CN110302745A - A kind of smoke abatement detergent and preparation method thereof - Google Patents
A kind of smoke abatement detergent and preparation method thereof Download PDFInfo
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- CN110302745A CN110302745A CN201910507219.3A CN201910507219A CN110302745A CN 110302745 A CN110302745 A CN 110302745A CN 201910507219 A CN201910507219 A CN 201910507219A CN 110302745 A CN110302745 A CN 110302745A
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- smoke abatement
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/14—Diatomaceous earth
Abstract
The invention discloses a kind of smoke abatement detergents and preparation method thereof.Modified diatomite is used microwave heating treatment by the present invention in the state of wetting, the surface of modified diatomite particle is set to produce many small crackles, the modification infusorial earth particle of the microporous further rinsed using the nitric acid after atomization, the present invention also utilizes the modification infusorial earth particulate load nicotine absorbent and tar destruction agent of microporous, then after mixing water-absorbing resins powder, mixed material, tourmaline, nano-titanium dioxide etc., granular smoke abatement detergent is made；Granular smoke abatement detergent can effectively adsorb the harmful chemical in smoke from cigarette, harmful chemical can be lockked again, it is set to be not easy to be dispersed in air again, the time for making the ingredients such as tourmaline, nano-titanium dioxide, nicotine absorbent have ingredient reacts with harmful chemical, by harmful chemical oxygenolysis at harmless objects such as hydrone, carbon dioxide.
Description
Technical field
The present invention relates to technical field of air purification, in particular to a kind of smoke abatement detergent and preparation method thereof.
Background technique
Secondhand smoke, also known as passive smoking, cigarette smoking refer to and are released by cigarette or other tobacco product fire ends
And by smoker breathe out tobacco smoke be formed by mixing smog.It is also to endanger most extensive, most serious room air
Pollution is the great cause of death in the whole world.Studies have pointed out that secondhand smoke have tar, carbon monoxide, nicotine, suspended particulates,
The harmful chemicals such as PM2.5.Secondhand smoke is actually made of two kinds of smog, and one is the smog of smoker's exhalation, referred to as main
Flow cigarette；One is smog generated when cigarette combustion, referred to as sidestream smoke.Which kind of smog no matter the people of non-smoking suck, and all calculates
Secondhand smoke.It is with object currently used for purifying detergent product mainly active charcoal and the high hydroscopic resin powder of smoke from cigarette
Based on reason absorption, the processing time is long, if storing and handling not in time, the meeting again of the harmful substances such as tar, carbon monoxide for a long time
Again it releases, pollutes environment.
Summary of the invention
The purpose of the present invention is to provide a kind of smoke abatement detergents and preparation method thereof.
In order to solve the above-mentioned technical problem, the technical solution of the present invention is as follows:
In a first aspect, a kind of preparation method of smoke abatement detergent provided by the invention, includes the following steps:
(1) it by calcination processing after diatomite drying, is then placed in hydrochloric acid solution and impregnates 0.5~2 hour, after acidleach
Diatomite, which is put into sodium hydroxide solution, to be impregnated 10~30 minutes, and modification infusorial earth is obtained, after modification infusorial earth is soaked with water,
Microwave heating is to 60~90 DEG C, and insulated and stirred 10~30 minutes, then be rinsed using the nitric acid of atomization, it is washed, dry
After obtain the modified diatom ball of microporous；
(2) after being dispersed in water nicotine absorbent and tar destruction agent, it is modified that step (1) resulting microporous is added
Diatom ball, stirs evenly, and mixed material is made；
(3) following raw materials according to parts by weight: 80~120 parts of water-absorbing resins powder, step (2) resulting mixing are weighed
10~30 parts of material, 3~10 parts of tourmaline, 3~10 parts of nano-titanium dioxide, 5~15 parts of adhesive；By water-absorbing resins powder,
Mixed material, tourmaline, nano-titanium dioxide, adhesive mixing after, under the conditions of 130~250 DEG C mixing, extrusion molding, be granulated
To smoke abatement detergent, finished product is finally packaged into using oilpaper packaging bag.
Preferably, in the step (1), the condition of the calcination processing are as follows: 800~1000 DEG C of calcination temperature, when calcining
Between 1~3 hour.
Preferably, in the step (1), the concentration of the hydrochloric acid solution is 1~2mol/L.
Preferably, in the step (1), the concentration of the sodium hydroxide solution is 1~2mol/L.
Preferably, in the step (1), the weight ratio of the modification infusorial earth and the water is 5~10:1.
Preferably, in the step (2), the nicotine absorbent is graphene oxide.
Preferably, in the step (2), the tar destruction agent is neopelex, sodium secondary alkyl sulfonate, rouge
One of fat alcohol polyoxyethylene ether, secondary alcohol polyoxyethylene ether are a variety of.
Preferably, in the step (2), the nicotine absorbent and the weight ratio of the modified diatom ball of the microporous are
0.5~3:100.
Preferably, in the step (2), the tar destruction agent and the weight ratio of the modified diatom ball of the microporous are
0.5~3:100.
Preferably, in the step (3), the water-absorbing resins powder absorbs water selected from starch xanthate grafted propylene hydrochlorate
Resin, starch graft acrylic acid/acrylamide water-absorbing resin, cross-linking type hydroxyethyl cellulose graft acrylamide polymer,
One of AMPS grafting polyvinyl alcohol water-absorbing resin is a variety of.
It is further preferred that the water-absorbing resins powder is starch graft acrylic acid/acrylamide in the step (3)
Water-absorbing resin.
Preferably, in the step (3), described adhesive is polyurethane binder.
Preferably, in the step (4), the method for being packaged into finished product using oilpaper packaging bag includes the following steps:
Smoke abatement detergent is put into oilpaper packaging bag, it is vertical that the outside of oilpaper packaging bag sets that there are two horizontal sealing side and two
Edge sealing, using packing machine by horizontal sealing side in 160~200 DEG C of condition lower sealing edges, using packing machine by longitudinal sealing side at 130~150 DEG C
Condition lower sealing edge.
Second aspect, a kind of smoke abatement detergent provided by the invention are using smoke abatement detergent as described in relation to the first aspect
Preparation method is made.
Compared with prior art, the beneficial effects of the present invention are:
The present invention is modified diatomite by acidleach, alkali leaching, and by modified diatomite in the state of wetting
Using microwave heating treatment, so that the surface of modified diatomite particle is produced many small crackles, further use
Nitric acid after atomization rinses modified diatomite particle, and the modification infusorial earth particle of finally obtained microporous has porosity
The high and good characteristic of absorption property；The present invention also utilizes the modification infusorial earth particulate load nicotine absorbent and tar of microporous
Particle is made after then mixing water-absorbing resins powder, mixed material, tourmaline, nano-titanium dioxide, adhesive in distintegrant
The smoke abatement detergent of shape, granular smoke abatement detergent can effectively adsorb the harmful chemical in smoke from cigarette, and can
Harmful chemical is lockked, makes it be not easy to be dispersed in air again, makes tourmaline, nano-titanium dioxide, nicotine absorbent
Equal ingredients have the time of ingredient to react with harmful chemical, by harmful chemical oxygenolysis at hydrone, carbon dioxide
Equal harmless objects.
Specific embodiment
Specific embodiments of the present invention will be further explained below.It should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, invention described below
Technical characteristic involved in each embodiment can be combined with each other as long as they do not conflict with each other.
Embodiment 1
A kind of preparation method of smoke abatement detergent provided in this embodiment, includes the following steps:
(1) it will be calcined 2 hours under the conditions of 950 DEG C after diatomite drying, it is molten to be then placed in the hydrochloric acid that concentration is 2mol/L
It is impregnated 1 hour in liquid, the diatomite after acidleach, which is put into the sodium hydroxide solution that concentration is 2mol/L, to be impregnated 20 minutes, is obtained
Modification infusorial earth, according to the ratio that the weight ratio of modification infusorial earth and deionized water is 8:1 by modification infusorial earth deionized water
After wetting, microwave heating is to 70 DEG C, and insulated and stirred 20 minutes, then be rinsed using the nitric acid of atomization, after washed, dry
Obtain the modified diatom ball of microporous；
(2) after dispersing graphene oxide and neopelex in deionized water, it is resulting that step (1) is added
Microporous is modified diatom ball, stirs evenly, and graphene oxide and neopelex is made to enter the modified diatom ball of microporous
Micropore in, mixed material is made, wherein the weight ratio of graphene oxide, neopelex and modified diatom ball is
The weight ratio of 2:2.5:100, graphene oxide and deionized water is 0.2:1；
(3) following raw materials according to parts by weight: starch graft acrylic acid/100 parts of acrylamide water-absorbing resin, step are weighed
Suddenly 25 parts of (2) resulting mixed material, 7 parts of tourmaline, 5 parts of nano-titanium dioxide, 12 parts of adhesive；By water-absorbing resins powder,
Mixed material, tourmaline, nano-titanium dioxide, polyurethane binder mixing after, under the conditions of 230 DEG C mixing, extrusion molding, be granulated
To granular smoke abatement detergent, finished product is finally packaged into using oilpaper packaging bag；
Wherein, the method for being packaged into finished product using oilpaper packaging bag, includes the following steps:
Smoke abatement detergent is put into oilpaper packaging bag, it is vertical that the outside of oilpaper packaging bag sets that there are two horizontal sealing side and two
Edge sealing, using packing machine by horizontal sealing side in 180 DEG C of condition lower sealing edges, using packing machine by longitudinal sealing side in 140 DEG C of condition lower sealing edges.
Embodiment 2
A kind of preparation method of smoke abatement detergent provided in this embodiment, includes the following steps:
(1) the modified diatom ball of microporous is made in the step of repeating embodiment 1 (1)；
(2) after dispersing graphene oxide and neopelex in deionized water, it is resulting that step (1) is added
Microporous is modified diatom ball, stirs evenly, and graphene oxide and neopelex is made to enter the modified diatom ball of microporous
Micropore in, mixed material is made, wherein the weight ratio of graphene oxide, neopelex and modified diatom ball is
3:3:100；
(3) following raw materials according to parts by weight: starch graft acrylic acid/120 parts of acrylamide water-absorbing resin, step are weighed
Suddenly 30 parts of (2) resulting mixed material, 10 parts of tourmaline, 10 parts of nano-titanium dioxide, 15 parts of adhesive；Then according to embodiment
1 the step of (3), is made smoke abatement detergent and is packaged into finished product.
Embodiment 3
A kind of preparation method of smoke abatement detergent provided in this embodiment, includes the following steps:
(1) the modified diatom ball of microporous is made in the step of repeating embodiment 1 (1)；
(2) after dispersing graphene oxide and neopelex in deionized water, it is resulting that step (1) is added
Microporous is modified diatom ball, stirs evenly, and graphene oxide and neopelex is made to enter the modified diatom ball of microporous
Micropore in, mixed material is made, wherein the weight ratio of graphene oxide, neopelex and modified diatom ball is
The weight ratio of 0.5:0.5:100, graphene oxide and deionized water is 0.2:1；
(3) following raw materials according to parts by weight: starch graft acrylic acid/80 parts of acrylamide water-absorbing resin, step are weighed
Suddenly 10 parts of (2) resulting mixed material, 3 parts of tourmaline, 3 parts of nano-titanium dioxide, 5 parts of adhesive；Then according to embodiment 1
Step (3) is made smoke abatement detergent and is packaged into finished product.
Embodiment 4
A kind of preparation method of smoke abatement detergent provided in this embodiment, includes the following steps:
(1) the modified diatom ball of microporous is made in the step of repeating embodiment 1 (1)；
(2) after dispersing graphene oxide and neopelex in deionized water, it is resulting that step (1) is added
Microporous is modified diatom ball, stirs evenly, and graphene oxide and neopelex is made to enter the modified diatom ball of microporous
Micropore in, mixed material is made, wherein the weight ratio of graphene oxide, neopelex and modified diatom ball is
The weight ratio of 1:2:100, graphene oxide and deionized water is 0.2:1；
(3) following raw materials according to parts by weight: starch graft acrylic acid/100 parts of acrylamide water-absorbing resin, step are weighed
Suddenly 24 parts of (2) resulting mixed material, 8 parts of tourmaline, 6 parts of nano-titanium dioxide, 12 parts of adhesive；Then according to embodiment 1
The step of (3) be made and smoke abatement detergent and be packaged into finished product.
Embodiment 5
A kind of preparation method of smoke abatement detergent provided in this embodiment, includes the following steps:
(1) the modified diatom ball of microporous is made in the step of repeating embodiment 1 (1)；
(2) after dispersing graphene oxide and neopelex in deionized water, it is resulting that step (1) is added
Microporous is modified diatom ball, stirs evenly, and graphene oxide and neopelex is made to enter the modified diatom ball of microporous
Micropore in, mixed material is made, wherein the weight ratio of graphene oxide, neopelex and modified diatom ball is
The weight ratio of 2:2.4:100, graphene oxide and deionized water is 0.2:1；
(3) following raw materials according to parts by weight: starch graft acrylic acid/100 parts of acrylamide water-absorbing resin, step are weighed
Suddenly 18 parts of (2) resulting mixed material, 9 parts of tourmaline, 8 parts of nano-titanium dioxide, 12 parts of adhesive；Then according to embodiment 1
The step of (3) be made and smoke abatement detergent and be packaged into finished product.
Embodiment 6
A kind of preparation method of smoke abatement detergent provided in this embodiment, includes the following steps:
(1) the modified diatom ball of microporous is made in the step of repeating embodiment 1 (1)；
(2) after dispersing graphene oxide and neopelex in deionized water, it is resulting that step (1) is added
Microporous is modified diatom ball, stirs evenly, and graphene oxide and neopelex is made to enter the modified diatom ball of microporous
Micropore in, mixed material is made, wherein the weight ratio of graphene oxide, neopelex and modified diatom ball is
The weight ratio of 2:2.4:100, graphene oxide and deionized water is 0.2:1；
(3) following raw materials according to parts by weight: starch graft acrylic acid/100 parts of acrylamide water-absorbing resin, step are weighed
Suddenly 27 parts of (2) resulting mixed material, 5 parts of tourmaline, 8 parts of nano-titanium dioxide, 10 parts of adhesive；Then according to embodiment 1
The step of (3) be made and smoke abatement detergent and be packaged into finished product.
Above the embodiments of the present invention are described in detail, but the present invention is not limited to described embodiments.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more
Kind change, modification, replacement and modification, still fall in protection scope of the present invention.
Claims (10)
1. a kind of preparation method of smoke abatement detergent, which comprises the steps of:
(1) it by calcination processing after diatomite drying, is then placed in hydrochloric acid solution and impregnates 0.5~2 hour, the diatom after acidleach
Soil, which is put into sodium hydroxide solution, to be impregnated 10~30 minutes, and modification infusorial earth is obtained, after modification infusorial earth is soaked with water, microwave
60~90 DEG C, and insulated and stirred 10~30 minutes are heated to, then are rinsed using the nitric acid of atomization, are obtained after washed, dry
To the modified diatom ball of microporous；
(2) after being dispersed in water nicotine absorbent and tar destruction agent, the modified diatom of step (1) resulting microporous is added
Ball stirs evenly, and mixed material is made；
(3) following raw materials according to parts by weight: 80~120 parts of water-absorbing resins powder, step (2) resulting mixed material are weighed
10~30 parts, 3~10 parts of tourmaline, 3~10 parts of nano-titanium dioxide, 5~15 parts of adhesive；By water-absorbing resins powder, mixing
After material, tourmaline, nano-titanium dioxide, adhesive mixing, mixing, extrusion molding, granulation are removed under the conditions of 130~250 DEG C
Cigarette detergent is finally packaged into finished product using oilpaper packaging bag.
2. the preparation method of smoke abatement detergent according to claim 1, which is characterized in that described to forge in the step (1)
Burn the condition of processing are as follows: 800~1000 DEG C of calcination temperature, calcination time 1~3 hour.
3. the preparation method of smoke abatement detergent according to claim 1, which is characterized in that in the step (1), the salt
The concentration of acid solution is 1~2mol/L.
Preferably, in the step (1), the concentration of the sodium hydroxide solution is 1~2mol/L.
Preferably, in the step (1), the weight ratio of the modification infusorial earth and the water is 5~10:1.
4. the preparation method of smoke abatement detergent according to claim 1, which is characterized in that in the step (2), the Buddhist nun
Ancient fourth adsorbent is graphene oxide.
5. the preparation method of smoke abatement detergent according to claim 1, which is characterized in that in the step (2), the coke
Oil decomposition agent is neopelex, sodium secondary alkyl sulfonate, fatty alcohol polyoxyethylene ether, one in secondary alcohol polyoxyethylene ether
Kind is a variety of.
6. the preparation method of smoke abatement detergent according to claim 1, which is characterized in that in the step (2), the Buddhist nun
The weight ratio of ancient fourth adsorbent and the modified diatom ball of the microporous is 0.5~3:100.
7. the preparation method of smoke abatement detergent according to claim 1, which is characterized in that in the step (2), the coke
The weight ratio of oil decomposition agent and the modified diatom ball of the microporous is 0.5~3:100.
8. the preparation method of smoke abatement detergent according to claim 1, which is characterized in that in the step (3), the suction
Water-base resin powder is selected from starch xanthate grafted propylene hydrochlorate water-absorbing resin, starch graft acrylic acid/acrylamide water suction tree
One of rouge, cross-linking type hydroxyethyl cellulose graft acrylamide polymer, AMPS grafting polyvinyl alcohol water-absorbing resin are more
Kind.
9. the preparation method of smoke abatement detergent according to claim 1, which is characterized in that described viscous in the step (3)
Mixture is polyurethane binder.
10. a kind of smoke abatement detergent, which is characterized in that for using such as smoke abatement detergent according to any one of claims 1 to 9
Preparation method be made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910507219.3A CN110302745A (en) | 2019-06-12 | 2019-06-12 | A kind of smoke abatement detergent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910507219.3A CN110302745A (en) | 2019-06-12 | 2019-06-12 | A kind of smoke abatement detergent and preparation method thereof |
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| CN110302745A true CN110302745A (en) | 2019-10-08 |
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| CN201910507219.3A Pending CN110302745A (en) | 2019-06-12 | 2019-06-12 | A kind of smoke abatement detergent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110743337A (en) * | 2019-10-30 | 2020-02-04 | 厦门力嘉诚防水工程有限公司 | A smoke-purifying powder containing graphene for adsorbing and degrading nicotine |
-
2019
- 2019-06-12 CN CN201910507219.3A patent/CN110302745A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110743337A (en) * | 2019-10-30 | 2020-02-04 | 厦门力嘉诚防水工程有限公司 | A smoke-purifying powder containing graphene for adsorbing and degrading nicotine |
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