CN110294512A - A kind of quantum cracking reaction method and its reactor for sewage treatment - Google Patents
A kind of quantum cracking reaction method and its reactor for sewage treatment Download PDFInfo
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- CN110294512A CN110294512A CN201910716480.4A CN201910716480A CN110294512A CN 110294512 A CN110294512 A CN 110294512A CN 201910716480 A CN201910716480 A CN 201910716480A CN 110294512 A CN110294512 A CN 110294512A
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- microwave
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- sewage
- sewage treatment
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- 239000010865 sewage Substances 0.000 title claims abstract description 34
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000005336 cracking Methods 0.000 title claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 230000005684 electric field Effects 0.000 claims abstract description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 5
- 239000011790 ferrous sulphate Substances 0.000 claims description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- -1 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 12
- 238000007254 oxidation reaction Methods 0.000 abstract description 8
- 238000009279 wet oxidation reaction Methods 0.000 abstract description 7
- 230000003647 oxidation Effects 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 5
- 238000012545 processing Methods 0.000 abstract description 5
- 230000003197 catalytic effect Effects 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 238000010586 diagram Methods 0.000 description 4
- 239000002957 persistent organic pollutant Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000010842 industrial wastewater Substances 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 229930182555 Penicillin Natural products 0.000 description 2
- JGSARLDLIJGVTE-MBNYWOFBSA-N Penicillin G Chemical compound N([C@H]1[C@H]2SC([C@@H](N2C1=O)C(O)=O)(C)C)C(=O)CC1=CC=CC=C1 JGSARLDLIJGVTE-MBNYWOFBSA-N 0.000 description 2
- 238000002306 biochemical method Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229940049954 penicillin Drugs 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- VGVRPFIJEJYOFN-UHFFFAOYSA-N 2,3,4,6-tetrachlorophenol Chemical class OC1=C(Cl)C=C(Cl)C(Cl)=C1Cl VGVRPFIJEJYOFN-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- LSQZJLSUYDQPKJ-NJBDSQKTSA-N amoxicillin Chemical compound C1([C@@H](N)C(=O)N[C@H]2[C@H]3SC([C@@H](N3C2=O)C(O)=O)(C)C)=CC=C(O)C=C1 LSQZJLSUYDQPKJ-NJBDSQKTSA-N 0.000 description 1
- 229960003022 amoxicillin Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 229910001410 inorganic ion Inorganic materials 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- LSQZJLSUYDQPKJ-UHFFFAOYSA-N p-Hydroxyampicillin Natural products O=C1N2C(C(O)=O)C(C)(C)SC2C1NC(=O)C(N)C1=CC=C(O)C=C1 LSQZJLSUYDQPKJ-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000009284 supercritical water oxidation Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/126—Microwaves
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/302—Treatment of water, waste water, or sewage by irradiation with microwaves
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/12—Processes employing electromagnetic waves
- B01J2219/1203—Incoherent waves
- B01J2219/1206—Microwaves
- B01J2219/1248—Features relating to the microwave cavity
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Water Supply & Treatment (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The invention discloses a kind of quantum cracking reaction methods and its reactor for sewage treatment, strong microwave field (electric field > 100kV/m) is established in reactor, dirty underwater bubble is ionized and generates high-energy electron (~100eV), it is heated by the collision of high energy electron and organic molecule, targetedly improve the kinetic energy of organic molecule in sewage, increase reaction cross-section, difficult biochemical and hardly degraded organic substance decomposition and cracking are realized in a mild condition, to replace the harsh conditions (acid condition required such as conventional Fenton's reaction of conventional high level oxidation technology requirement, the high-temperature and high-pressure conditions etc. that catalytic wet oxidation requires), reduce the processing cost of dirty Organic substance in water, improve treatment effeciency.
Description
Technical field
It is specifically a kind of to be used for sewage treatment the invention belongs to bio-refractory material technology field of degrading in sewage treatment
Quantum cracking reaction method and its reactor.
Background technique
Water pollution species are extremely complex, can generally be divided into inorganic ions, heavy metal ion and organic pollutant three
Major class.In the priority pollutants list that various countries propose, organic pollutant is priority control object.Influence water environment matter
The organic pollutant of amount is mainly derived from sanitary sewage and industrial wastewater, especially industrial wastewater.Its complicated component, variation water quality
Greatly, it is useless to become one kind that processing difficulty is big, treatment effeciency is low for the features such as coloration is deep, Toxic content is high, biodegradability is poor
Water.Since many toxic organic pollutants cannot be using traditional biology and physical method processing, many countries are being thrown
Enter a large amount of manpower and material resources and carries out exploration and research and development in relation to new technology, new method.
Advanced chemical oxidation is the very effective method for decomposing these hardly degraded organic substances, in the past 20 years, various height
Grade oxidizing process is found simultaneously to apply in water treatment field rapidly, mainly includes photochemical catalytic oxidation, sonochemical oxidation, electrochemistry oxygen
Change, wet oxidation, supercritical water oxidation etc., these methods are exactly that organic molecule kinetic energy is made to reach chemical reaction threshold value, especially
It is wet oxidation, is realized by improving the means of temperature, therefore wet oxidation must be in high temperature (125~320 DEG C) and high pressure
It is carried out under harsh conditions as (0.5~20MPa), but the use condition of this harshness limits application and the hair of the technology
Exhibition.
There is the organic wastewater of a large amount of biochemistry with high salt, difficult to degrade, difficult in industrial wastewater simultaneously, such as phenolic compound, this is
The substance of a kind of toxic bio-refractory is widely used as the centre of preservative, herbicide, insecticide and pharmaceuticals preparation
Body.Due to strong toxicity and bio-refractory, phenol wastewater has to pass through specially treated before discharging, at present to the master of the substance
Want processing method to have biochemical method, incineration method, chemical method, wherein biochemical method only for handle low concentration chlorophenols effect compared with
It is good, and the longer reaction time is needed, incineration method is easy to produce other noxious materials, and chemical method is primarily referred to as wet oxidation
Method needs harsh conditions as high temperature (125~320 DEG C) and high pressure (0.5~20MPa), causes processing cost higher.
Summary of the invention
It is an object of the invention to overcome the technical problem of the mass degradation of bio-refractory in existing sewage treatment hardly possible, mention
For a kind of quantum cracking reaction method and its reactor for sewage treatment.
To achieve the above object, The technical solution adopted by the invention is as follows:
A kind of quantum cracking reaction method for sewage treatment, sewage-treating agent is added in sewage, draws into sewage
Enter bubble, and establishes strong microwave field of the microwave electric field greater than 100kV/m in sewage reaction system.
The bubble in strong microwave field and sewage is combined in the present invention, in small part (i.e. near bubble), is realized normal
The harsh conditions that advanced oxidation reaction requires are advised, and (in i.e. entire reaction chamber) are being macroscopically that (i.e. room temperature is normal for temperate condition
Pressure), thus replace the harsh conditions of conventional high level oxidation requirements (such as conventional sweet smell with temperate condition (normal temperature and pressure) macroscopically
Acid condition, high-temperature and high-pressure conditions of catalytic wet oxidation requirement that reaction of pausing requires etc.).
Preferably, the sewage-treating agent is the one or more of hydrogen peroxide, active carbon and ferrous sulfate.
Preferably, the bubble is directly provided by outside air compressor.
A kind of quantum cracking reaction method and its reactor for sewage treatment, including at least one quantum cracking reaction
Device unit, the quantum cracker unit includes microwave cavity, the microwave cavity be provided with microwave feed-in mouth, into
Waterpipe and outlet conduit, the microwave feed-in mouth are externally connected with the microwave tube for being greater than 100kV/m for generating microwave electric field,
It is equipped in microwave feed-in mouth and microwave electric field is transferred to the intracavitary microwave feed-in window of microwave resonance.
Preferably, the quantum cracker unit is equipped with multiple, between multiple quantum cracker units
Connection type be series, parallel, series-parallel and and one kind of connecting.
Preferably, the microwave cavity is set as square cavity, and microwave cavity is arranged in microwave feed-in mouth
Top, inlet and outlet pipes are separately positioned on the two sides of microwave cavity.Microwave energy enters chemical reactor and microwave
It does not leak from inlet and outlet.
Preferably, the material of the microwave feed-in window is polytetrafluoroethylene (PTFE).By the intracavitary dirt processed of microwave resonance
Water and microwave feed-in mouth seal isolation also guarantee that microwave enters microwave cavity simultaneously.
Compared with prior art, the invention has the following advantages:
The present invention presents inlet by the way that microwave tube is mounted on microwave, and microwave tube is established micro- in microwave cavity when working
Dirty underwater bubble is ionized and is generated high-energy electron (~100eV) by wave field (electric field > 100kV/m), by high energy electron with have
The collision of machine object molecule is heated, and the kinetic energy of organic molecule in sewage is targetedly improved, and increases reaction cross-section, in mild item
Difficult biochemical and hardly degraded organic substance decomposition and cracking are realized under part, to replace the harshness of conventional high level oxidation technology requirement
Condition (high-temperature and high-pressure conditions that acid condition, the catalytic wet oxidation that such as conventional Fenton's reaction requires require), reduces dirt
The processing cost of Organic substance in water, improves treatment effeciency.
Detailed description of the invention
Fig. 1 is the cross-sectional view of quantum cracker unit；
Fig. 2 is the external structure schematic diagram of quantum cracker unit；
Fig. 3 is the structural schematic diagram of microwave feed-in window；
Fig. 4 be multiple quantum cracker units and be used in series exemplary diagram；
Figure label is respectively as follows: 1, microwave feed-in mouth；2, microwave feed-in window；3, microwave cavity；4, water inlet line；5, go out
Waterpipe；6, microwave tube.
Specific embodiment
The invention will be further described with embodiment for explanation with reference to the accompanying drawing, and mode of the invention includes but not only limits
In following embodiment.
It as shown in Figs. 1-2, is the structural schematic diagram of quantum cracker unit provided by the invention, the quantum cracking
Reactor unit includes microwave cavity 3, and the microwave cavity 3 is provided with microwave feed-in mouth 1, water inlet line 4 and water outlet
Pipeline 5, the microwave feed-in mouth 1 are externally connected with the microwave tube 6 for being greater than 100kV/m for generating microwave electric field, microwave feed-in mouth 1
The microwave feed-in window 2 microwave electric field being transferred in microwave cavity 3 is inside installed, wherein the structure of microwave feed-in window 2 such as Fig. 3
It is shown, resonance frequency 2450MHz.
The working principle of quantum cracker unit are as follows: microwave tube 6 is mounted at microwave feed-in mouth 1, and work Shi Wei
Microwave field is established in wave resonance chamber 3；The sewage for preparing oxidant content enters microwave resonance from water inlet line 4 together with compressed air
Chamber 3, in microwave cavity 3, due to the effect of strong microwave field, the bubble that compressed air generates is ionized, and generates high-energy electricity
Sub (~100eV), organic molecule kinetic energy in sewage is improved, and realizes the item that advanced oxidation reaction requires in a mild condition
Part.To making the organic matter in sewage be converted into CO2, H2O and small organic molecule, direct effect has: 1) in sewage COD value at
Times decline, 2) TOC in sewage is eliminated, improve the biodegradability of sewage, 3) colour killing.
Microwave cavity 3 is a square chamber (long 8cm, wide 7cm, high 6cm), resonance frequency 2450MHz, 2) microwave is from micro-
1 feed-in of microwave feed-in mouth on 3 top of wave resonance chamber, microwave feed-in mouth 1 is the circular hole of diameter 5cm, for installing microwave feed-in window
2,3) microwave feed-in window 2 is polytetrafluoroethylene (PTFE), the intracavitary sewage processed of microwave resonance and microwave feed-in mouth is sealed off same
When also guarantee that microwave enters microwave cavity, 4) chemical reactor both ends be sewage processed inlet and outlet, can guarantee microwave not
It leaks from inlet and outlet, inlet and outlet pipe diameter is 1-2cm, and duct length is greater than 5cm.
Embodiment 1
As shown in figure 4, combining to form quantum cracker for multiple quantum cracker units, for handling one
The kettle base solution (dense black, COD is greater than 40000mg/L) in Amoxicillin pharmaceutical factory, 120 kg stoste is incorporated 2 kilogram of 30% hydrogen peroxide,
1000g active carbon, 800 ferrous sulfate recycle 20 minutes in quantum cracker, and water outlet is limpid colourless, and C0D is less than
2000mg/L。
Microwave field density: greater than 1MV/m.
Embodiment 2
The kettle base solution (dense black, COD is greater than 20000mg/L) in one penicillin pharmaceutical factory, 50 kilograms of stostes are incorporated 1 kilogram
30% hydrogen peroxide, 500g active carbon, 500 ferrous sulfate recycle 25 minutes in four series units, are discharged limpid colourless, C0D
Less than 2000mg/L.
Microwave field density: greater than 1MV/m.
Embodiment 3
The kettle base solution (dense black, COD is greater than 20000mg/L) in one penicillin pharmaceutical factory, 5 kilograms of stostes are incorporated 0.5 kilogram
30% hydrogen peroxide, 100g active carbon, 100 ferrous sulfate recycle 20 minutes in single quantum cracker unit, and water outlet is clear
Clear colourless, C0D is less than 2000mg/L.
Microwave field density: greater than 1MV/m.
Above-described embodiment is only one of the preferred embodiment of the present invention, should not be taken to limit protection model of the invention
It encloses, as long as that in body design thought of the invention and mentally makes has no the change of essential meaning or polishing, is solved
The technical issues of it is still consistent with the present invention, should all be included within protection scope of the present invention.
Claims (7)
1. a kind of quantum cracking reaction method for sewage treatment, is added sewage-treating agent in sewage, it is characterised in that: to
Bubble is introduced in sewage, and strong microwave field of the microwave electric field greater than 100kV/m is established in sewage reaction system.
2. a kind of quantum cracking reaction method for sewage treatment according to claim 1, it is characterised in that: the dirt
Water treatment agent is the one or more of hydrogen peroxide, active carbon and ferrous sulfate.
3. a kind of quantum cracking reaction method for sewage treatment according to claim 1, it is characterised in that: the gas
Bubble is directly provided by outside air compressor.
4. a kind of quantum cracker for sewage treatment, it is characterised in that: including at least one quantum cracker
Unit, the quantum cracker unit includes microwave cavity, and the microwave cavity is provided with microwave feed-in mouth, water inlet
Pipeline and outlet conduit, the microwave feed-in mouth is externally connected with the microwave tube for being greater than 100kV/m for generating microwave electric field, micro-
It is equipped in wave feed-in mouth and microwave electric field is transferred to the intracavitary microwave feed-in window of microwave resonance.
5. a kind of quantum cracker for sewage treatment according to claim 4, it is characterised in that: the quantum
Cracker unit is equipped with multiple, and connection type between multiple quantum cracker units is series, parallel, series-parallel
And and one kind of connecting.
6. a kind of quantum cracker for sewage treatment according to claim 4, it is characterised in that: the microwave
Resonant cavity is set as square cavity, and the top of microwave cavity, inlet and outlet pipes difference is arranged in microwave feed-in mouth
The two sides of microwave cavity are set.
7. a kind of quantum cracker for sewage treatment according to claim 4, it is characterised in that: the microwave
The material of feed-in window is polytetrafluoroethylene (PTFE).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910716480.4A CN110294512A (en) | 2019-08-05 | 2019-08-05 | A kind of quantum cracking reaction method and its reactor for sewage treatment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910716480.4A CN110294512A (en) | 2019-08-05 | 2019-08-05 | A kind of quantum cracking reaction method and its reactor for sewage treatment |
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| Publication Number | Publication Date |
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| CN110294512A true CN110294512A (en) | 2019-10-01 |
Family
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| CN201910716480.4A Pending CN110294512A (en) | 2019-08-05 | 2019-08-05 | A kind of quantum cracking reaction method and its reactor for sewage treatment |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112979010A (en) * | 2021-02-08 | 2021-06-18 | 中国工程物理研究院应用电子学研究所 | Microwave high-field advanced oxidation reaction treatment method for organic wastewater |
| CN113651483A (en) * | 2021-09-27 | 2021-11-16 | 四川和诚振药科技有限公司 | Advanced oxidation reaction treatment device and method for organic waste liquid |
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| CN102849889A (en) * | 2012-10-19 | 2013-01-02 | 安徽工业大学 | System and device for treating phosphorus-containing wastewater by means of high-temperature and high-pressure microwave materialization |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112979010A (en) * | 2021-02-08 | 2021-06-18 | 中国工程物理研究院应用电子学研究所 | Microwave high-field advanced oxidation reaction treatment method for organic wastewater |
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