CN110330134A - A kind of alumina efficient treatment process for waster water with high - Google Patents

A kind of alumina efficient treatment process for waster water with high Download PDF

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Publication number
CN110330134A
CN110330134A CN201910544823.3A CN201910544823A CN110330134A CN 110330134 A CN110330134 A CN 110330134A CN 201910544823 A CN201910544823 A CN 201910544823A CN 110330134 A CN110330134 A CN 110330134A
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CN
China
Prior art keywords
waste water
water
pond
reservoir
settling tank
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Pending
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CN201910544823.3A
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Chinese (zh)
Inventor
金爱军
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Zhejiang Xianghe Environmental Protection Engineering Co Ltd
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Zhejiang Xianghe Environmental Protection Engineering Co Ltd
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Priority to CN201910544823.3A priority Critical patent/CN110330134A/en
Publication of CN110330134A publication Critical patent/CN110330134A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/122Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/40Devices for separating or removing fatty or oily substances or similar floating material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a kind of alumina efficient treatment process for waster water with high, the waste water treatment system is made of effluent storage pond, three oil separators, No.1 reaction tank, No. two reaction tanks, comprehensive adjustment pond, flocculation basin, settling tank, sand filter, reservoir, backwashing pump, pumping pulp pump, filter press, pipeline and valve.Compared with other treatment process, the present invention is for Continuous Wastewater Treatment system, using the method for two reaction tanks of series connection, previous pond coarse adjustment pH, the latter pond accurate adjustment pH, it may insure effective control to wastewater pH, the treatment effeciency to waste water is improved in turn, since main component is acid, alkali, aluminium ion in aluminium oxidized waste water, so with flocculation sedimentation significant effect, quickly sediment can be handled using settling tank, sand coarse aggregate ratio pond and filter press, structure is simple and efficient.

Description

A kind of alumina efficient treatment process for waster water with high
Technical field
The invention belongs to field of waste water treatment, and in particular to a kind of alumina efficient treatment process for waster water with high.
Background technique
Wastewater treatment is exactly to be handled using the method for physics, chemistry and biology waste water, makes purification of waste water, is reduced dirty Dye makes full use of water resource so that reaching Sewage treatment, multiplexing.
Existing aluminium oxidized waste water continuous processing technique, it is more complicated, and simultaneously for the efficiency of alumina wastewater treatment It is not high, for this purpose, it is proposed that a kind of alumina efficient treatment process for waster water with high.
Summary of the invention
It is an object of the invention to overcome the deficiencies of existing technologies, a kind of alumina efficient treatment process for waster water with high of proposition, Using the method for two reaction tanks of series connection, previous pond coarse adjustment pH, the latter pond accurate adjustment pH, it can be ensured that the effective of wastewater pH Control, and then the treatment effeciency to waste water is improved, since main component is acid, alkali, aluminium ion in aluminium oxidized waste water, so with wadding Solidifying sedimentation significant effect, can quickly be handled sediment, structure is simple using settling tank, sand coarse aggregate ratio pond and filter press And it is efficient.
To achieve the goals above, technical scheme is as follows:
1, a kind of alumina efficient treatment process for waster water with high: the waste water treatment system by effluent storage pond, three oil separators, No.1 reaction tank, comprehensive adjustment pond, flocculation basin, settling tank, sand filter, reservoir, backwashing pump, takes out pulp pump, pressure at No. two reaction tanks Filter, pipeline and valve composition.
2, a kind of alumina efficient treatment process for waster water with high as described in claim 1: its processing technological flow is specific as follows:
S1, wastewater collection: check whether the state of valve everywhere is correct, and aluminium oxidized waste water clearance tubing is transported to waste water In storage pool;
S2, waste water oil removing: by the waste water extraction in effluent storage pond into three oil separators, due to the grease in the waste water It is mostly mixed in together with surfactant etc., relative density less than 1, can bubble through the water column in the quiescent state on, therefore, pass through first After oil separator removes oil substances most in waste water, then carry out subsequent advanced treating;
S3, waste water neutralize: by the waste water extraction of three oil separators into comprehensive adjustment pond, and being distinguished by comprehensive adjustment pond By in discharge of wastewater to No.1 reaction tank and No. two reaction tanks, start the blender of reaction tank, measure wastewater pH with pH test paper, Corresponding neutralizer is added into waste water according to pH, the pH of waste water is adjusted to close to discharge standard, waste water flows to No. two reactions Chi Hou, repeated measurement wastewater pH, and neutralizer is added until pH is reached discharge standard, it is then refluxed in comprehensive adjustment pond;
S4, waste water flocculating: being pumped into flocculation basin from comprehensive adjustment pond for the waste water for regulating pH, opens flocculation basin stirring, and The waste water of flocculation reaction occurs for the flow for adjusting flocculant from person who lives in exile's settling tank;
S5, waste water sedimentation: the waste water flowed into settling tank carries out the settlement treatment of 1.5-2h, obtains supernatant and precipitating Object, the overflow port that clear water then passes through settling tank top enters discharge pipe, and is flowed into reservoir;
S6, sediment processing: flocky precipitate is pumped into sand filter, for removing the water in floccule, to obtain The lower sludge of water content, the water filtered out are flowed into reservoir by pipeline, and the water in reservoir is transported to sand by backwashing pump Inside filter tank, secondary flushing is carried out to sand filter, flushing water is back in reservoir;
S7, sediment secondary treatment: the sludge in sand filter is pumped into filter press by taking out pulp pump, obtains pie Sludge after drying and is transported outward.
Preferred: in the S3 step, neutralizer includes calcium oxide, magnesium hydroxide and sodium carbonate, mass ratio 2.2: 1.5:1。
It is preferred: secondary flushing to be carried out to sand filter in the S6 step, flushing water is back in reservoir, with pH test paper The pH value in reservoir is measured, is discharged after being adjusted to discharge standard with ferrous sulfate.
Preferred: in the S4 step, the mass ratio between waste water and flocculant is between 8:100-10:100.
Preferred: connection, three oil separator and comprehensive adjustment pond are connected with three oil separators for the effluent storage pond Connection, the comprehensive adjustment pond and wadding is connected in conducting connection, the No.1 reaction tank and No. two reaction tanks with comprehensive adjustment pond Connection is connected with settling tank for solidifying pond conducting connection, the flocculation basin, and the settling tank is connected with sand filter to be connected, the reservoir It is connected and is connected with settling tank and sand filter, backwashing pump, the sand filter and filters pressing are equipped between the reservoir and sand filter Between machine be connected be connected, between the sand filter and filter press between pumping pulp pump is installed.
Technical effect and advantage of the invention:
1, the present invention is for Continuous Wastewater Treatment system, using the method for two reaction tanks of series connection, previous pond coarse adjustment pH, The latter pond accurate adjustment pH, it can be ensured that effective control to wastewater pH, and then improve the treatment effeciency to waste water.
2, the present invention due in aluminium oxidized waste water main component be acid, alkali, aluminium ion, so being shown with flocculation sedimentation effect It writes.
3, the present invention can quickly be handled sediment using settling tank, sand coarse aggregate ratio pond and filter press, and structure is simple And it is efficient.
Detailed description of the invention
To describe the technical solutions in the embodiments of the present invention more clearly, make required in being described below to embodiment Attached drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for For those of ordinary skill in the art, without creative efforts, it can also be obtained according to these attached drawings other Attached drawing.
Fig. 1 is a kind of alumina efficient treatment process for waster water with high flow diagram of the embodiment of the present invention;
Specific embodiment
The present invention is described in further details below with reference to embodiment.
Embodiment 1:
Embodiment 1 proposes a kind of alumina efficient treatment process for waster water with high, includes the following steps:
1, aluminium oxidized waste water is collected with effluent storage pond first, by the waste water extraction in effluent storage pond to three oil separators In, due to the grease in the waste water mostly with surfactant etc. it is mixed in together, relative density can float in the quiescent state less than 1 In on the water surface, therefore, after first oil substances most in waste water being removed by oil separator, then carry out subsequent depth Processing.
2, by the waste water extraction of three oil separators into comprehensive adjustment pond, and it is respectively that waste water is uniform by comprehensive adjustment pond Be discharged into No.1 reaction tank and No. two reaction tanks, add neutralizer into No.1 reaction tank and No. two reaction tanks respectively, in It is made of with agent calcium oxide, magnesium hydroxide and sodium carbonate, starts the blender of reaction tank, wastewater pH is measured with pH test paper, by one The pH of waste water in number reaction tank is adjusted to 4.5, and the pH of the waste water in reaction tank is adjusted to 5, and the waste water in No.1 reaction tank is arranged Enter into No. two reaction tanks and mixed, be then refluxed in comprehensive adjustment pond, wherein calcium oxide, magnesium hydroxide and sodium carbonate Mass ratio is 2.2:1.5:1.
3, the waste water for mixing pH is pumped into flocculation basin from comprehensive adjustment pond, opens flocculation basin stirring, and adjust flocculation The waste water of flocculation reaction occurs for the flow of agent from person who lives in exile's settling tank, and the overflow port that clear water then passes through settling tank top enters row Pipeline is put, wherein the mass ratio between waste water and flocculant is 8:100.
4, the waste water flowed into settling tank carries out the settlement treatment of 1.5-2h, obtains supernatant and sediment, clear water then leads to The overflow port for crossing settling tank top enters discharge pipe, and is flowed into reservoir, and the waste water flowed into settling tank carries out 1.5- The settlement treatment of 2h, obtains supernatant and sediment, and the overflow port that clear water then passes through settling tank top enters discharge pipe, cocurrent Enter into reservoir, with clean beaker dress clear water observation, water quality should be clarified, and be adjusted to discharge standard heel row with ferrous sulfate Out, pH controlling value is 6.
5, the sludge in sand filter is pumped into filter press by taking out pulp pump, obtains pie sludge, it is after drying and outer Fortune.
Embodiment 2:
Embodiment 2 proposes a kind of alumina efficient treatment process for waster water with high, includes the following steps:
1, aluminium oxidized waste water is collected with effluent storage pond first, by the waste water extraction in effluent storage pond to three oil separators In, due to the grease in the waste water mostly with surfactant etc. it is mixed in together, relative density can float in the quiescent state less than 1 In on the water surface, therefore, after first oil substances most in waste water being removed by oil separator, then carry out subsequent depth Processing.
2, by the waste water extraction of three oil separators into comprehensive adjustment pond, and it is respectively that waste water is uniform by comprehensive adjustment pond Be discharged into No.1 reaction tank and No. two reaction tanks, add neutralizer into No.1 reaction tank and No. two reaction tanks respectively, in It is made of with agent calcium oxide, magnesium hydroxide and sodium carbonate, starts the blender of reaction tank, wastewater pH is measured with pH test paper, by one The pH of waste water in number reaction tank is adjusted to 5, and the pH of the waste water in reaction tank is adjusted to 5.5, and the waste water in No.1 reaction tank is arranged Enter into No. two reaction tanks and mixed, be then refluxed in comprehensive adjustment pond, wherein calcium oxide, magnesium hydroxide and sodium carbonate Mass ratio is 2.2:1.5:1.
3, the waste water for mixing pH is pumped into flocculation basin from comprehensive adjustment pond, opens flocculation basin stirring, and adjust flocculation The waste water of flocculation reaction occurs for the flow of agent from person who lives in exile's settling tank, and the overflow port that clear water then passes through settling tank top enters row Pipeline is put, wherein the mass ratio between waste water and flocculant is 9:100.
4, the waste water flowed into settling tank carries out the settlement treatment of 1.5-2h, obtains supernatant and sediment, clear water then leads to The overflow port for crossing settling tank top enters discharge pipe, and is flowed into reservoir, and the waste water flowed into settling tank carries out 1.5- The settlement treatment of 2h, obtains supernatant and sediment, and the overflow port that clear water then passes through settling tank top enters discharge pipe, cocurrent Enter into reservoir, with clean beaker dress clear water observation, water quality should be clarified, and be adjusted to discharge standard heel row with ferrous sulfate Out, pH controlling value is 6.5.
5, the sludge in sand filter is pumped into filter press by taking out pulp pump, obtains pie sludge, it is after drying and outer Fortune.
Embodiment 3:
Embodiment 3 proposes a kind of alumina efficient treatment process for waster water with high, includes the following steps:
1, aluminium oxidized waste water is collected with effluent storage pond first, by the waste water extraction in effluent storage pond to three oil separators In, due to the grease in the waste water mostly with surfactant etc. it is mixed in together, relative density can float in the quiescent state less than 1 In on the water surface, therefore, after first oil substances most in waste water being removed by oil separator, then carry out subsequent depth Processing.
2, by the waste water extraction of three oil separators into comprehensive adjustment pond, and it is respectively that waste water is uniform by comprehensive adjustment pond Be discharged into No.1 reaction tank and No. two reaction tanks, add neutralizer into No.1 reaction tank and No. two reaction tanks respectively, in It is made of with agent calcium oxide, magnesium hydroxide and sodium carbonate, starts the blender of reaction tank, wastewater pH is measured with pH test paper, by one The pH of waste water in number reaction tank is adjusted to 5.5, and the pH of the waste water in reaction tank is adjusted to 6, and the waste water in No.1 reaction tank is arranged Enter into No. two reaction tanks and mixed, be then refluxed in comprehensive adjustment pond, wherein calcium oxide, magnesium hydroxide and sodium carbonate Mass ratio is 2.2:1.5:1.
3, the waste water for mixing pH is pumped into flocculation basin from comprehensive adjustment pond, opens flocculation basin stirring, and adjust flocculation The waste water of flocculation reaction occurs for the flow of agent from person who lives in exile's settling tank, and the overflow port that clear water then passes through settling tank top enters row Pipeline is put, wherein the mass ratio between waste water and flocculant is 10:100.
4, the waste water flowed into settling tank carries out the settlement treatment of 1.5-2h, obtains supernatant and sediment, clear water then leads to The overflow port for crossing settling tank top enters discharge pipe, and is flowed into reservoir, and the waste water flowed into settling tank carries out 1.5- The settlement treatment of 2h, obtains supernatant and sediment, and the overflow port that clear water then passes through settling tank top enters discharge pipe, cocurrent Enter into reservoir, with clean beaker dress clear water observation, water quality should be clarified, and be adjusted to discharge standard heel row with ferrous sulfate Out, pH controlling value is 7.
5, the sludge in sand filter is pumped into filter press by taking out pulp pump, obtains pie sludge, it is after drying and outer Fortune.

Claims (6)

1. a kind of alumina efficient treatment process for waster water with high, it is characterised in that: the waste water treatment system is by effluent storage pond, three Oil separator, No.1 reaction tank, No. two reaction tanks, comprehensive adjustment pond, flocculation basin, settling tank, sand filter, reservoir, backwashing pump, pumping Pulp pump, filter press, pipeline and valve composition.
2. a kind of alumina efficient treatment process for waster water with high as described in claim 1, it is characterised in that: its processing technological flow tool Body is as follows:
S1, wastewater collection: check whether the state of valve everywhere is correct, and aluminium oxidized waste water clearance tubing is transported to effluent storage In pond;
S2, waste water oil removing: by the waste water extraction in effluent storage pond into three oil separators, due to the grease in the waste water mostly with Surfactant etc. is mixed in together, relative density less than 1, can bubble through the water column in the quiescent state on, therefore, pass through oil removal first After pond removes oil substances most in waste water, then carry out subsequent advanced treating;
S3, waste water neutralize: by the waste water extraction of three oil separators into comprehensive adjustment pond, and will be given up respectively by comprehensive adjustment pond Water is discharged into No.1 reaction tank and No. two reaction tanks, starts the blender of reaction tank, wastewater pH is measured with pH test paper, according to pH Corresponding neutralizer is added into waste water, the pH of waste water is adjusted to close to discharge standard, after waste water flows to No. two reaction tanks, instead Repetition measurement amount wastewater pH, and neutralizer is added until pH is reached discharge standard, it is then refluxed in comprehensive adjustment pond;
S4, waste water flocculating: the waste water for regulating pH is pumped into flocculation basin from comprehensive adjustment pond, opens flocculation basin stirring, and adjust The waste water of flocculation reaction occurs for the flow of good flocculant from person who lives in exile's settling tank;
S5, waste water sedimentation: the waste water flowed into settling tank carries out the settlement treatment of 1.5-2h, obtains supernatant and sediment, clearly The overflow port that water then passes through settling tank top enters discharge pipe, and is flowed into reservoir;
S6, sediment processing: flocky precipitate is pumped into sand filter, aqueous to obtain for removing the water in floccule Lower sludge is measured, the water filtered out is flowed into reservoir by pipeline, and the water in reservoir is transported to sand filter by backwashing pump Inside carries out secondary flushing to sand filter, and flushing water is back in reservoir;
Sludge in sand filter: being pumped into filter press by S7, sediment secondary treatment by taking out pulp pump, obtains pie dirt Mud after drying and is transported outward.
3. a kind of alumina efficient treatment process for waster water with high as claimed in claim 2, it is characterised in that: in the S3 step, in It include calcium oxide, magnesium hydroxide and sodium carbonate, mass ratio 2.2:1.5:1 with agent.
4. a kind of alumina efficient treatment process for waster water with high as claimed in claim 2, it is characterised in that: to sand in the S6 step Filter tank carries out secondary flushing, and flushing water is back in reservoir, the pH value in reservoir is measured with pH test paper, with ferrous sulfate tune It is discharged after section to discharge standard.
5. a kind of alumina efficient treatment process for waster water with high as claimed in claim 2, it is characterised in that: in the S4 step, give up Mass ratio between water and flocculant is between 8:100-10:100.
6. a kind of alumina efficient treatment process for waster water with high as described in claim 1, it is characterised in that: the effluent storage pond with The conducting connection of three oil separators, three oil separator are connected connection with comprehensive adjustment pond, and the No.1 reaction tank and No. two are instead Connection is connected with comprehensive adjustment pond by Ying Chijun, and connection, the flocculation basin and settling tank are connected with flocculation basin for the comprehensive adjustment pond Conducting connection, the settling tank is connected with sand filter to be connected, and the reservoir, which is connected with settling tank and sand filter, to be connected, described Backwashing pump is equipped between reservoir and sand filter, conducting is connected between the sand filter and filter press, the sand filter and filters pressing Pumping pulp pump is installed between machine.
CN201910544823.3A 2019-06-21 2019-06-21 A kind of alumina efficient treatment process for waster water with high Pending CN110330134A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102050536A (en) * 2010-12-03 2011-05-11 东莞市可迪环保科技有限公司 Process for treating electroplating wastewater
CN102795722A (en) * 2012-08-15 2012-11-28 张宏智 Method for treating waste water generated from surface treatment of aluminum products
CN204824302U (en) * 2015-08-01 2015-12-02 浙江江腾环保科技有限公司 PH adjusting device
CN205133304U (en) * 2015-11-20 2016-04-06 江西凯美达铝业有限公司 Aluminium alloy waste water processing cycle utilizes system
CN108017236A (en) * 2017-12-26 2018-05-11 湖南千幻科技有限公司 A kind of High Strength Organic Pharmaceutical Wastewater processing method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102050536A (en) * 2010-12-03 2011-05-11 东莞市可迪环保科技有限公司 Process for treating electroplating wastewater
CN102795722A (en) * 2012-08-15 2012-11-28 张宏智 Method for treating waste water generated from surface treatment of aluminum products
CN204824302U (en) * 2015-08-01 2015-12-02 浙江江腾环保科技有限公司 PH adjusting device
CN205133304U (en) * 2015-11-20 2016-04-06 江西凯美达铝业有限公司 Aluminium alloy waste water processing cycle utilizes system
CN108017236A (en) * 2017-12-26 2018-05-11 湖南千幻科技有限公司 A kind of High Strength Organic Pharmaceutical Wastewater processing method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘国良: "简析铝型材阳极氧化电解着色废水的处理工艺", 《2018年中国铝加工产业年度大会论文集》 *
李玉兰等: "中和―絮凝沉降法处理氧化着色废水 ", 《污染防治技术》 *

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Application publication date: 20191015