CN110327754A - A kind of tunnel stove denitrating system - Google Patents

A kind of tunnel stove denitrating system Download PDF

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Publication number
CN110327754A
CN110327754A CN201910679973.5A CN201910679973A CN110327754A CN 110327754 A CN110327754 A CN 110327754A CN 201910679973 A CN201910679973 A CN 201910679973A CN 110327754 A CN110327754 A CN 110327754A
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CN
China
Prior art keywords
pipe
kiln body
pipeline
mixed
denitrating system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910679973.5A
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Chinese (zh)
Inventor
张久明
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Star Yu Energy-Saving Polytron Technologies Inc
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Star Yu Energy-Saving Polytron Technologies Inc
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Priority to CN201910679973.5A priority Critical patent/CN110327754A/en
Publication of CN110327754A publication Critical patent/CN110327754A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/79Injecting reactants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/004Systems for reclaiming waste heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Treating Waste Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

The invention discloses a kind of tunnel stove denitrating system, including furnace kiln body, there is blast pipe, flue, injector import in blast pipe connection furnace kiln body on furnace kiln body, furnace kiln body blast pipe side is equipped with hydrogenation plant, compressed air source, water tank, reducing agent storage tank;Hydrogenation plant is by adding hydrogen pipeline connection blast pipe;Compressed air source by aerial cooler branch pipe, air vaporizers branch pipe with hydrogenation plant pipeline and access blast pipe;Water tank supplies water, reducing agent storage tank feed, flowmeter is installed on mixed pipe line after water supply pipe is in parallel with reducing agent pipeline, with air purifier branch pipe access air vaporizers branch pipe in parallel again in the middle part of mixed pipe line, the static mixer mixed for water with reducing agent is installed on mixed pipe line;Mixed pipe line end connects broken key machine, and the key machine outlet of breaking passes through the fume high-temperature region of medium pipeline connection furnace kiln body upper end.The minimum discharge of nitrogen oxides may be implemented in the present invention, and design improvement is low in cost, practical.

Description

A kind of tunnel stove denitrating system
Technical field:
The present invention relates to furnace flue gas exhaust apparatus field more particularly to a kind of tunnel stove denitrating systems.
Background technique:
The process of denitrification is gone in combustion product gases, antipollution importance has been used as worldwide ask It inscribes and is shrilly contemplated.The technique for comparing mainstream in the world is divided into: SCR and SNCR.Both techniques are in addition to due to SCR Cause reaction temperature ratio SNCR low outer using catalyst, other have no too big difference, but if from construction cost and operating cost From the point of view of two angles, the investment of SCR is at least the several times that SNCR is put into or even 10 times more than.To prevent in boiler after coal combustion Excessive NOx pollution environment is generated, denitration process should be carried out to coal, is taken off after being divided into burning preceding denitration, combustion process denitration, burning Nitre.
National stove carries out minimum discharge transformation within 2019.New rule boiler emission limit specific requirement: soot dust granule object 10mg/m3, sulfur dioxide 20mg/m3, nitrogen oxides 50mg/m3, stove is the equipment that present stove industry all generallys use, this Kind of stove is unenclosed construction, and stove feeds from front, behind discharge, center is high-temperature region, causes flue gas oxygen content super in this way It marks (18%), also, calcination process is also open type, control flue gas oxygen content is extremely important.
Currently, continuous tunnel furnace kiln air-tightness is excessively poor, flue gas oxygen content reaches 20% or so, and Chinese tradition bag-type dust takes off The method of denitration that the system that a series of equipment such as sulphur tower, SCR, SNCR are constituted uses is single, is unable to reach current minimum discharge It is required that.
For tunnel stove minimum discharge transformation project particularity, complete set renovation technique scheme is designed.
Summary of the invention:
It is more the object of the present invention is to provide a kind of tunnel stove denitrating system in order to make up the deficiency of prior art problem The structurally reasonable arrangement of denitration again, it is compact-sized, the minimum discharge of nitrogen oxides may be implemented, meet national stove in 2019 and carry out Minimum discharge transformation, design improvement is low in cost, practical.
Technical scheme is as follows:
Tunnel stove denitrating system, including furnace kiln body, furnace kiln body lower sidewall, top are respectively provided with blast pipe, flue, into Injector import connection in air hose and furnace kiln body, which is characterized in that the furnace kiln body blast pipe side be respectively equipped with hydrogenation plant, Compressed air source, water tank, reducing agent storage tank;
The hydrogenation plant is by adding hydrogen pipeline connection blast pipe;
The compressed air source by pipeline parallel connection aerial cooler, air vaporizers, wherein aerial cooler branch pipe, Air vaporizers branch pipe with hydrogenation plant pipeline and access blast pipe;
The water tank is fed by the water supply water supplying pump on water supply pipe, reducing agent storage tank by feed pump, is supplied Flowmeter, mixed pipe line middle part and the air purifier are installed on the mixed pipe line after water lines are in parallel with reducing agent pipeline Branch pipe is in parallel again to access air vaporizers branch pipe, is equipped with the static mixing mixed for water with reducing agent on mixed pipe line Device;
The mixed pipe line end connects broken key machine, and the key machine outlet of breaking passes through the flue gas of medium pipeline connection furnace kiln body upper end High-temperature area.
The tunnel stove denitrating system, which is characterized in that the temperature in the fume high-temperature region of the broken kiln body Range is at 880~1250 DEG C.
The tunnel stove denitrating system, which is characterized in that dust-extraction unit, dust-extraction unit are equipped on the flue Flue afterwards is equipped with smoke backflow pipeline, smoke backflow pipeline and hydrogenation plant plus hydrogen pipeline connection.
The tunnel stove denitrating system, which is characterized in that described adds hydrogen pipeline, aerial cooler branch pipe, air Vaporizer branch pipe, water supply pipe, mixed pipe line, is equipped with control valve on smoke backflow pipeline at blast pipe.
The tunnel stove denitrating system, which is characterized in that the hydrogenation plant by adding hydrogen pipeline connection blast pipe, and And the flow of hydrogen is controlled in 40~50m/s in described plus hydrogen pipeline.
The tunnel stove denitrating system, which is characterized in that the compressed air source is connected in parallel nitrogen oxides and breaks key machine, The nitrogen oxides breaks and medium is added in key machine, and when pressure is 0.6MPa, temperature is 220 DEG C.
The tunnel stove denitrating system, which is characterized in that the medium is softened water and foaming agent, and foaming agent is denitration Common foaming, and the ratio of foaming agent and water is 1/10000~1.5/10000.
The tunnel stove denitrating system, which is characterized in that smoke backflow amount is 18%- with air supply volume ratio 32%.
The invention has the advantages that
1, hydrogenation plant of the invention controls opening and closing and flow by valve, before increasing burning according to real work demand NOx reducing agent amount in air inlet improves the removal rate of nitrogen oxides in burning, reduces discharge amount;
2, backflow flue gas in smoke backflow pipeline of the present invention, on the one hand can efficiently use waste heat to enter furnace kiln body in spray Air-flow in emitter is heated, and the amount of oxygen in compressed air on the other hand can be reduced, to improve low nitrogen burning efficiency;
3, storage reducing agent is conventional reduction agent in the market in reducing agent storage tank of the present invention, be can effectively improve burned The reduction of nitrogen oxides in journey, reduces the discharge of nitrogen oxides in effluent;
4, the multiple structurally reasonable arrangement of denitration of the present invention, it is compact-sized, the minimum discharge of nitrogen oxides may be implemented, meet National stove carries out minimum discharge transformation within 2019, and design improvement is low in cost, practical.
Detailed description of the invention:
Fig. 1 is the structural diagram of the present invention.
Specific embodiment:
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Referring to attached drawing 1, tunnel stove denitrating system, including furnace kiln body 1,1 lower sidewall of furnace kiln body, top be respectively provided with into 4 import connection of injector in air hose 2, flue 3, blast pipe 2 and furnace kiln body, 1 blast pipe side of furnace kiln body is respectively equipped with hydrogenation plant 5, compressed air source 6, water tank 7, reducing agent storage tank 8.
Hydrogenation plant 5 usually requires that the flow control for adding hydrogen in hydrogen pipeline 40 by adding hydrogen pipeline connection blast pipe 2 ~50m/s.
Compressed air source 6 passes through pipeline parallel connection aerial cooler 9, air vaporizers 10, wherein aerial cooler branch pipe, sky Gas vaporizer branch pipe with hydrogenation plant pipeline and access blast pipe 2.
Water tank 7 is supplied water by the water supply pump 11 on water supply pipe, and reducing agent storage tank 8 is fed by feed pump 12, is supplied Flowmeter 13, mixed pipe line middle part and air purifier branch are installed on the mixed pipe line after water lines are in parallel with reducing agent pipeline Pipe is in parallel again to access air vaporizers branch pipe, is equipped with the static mixer mixed for water with reducing agent on mixed pipe line 19。
Mixed pipe line end connects broken key machine 14, and key machine 14 outlet of breaking passes through the cigarette of 1 upper end of medium pipeline connection furnace kiln body Gas high-temperature area 15;In addition, the nitrogen oxides in parallel of compressed air source 6 breaks key machine 10, and nitrogen oxides breaks in key machine 10 and is added Medium, and start the temperature-pressure device that nitrogen oxides breaks key machine 10, when pressure reaches 0.6MPa, temperature reaches 220 DEG C;Medium For softened water and foaming agent, foaming agent is denitration common foaming, ratio=1/10000~1.5/10000 of foaming agent and water.
The temperature range in the fume high-temperature region 15 of broken kiln body 1 is at 880~1250 DEG C.Preferably, fume high-temperature region 15 temperature range is controlled in 1000~1050 DEG C.
Dust-extraction unit 16 is installed, the flue after dust-extraction unit 16 is equipped with smoke backflow pipeline 17, and flue gas returns on flue 3 Flow tube road 17 adds hydrogen pipeline connection with hydrogenation plant 5, on the one hand can efficiently use waste heat to injector 4 in entrance furnace kiln body Interior air-flow is heated, and the amount of oxygen in compressed air, smoke backflow amount and air supply body on the other hand can be reduced Product ratio is according to 18%-32% ratio.
Add hydrogen pipeline, aerial cooler branch pipe, air vaporizers branch pipe, blast pipe, water supply pipe, mixed pipe line, flue gas Control valve 18 is equipped on return line 17, each pipeline is deposited according to hydrogenation plant 5, compressed air source 6, water tank 7, reducing agent 8 place branch of storage tank name, 18 quantity of control valve of each branch road according to the actual situation depending on.
The present invention in application process, has the sensor of nitrogen oxides detection NOx component concentration by being arranged in chimney, Sensor acquires data feedback to the controller of DCS control system, is lower than 42mg/m through detection through detection discharged nitrous oxides3
Preferable specific embodiment of the invention is described in detail above.It should be appreciated that those skilled in the art It according to the present invention can conceive without creative work and make many modifications and variations.Therefore, all skills in the art Art personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea Technical solution, all should be within the scope of protection determined by the claims.

Claims (9)

1. a kind of tunnel stove denitrating system, including furnace kiln body, furnace kiln body lower sidewall, top are respectively provided with blast pipe, flue, Injector import connection in blast pipe and furnace kiln body, which is characterized in that the furnace kiln body blast pipe side is respectively equipped with plus hydrogen dress It sets, compressed air source, water tank, reducing agent storage tank;
The hydrogenation plant is by adding hydrogen pipeline connection blast pipe;
The compressed air source passes through pipeline parallel connection aerial cooler, air vaporizers, wherein aerial cooler branch pipe, air Vaporizer branch pipe with hydrogenation plant pipeline and access blast pipe;
The water tank is fed by the water supply water supplying pump on water supply pipe, reducing agent storage tank by feed pump, water supplying pipe Flowmeter, mixed pipe line middle part and the air purifier branch pipe are installed on the mixed pipe line after road is in parallel with reducing agent pipeline It is in parallel again to access air vaporizers branch pipe, the static mixer mixed for water with reducing agent is installed on mixed pipe line;
The mixed pipe line end connects broken key machine, and the key machine outlet of breaking passes through the fume high-temperature of medium pipeline connection furnace kiln body upper end Region.
2. stove denitrating system in tunnel according to claim 1, which is characterized in that the fume high-temperature of the broken kiln body The temperature range in region is at 880~1250 DEG C.
3. stove denitrating system in tunnel according to claim 2, which is characterized in that the fume high-temperature of the broken kiln body The temperature range in region is at 1000~1050 DEG C.
4. stove denitrating system in tunnel according to claim 1, which is characterized in that be equipped with dedusting dress on the flue Set, the flue after dust-extraction unit is equipped with smoke backflow pipeline, smoke backflow pipeline and hydrogenation plant plus hydrogen pipeline connection.
5. stove denitrating system in tunnel according to claim 1, which is characterized in that described adds hydrogen pipeline, air cooling Device branch pipe, blast pipe, water supply pipe, mixed pipe line, is equipped with control valve on smoke backflow pipeline at air vaporizers branch pipe.
6. stove denitrating system in tunnel according to claim 1, which is characterized in that the hydrogenation plant is by adding hydrogen pipeline Connection blast pipe, and the flow of hydrogen is controlled in 40~50m/s in described plus hydrogen pipeline.
7. stove denitrating system in tunnel according to claim 1, which is characterized in that the compressed air source is connected in parallel nitrogen Oxide breaks key machine, and the nitrogen oxides breaks and medium is added in key machine, and when pressure is 0.6MPa, temperature is 220 DEG C.
8. stove denitrating system in tunnel according to claim 7, which is characterized in that the medium is softened water and foaming Agent, foaming agent is denitration common foaming, and the ratio of foaming agent and water is 1/10000~1.5/10000.
9. stove denitrating system in tunnel according to claim 1, which is characterized in that smoke backflow amount and air supply body Product is than being 18%-32%.
CN201910679973.5A 2019-07-26 2019-07-26 A kind of tunnel stove denitrating system Pending CN110327754A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910679973.5A CN110327754A (en) 2019-07-26 2019-07-26 A kind of tunnel stove denitrating system

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Application Number Priority Date Filing Date Title
CN201910679973.5A CN110327754A (en) 2019-07-26 2019-07-26 A kind of tunnel stove denitrating system

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Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5438269A (en) * 1977-09-02 1979-03-22 Toray Ind Inc Treating system for exhaust gas
WO1989007004A1 (en) * 1988-02-02 1989-08-10 Dale Gordon Jones Process and apparatus using two-stage boiler injection for reduction of oxides of nitrogen
SE9401196D0 (en) * 1994-04-11 1994-04-11 Ingvar Nilsson Device for promoting high separation of ammonia in ammonia containing flue gas over textile barrier filter
CN101187475A (en) * 2007-12-28 2008-05-28 上海电力学院 Method for reducing elemental mercury, nitrogen oxide discharging for coal-fired boiler classified recombustion
JP2012120992A (en) * 2010-12-09 2012-06-28 Mitsubishi Heavy Ind Ltd Exhaust gas denitrification apparatus
CN103752160A (en) * 2014-01-28 2014-04-30 上海交通大学 Method for realizing ultra-low emission of NOx of circulating fluidized bed boiler
CN105485664A (en) * 2015-12-07 2016-04-13 山西大学 Composite denitration method and device
CN105642101A (en) * 2016-01-27 2016-06-08 西安航天源动力工程有限公司 Flue gas recirculation and SNCR joint denitration process system
CN106322360A (en) * 2016-09-12 2017-01-11 西安交通大学 Selective non-catalytic reduction (SNCR) and flue gas recirculation coupling denitration system for chain furnace
JP2017131867A (en) * 2016-01-29 2017-08-03 三菱日立パワーシステムズ株式会社 Ammonia treatment device and ammonia treatment method
CN108201778A (en) * 2018-02-09 2018-06-26 石家庄新华能源环保科技股份有限公司 A kind of limekiln combined denitration system
CN108905590A (en) * 2018-08-13 2018-11-30 中国华能集团有限公司 A kind of denitrating system and method for station boiler low NO collaboration high temperature spray ammonia
CN211328841U (en) * 2019-07-26 2020-08-25 启明星宇节能科技股份有限公司 Tunnel furnace denitration system

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5438269A (en) * 1977-09-02 1979-03-22 Toray Ind Inc Treating system for exhaust gas
WO1989007004A1 (en) * 1988-02-02 1989-08-10 Dale Gordon Jones Process and apparatus using two-stage boiler injection for reduction of oxides of nitrogen
SE9401196D0 (en) * 1994-04-11 1994-04-11 Ingvar Nilsson Device for promoting high separation of ammonia in ammonia containing flue gas over textile barrier filter
CN101187475A (en) * 2007-12-28 2008-05-28 上海电力学院 Method for reducing elemental mercury, nitrogen oxide discharging for coal-fired boiler classified recombustion
JP2012120992A (en) * 2010-12-09 2012-06-28 Mitsubishi Heavy Ind Ltd Exhaust gas denitrification apparatus
CN103752160A (en) * 2014-01-28 2014-04-30 上海交通大学 Method for realizing ultra-low emission of NOx of circulating fluidized bed boiler
CN105485664A (en) * 2015-12-07 2016-04-13 山西大学 Composite denitration method and device
CN105642101A (en) * 2016-01-27 2016-06-08 西安航天源动力工程有限公司 Flue gas recirculation and SNCR joint denitration process system
JP2017131867A (en) * 2016-01-29 2017-08-03 三菱日立パワーシステムズ株式会社 Ammonia treatment device and ammonia treatment method
CN106322360A (en) * 2016-09-12 2017-01-11 西安交通大学 Selective non-catalytic reduction (SNCR) and flue gas recirculation coupling denitration system for chain furnace
CN108201778A (en) * 2018-02-09 2018-06-26 石家庄新华能源环保科技股份有限公司 A kind of limekiln combined denitration system
CN108905590A (en) * 2018-08-13 2018-11-30 中国华能集团有限公司 A kind of denitrating system and method for station boiler low NO collaboration high temperature spray ammonia
CN211328841U (en) * 2019-07-26 2020-08-25 启明星宇节能科技股份有限公司 Tunnel furnace denitration system

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