CN110295508A - The processing method of the low strong waste paper of levels of transition metals high humidity of low content of lignin - Google Patents
The processing method of the low strong waste paper of levels of transition metals high humidity of low content of lignin Download PDFInfo
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- CN110295508A CN110295508A CN201910588657.7A CN201910588657A CN110295508A CN 110295508 A CN110295508 A CN 110295508A CN 201910588657 A CN201910588657 A CN 201910588657A CN 110295508 A CN110295508 A CN 110295508A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
- D21B1/06—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods
- D21B1/08—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods the raw material being waste paper; the raw material being rags
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
- D21B1/12—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
- D21B1/30—Defibrating by other means
- D21B1/32—Defibrating by other means of waste paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/005—Treatment of cellulose-containing material with microorganisms or enzymes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling
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- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Paper (AREA)
Abstract
The present invention is to provide a kind of processing method of the waste paper of high wet strength of low content of lignin, low levels of transition metals, and in particular to is starched using above-mentioned waste paper preparation OCC, and utilizes the coated manila of OCC slurry preparation.Specifically, the coated manila includes surface layer, lining, sandwich layer and bottom, the lining is manufactured paper with pulp by OCC slurry.The present invention prepares advanced coated manila, low in cost, simple production process using OCC slurry.Simultaneously, using enzyme modification and the modified OCC slurry of addition cationic polymer, the physical property of white board is for single modification mode, there is raising by a relatively large margin, and the additive amount of optimal enzyme processing time, concentration and cationic polymer is found out by experiment, further collaboration improves the physical property of paper, obtains excellent effect, has good market prospects.
Description
Technical field
The present invention relates to pulping and paper-making production technical field, in particular to a kind of low content of lignin, low transition metal contain
The processing method of the waste paper of the high wet strength of amount, and in particular to starched using above-mentioned waste paper preparation OCC, and utilize OCC slurry preparation
Coated manila.
Background technique
Coated manila is the coating for having good absorption to ink at one layer of covering of paper surface coating, to be had
There is the paper of good uniformity and smoothness, while improving the whiteness of paper, glossiness, improves paper printing ink absorbability and not
Transparency, so as to improve the printability of paper, defect itself that improve printing effect, make up body paper.Coating is mostly with kaolin, carbon
Based on the white pigments such as sour calcium, barium sulfate and titanium dioxide, in addition various adhesives and being incorporated various chemistry as needed
Adjuvant and be modulated into, by it is a certain amount of equably coating be covered on Paper or cardboard surface, processed through ornamenting to be formed meet it is a variety of
The coated manila of demand.
White board generally comprises surface layer, lining, sandwich layer and bottom, and first layer is surface layer slurry, it is desirable that whiteness is high, has certain
Intensity, generally use masson pine or with addition of partial bleaching chemistry straw pulp and blank sheet of paper side secondary stock；The second layer is lining
Layer, also requires certain whiteness, usually with 100% groundwood pulp or light secondary stock；Third layer is sandwich layer, main to play filling
Effect generally uses mixed waste pulp or straw pulp to increase the thickness of cardboard, and the last layer is bottom, and having improves outside cardboard
It sees, improves intensity, be usually that raw material is manufactured paper with pulp with high yield pulp or preferable secondary stock, cardboard bottom surface color multidigit grey can also
Other bottom surfaces color is produced as required.
The quality of coated manila and original paper quality are closely related, and there are many raw material variety for producing coated manila body paper,
It is raw material of wood pulp that China's coated white paperboard, which produced the used raw material overwhelming majority, in the past, with the shortage of timber resources, wood pulp
Price is continuously increased, and many enterprises is promoted to have to find wastepaper as raw material that is more cheap and can guaranteeing product quality, example
Such as, the useless 3# of import ONP (Old News Paper, old newsprint) such as U.S., the useless 6# of U.S., the useless 8# of U.S., the useless 9# and OMG (Old of U.S.
Magazine, outdated magazine) etc. for bottom or sandwich layer slurry raw material, still, the production of ONP slurry, water consume power consumption is big, deinking chemical industry
Supplementary product onsumption, deslagging draining are more, and slag and effluent environmental protection treatment is costly, cause ONP tons of slurry overall costs high.In order to solve this
Problem, generalling use the less expensive OCC slurry of preparation cost in the prior art, (Old Corrugated Container, give up boxboard
Paper) as substitution.However, the raw material of boxboard be generally also be prepared by reclaimed waste paper, the increase of waste paper recycling number,
Fibre swelling is difficult, and intensity decline, water filtering performance reduces, and fiber keratinization reduces fiber bonding strength, seriously affect slurrying
Paper production is unable to satisfy industry requirement.
In the prior art in order to improve reclaimed waste paper, such as the fibre strength in OCC slurry, it will usually use drying strengthening agent conduct
Additive is improved, and drying strengthening agent is usually to have water-soluble, hydrophilic natural or synthetic polymer.It is common dry strong
Agent has cationic starch (CS) and polyvinyl alcohol (PVA).Drying strengthening agent can improve knot in several ways with fiber interaction
Close intensity.But fibre strength in OCC slurry is improved using drying strengthening agent or there are complex process, the problem of higher cost,
Limitation is improved for the fibre strength in OCC slurry, it is difficult to meet the requirement of industrial production high quality white board.
It can be seen that obtaining a kind of method for improving the fibre strength in OCC slurry of simple process and low cost, in turn
High quality coated manila is produced, is this field urgent problem.
Summary of the invention
The present invention produces work existing for coated manila to solve to starch using reclaimed waste paper, such as OCC in the prior art
Skill is complicated, higher cost, and the white board fibre strength produced is not high, it is difficult to meet requirement etc. of the market for ivory
Problem provides a kind of coated manila and preparation method thereof, and coated manila of the invention is a certain amount of by adding in starching to OCC
Cationic polymer and combine cellulase treatment, so that coated manila is obtained good physical property.
In one embodiment, the present invention provides a kind of coated manila, the lining is manufactured paper with pulp by OCC slurry,
The OCC slurry is handled using cellulase and lignoenzyme, and adds cationic polymer P (St-BA-AA-GMA), institute
The dosage for stating cellulase is 50-100IU/g, and lignoenzyme dosage is 20-40IU/g, and P (St-BA-AA-GMA's) adds
Dosage is 0.5%-2%.
The OCC slurry is made of using waste paper as raw material, it is preferred that can be selected from low content of lignin and/or low transition gold
Belong to the waste paper of the high wet strength of content, it is furthermore preferred that the waste paper is waste and old corrugated paper.
In one embodiment, the time that the cellulase and lignoenzyme are handled is 60-120min.
In one embodiment, the dosage of the cellulase is 92IU/g, and lignoenzyme dosage is 33IU/g.
In one embodiment, the time that the cellulase and lignoenzyme are handled is 90min, it is preferred that
The additive amount of the P (St-BA-AA-GMA) is 1.5%.
The fibre that the cellulase and lignoenzyme can be enzyme well known in the prior art or commercial sources can be bought
Tie up plain enzyme and lignoenzyme.
The P (St-BA-AA-GMA) is that a kind of cationic polymer is used on fiber in the prior art
Absorption film-forming passes through styrene (St), butyl acrylate (BA), acrylic acid for purposes such as fibre modification, pigment dyeings
(AA), glycidyl methacrylate (GMA) is monomer, and hexadecyltrimethylammonium chloride (CTAC) is emulsifier, azo
Diisobutyl miaow hydrochloride (AIBA) is initiator, has synthesized cationic P (St-BA-AA- using semi-continuous emulsion polymerization
GMA), specific preparation method may refer to " synthesis of cationic P (St-BA-AA-GMA) lotion and its fixation work to coating
With " Song Tingle, University Of Qingdao's master thesis, 2015 ", and by corresponding adjustment, it is specific as follows:
It is passed through nitrogen, deionized water, the emulsifier dissolved and sodium acetate buffer agent is added, opens agitating device stirring,
It is uniformly dissolved emulsifier in water；Then St, BA, AA mix monomer being incorporated as, pre-emulsification are warming up to (80 after a certain period of time
± 1) remaining GMA, BA, St mix monomer (rate of addition is controlled in 5s/ drop) DEG C, is added dropwise, while the AIBA dissolved is added dropwise
Initiator keeps pH between 6~8 by the way that sodium acetate buffer agent is added.In 80 DEG C of reaction 3.5h, Temperature fall after completion of dropwise addition
It discharges to 40~50 DEG C, wherein the dosage of St, BA, AA, GMA are 7:11:0.2:1.8
In one embodiment, the surface layer of the white board pair includes ONP slurry and DIP slurry is surface layer slurry, wherein ONP
The use ratio of slurry and DIP slurry is 2:1；Lining includes ONP slurry and OCC slurry is lining slurry, and what wherein ONP slurry and OCC were starched makes
It is 1:1 with ratio；Bottom includes ONP slurry and OCC slurry is lining slurry, and wherein the use ratio of ONP slurry and OCC slurry is 1:3.
In one embodiment, the present invention provides a kind of preparation method of coated manila, which is characterized in that the step
It is rapid as follows:
(1) preparation of ONP slurry, DIP slurry, OCC slurry；
(2) slurry preparation of surface layer, lining, sandwich layer and bottom
(3) body paper is manufactured paper with pulp；
(4) coating, soft calendaring, batch.
In one embodiment, in the step (1), the OCC is starched at using cellulase and lignoenzyme
Reason, and cationic polymer P (St-BA-AA-GMA) is added, the dosage of the cellulase is 50-100IU/g, lignoenzyme
Dosage is 20-40IU/g, and the additive amount of the P (St-BA-AA-GMA) is 0.5%-2%.
In one embodiment, in preparation method, the time that the cellulase and lignoenzyme are handled is
60-120min。
In one embodiment, in preparation method, the dosage of the cellulase is 92IU/g, lignoenzyme dosage
For 33IU/g, it is preferred that the time that the cellulase and lignoenzyme are handled is 90min, it is further preferred that described
The additive amount of P (St-BA-AA-GMA) is 1.5%.
In one embodiment, the preparation step of the OCC slurry is as follows:
A. using domestic waste and old corrugated paper as raw material, through size degradation, screening, slagging-off, concentration, heat partition obtains OCC slurry；
B. OCC slurry is handled using cellulase and lignoenzyme, OCC slurry is adjusted to concentration 4-8wt%, addition
Cellulase and lignoenzyme are handled, and 50 DEG C for the treatment of temperature, pH=8, the processing time is 90min, the cellulase
Dosage is 92IU/g, when lignoenzyme dosage is 33IU/g.
C. addition cationic polymer is modified OCC slurry, and the cationic polymer is P (St-BA-AA-GMA),
With styrene (St), butyl acrylate (BA), acrylic acid (AA), glycidyl methacrylate (GMA) for monomer, hexadecane
Base trimethyl ammonium chloride (CTAC) is emulsifier, and azo diisobutyl miaow hydrochloride (AIBA) is initiator, using semicontinuous cream
Liquid polymerization has synthesized cationic polymer P (St-BA-AA-GMA), is P (St-BA-AA-GMA) configuration by cationic polymer
At the lotion of 2g/L, it is added in the OCC slurry handled in step b through cellulase and lignoenzyme, specific dosage is 1.5%,
It is spare and at 25 DEG C of room temperature after stirring 40min.
Compared with prior art, present invention has the advantage that the present invention prepares advanced coated manila using OCC slurry,
It is low in cost, simple production process.Meanwhile using enzyme modification and the modified OCC slurry of addition cationic polymer, the physics of white board
Performance is for single modification mode, when having raising by a relatively large margin, and finding out optimal enzymatic treatment by experiment
Between, the additive amount of concentration and cationic polymer, further collaboration improves the physical property of paper, obtains good effect
Fruit has good market prospects.
Specific embodiment
It is described in detail below by way of the effect of preferred forms of the invention to coated manila of the invention, but
It is that the following contents should not be construed as limiting the scope of the invention.
A kind of preparation method of the advanced coated manila of the good physical properties of embodiment 1
The present embodiment provides one kind by being modified to sandwich layer OCC slurry, and obtains a kind of the advanced of good physical properties
The preparation method of coated manila
Specific step is as follows:
1, the preparation of various slurries:
(1) preparation of ONP slurry: using Japanese 3#, the useless 8# of U.S. as raw material, the weight ratio of the useless 8# of Japanese 3#, U.S. is 3:7, described
Raw material crosses bale opener and tentatively selects reason, with rotary drum pulping machine size degradation at paper pulp, removes the gred by highly concentrated slag removing system, scalping goes to clean
Matter after scalping, carries out washing removal ink, carries out flotation subsequently into flotation cell, screen by three sections of fine screens, concentration is sent to
Heat dispersion machine carries out heat partition with the sticky matter in dispersed paste, and treated, and slurry enters stock tank, spare；
The ONP starches freedom 210csf, whiteness value 40ISO, impure point content 980mm2/m2；
(2) preparation of DIP slurry: using the useless 3# of U.S., the useless 8# of U.S. as raw material, the useless 3# of U.S., the useless 8# of U.S. weight ratio be 1:1, it is described
Raw material crosses bale opener and tentatively selects reason, is sent to rotary drum pulping machine size degradation into paper pulp, screens impurity by scalping, good after screening starch into
Enter scummer slagging-off, carries out washing deinking processing and carry out flotation processing after two sections of fine screens are screened, be sent into after flotation processing dense
The concentration of contracting machine is then delivered to heat dispersion machine and carries out heat partition with the sticky matter in dispersed paste, to slurry after dirt count
Material carries out highly concentrated oxidation bleaching, and thickener concentration is again introduced into after oxidation bleaching, carries out reducing bleach to the slurry after concentration,
Through reducing bleach, treated that slurry enters stock tank, spare.
The DIP starches freedom 230csf, whiteness value 55ISO, impure point content 800mm2/m2
(3) preparation of OCC slurry:
A. using domestic waste and old corrugated paper as raw material, the raw material crosses bale opener and tentatively selects reason, is sent to rotary drum pulping machine size degradation
At paper pulp, impurity is screened by scalping, the good slurry after screening enters scummer slagging-off, carries out flotation after two sections of fine screens are screened
Processing, flotation processing after be sent into thickener concentration, be then delivered to heat dispersion machine carry out heat partition in dispersed paste sicker,
The heat such as oily wax melt object, and treated, and slurry enters stock tank, spare；The beating degree of the OCC slurry is 48.5 ° of SR.
B. OCC slurry is handled using cellulase and lignoenzyme, OCC slurry is adjusted to concentration 4-8wt%, addition
Cellulase and lignoenzyme are handled, and 40-60 DEG C for the treatment of temperature, pH=6-9, the processing time is 60-120min, the fibre
The dosage for tieing up plain enzyme is 50-100IU/g, and lignoenzyme dosage is 20-40IU/g.
C. addition cationic polymer is modified OCC slurry, and the cationic polymer is P (St-BA-AA-GMA),
With styrene (St), butyl acrylate (BA), acrylic acid (AA), glycidyl methacrylate (GMA) for monomer, hexadecane
Base trimethyl ammonium chloride (CTAC) is emulsifier, and azo diisobutyl miaow hydrochloride (AIBA) is initiator, using semicontinuous cream
Liquid polymerization has synthesized cationic polymer P (St-BA-AA-GMA), method particularly includes:
It is passed through nitrogen, deionized water, the emulsifier dissolved and sodium acetate buffer agent is added, opens agitating device stirring,
It is uniformly dissolved emulsifier in water；Then St, BA, AA mix monomer is added, pre-emulsification is warming up to (80 ± 1) after a certain period of time
DEG C, remaining GMA, BA, St mix monomer (rate of addition is controlled in 5s/ drop) is added dropwise, while the AIBA dissolved is added dropwise and causes
Agent keeps pH between 6~8 by the way that sodium acetate buffer agent is added.In 80 DEG C of reaction 3.5h after completion of dropwise addition, it is naturally cooling to 40
~50 DEG C of dischargings, wherein the dosage of St, BA, AA, GMA are 7:11:0.2:1.8；
It is the lotion that P (St-BA-AA-GMA) is configured to 2g/L by cationic polymer, is added in step b through cellulose
In enzyme and the OCC slurry of lignoenzyme processing, specific dosage is 0.5%-2% (relative to absolute dry pulp), and at 25 DEG C of room temperature
It is spare after stirring 20min-60min.
2. the slurry preparation of different levels
Surface layer slurry is prepared: being starched with the ONP slurry and DIP of above-mentioned steps preparation as surface layer slurry, wherein ONP slurry and DIP slurry
Use ratio be 2:1, weight with slurry be 32.9g/m2；
Lining slurry preparation is with slurry: with above-mentioned steps preparation ONP slurry and OCC slurry be lining slurry, wherein ONP slurry and
The use ratio of OCC slurry is 1:1, and weight with slurry is 21.2g/m2；
Center stock is prepared with slurry: being starched with the OCC of above-mentioned steps preparation as center stock, sandwich layer quantitative 96g/m with slurry2；
Base pastes prepare it is with slurry: with above-mentioned steps preparation ONP slurry and OCC slurry be lining slurry, wherein ONP slurry and
The use ratio of OCC slurry is 1:3, and weight with slurry is 31.6g/m2；
3. body paper is manufactured paper with pulp:
Each layer slurry is transported to paper machine slurry flowing box by respective feeding system, by certain density above layers slurry
Upper four formable layers net forms l Water Paper page, carries out body paper through squeezing, front baking cadre, top sizing, hard press polish and manufactures paper with pulp, body paper weight
For 410g/m2；
4. coating, is batched soft calendaring:
Bodystock paper after above-mentioned hard press polish is sent to curtain coater, it is enterprising in the positive glue application layer of the bodystock paper
Row curtain coating forms curtain coating, and the bodystock paper for forming curtain coating is then sent to knife type coater progress blade coating and is formed
Finishing coat, wherein the coating weight of curtain coating is 11g/m2, the coating weight of finishing coat is 15g/m2.Coating complete after through soft calendaring,
It batches, rewinding storage.
The modified OCC of the different enzyme concentrations of embodiment 2 starches the influence to white board physical property
In order to probe into influence of the modified OCC slurry of different enzyme concentrations to white board physical property, make every effort to search out most suitable
Enzymatic treatment concentration, the present embodiment use following experimental design:
OCC slurry preparation in, handled using the cellulase and lignoenzyme of various concentration, and remove to
The step of adding cationic polymer in OCC slurry, to analyze and determine most suitable enzymatic treatment concentration, specific enzyme concentration additive amount
As shown in table 1,
The additive amount of 1 OCC of table slurry cellulase and lignoenzyme
Above-mentioned various concentration, 3 parallel laboratory tests of every group of setting, specific step is as follows
1, the preparation of various slurries:
(1) preparation of ONP slurry: using Japanese 3#, the useless 8# of U.S. as raw material, the weight ratio of the useless 8# of Japanese 3#, U.S. is 3:7, described
Raw material crosses bale opener and tentatively selects reason, with rotary drum pulping machine size degradation at paper pulp, removes the gred by highly concentrated slag removing system, scalping goes to clean
Matter after scalping, carries out washing removal ink, carries out flotation subsequently into flotation cell, screen by three sections of fine screens, concentration is sent to
Heat dispersion machine carries out heat partition with the sticky matter in dispersed paste, and treated, and slurry enters stock tank, spare；
The ONP Deinking Pulp freedom 210csf, whiteness value 40ISO, impure point content 980mm2/m2；
(2) preparation of DIP slurry: using the useless 3# of U.S., the useless 8# of U.S. as raw material, the useless 3# of U.S., the useless 8# of U.S. weight ratio be 1:1, it is described
Raw material crosses bale opener and tentatively selects reason, is sent to rotary drum pulping machine size degradation into paper pulp, screens impurity by scalping, good after screening starch into
Enter scummer slagging-off, carries out washing deinking processing and carry out flotation processing after two sections of fine screens are screened, be sent into after flotation processing dense
The concentration of contracting machine is then delivered to heat dispersion machine and carries out heat partition with the sticky matter in dispersed paste, to slurry after dirt count
Material carries out highly concentrated oxidation bleaching, and thickener concentration is again introduced into after oxidation bleaching, carries out reducing bleach to the slurry after concentration,
Through reducing bleach, treated that slurry enters stock tank, spare.
The DIP starches freedom 230csf, whiteness value 55ISO, impure point content 800mm2/m2
(3) preparation of OCC slurry:
A. using domestic waste and old corrugated paper as raw material, the raw material crosses bale opener and tentatively selects reason, is sent to rotary drum pulping machine size degradation
At paper pulp, impurity is screened by scalping, the good slurry after screening enters scummer slagging-off, carries out flotation after two sections of fine screens are screened
Processing, flotation processing after be sent into thickener concentration, be then delivered to heat dispersion machine carry out heat partition in dispersed paste sicker,
The heat such as oily wax melt object, and treated, and slurry enters stock tank, spare；The beating degree of the OCC slurry is 48.5 ° of SR.
B. OCC slurry is handled using cellulase and lignoenzyme, OCC slurry is adjusted to concentration 4-8wt%, addition
Cellulase and lignoenzyme are handled, 50 DEG C for the treatment of temperature, pH=8, the processing time be 60min, the cellulase and
The dosage ginseng of lignoenzyme is shown in Table 1.
2. the slurry preparation of different levels
Surface layer slurry is prepared: being starched with the ONP slurry and DIP of above-mentioned steps preparation as surface layer slurry, wherein ONP slurry and DIP slurry
Use ratio be 2:1, weight with slurry be 32.9g/m2；
Lining slurry preparation is with slurry: with above-mentioned steps preparation ONP slurry and OCC slurry be lining slurry, wherein ONP slurry and
The use ratio of OCC slurry is 1:1, and weight with slurry is 21.2g/m2；
Center stock is prepared with slurry: being starched with the OCC of above-mentioned steps preparation as center stock, sandwich layer quantitative 96g/m with slurry2；
Base pastes prepare it is with slurry: with above-mentioned steps preparation ONP slurry and OCC slurry be lining slurry, wherein ONP slurry and
The use ratio of OCC slurry is 1:3, and weight with slurry is 31.6g/m2；
3. body paper is manufactured paper with pulp:
Each layer slurry is transported to paper machine slurry flowing box by respective feeding system, by certain density above layers slurry
Upper four formable layers net forms l Water Paper page, carries out body paper through squeezing, front baking cadre, top sizing, hard press polish and manufactures paper with pulp, body paper weight
For 410g/m2；
4. coating, is batched soft calendaring:
Bodystock paper after above-mentioned hard press polish is sent to curtain coater, it is enterprising in the positive glue application layer of the bodystock paper
Row curtain coating forms curtain coating, and the bodystock paper for forming curtain coating is then sent to knife type coater progress blade coating and is formed
Finishing coat, wherein the coating weight of curtain coating is 11g/m2, the coating weight of finishing coat is 15g/m2.Coating complete after through soft calendaring,
It batches, rewinding storage.
5. white board testing result
The physical property of the white board 1- white board 12 prepared using the above method is detected, the physics specifically detected
Performance indicator is quantitative, lateral stiffness, folding strength (transverse direction) burst index, interlaminar strength, ring crush index, wherein
Coated manila is quantitative to be detected according to GB/T 451.2；
The burst index of coated manila is detected according to GB/T 1539；
The ring crush index of coated manila is detected according to GB/T 2679.8；
The folding test of coated manila is carried out according to the measurement of GB/T 1539-2007 cardboard bursting strength
The interlaminar strength of coated manila is according to the GB/T 26203-2010 " measurement of paper and cardboard internal bond strength
(Scott) " it measures；
The stiffness of coated manila is measured according to GB/T 22364-2008 " measurement of paper and cardboard bending break stiffness "
The physical property of the white board of the OCC slurry preparation of different enzyme concentration processing is as shown in table 2
The physical property of 2 white board 1- white board 12 of table
The result shown from table 2 can be seen that the white board by the OCC slurry preparation of enzymatic treatment, and (OCC is starched not with control group
It is enzyme treated) it compares, physical properties parameter is improved, this explanation, cellulase and lignoenzyme Combined Treatment OCC
Slurry is conducive to the physical property for improving the white board of its preparation.Further, it can also be seen that as enzyme is dense from the result of table 2
The physical property of the promotion of degree, white board also increases accordingly, still, when enzyme concentration is increased to it is a certain amount of when, continue growing enzyme
Concentration can be such that the physical property of white board declines instead, and analysis reason may be that cellulase and lignoenzyme eliminate OCC slurry
Middle fiber fines improve the content of medium-length fibre, are conducive to the physical property for improving white board, still, enzyme concentration therewith
It further increases, medium-length fibre also will receive corresponding influence, the physical property of white board can instead declined.From the knot of table 2
It can be obtained in fruit, the dosage of cellulase is that 92IU/g is prepared when lignoenzyme dosage is 33IU/g (white board 10)
White board physical property is best.
The modified OCC of the different enzyme processing times of embodiment 3 starches the influence to white board physical property
In order to probe into influence of the modified OCC slurry of different enzyme processing times to white board physical property, makes every effort to search out and most close
Suitable enzyme processing time, the present embodiment use following experimental design:
In the preparation of OCC slurry, use the dosage of cellulase for 92IU/g, lignoenzyme dosage is the mixing of 33IU/g
Enzyme solutions are handled, and set different enzyme processing times, while removing the step that cationic polymer is added into OCC slurry from
Suddenly, to analyze and determine most suitable enzyme processing time, specific enzyme processing time is as shown in table 3,
The processing time of 3 OCC of table slurry cellulase and lignoenzyme
Above-mentioned various concentration, 3 parallel laboratory tests of every group of setting, specific step is as follows
1, the preparation of various slurries:
(1) preparation of ONP slurry: using Japanese 3#, the useless 8# of U.S. as raw material, the weight ratio of the useless 8# of Japanese 3#, U.S. is 3:7, described
Raw material crosses bale opener and tentatively selects reason, with rotary drum pulping machine size degradation at paper pulp, removes the gred by highly concentrated slag removing system, scalping goes to clean
Matter after scalping, carries out washing removal ink, carries out flotation subsequently into flotation cell, screen by three sections of fine screens, concentration is sent to
Heat dispersion machine carries out heat partition with the sticky matter in dispersed paste, and treated, and slurry enters stock tank, spare；
The ONP Deinking Pulp freedom 210csf, whiteness value 40ISO, impure point content 980mm2/m2；
(2) preparation of DIP slurry: using the useless 3# of U.S., the useless 8# of U.S. as raw material, the useless 3# of U.S., the useless 8# of U.S. weight ratio be 1:1, it is described
Raw material crosses bale opener and tentatively selects reason, is sent to rotary drum pulping machine size degradation into paper pulp, screens impurity by scalping, good after screening starch into
Enter scummer slagging-off, carries out washing deinking processing and carry out flotation processing after two sections of fine screens are screened, be sent into after flotation processing dense
The concentration of contracting machine is then delivered to heat dispersion machine and carries out heat partition with the sticky matter in dispersed paste, to slurry after dirt count
Material carries out highly concentrated oxidation bleaching, and thickener concentration is again introduced into after oxidation bleaching, carries out reducing bleach to the slurry after concentration,
Through reducing bleach, treated that slurry enters stock tank, spare.
The DIP starches freedom 230csf, whiteness value 55ISO, impure point content 800mm2/m2
(3) preparation of OCC slurry:
A. using domestic waste and old corrugated paper as raw material, the raw material crosses bale opener and tentatively selects reason, is sent to rotary drum pulping machine size degradation
At paper pulp, impurity is screened by scalping, the good slurry after screening enters scummer slagging-off, carries out flotation after two sections of fine screens are screened
Processing, flotation processing after be sent into thickener concentration, be then delivered to heat dispersion machine carry out heat partition in dispersed paste sicker,
The heat such as oily wax melt object, and treated, and slurry enters stock tank, spare；The beating degree of the OCC slurry is 48.5 ° of SR.
B. OCC slurry is handled using cellulase and lignoenzyme, OCC slurry is adjusted to concentration 4-8wt%, addition
Cellulase and lignoenzyme are handled, and 50 DEG C for the treatment of temperature, pH=8, the dosage of cellulase is 92IU/g, lignoenzyme
Dosage is 33IU/g, and the processing time is that ginseng is shown in Table 3.
2. the slurry preparation of different levels
Surface layer slurry is prepared: being starched with the ONP slurry and DIP of above-mentioned steps preparation as surface layer slurry, wherein ONP slurry and DIP slurry
Use ratio be 2:1, weight with slurry be 32.9g/m2；
Lining slurry preparation is with slurry: with above-mentioned steps preparation ONP slurry and OCC slurry be lining slurry, wherein ONP slurry and
The use ratio of OCC slurry is 1:1, and weight with slurry is 21.2g/m2；
Center stock is prepared with slurry: being starched with the OCC of above-mentioned steps preparation as center stock, sandwich layer quantitative 96g/m with slurry2；
Base pastes prepare it is with slurry: with above-mentioned steps preparation ONP slurry and OCC slurry be lining slurry, wherein ONP slurry and
The use ratio of OCC slurry is 1:3, and weight with slurry is 31.6g/m2；
3. body paper is manufactured paper with pulp:
Each layer slurry is transported to paper machine slurry flowing box by respective feeding system, by certain density above layers slurry
Upper four formable layers net forms l Water Paper page, carries out body paper through squeezing, front baking cadre, top sizing, hard press polish and manufactures paper with pulp, body paper weight
For 410g/m2；
4. coating, is batched soft calendaring:
Bodystock paper after above-mentioned hard press polish is sent to curtain coater, it is enterprising in the positive glue application layer of the bodystock paper
Row curtain coating forms curtain coating, and the bodystock paper for forming curtain coating is then sent to knife type coater progress blade coating and is formed
Finishing coat, wherein the coating weight of curtain coating is 11g/m2, the coating weight of finishing coat is 15g/m2.Coating complete after through soft calendaring,
It batches, rewinding storage.
5. white board testing result
The physical property of the white board 13- white board 18 prepared using the above method is detected, the object specifically detected
Managing performance indicator is quantitative, lateral stiffness, folding strength (transverse direction) burst index, interlaminar strength, ring crush index, wherein
Coated manila is quantitative to be detected according to GB/T 451.2；
The burst index of coated manila is detected according to GB/T 1539；
The ring crush index of coated manila is detected according to GB/T 2679.8；
The folding test of coated manila is carried out according to the measurement of GB/T 1539-2007 cardboard bursting strength
The interlaminar strength of coated manila is according to the GB/T 26203-2010 " measurement of paper and cardboard internal bond strength
(Scott) " it measures；
The stiffness of coated manila is measured according to GB/T 22364-2008 " measurement of paper and cardboard bending break stiffness "
The physical property of the white board of the OCC slurry preparation of different enzyme processing times is as shown in table 4
The physical property of 4 white board 13- white board 18 of table
It can also be seen that the extension with enzyme processing time from the result of table 4, the physical property of white board also mentions therewith
Height, still, after enzyme processing time is more than 95min, the processing time for continuing growing enzyme can make the physical property of white board instead
The reason of declining, causing this phenomenon may be identical with the reason of increasing enzyme concentration, i.e. cellulase and lignoenzyme eliminates
Fiber fines in OCC slurry, improve the content of medium-length fibre, are conducive to the physical property for improving white board, still, at enzyme
The extension of time is managed, medium-length fibre also will receive corresponding influence, the physical property of white board can instead declined.From table 4
As a result it can be obtained in, when the dosage of cellulase is 92IU/g, and lignoenzyme dosage is 33IU/g, best enzyme processing time is
90min (i.e. white board 16).
The modified OCC of the additive amount of the different cationic polymer P (St-BA-AA-GMA) of embodiment 4 is starched to white board physics
The influence of performance
The modified OCC of additive amount in order to probe into different cationic polymer P (St-BA-AA-GMA) is starched to white board object
The influence of rationality energy, makes every effort to the additive amount for searching out most suitable cationic polymer P (St-BA-AA-GMA), the present embodiment is adopted
With following experimental design:
In the preparation of OCC slurry, when not using cellulase and lignoenzyme to be handled, and setting different enzymatic treatments
Between, and cationic polymer P (St-BA-AA-GMA) is added into OCC slurry, to analyze and determine cationic polymer P (St-
BA-AA-GMA the additive amount of additive amount), specific cationic polymer P (St-BA-AA-GMA) is as shown in table 5,
The additive amount of cationic polymer P (St-BA-AA-GMA) in 5 OCC of table slurry
Above-mentioned various concentration, 3 parallel laboratory tests of every group of setting, specific step is as follows
1, the preparation of various slurries:
(1) preparation of ONP slurry: using Japanese 3#, the useless 8# of U.S. as raw material, the weight ratio of the useless 8# of Japanese 3#, U.S. is 3:7, described
Raw material crosses bale opener and tentatively selects reason, with rotary drum pulping machine size degradation at paper pulp, removes the gred by highly concentrated slag removing system, scalping goes to clean
Matter after scalping, carries out washing removal ink, carries out flotation subsequently into flotation cell, screen by three sections of fine screens, concentration is sent to
Heat dispersion machine carries out heat partition with the sticky matter in dispersed paste, and treated, and slurry enters stock tank, spare；
The ONP Deinking Pulp freedom 210csf, whiteness value 40ISO, impure point content 980mm2/m2；
(2) preparation of DIP slurry: using the useless 3# of U.S., the useless 8# of U.S. as raw material, the useless 3# of U.S., the useless 8# of U.S. weight ratio be 1:1, it is described
Raw material crosses bale opener and tentatively selects reason, is sent to rotary drum pulping machine size degradation into paper pulp, screens impurity by scalping, good after screening starch into
Enter scummer slagging-off, carries out washing deinking processing and carry out flotation processing after two sections of fine screens are screened, be sent into after flotation processing dense
The concentration of contracting machine is then delivered to heat dispersion machine and carries out heat partition with the sticky matter in dispersed paste, to slurry after dirt count
Material carries out highly concentrated oxidation bleaching, and thickener concentration is again introduced into after oxidation bleaching, carries out reducing bleach to the slurry after concentration,
Through reducing bleach, treated that slurry enters stock tank, spare.
The DIP starches freedom 230csf, whiteness value 55ISO, impure point content 800mm2/m2
(3) preparation of OCC slurry:
A. using domestic waste and old corrugated paper as raw material, the raw material crosses bale opener and tentatively selects reason, is sent to rotary drum pulping machine size degradation
At paper pulp, impurity is screened by scalping, the good slurry after screening enters scummer slagging-off, carries out flotation after two sections of fine screens are screened
Processing, flotation processing after be sent into thickener concentration, be then delivered to heat dispersion machine carry out heat partition in dispersed paste sicker,
The heat such as oily wax melt object, and treated, and slurry enters stock tank, spare；The beating degree of the OCC slurry is 48.5 ° of SR.
B. addition cationic polymer is modified OCC slurry, and the cationic polymer is P (St-BA-AA-GMA),
With styrene (St), butyl acrylate (BA), acrylic acid (AA), glycidyl methacrylate (GMA) for monomer, hexadecane
Base trimethyl ammonium chloride (CTAC) is emulsifier, and azo diisobutyl miaow hydrochloride (AIBA) is initiator, using semicontinuous cream
Liquid polymerization has synthesized cationic polymer P (St-BA-AA-GMA), method particularly includes:
It is passed through nitrogen, deionized water, the emulsifier dissolved and sodium acetate buffer agent is added, opens agitating device stirring,
It is uniformly dissolved emulsifier in water；Then St, BA, AA mix monomer being incorporated as, pre-emulsification are warming up to (80 after a certain period of time
± 1) remaining GMA, BA, St mix monomer (rate of addition is controlled in 5s/ drop) DEG C, is added dropwise, while the AIBA dissolved is added dropwise
Initiator keeps pH between 6~8 by the way that sodium acetate buffer agent is added.In 80 DEG C of reaction 3.5h, Temperature fall after completion of dropwise addition
It discharges to 40~50 DEG C, wherein the dosage of St, BA, AA, GMA are 7:11:0.2:1.8；It is P (St-BA- by cationic polymer
AA-GMA it) is configured to the lotion of 2g/L, is added in OCC slurry, specific dosage ginseng is shown in Table 5, and is stirred at 25 DEG C of room temperature
It is spare after 40min.
2. the slurry preparation of different levels
Surface layer slurry is prepared: being starched with the ONP slurry and DIP of above-mentioned steps preparation as surface layer slurry, wherein ONP slurry and DIP slurry
Use ratio be 2:1, weight with slurry be 32.9g/m2；
Lining slurry preparation is with slurry: with above-mentioned steps preparation ONP slurry and OCC slurry be lining slurry, wherein ONP slurry and
The use ratio of OCC slurry is 1:1, and weight with slurry is 21.2g/m2；
Center stock is prepared with slurry: being starched with the OCC of above-mentioned steps preparation as center stock, sandwich layer quantitative 96g/m with slurry2；
Base pastes prepare it is with slurry: with above-mentioned steps preparation ONP slurry and OCC slurry be lining slurry, wherein ONP slurry and
The use ratio of OCC slurry is 1:3, and weight with slurry is 31.6g/m2；
3. body paper is manufactured paper with pulp:
Each layer slurry is transported to paper machine slurry flowing box by respective feeding system, by certain density above layers slurry
Upper four formable layers net forms l Water Paper page, carries out body paper through squeezing, front baking cadre, top sizing, hard press polish and manufactures paper with pulp, body paper weight
For 410g/m2；
4. coating, is batched soft calendaring:
Bodystock paper after above-mentioned hard press polish is sent to curtain coater, it is enterprising in the positive glue application layer of the bodystock paper
Row curtain coating forms curtain coating, and the bodystock paper for forming curtain coating is then sent to knife type coater progress blade coating and is formed
Finishing coat, wherein the coating weight of curtain coating is 11g/m2, the coating weight of finishing coat is 15g/m2.Coating complete after through soft calendaring,
It batches, rewinding storage.
5. white board testing result
The physical property of the white board 19- white board 24 prepared using the above method is detected, the object specifically detected
Managing performance indicator is quantitative, lateral stiffness, folding strength (transverse direction) burst index, interlaminar strength, ring crush index, wherein
Coated manila is quantitative to be detected according to GB/T 451.2；
The burst index of coated manila is detected according to GB/T 1539；
The ring crush index of coated manila is detected according to GB/T 2679.8；
The folding test of coated manila is carried out according to the measurement of GB/T 1539-2007 cardboard bursting strength
The interlaminar strength of coated manila is according to the GB/T 26203-2010 " measurement of paper and cardboard internal bond strength
(Scott) " it measures；
The stiffness of coated manila is measured according to GB/T 22364-2008 " measurement of paper and cardboard bending break stiffness ".
Influence of the additive amount of different cationic polymer P (St-BA-AA-GMA) to white board physical property such as 6 institute of table
Show.
The physical property of 6 white board 19- white board 24 of table
It can also be seen that the additive amount with cationic polymer P (St-BA-AA-GMA) increases from the result of table 6,
The physical property of white board also increases accordingly, still, when the additive amount of cationic polymer P (St-BA-AA-GMA) reaches certain
When amount, the reason of increase trend of the physical property of white board slows down, causes this phenomenon may be cationic polymer P
(St-BA-AA-GMA) physics of paper is improved in conjunction with the negative electrical charge of cellulose in paper pulp by its highdensity positive electricity
Performance, after P (St-BA-AA-GMA) arrival is a certain amount of, the principal element improved for physical property is no longer that positive electricity is close
The deficiency of degree is the quality problem of fiber instead.It can be obtained from the result of table 6, cationic polymer P (St-BA-AA-GMA)
Additive amount be 1.5% (being equivalent to absolute dry pulp) (i.e. white board 23), the physical property of white board is best.
Embodiment 5 is starched OCC while being carried out enzyme modification and adds influence of the cationic polymer to white board physical property
As can be seen that being either modified using enzyme to OCC slurry from above-described embodiment, or add into OCC slurry
Add cationic polymer, the physical property of white board can be improved to a certain extent, the present embodiment progress, which is probed into, starches OCC
Enzyme modification is carried out simultaneously and adds whether cationic polymer can cooperate with the physical property for improving white board, and experimental design is such as
Under:
It selects the best enzymatic treatment concentration determined in above-described embodiment and time, i.e., the dosage of cellulase is 92IU/g,
When lignoenzyme dosage is 33IU/g, best enzyme processing time is 90min and best cationic polymer P (St-BA-AA-GMA)
Additive amount 1.5% (being equivalent to absolute dry pulp), while to OCC slurry be modified, the specific steps are as follows:
1, the preparation of various slurries:
(1) preparation of ONP slurry: using Japanese 3#, the useless 8# of U.S. as raw material, the weight ratio of the useless 8# of Japanese 3#, U.S. is 3:7, described
Raw material crosses bale opener and tentatively selects reason, with rotary drum pulping machine size degradation at paper pulp, removes the gred by highly concentrated slag removing system, scalping goes to clean
Matter after scalping, carries out washing removal ink, carries out flotation subsequently into flotation cell, screen by three sections of fine screens, concentration is sent to
Heat dispersion machine carries out heat partition with the sticky matter in dispersed paste, and treated, and slurry enters stock tank, spare；
The ONP Deinking Pulp freedom 210csf, whiteness value 40ISO, impure point content 980mm2/m2；
(2) preparation of DIP slurry: using the useless 3# of U.S., the useless 8# of U.S. as raw material, the useless 3# of U.S., the useless 8# of U.S. weight ratio be 1:1, it is described
Raw material crosses bale opener and tentatively selects reason, is sent to rotary drum pulping machine size degradation into paper pulp, screens impurity by scalping, good after screening starch into
Enter scummer slagging-off, carries out washing deinking processing and carry out flotation processing after two sections of fine screens are screened, be sent into after flotation processing dense
The concentration of contracting machine is then delivered to heat dispersion machine and carries out heat partition with the sticky matter in dispersed paste, to slurry after dirt count
Material carries out highly concentrated oxidation bleaching, and thickener concentration is again introduced into after oxidation bleaching, carries out reducing bleach to the slurry after concentration,
Through reducing bleach, treated that slurry enters stock tank, spare.
The DIP starches freedom 230csf, whiteness value 55ISO, impure point content 800mm2/m2
(3) preparation of OCC slurry:
A. using domestic waste and old corrugated paper as raw material, the raw material crosses bale opener and tentatively selects reason, is sent to rotary drum pulping machine size degradation
At paper pulp, impurity is screened by scalping, the good slurry after screening enters scummer slagging-off, carries out flotation after two sections of fine screens are screened
Processing, flotation processing after be sent into thickener concentration, be then delivered to heat dispersion machine carry out heat partition in dispersed paste sicker,
The heat such as oily wax melt object, and treated, and slurry enters stock tank, spare；The beating degree of the OCC slurry is 48.5 ° of SR.
B. OCC slurry is handled using cellulase and lignoenzyme, OCC slurry is adjusted to concentration 4-8wt%, addition
Cellulase and lignoenzyme are handled, and 50 DEG C for the treatment of temperature, pH=8, the processing time is 90min, the cellulase
Dosage is 92IU/g, when lignoenzyme dosage is 33IU/g.
C. addition cationic polymer is modified OCC slurry, and the cationic polymer is P (St-BA-AA-GMA),
With styrene (St), butyl acrylate (BA), acrylic acid (AA), glycidyl methacrylate (GMA) for monomer, hexadecane
Base trimethyl ammonium chloride (CTAC) is emulsifier, and azo diisobutyl miaow hydrochloride (AIBA) is initiator, using semicontinuous cream
Liquid polymerization has synthesized cationic polymer P (St-BA-AA-GMA), method particularly includes:
It is passed through nitrogen, deionized water, the emulsifier dissolved and sodium acetate buffer agent is added, opens agitating device stirring,
It is uniformly dissolved emulsifier in water；Then St, BA, AA mix monomer being incorporated as, pre-emulsification are warming up to (80 after a certain period of time
± 1) remaining GMA, BA, St mix monomer (rate of addition is controlled in 5s/ drop) DEG C, is added dropwise, while the AIBA dissolved is added dropwise
Initiator keeps pH between 6~8 by the way that sodium acetate buffer agent is added.In 80 DEG C of reaction 3.5h, Temperature fall after completion of dropwise addition
It discharges to 40~50 DEG C, wherein the dosage of St, BA, AA, GMA are 7:11:0.2:1.8；
It is the lotion that P (St-BA-AA-GMA) is configured to 2g/L by cationic polymer, is added in step b through cellulose
In enzyme and the OCC slurry of lignoenzyme processing, specific dosage is 1.5% (relative to absolute dry pulp), and is stirred at 25 DEG C of room temperature
It is spare after 40min.
2. the slurry preparation of different levels
Surface layer slurry is prepared: being starched with the ONP slurry and DIP of above-mentioned steps preparation as surface layer slurry, wherein ONP slurry and DIP slurry
Use ratio be 2:1, weight with slurry be 32.9g/m2；
Lining slurry preparation is with slurry: with above-mentioned steps preparation ONP slurry and OCC slurry be lining slurry, wherein ONP slurry and
The use ratio of OCC slurry is 1:1, and weight with slurry is 21.2g/m2；
Center stock is prepared with slurry: being starched with the OCC of above-mentioned steps preparation as center stock, sandwich layer quantitative 96g/m with slurry2；
Base pastes prepare it is with slurry: with above-mentioned steps preparation ONP slurry and OCC slurry be lining slurry, wherein ONP slurry and
The use ratio of OCC slurry is 1:3, and weight with slurry is 31.6g/m2；
3. body paper is manufactured paper with pulp:
Each layer slurry is transported to paper machine slurry flowing box by respective feeding system, by certain density above layers slurry
Upper four formable layers net forms l Water Paper page, carries out body paper through squeezing, front baking cadre, top sizing, hard press polish and manufactures paper with pulp, body paper weight
For 410g/m2；
4. coating, is batched soft calendaring:
Bodystock paper after above-mentioned hard press polish is sent to curtain coater, it is enterprising in the positive glue application layer of the bodystock paper
Row curtain coating forms curtain coating, and the bodystock paper for forming curtain coating is then sent to knife type coater progress blade coating and is formed
Finishing coat, wherein the coating weight of curtain coating is 11g/m2, the coating weight of finishing coat is 15g/m2.Coating complete after through soft calendaring,
It batches, rewinding storage.
5. white board testing result
The physical property of the white board 25 prepared using the above method is detected, the physical performance index specifically detected
For quantitative, lateral stiffness, folding strength (transverse direction) burst index, interlaminar strength, ring crush index, wherein
Coated manila is quantitative to be detected according to GB/T 451.2；
The burst index of coated manila is detected according to GB/T 1539；
The ring crush index of coated manila is detected according to GB/T 2679.8；
The folding test of coated manila is carried out according to the measurement of GB/T 1539-2007 cardboard bursting strength
The interlaminar strength of coated manila is according to the GB/T 26203-2010 " measurement of paper and cardboard internal bond strength
(Scott) " it measures；
The stiffness of coated manila is measured according to GB/T 22364-2008 " measurement of paper and cardboard bending break stiffness ".
The white board 25 prepared by the above method, physical property is as shown in table 7 below:
The physical property of 7 white board 25 of table
As shown in table 7, while using enzyme modification and the modified OCC slurry of addition cationic polymer, the physical property of white board
For single modification mode, there is raising by a relatively large margin, this explanation, cellulase and lignoenzyme eliminate OCC
Fiber fines in slurry improve the ratio of medium-length fibre, improve the fiber quality of slurry, further pass through cationic polymer
The high density positive electricity of P (St-BA-AA-GMA) is in conjunction with the negative electrical charge of cellulose in paper pulp, and further collaboration improves paper
Physical property, obtain good effect.
Above the present invention is described in detail with a general description of the specific embodiments, but in the present invention
On the basis of, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore, not
These modifications or improvements on the basis of deviation spirit of that invention, fall within the scope of the claimed invention.
Claims (10)
1. a kind of coated manila comprising surface layer, lining, sandwich layer and bottom, which is characterized in that the lining is copied by OCC slurry
It makes, the OCC slurry is handled using cellulase and lignoenzyme, and adds cationic polymer P (St-BA-AA-
GMA), the dosage that the cellulase is equivalent to OCC slurry is 50-100IU/g, and lignoenzyme is 20- with OCC slurry amount is equivalent to
40IU/g, the additive amount of the P (St-BA-AA-GMA) are 0.5%-2%.
2. coated manila described in claim 1, which is characterized in that the cellulase and lignoenzyme handled when
Between be 60-120min.
3. coated manila described in claim 1, which is characterized in that the dosage of the cellulase is 92IU/g, lignin
Enzyme dosage is 33IU/g.
4. coated manila described in claim 1-3 any one, which is characterized in that the cellulase and lignoenzyme into
The time of row processing is 90min, it is preferred that the additive amount of the P (St-BA-AA-GMA) is 1.5%.
5. coated manila described in claim 1-4 any one, which is characterized in that the surface layer includes ONP slurry and DIP slurry
For surface layer slurry, wherein the use ratio of ONP slurry and DIP slurry is 2:1；The lining includes ONP slurry and OCC slurry is that lining is starched
Material, wherein the use ratio of ONP slurry and OCC slurry is 1:1；The bottom includes ONP slurry and OCC slurry is lining slurry, wherein ONP
The use ratio of slurry and OCC slurry is 1:3.
6. the preparation method of coated manila described in claim 1-5 any one, which is characterized in that described steps are as follows:
(1) preparation of ONP slurry, DIP slurry, OCC slurry；
(2) slurry preparation of surface layer, lining, sandwich layer and bottom
(3) body paper is manufactured paper with pulp；
(4) coating, soft calendaring, batch.
7. the preparation method of coated manila as claimed in claim 6, which is characterized in that in the step (1), the OCC slurry
It is handled using cellulase and lignoenzyme, and adds cationic polymer P (St-BA-AA-GMA), the cellulase
Dosage be 50-100IU/g, lignoenzyme dosage is 20-40IU/g, and the additive amount of the P (St-BA-AA-GMA) is
0.5%-2%.
8. the preparation method of coated manila as claimed in claim 7, which is characterized in that the cellulase and lignoenzyme into
The time of row processing is 60-120min.
9. the preparation method of coated manila described in claim 6-8 any one, which is characterized in that the cellulase
Dosage is 92IU/g, and lignoenzyme dosage is 33IU/g, it is preferred that the time that the cellulase and lignoenzyme are handled
For 90min, it is further preferred that the additive amount of the P (St-BA-AA-GMA) is 1.5%.
10. the preparation method of coated manila described in claim 6-9 any one, which is characterized in that the system of the OCC slurry
It is standby that steps are as follows:
A. using domestic waste and old corrugated paper as raw material, through size degradation, screening, slagging-off, concentration, heat partition obtains OCC slurry；
B. OCC slurry is handled using cellulase and lignoenzyme, OCC slurry is adjusted to concentration 4-8wt%, fiber is added
Plain enzyme and lignoenzyme are handled, and 50 DEG C for the treatment of temperature, pH=8, the processing time is 90min, the dosage of the cellulase
For 92IU/g, when lignoenzyme dosage is 33IU/g.
C. addition cationic polymer is modified OCC slurry, and the cationic polymer is P (St-BA-AA-GMA), with benzene
Ethylene (St), butyl acrylate (BA), acrylic acid (AA), glycidyl methacrylate (GMA) are monomer, cetyl three
Ammonio methacrylate (CTAC) is emulsifier, and azo diisobutyl miaow hydrochloride (AIBA) is initiator, poly- using semicontinuous lotion
It is legal to have synthesized cationic polymer P (St-BA-AA-GMA), it is that P (St-BA-AA-GMA) is configured to by cationic polymer
The lotion of 2g/L is added in the OCC slurry handled in step b through cellulase and lignoenzyme, and specific dosage is 1.5%, and
It is spare after stirring 40min at 25 DEG C of room temperature.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111485438A (en) * | 2020-04-17 | 2020-08-04 | 江苏理文造纸有限公司 | Production process of biological enzyme modified high-strength corrugated paper |
| CN112553935A (en) * | 2020-12-02 | 2021-03-26 | 浙江金龙再生资源科技股份有限公司 | Method for treating high-wet-strength waste paper with low lignin content and low transition metal content |
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| CN112553935A (en) * | 2020-12-02 | 2021-03-26 | 浙江金龙再生资源科技股份有限公司 | Method for treating high-wet-strength waste paper with low lignin content and low transition metal content |
| CN112553935B (en) * | 2020-12-02 | 2022-11-11 | 浙江金龙再生资源科技股份有限公司 | Method for treating high-wet-strength waste paper with low lignin content and low transition metal content |
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