CN110306363A - A kind of free water washing dyeing mill base - Google Patents
A kind of free water washing dyeing mill base Download PDFInfo
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- CN110306363A CN110306363A CN201910660165.4A CN201910660165A CN110306363A CN 110306363 A CN110306363 A CN 110306363A CN 201910660165 A CN201910660165 A CN 201910660165A CN 110306363 A CN110306363 A CN 110306363A
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- mill base
- water washing
- free water
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
- D06P1/625—Aromatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6491—(Thio)urea or (cyclic) derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67358—Halides or oxyhalides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67366—Phosphates or polyphosphates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
The present invention relates to a kind of free water washing dyeing mill bases, by weight include following components: 40-60 parts of solvent, 25-40 parts of binder, 10-30 parts of pigment powder, 3-7 parts of thickener, 2-6 parts of moisturizer, 1-5 parts of ammonium chloride and 1-3 parts of diammonium hydrogen phosphate;The binder includes following components by weight: 40-50 parts of water, 40-50 parts of ETHYL CYANOACRYLATE, 10-20 parts of butyl acrylate, 15-20 parts of acetone, 8-10 parts of xanthan gum, 2-4 parts of acrylonitrile, 1-3 parts of polyacrylamide and 1-3 parts of neopelex.The present invention has the effect of improving mill base tinctorial property.
Description
Technical field
The present invention relates to the technical fields of printing and dyeing ingredient, more particularly, to a kind of free water washing dyeing mill base.
Background technique
Textile printing, which prolongs always, to be attacked wire mark, evaporates, washes, drying, the traditional handicraft of finished product, and evaporating washing is directly to make
Not only water consumption is big for the main reason for sheltering defect at fabric, especially washing process, but also is discharged with a large amount of sewage, causes ring
Border pollution, though it is not yet fundamentally solved although country has changed a large amount of man power and material in environmental protection and undergone technological transformation
Problem.
Major way currently used for solving stamp washing pollution problem is free water washing dyeing stamp, due to evaporating washing
Main purpose is to wash away embryo cloth various auxiliary agents remained on surface, and existing technology improves mill base ingredient, reduces and even disappears
In addition to the addition of auxiliary agent, thus the step of subtracting washing.But the problem that this kind of mill base itself has pigment adhesive force low, it leads
The embryo cloth dyed is caused easily to fade.
Summary of the invention
The object of the present invention is to provide a kind of free water washing dyeing mill base, have the effect of improving mill base tinctorial property.
Above-mentioned technical purpose of the invention has the technical scheme that a kind of free water washing dyeing mill base,
By weight include following components: 40-60 parts of solvent, 10-30 parts of pigment powder, 3-7 parts of thickener, is protected 25-40 parts of binder
2-6 parts of humectant, 1-5 parts of ammonium chloride and 1-3 parts of diammonium hydrogen phosphate;
The binder includes following components by weight: 40-50 parts of water, 40-50 parts of ETHYL CYANOACRYLATE, butyl acrylate 10-
20 parts, 15-20 parts of acetone, 8-10 parts of xanthan gum, 2-4 parts of acrylonitrile, 1-3 parts of polyacrylamide and neopelex
1-3 parts.
It is with water and acetone using ethyl acrylate and butyl acrylate as major ingredient by using above-mentioned technical proposal
Solvent prepares binder;Xanthan gum meets water dispersion, emulsification becomes stable hydrophily thick gel, so as to improve binder
Bond effect;Polyacrylamide is added in binder major ingredient, a large amount of amide groups is had on the main chain of polyacrylamide, makes it
Chemical activity with higher reduces rubbing between liquid to promote the combination between major ingredient and auxiliary material molecular radical
Resistance is wiped, the flocculability and adhesive of binder are improved;Neopelex has good surface-active, parent
It is aqueous relatively strong, interfacial tension is effectively reduced, binder is made to form uniform and stable dispersion;The addition of aluminium oxide is for changing
It is kind;The binder of proper proportion is added, in mill base raw material so as to improve the tinctorial property of mill base.
The present invention is further arranged to: the pigment powder is that mass fraction ratio is 1:(0-2): the magenta-product of (0-2)
Blueness-lemon yellow mixed powder.
By using above-mentioned technical proposal, since pinkish red, product are green and lemon yellow is pigment three primary colors, three primary colors, which have, to be adjusted
The effect for allotting random color mixes pinkish red, product blueness and lemon yellow according to different ratios, to mix different colours
Mill base, the dyeing needs of embryo cloth different colours are met with this.
The present invention is further arranged to: special-shaped 2-6 parts of coloured fiber is added in Xiang Suoshu mill base raw material.
By using above-mentioned technical proposal, coloured fiber is added in mill base, before being dyed, pigment is attached to coloring
On fiber, so as to improve the stability of pigment, meanwhile, coloured fiber is by binder and embryo cloth adhesion, and by pigment molecular band
Enter the inside of fiber molecule in embryo cloth, and with the fiber molecule close-packed arrays in embryo cloth, so as to improve the tinctorial property of mill base.
The present invention is further arranged to: the solvent is that mass fraction ratio is 1:(0.1-0.2) water-ethanol mixed liquor.
By using above-mentioned technical proposal, solvent selects the water-ethanol mixed liquor suitably matched, so as to improve mill base each group
The solubility divided, so that the mill base suspension homogeneous stability prepared.
The present invention is further arranged to: the moisturizer is urea or glycerol.
By using above-mentioned technical proposal, a large amount of nitrogen is contained in urea, protein synthesis is may advantageously facilitate, has
Superpower performance of keeping humidity;Glycerol has good water lock performance as oily organic matter;Since urea and glycerol stocks are inexpensive easily
, consider from cost factor, selects glycerol or urea as moisturizer.
The present invention is further arranged to: the thickener is any in sodium bentonite, organobentonite or diatomite
It is a kind of.
By using above-mentioned technical proposal, sodium bentonite, organobentonite or diatomite are for improving the sticky of mill base
Degree, changes the physical behavior of mill base with this, to improve the stability of mill base suspension;Sodium bentonite, organobentonite or
Diatomite has many advantages, such as that good thixotropy, pH value wide adaptation range, stability are strong, so thrin is selected to make as thickener
With.
In conclusion advantageous effects of the invention are as follows:
1. xanthan gum meets water dispersion, emulsification becomes stable hydrophily thick gel, so as to improve the bond effect of binder;
2. polyacrylamide promotes the combination between major ingredient and auxiliary material molecular radical, the frictional resistance between liquid is reduced,
Improve the flocculability and adhesive of binder;
3. pinkish red, product blueness and lemon yellow are mixed according to different ratios, so that the mill base of different colours is mixed, it is full with this
The dyeing of sufficient embryo cloth different colours needs.
Specific embodiment
Embodiment 1 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Embodiment 2 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Embodiment 3 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Comparative example 1 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Comparative example 2 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Comparative example 3 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Embodiment 4 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Embodiment 5 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Embodiment 6 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Embodiment 7 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Comparative example 4 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight.
Comparative example 5 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Comparative example 6 is a kind of free water washing dyeing mill base disclosed by the invention, by weight includes following components:
Binder includes following components by weight:
Special-shaped coloured fiber section is trilobal, and the structure of trilobal is conducive to increase the surface area of coloured fiber, to improve
Adhesion effect of the pigment on coloured fiber.
Embodiment 1-7 and comparative example the 1-6 mill base prepared are sampled, observe the color of mill base and to mill base
Tinctorial property is detected, and data record is as shown in table 1:
Mill base tinctorial strength is an important indicator, it reflects colour saturation, color development performance and pigment dispersion the flocculation feelings of mill base
Condition;Mill base tinctorial strength generally detects dark (1/1ST waters down) and light color (1/25ST waters down), and numerical value is smaller, and tinting strength, tinting power is higher,
Numerical value represents the mill base grams needed to be added in white basis paint, and white basis paint titanium white content is 25% in emulsion paint;
The data parameters of mill base sample in table 1- embodiment 1-7 and comparative example 1-6
According to data in table 1 of embodiment 1-3 and comparative example 1-3 it is found that addition xanthan gum be conducive to improve mill base
Color power;When xanthan gum additive amount is lower than 8 parts, mill base adds grams and increases, and the coloring dynamics of mill base reduces, and xanthan gum additive amount is big
When 10 parts, it is close with mill base addition grams when adding 10 parts of xanthan gum that mill base adds grams, it is contemplated that cost problem, it is not necessary to
It is further added by the addition number of xanthan gum, so the additive amount of xanthan gum is more appropriate at 8-10 parts;
According to the data of embodiment 1, embodiment 4-7 and comparative example 4-6 in table 1 it is found that the special-shaped coloured fiber of addition is advantageous
In the tinting strength, tinting power for improving mill base;When special-shaped coloured fiber additive amount is lower than 2 parts, mill base adds grams and increases, the tinting strength, tinting power of mill base
Degree reduces, and when special-shaped coloured fiber additive amount is greater than 6 parts, mill base adds mill base when 10 parts of special-shaped coloured fibers of grams and addition
It is close to add grams, it is contemplated that cost problem, it is not necessary to it is further added by the addition number of special-shaped coloured fiber, so special-shaped coloured fiber
Additive amount it is more appropriate at 2-6 parts;
According to the data of mill base color in embodiment 1-7 it is found that by changing the proportion between pinkish red, product blueness and lemon yellow,
The mill base of available different colours meets the different toning demand of mill base with this, to dye the cloth of different colours.
The embodiment of present embodiment is presently preferred embodiments of the present invention, not limits protection of the invention according to this
Range, therefore: the equivalence changes that all structures under this invention, shape, principle are done, should all be covered by protection scope of the present invention it
It is interior.
Claims (6)
1. a kind of free water washing dyeing mill base includes following components: 40-60 parts of solvent, 25-40 parts of binder, pigment by weight
10-30 parts of powder, 3-7 parts of thickener, 2-6 parts of moisturizer, 1-5 parts of ammonium chloride and 1-3 parts of diammonium hydrogen phosphate;
The binder includes following components by weight: 40-50 parts of water, 40-50 parts of ETHYL CYANOACRYLATE, butyl acrylate 10-
20 parts, 15-20 parts of acetone, 8-10 parts of xanthan gum, 2-4 parts of acrylonitrile, 1-3 parts of polyacrylamide and neopelex
1-3 parts.
2. a kind of free water washing dyeing mill base according to claim 1, it is characterised in that: the pigment powder is mass fraction
Than the magenta for 1:(0-2): (0-2)-product blueness-lemon yellow mixed powder.
3. a kind of free water washing dyeing mill base according to claim 1, it is characterised in that: added in Xiang Suoshu mill base raw material different
2-6 parts of shape coloured fiber.
4. a kind of free water washing dyeing mill base according to claim 1, it is characterised in that: the solvent is that mass fraction ratio is
1:(0.1-0.2) water-ethanol mixed liquor.
5. a kind of free water washing dyeing mill base according to claim 1, it is characterised in that: the moisturizer is urea or sweet
Oil.
6. a kind of free water washing dyeing mill base according to claim 1, it is characterised in that: the thickener is Na-bentonite
Any one in soil, organobentonite or diatomite.
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CN201910660165.4A CN110306363A (en) | 2019-07-22 | 2019-07-22 | A kind of free water washing dyeing mill base |
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CN201910660165.4A CN110306363A (en) | 2019-07-22 | 2019-07-22 | A kind of free water washing dyeing mill base |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102864658A (en) * | 2012-09-19 | 2013-01-09 | 吴江市意胜纺织有限公司 | Pigment printing binder |
CN105524524A (en) * | 2016-03-14 | 2016-04-27 | 苏州中徽纳米科技有限公司 | Neutral ink prepared from self-dispersing pigment color paste and preparation method thereof |
CN107938393A (en) * | 2017-11-01 | 2018-04-20 | 浙江圣山科纺有限公司 | A kind of Non-water washing pigment printing umbrella cloth |
-
2019
- 2019-07-22 CN CN201910660165.4A patent/CN110306363A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102864658A (en) * | 2012-09-19 | 2013-01-09 | 吴江市意胜纺织有限公司 | Pigment printing binder |
CN105524524A (en) * | 2016-03-14 | 2016-04-27 | 苏州中徽纳米科技有限公司 | Neutral ink prepared from self-dispersing pigment color paste and preparation method thereof |
CN107938393A (en) * | 2017-11-01 | 2018-04-20 | 浙江圣山科纺有限公司 | A kind of Non-water washing pigment printing umbrella cloth |
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Application publication date: 20191008 |