti-in hybrid reactor
Answer the high-speed stirring apparatus of substance.
The technology of the present invention effect major embodiment is in the following areas: solvent is free of, to eliminate organic volatile matter significantly
(VOC) environmentally protective to the pollution of environment；With preferable water-resistance and resistance to oil stains, glossiness height, attachment fastness height, tool
There are preferable weatherability and frost resistance.
Detailed description of the invention
Fig. 1 is the process equipment of embodiment 1.
Appended drawing reference: 1, reaction kettle；2, high-speed stirring apparatus.
Specific embodiment
Below in conjunction with attached drawing, a specific embodiment of the invention is described in further detail, so that technical solution of the present invention is more
It should be readily appreciated that and grasp.
Embodiment 1: a kind of freeze proof table printing ink of grease resistance, process equipment include 1 He of reaction kettle with temperature control device
High-speed stirring apparatus 2 for reactive material in hybrid reactor 1.The processing method of the freeze proof table printing ink of the grease resistance include with
Lower step: water-based acrylic resin, aqueous dispersion and water are mixed, and stir to being uniformly dispersed, aqueous color paste is added thereto
With levelling agent and stir to being uniformly dispersed, be added aqueous binding resin thereto, stirring is to being uniformly dispersed.
The formula of the freeze proof table printing ink of the grease resistance are as follows: according to the mass fraction, including it is 32 parts of water-based acrylic resin, aqueous
8 parts of binding resin, 3 parts of aqueous dispersion, 40 parts of aqueous color paste, 0.8 part of levelling agent and 16 parts of water.Water-based acrylic resin is selected
Acrylamide and acrylic acid-metering system ammonium chloride copolymer and acrylamide and acrylic acid-metering system ammonium chloride copolymerization
The weight ratio of acrylamide, acrylic acid and metering system ammonium chloride is 1.5:1:3.5 in object.Aqueous dispersion includes molar ratio
For the PEO-PPO-PEO triblock copolymer and neopelex of 0.50:1.Aqueous color paste is selected from C.I. acid black
191.Levelling agent includes the dimethyl silicone polymer and esters of acrylic acid that mass ratio is 0.33:1.Aqueous binding resin passes through following
Method is prepared: 35g water and 1.2g emulsifier mixed and is passed through nitrogen, stirs and is warming up to 60 DEG C, addition 25g acrylic acid
Butyl ester and 30g methyl methacrylate are stirred, and 0.14g benzoyl peroxide is then added and causes polymerization, form seed cream
25g butyl acrylate, 30g methyl methacrylate and 5.2g vinyltriethoxysilane are added dropwise after stable reaction, drips off for liquid
After keep the temperature 1.5hr, be then cooled to 40 DEG C, adjust pH to 8.5 after discharge.
Embodiment 2: a kind of freeze proof table printing ink of grease resistance, the difference from embodiment 1 is that, the freeze proof table of the grease resistance prints water
Ink formula are as follows: according to the mass fraction, including 25 parts of water-based acrylic resin, 5 parts of aqueous binding resin, 2 parts of aqueous dispersion,
30 parts of aqueous color paste, 0.5 part of levelling agent and 10 parts of water.Water-based acrylic resin selects acrylamide and acrylic acid-methylpropenyl
Acrylamide, acrylic acid and methyl-prop in ammonium chloride copolymer and acrylamide and acrylic acid-metering system ammonium chloride copolymer
The weight ratio of alkenyl ammonium chloride is 1.4:1:3.4.Aqueous dispersion includes the PEO-PPO-PEO three block that molar ratio is 0.45:1
Copolymer and neopelex.Aqueous color paste is selected from C.I. acid black 1 91.Levelling agent includes that mass ratio is 0.30:1
Dimethyl silicone polymer and esters of acrylic acid.Aqueous binding resin is prepared by the following method to obtain: by 30g water and 1g emulsifier
Nitrogen is mixed and is passed through, stir and is warming up to 58 DEG C, 24g butyl acrylate is added and 29g methyl methacrylate is stirred,
0.1g benzoyl peroxide is then added and causes polymerization, forms seed emulsion, 24g butyl acrylate, 29g is added dropwise after stable reaction
Methyl methacrylate and 5g vinyltriethoxysilane, keep the temperature 2hr after dripping off, after being then cooled to 38 DEG C, adjusting pH to 8
Discharging.
Embodiment 3: a kind of freeze proof table printing ink of grease resistance, the difference from embodiment 1 is that, the freeze proof table of the grease resistance prints water
The formula of ink are as follows: according to the mass fraction, including 40 parts of water-based acrylic resin, 10 parts of aqueous binding resin, aqueous dispersion 4
Part, 50 parts of aqueous color paste, 1.0 parts of levelling agent and 20 parts of water.Water-based acrylic resin selects acrylamide and acrylic acid-methyl-prop
Acrylamide, acrylic acid and first in alkenyl ammonium chloride copolymer and acrylamide and acrylic acid-metering system ammonium chloride copolymer
The weight ratio of base acrylic ammonium chloride is 1.6:1:3.6.Aqueous dispersion includes the PEO-PPO-PEO tri- that molar ratio is 0.55:1
Block copolymer and neopelex.Aqueous color paste is selected from C.I. acid black 1 91.Levelling agent includes that mass ratio is
The dimethyl silicone polymer and esters of acrylic acid of 0.35:1.Aqueous binding resin is prepared by the following method to obtain: by 40g water and
2g emulsifier mixes and is passed through nitrogen, stirs and is warming up to 62 DEG C, and 26g butyl acrylate and 31g methyl methacrylate is added
It is stirred, 0.2g benzoyl peroxide is then added and causes polymerization, form seed emulsion, 26g propylene is added dropwise after stable reaction
Acid butyl ester, 31g methyl methacrylate and 6g vinyltriethoxysilane, keep the temperature 1hr after dripping off, be then cooled to 42 DEG C,
It discharges after adjusting pH to 9.
Embodiment 4: a kind of freeze proof table printing ink of grease resistance, process equipment include 1 He of reaction kettle with temperature control device
High-speed stirring apparatus 2 for reactive material in hybrid reactor 1.The processing method of the freeze proof table printing ink of the grease resistance include with
Lower step: water-based acrylic resin, aqueous dispersion, maleic anhydride, sodium cocoyl glycinate, phosphoethanolamine and water are mixed
It closes, stirs to being uniformly dispersed, aqueous color paste and levelling agent are added thereto and stirs to being uniformly dispersed, aqueous idol is added thereto
Join resin, stirring is to being uniformly dispersed.
The formula of the freeze proof table printing ink of the grease resistance are as follows: according to the mass fraction, including it is 32 parts of water-based acrylic resin, aqueous
8 parts of binding resin, 3 parts of aqueous dispersion, 40 parts of aqueous color paste, 0.8 part of levelling agent, 16 parts of water, 0.06 part of maleic anhydride, cocounut oil
0.20 part and 0.12 part of phosphoethanolamine of acyl Sodium Glycinate.Water-based acrylic resin selects acrylamide and acrylic acid-metering system
Acrylamide, acrylic acid and methyl in ammonium chloride copolymer and acrylamide and acrylic acid-metering system ammonium chloride copolymer
The weight ratio of acrylic ammonium chloride is 1.5:1:3.5.Aqueous dispersion includes the PEO-PPO-PEO tri- that molar ratio is 0.50:1 embedding
Section copolymer and neopelex.Aqueous color paste is selected from C.I. acid black 1 91.Levelling agent includes that mass ratio is 0.33:1
Dimethyl silicone polymer and esters of acrylic acid.Aqueous binding resin is prepared by the following method to obtain: by 35g water and 1.2g cream
Agent mixes and is passed through nitrogen, stirs and is warming up to 60 DEG C, and 25g butyl acrylate and the stirring of 30g methyl methacrylate is added
Mixing is then added 0.14g benzoyl peroxide and causes polymerization, forms seed emulsion, 25g acrylic acid fourth is added dropwise after stable reaction
Ester, 30g methyl methacrylate and 5.2g vinyltriethoxysilane, keep the temperature 1.5hr after dripping off, be then cooled to 40 DEG C,
It discharges after adjusting pH to 8.5.
Embodiment 5: a kind of freeze proof table printing ink of grease resistance, the difference with embodiment 4 are that the freeze proof table of the grease resistance prints water
Ink formula are as follows: according to the mass fraction, including 32 parts of water-based acrylic resin, 8 parts of aqueous binding resin, 3 parts of aqueous dispersion,
40 parts of aqueous color paste, 0.8 part of levelling agent, 16 parts of water, 0.05 part of maleic anhydride, 0.18 part of sodium cocoyl glycinate and phosphoric acid ethyl alcohol
0.10 part of amine.Water-based acrylic resin selects acrylamide and acrylic acid-metering system ammonium chloride copolymer and acrylamide-
The weight ratio of acrylamide, acrylic acid and metering system ammonium chloride is in acrylic acid-metering system ammonium chloride copolymer
1.5:1:3.5.Aqueous dispersion includes the PEO-PPO-PEO triblock copolymer and detergent alkylate sulphur that molar ratio is 0.50:1
Sour sodium.Aqueous color paste is selected from C.I. acid black 1 91.Levelling agent includes the dimethyl silicone polymer and propylene that mass ratio is 0.33:1
Esters of gallic acid.Aqueous binding resin is prepared by the following method to obtain: mixing and is passed through nitrogen for 35g water and 1.2g emulsifier, stir
It mixes and is warming up to 60 DEG C, 25g butyl acrylate is added and 30g methyl methacrylate is stirred, 0.14g peroxide is then added
Change benzoyl and cause polymerization, form seed emulsion, be added dropwise after stable reaction 25g butyl acrylate, 30g methyl methacrylate and
5.2g vinyltriethoxysilane, keeps the temperature 1.5hr after dripping off, be then cooled to 40 DEG C, adjust pH to 8.5 after discharge.
Embodiment 6: a kind of freeze proof table printing ink of grease resistance, the difference with embodiment 4 are that the freeze proof table of the grease resistance prints water
Ink formula are as follows: according to the mass fraction, including 32 parts of water-based acrylic resin, 8 parts of aqueous binding resin, 3 parts of aqueous dispersion,
40 parts of aqueous color paste, 0.8 part of levelling agent, 16 parts of water, 0.08 part of maleic anhydride, 0.21 part of sodium cocoyl glycinate and phosphoric acid ethyl alcohol
0.20 part of amine.Water-based acrylic resin selects acrylamide and acrylic acid-metering system ammonium chloride copolymer and acrylamide-
The weight ratio of acrylamide, acrylic acid and metering system ammonium chloride is in acrylic acid-metering system ammonium chloride copolymer
1.5:1:3.5.Aqueous dispersion includes the PEO-PPO-PEO triblock copolymer and detergent alkylate sulphur that molar ratio is 0.50:1
Sour sodium.Aqueous color paste is selected from C.I. acid black 1 91.Levelling agent includes the dimethyl silicone polymer and propylene that mass ratio is 0.33:1
Esters of gallic acid.Aqueous binding resin is prepared by the following method to obtain: mixing and is passed through nitrogen for 35g water and 1.2g emulsifier, stir
It mixes and is warming up to 60 DEG C, 25g butyl acrylate is added and 30g methyl methacrylate is stirred, 0.14g peroxide is then added
Change benzoyl and cause polymerization, form seed emulsion, be added dropwise after stable reaction 25g butyl acrylate, 30g methyl methacrylate and
5.2g vinyltriethoxysilane, keeps the temperature 1.5hr after dripping off, be then cooled to 40 DEG C, adjust pH to 8.5 after discharge.
Performance test
The ink of embodiment 1-6 is tested for the property, test result is as shown in table 2 and table 3.
Water-resistance, resistance to oil stains test: water, soybean oil are soaked in that is, by dry ink sample using infusion method respectively
In, it is taken out after 5min and scrapes sample, graded according to the situation of change for scraping sample and (be shown in Table 1, and ink water-resistance is characterized with this.Ink is anti-
Aqueous and resistance to oil stains rank is higher, and performance is better.
Glossiness of ink test: it is surveyed referring to " the GB/T13217.2-2009 liquid ink color gloss method of inspection "
Examination.
Attachment fastness test: it is tested referring to kgB/T13217.7-2009.Before test, sample is placed on 0 DEG C respectively
3d and 30d at 25 DEG C, with place before data compare.
1 ink water-resistance of table and resistance to oil stains rank
Table 2
Table 2 shows that the water-resistance of embodiment 1-6 and resistance to oil pollution level are 5 grades, has preferable water-resistance and resistance to oil stains；
The glossiness of embodiment 1-6 is 82 ~ 95%, and wherein the glossiness of embodiment 4-6 is higher, and embodiment 4 is best.
Table 3
Table 3 shows that attachment fastness of the embodiment 1-6 before placement is higher, is above 90%, and wherein embodiment 4-6 is more preferably；25
After placing a period of time at 0 DEG C, the attachment fastness of embodiment 1-6 is all declined, and wherein the slippage of embodiment 4 can be basic
It ignores, illustrates that its weatherability and frost resistance are best.Sample is placed on 30d at 4 DEG C simultaneously, embodiment 1-6 does not have found
Curdled appearance.
Certainly, above is representative instance of the invention, and in addition to this, the present invention can also have other a variety of specific implementations
Mode, all technical solutions formed using equivalent substitution or equivalent transformation, is all fallen within the scope of protection of present invention.
Claims (8)
1. a kind of freeze proof table printing ink of grease resistance, characterized in that according to the mass fraction, including following component: water soluble acrylic acid tree
25 ~ 40 parts of rouge, 5 ~ 10 parts of aqueous binding resin, 2 ~ 4 parts of aqueous dispersion, 30 ~ 50 parts of aqueous color paste, 0.5 ~ 1.0 part of levelling agent
With 10 ~ 20 parts of water.
2. the freeze proof table printing ink of grease resistance according to claim 1, characterized in that the water-based acrylic resin selects third
Acrylamide-acrylic acid-metering system ammonium chloride copolymer and acrylamide and acrylic acid-metering system ammonium chloride copolymer
The weight ratio of middle acrylamide, acrylic acid and metering system ammonium chloride is 1.4 ~ 1.6:1:3.4 ~ 3.6, the aqueous dispersion
The PEO-PPO-PEO triblock copolymer and neopelex for being 0.45 ~ 0.55:1 including molar ratio, the aqueous color
The pigment of dyestuff or azo structure of the slurry selected from azo structure, the levelling agent include poly- two that mass ratio is 0.30 ~ 0.35:1
Methylsiloxane and esters of acrylic acid；The aqueous binding resin is prepared by the following method to obtain: by 30 ~ 40g water and 1 ~ 2g
Emulsifier mixes and is passed through nitrogen, stirs and is warming up to 58 ~ 62 DEG C, and 24 ~ 26g butyl acrylate and 29 ~ 31g metering system is added
Sour methyl esters is stirred, and 0.1 ~ 0.2g initiator is then added and causes polymerization, forms seed emulsion, it is added dropwise 24 after stable reaction ~
26g butyl acrylate, 29 ~ 31g methyl methacrylate and 5 ~ 6g silane coupling agent keep the temperature 1 ~ 2hr, are then cooled to after dripping off
38 ~ 42 DEG C, adjust pH to 8 ~ 9 after discharge.
3. the freeze proof table printing ink of grease resistance according to claim 2, characterized in that according to the mass fraction, including with the following group
Part: 32 parts of water-based acrylic resin, 8 parts of aqueous binding resin, 3 parts of aqueous dispersion, 40 parts of aqueous color paste, 0.8 part of levelling agent
With 16 parts of water；The water-based acrylic resin selects acrylamide and acrylic acid-metering system ammonium chloride copolymer and acryloyl
The weight ratio of acrylamide, acrylic acid and metering system ammonium chloride is in amine-acrylic acid-metering system ammonium chloride copolymer
1.5:1:3.5, the aqueous dispersion include the PEO-PPO-PEO triblock copolymer and dodecyl that molar ratio is 0.50:1
Benzene sulfonic acid sodium salt, the aqueous color paste are selected from C.I. acid black 1 91, and the levelling agent includes the poly dimethyl that mass ratio is 0.33:1
Siloxanes and esters of acrylic acid；The aqueous binding resin is prepared by the following method to obtain: 35g water and 1.2g emulsifier are mixed
Merging is passed through nitrogen, stirs and is warming up to 60 DEG C, and 25g butyl acrylate is added and 30g methyl methacrylate is stirred, with
0.14g benzoyl peroxide is added afterwards and causes polymerization, forms seed emulsion, 25g butyl acrylate, 30g is added dropwise after stable reaction
Methyl methacrylate and 5.2g vinyltriethoxysilane, keep the temperature 1.5hr after dripping off, be then cooled to 40 DEG C, adjust pH
It discharges after to 8.5.
4. the freeze proof table printing ink of grease resistance according to claim 3, characterized in that according to the mass fraction, the grease resistance
Freeze proof table printing ink further includes 0.05 ~ 0.08 part of maleic anhydride, 0.18 ~ 0.21 part of sodium cocoyl glycinate and phosphoethanolamine
0.10 ~ 0.20 part.
5. the freeze proof table printing ink of grease resistance according to claim 4, characterized in that according to the mass fraction, the grease resistance
Freeze proof table printing ink further includes 0.06 part of maleic anhydride, 0.20 part of sodium cocoyl glycinate and 0.12 part of phosphoethanolamine.
6. the processing method of the freeze proof table printing ink of grease resistance as described in any one in claim 1-5, characterized in that including following
Step: by water-based acrylic resin, aqueous dispersion and water mix, stir to being uniformly dispersed, thereto be added aqueous color paste and
Levelling agent is simultaneously stirred to being uniformly dispersed, and is added aqueous binding resin thereto, and stirring is to being uniformly dispersed.
7. the processing method of the freeze proof table printing ink of grease resistance according to claim 6, characterized in that the following steps are included:
Water-based acrylic resin, aqueous dispersion, maleic anhydride, sodium cocoyl glycinate, phosphoethanolamine and water are mixed, stirring is extremely
It is uniformly dispersed, aqueous color paste and levelling agent are added thereto and stir to being uniformly dispersed, aqueous binding resin is added thereto, stirs
It mixes to being uniformly dispersed.
8. the process equipment of the freeze proof table printing ink of grease resistance as described in any one in claim 1-5, characterized in that including having
The reaction kettle of temperature control device and high-speed stirring apparatus for reactive material in hybrid reactor.
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Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003026982A (en) * | 2001-07-18 | 2003-01-29 | Toyo Ink Mfg Co Ltd | Aqueous printing ink composition and packaging material made of paper and package container using the composition |
| JP2004083881A (en) * | 2002-06-28 | 2004-03-18 | Pentel Corp | Oil-based ink composition for ball-point pen |
| JP2005219000A (en) * | 2004-02-06 | 2005-08-18 | Kansai Paint Co Ltd | Mirror finishing method of inorganic porous material and coated article |
| WO2006063266A2 (en) * | 2004-12-10 | 2006-06-15 | Omnitech Environmental, Llc | Additive and vehicle for inks, paints, coatings and adhesives |
| CN101319026A (en) * | 2008-06-18 | 2008-12-10 | 江苏飞翔化工股份有限公司 | Method for preparing cationic polymer for auxiliary colophony dispersion in colophony sizing agent |
| CN101531106A (en) * | 2008-03-14 | 2009-09-16 | 富士施乐株式会社 | Image recording composition, image recording ink set and recording apparatus |
| CN101851447A (en) * | 2010-06-21 | 2010-10-06 | 东莞市凯迪克高分子材料有限公司 | Method for preparing micro-gel reactive emulsion water-based ink and product thereof |
| CN101921360A (en) * | 2010-01-27 | 2010-12-22 | 陕西科技大学 | A kind of latex coating preparation method of nano silicone-acrylate core shell type composite emulsion |
| CN103319953A (en) * | 2013-07-12 | 2013-09-25 | 鲁继烈 | Water-based pigment ink for quality improvement |
| CN103772625A (en) * | 2014-01-17 | 2014-05-07 | 广州市东雄化工有限公司 | Freezing-resistant acrylate suspended thickening emulsion and preparation method thereof |
| CN104877453A (en) * | 2015-04-27 | 2015-09-02 | 安徽宏洋包装集团有限公司 | Photosensitive waterproof and antifreeze water-based printing ink |
| CN107417189A (en) * | 2017-09-02 | 2017-12-01 | 新沂市中诺新材料科技有限公司 | A kind of preparation method of high intensity frost-resistant concrete |
| CN108410261A (en) * | 2018-05-31 | 2018-08-17 | 深圳市零度智控科技有限公司 | A kind of waterborne antibacterial ink and preparation method thereof |
| CN108587318A (en) * | 2018-08-01 | 2018-09-28 | 湖南七纬科技有限公司 | A kind of advertising and printing water-based ink and preparation method thereof |
| CN109321030A (en) * | 2018-11-07 | 2019-02-12 | 顾洪杰 | Water-based plastic inner printing ink and water-based plastic table printing ink |
| CN109337656A (en) * | 2018-11-02 | 2019-02-15 | 饶会均 | A kind of automotive antifreezing liquid and preparation method thereof |
-
2019
- 2019-08-12 CN CN201910741172.7A patent/CN110330835B/en active Active
Patent Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003026982A (en) * | 2001-07-18 | 2003-01-29 | Toyo Ink Mfg Co Ltd | Aqueous printing ink composition and packaging material made of paper and package container using the composition |
| JP2004083881A (en) * | 2002-06-28 | 2004-03-18 | Pentel Corp | Oil-based ink composition for ball-point pen |
| JP2005219000A (en) * | 2004-02-06 | 2005-08-18 | Kansai Paint Co Ltd | Mirror finishing method of inorganic porous material and coated article |
| WO2006063266A2 (en) * | 2004-12-10 | 2006-06-15 | Omnitech Environmental, Llc | Additive and vehicle for inks, paints, coatings and adhesives |
| CN101531106A (en) * | 2008-03-14 | 2009-09-16 | 富士施乐株式会社 | Image recording composition, image recording ink set and recording apparatus |
| CN101319026A (en) * | 2008-06-18 | 2008-12-10 | 江苏飞翔化工股份有限公司 | Method for preparing cationic polymer for auxiliary colophony dispersion in colophony sizing agent |
| CN101921360A (en) * | 2010-01-27 | 2010-12-22 | 陕西科技大学 | A kind of latex coating preparation method of nano silicone-acrylate core shell type composite emulsion |
| CN101851447A (en) * | 2010-06-21 | 2010-10-06 | 东莞市凯迪克高分子材料有限公司 | Method for preparing micro-gel reactive emulsion water-based ink and product thereof |
| CN103319953A (en) * | 2013-07-12 | 2013-09-25 | 鲁继烈 | Water-based pigment ink for quality improvement |
| CN103772625A (en) * | 2014-01-17 | 2014-05-07 | 广州市东雄化工有限公司 | Freezing-resistant acrylate suspended thickening emulsion and preparation method thereof |
| CN104877453A (en) * | 2015-04-27 | 2015-09-02 | 安徽宏洋包装集团有限公司 | Photosensitive waterproof and antifreeze water-based printing ink |
| CN107417189A (en) * | 2017-09-02 | 2017-12-01 | 新沂市中诺新材料科技有限公司 | A kind of preparation method of high intensity frost-resistant concrete |
| CN108410261A (en) * | 2018-05-31 | 2018-08-17 | 深圳市零度智控科技有限公司 | A kind of waterborne antibacterial ink and preparation method thereof |
| CN108587318A (en) * | 2018-08-01 | 2018-09-28 | 湖南七纬科技有限公司 | A kind of advertising and printing water-based ink and preparation method thereof |
| CN109337656A (en) * | 2018-11-02 | 2019-02-15 | 饶会均 | A kind of automotive antifreezing liquid and preparation method thereof |
| CN109321030A (en) * | 2018-11-07 | 2019-02-12 | 顾洪杰 | Water-based plastic inner printing ink and water-based plastic table printing ink |
Non-Patent Citations (2)
| Title |
|---|
| SHEN, YAZHEN等: ""Aqueous Polyacrylate/Poly(silicone-co-acrylate) Emulsion Coated Fertilizers for Slow Nutrient-Release Application"", 《JOURNAL OF APPLIED POLYMER SCIENCE》 * |
| 罗得学等: ""阳离子丙烯酸酯树脂乳液的研究进展"", 《涂料技术与文摘》 * |
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