CN110289328A - A kind of high ultraviolet light mine open country high energy solar panel and its manufacturing method - Google Patents
A kind of high ultraviolet light mine open country high energy solar panel and its manufacturing method Download PDFInfo
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- CN110289328A CN110289328A CN201910615656.7A CN201910615656A CN110289328A CN 110289328 A CN110289328 A CN 110289328A CN 201910615656 A CN201910615656 A CN 201910615656A CN 110289328 A CN110289328 A CN 110289328A
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 105
- 239000011521 glass Substances 0.000 claims abstract description 75
- 238000006243 chemical reaction Methods 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 10
- 229920001721 polyimide Polymers 0.000 claims abstract description 10
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000009719 polyimide resin Substances 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 43
- 238000004528 spin coating Methods 0.000 claims description 40
- 239000000243 solution Substances 0.000 claims description 30
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 27
- 235000019441 ethanol Nutrition 0.000 claims description 24
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical class CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 239000007787 solid Substances 0.000 claims description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 16
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims description 11
- -1 dimethyl malonic ester Chemical compound 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 8
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052794 bromium Inorganic materials 0.000 claims description 8
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002238 carbon nanotube film Substances 0.000 claims description 8
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 8
- 229940043237 diethanolamine Drugs 0.000 claims description 8
- SLFLFNSLWZNOOG-UHFFFAOYSA-N ethanol;hydroiodide Chemical compound [I-].CC[OH2+] SLFLFNSLWZNOOG-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 229920000301 poly(3-hexylthiophene-2,5-diyl) polymer Polymers 0.000 claims description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 239000006227 byproduct Substances 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- 238000010276 construction Methods 0.000 claims description 6
- 150000004816 dichlorobenzenes Chemical class 0.000 claims description 6
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 230000004224 protection Effects 0.000 claims description 6
- 150000004694 iodide salts Chemical class 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 238000000137 annealing Methods 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 239000005457 ice water Substances 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 238000001953 recrystallisation Methods 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 230000006641 stabilisation Effects 0.000 claims description 3
- 238000011105 stabilization Methods 0.000 claims description 3
- 238000005292 vacuum distillation Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 claims description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims 2
- 125000002252 acyl group Chemical group 0.000 claims 1
- 238000002242 deionisation method Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 230000005611 electricity Effects 0.000 abstract description 7
- 230000006698 induction Effects 0.000 abstract 1
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 239000002210 silicon-based material Substances 0.000 description 5
- 239000004952 Polyamide Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- QZVHYFUVMQIGGM-UHFFFAOYSA-N 2-Hexylthiophene Chemical compound CCCCCCC1=CC=CS1 QZVHYFUVMQIGGM-UHFFFAOYSA-N 0.000 description 1
- 229910002899 Bi2Te3 Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000005678 Seebeck effect Effects 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- OREAFAJWWJHCOT-UHFFFAOYSA-N dimethylmalonic acid Chemical compound OC(=O)C(C)(C)C(O)=O OREAFAJWWJHCOT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Photovoltaic Devices (AREA)
- Hybrid Cells (AREA)
Abstract
The invention discloses a kind of high ultraviolet light mine open country high energy solar panel and its manufacturing methods, the solar panel is made of the thermoinduction layer on upper layer and the photoinduction layer of lower layer, thermoinduction layer is using polyimide resin, photo-thermal induction liquid and bismuth telluride powder as raw material, by them with mass ratio 30:(32-38): uniformly rear solidification obtains (30-40) proportion；Photoinduction layer is the perovskite-based photoelectric conversion material of the seven-layer structures such as upper lining, upper ito glass, upper absorbed layer, hole-conductive layer, lower absorbed layer, lower ito glass, bottom lining layer building.Integrated electro of the present invention conversion and heat to electricity conversion function, gross efficiency be high, it is applied widely, can assimilate that ultraviolet light, to be suitable for wilderness regional.
Description
Technical field
The present invention relates to light technical field of thermoelectric conversion more particularly to a kind of high ultraviolet light mine open country high energy solar batteries
Plate and its manufacturing method.
Background technique
Thermal energy can be directly changed into electric energy by thermoelectric conversion element, and compared with existing generation technology, is not present
Movable link.Therefore, thermoelectric conversion element has following many advantages: do not need maintenance, the service life is long, will not generate noise,
But also the waste heat of low temperature can be utilized.The performance of thermo-electric converting material passes through dimensionless performance index (ZT) usually to indicate.
That is, the material of ZT high is Seebeck coefficient and the material that conductivity is high and thermal conductivity is low.
Currently, the Bi2Te3 for being used as thermo-electric converting material has ZT=0.8 in 100~300 DEG C of the lower region of temperature
The dimensionless performance index of left and right.However, for thermo-electric converting material used at present, rare metal Bi, Sb, Te, Pb
Deng for main component.The reserves of these resources are few, material cost is high.In addition, since these thermo-electric converting materials are 300~400
DEG C high-temperature area be oxidized easily, therefore the service life as element is short, but also worries toxic.Therefore, for can lead to
It crosses the Si based material for being comparably low cost and hypotoxicity with BiTe based material and obtains the ZT same with BiTe based material, ground
Study carefully.For Si based material, due to 100 times of BiTe high of lattice thermal conductivity ratio or so, compared with BiTe based material, ZT
Significantly it is lower.It is therefore contemplated that Si based material is difficult to be used as thermo-electric converting material.However, discovered in recent years, because of the nano junction of material
Structure and the Si based material for producing phon scattering can reduce lattice thermal conductivity compared with block (bulk) body of Si based material.Cause
This, has used and has attracted attention through the thermoelectric conversion element of nano-structured Si.
Therefore, it is badly in need of that a kind of conversion of integrated electro and heat to electricity conversion function, gross efficiency be high, applied widely, energy on the market
Assimilate ultraviolet light, suitable for the solar panel in wilderness area.
Summary of the invention
The present invention is intended to provide a kind of conversion of integrated electro and heat to electricity conversion function, gross efficiency it is high, it is applied widely, can inhale
Receive digestion ultraviolet light, suitable for the solar panel in wilderness area.
To achieve the goals above, the invention adopts the following technical scheme: a kind of high ultraviolet light mine open country high energy solar energy
The manufacturing method of solar panel, comprising the following steps:
1) raw material prepare
1. raw material prepare: preparing 9 parts of the hydrogen iodide ethanol solution-of molar concentration 52mol/L-58mol/L by weight
12 parts, 16 parts -18 parts of aminomethane, enough lead iodides, 50 parts -55 parts of butyl titanate, 12 parts -15 parts of diethanol amine, poly- 3
1 part -1.2 parts of hexyl thiophene, the carbon nano-tube film of enough 70nm-120nm thickness, 6.5 parts -7 parts of metallic sodium, dimethyl malonic acid
45 parts -50 parts of diethylester, 58 parts -60 parts of 2- bromine bromobenzyl, 45 parts -48 parts of sodium hydroxide, 20 parts -22 parts of thionyl chloride, enough lead
Powder, enough ito glasses, enough polyimide resins, enough partial size 100nm-200nm bismuth telluride powder；
2. auxiliary material prepares: preparing enough ethyl alcohol, enough ethyl acetate, the hydrochloric acid of enough Solute mass fractions 20% is water-soluble
Liquid, enough saturated sodium-chloride water solutions, enough N,N-dimethylformamides, Enough Dl water, Solute mass fraction 10%
Aqueous solution of nitric acid, enough ether, enough nitrogen, enough dichloro-benzenes, sufficient isopropanol；
2) light-sensing region manufacturing method
1. prepare two pieces of stages 1) ito glass that 1. prepares of step,；
2. by the stage 1) step butyl titanate, diethanol amine and 150 parts of -160 parts of second by weight for 1. preparing
Alcohol is uniformly mixed, and stirs 1.5h-2h with the rate of 600rpm/min-800rpm/min, obtains mixed liquid A；It will by weight
15 parts of -17 parts of deionized waters and 75 parts of -80 parts of ethyl alcohol are compounded into alcohol water miscible fluid, as mixed liquid B；Mixed liquid A and mixed liquid B is mixed
And after mixing evenly, mixed liquid C is obtained, mixed liquid C is stood into 28h-30h in closed environment, mixes liquid C solation, obtains sol solutions
C；
3. 2. sol solutions C that step is obtained is with the spin coating rate of 1200rpm/min-1300rpm/min, each 45s-
The spin-coating time of 50s, spin coating twice, the technique of thickness 150nm-180nm, two pieces 1. obtained in step respectively after coating is dry and hard
Upper and lower total four surfaces of ito glass carry out spin-coat process, obtain in spin coating ito glass under ito glass and spin coating；
4. ito glass under ito glass in 3. spin coating that step obtains and spin coating is placed in resistance furnace, using 460 DEG C-
480 DEG C of temperature toasts 80min-100min, obtains prefabricated upper ito glass and prefabricated lower ito glass
5. by the stage 1) 2 parts -2.5 parts of the lead iodide by weight that 1. prepares of step and 5 parts -6 parts of N, N dimethyl
Diamides is uniformly mixed, and is heated to 75 DEG C -80 DEG C and is completely dissolved to lead iodide, obtains mixed liquid D；
6. by the stage 1) the hydrogen iodide ethanol solution that 1. prepares of step and aminomethane be uniformly mixed, then in ice-water bath 0
45min-50min is persistently stirred in DEG C environment, is then heated to 55 DEG C -60 DEG C while stirring until drying completely, drying is produced
Object is uniformly mixed with 250 parts -280 parts by weight of ether, is filtered after recrystallization, will filter the solid of acquisition under vacuum
Using 55 DEG C -60 DEG C drying completely, stand-by product a is obtained；
7. by 6. stand-by product a that step obtains and stage 1) isopropanol that 2. prepares of step is compounded into Solid content concentration
The mixed liquid E of 9mg/ml-12mg/ml；
8. in the lower surface of 4. prefabricated upper ito glass that step obtains and the upper surface of prefabricated lower ito glass, with
The spin coating rate of 1500rpm/min-1600rpm/min, 5. whole that the uniform spin-coating step of the spin-coating time of 65s-70s obtains are mixed
Liquid D, then by after spin coating prefabricated upper ito glass and prefabricated lower ito glass be placed in vacuum environment using 65 DEG C -70 DEG C completely
The upper ito glass of drying and lower ito glass, are then completely immersed in 7. mixed liquid E that step obtains by drying, keep 25min-
30min, then in the stage 1) under enough nitrogen protections for 2. preparing of step, dries and then be furnace-cooled to completely using 65 DEG C -70 DEG C
Room temperature obtains and makes upper ito glass eventually and make lower ito glass eventually；
9. by the stage 1) poly- 3 hexyl thiophene that 1. prepares of step and stage 1) dichloro-benzenes that 2. prepares of step is compounded into matter
Measure concentration 10mg/ml mixed liquid F, by mixed liquid F with the spin coating rate of 750rpm/min-800rpm/min, 32s-35s spin coating when
Between be spin-coated on the 8. whole lower surface for making upper ito glass and the upper surface for making lower ito glass eventually that step obtains respectively, then will rotation
The whole lower surface for making upper ito glass and the whole upper surface for making lower ito glass coated fits closely in vacuum environment, and in foot
35min-40min is dried under amount nitrogen protection, with being taken out after being furnace-cooled to room temperature, the following table of ito glass under the former system eventually of extract
Face fits closely the fixed stage 1) carbon nano-tube film that 1. prepares of step, the composite construction of acquisition be needed for light-sensing region；
3) thermoinduction liquid manufactures
1. by the stage 1) metallic sodium that 1. prepares of step puts into the ethyl alcohol of 30 times -40 times of its quality, stirs to Quan Rong, obtain
Liquid A must be mixed；
2. by the stage 1) the ethyl alcohol mixture of 1.2 times -1.3 times of the dimethyl malonic ester that 1. prepares of step and its volume
Uniformly, mixed liquid B is obtained；
3. 2. mixed liquid B that step obtains is slowly dropped in 1. mixed liquid A that step obtains by constant pressure funnel, stir
12min-15min obtains mixed liquid C；
4. be slowly added to the stage 1 in 3. mixed liquid C that step obtains) the 2- bromine bromobenzyl that 1. prepares of step, be warming up to 92 DEG C-
95 DEG C, stabilization is back to fully reacting, is cooled to room temperature, there is the mixed liquid D of Solid content in acquisition；
5. the Solid content in 4. mixed liquid D that step obtains is filtered out, by the solution of acquisition using enough ethyl acetate washing rotation
Extraction 3 times -5 times is steamed, colourless liquid is obtained；
It, will be with colourless liquid volume phase 6. 5. colourless liquid that step is obtained is dissolved in the ethyl alcohol of 5 times -8 times of its volume
Deng deionized water and the stage 1) sodium hydroxide that 1. prepares of step is uniformly added into the mixed liquor of colourless liquid and ethyl alcohol, heats
To boiling, be cooled to room temperature after being back to fully reacting, after revolving removal solvent, be added former colourless liquid volume 10% go from
Then sub- water uses the stage 1) aqueous hydrochloric acid solution that 2. prepares of step adjusts PH to 1-1.5, it is kept under 0 DEG C of -5 DEG C of environment
Then 18h-20h rotates to being completely dried, obtains white solid；
7. 6. white solid that step is obtained is dissolved in the n,N-Dimethylformamide of 2 times of its quality, it is heated to 135
DEG C -140 DEG C, 2.5h-3h is kept, revolving removal n,N-Dimethylformamide, residue, which is adopted, to be extracted with ethyl acetate, then uses rank
1) 2. saturated sodium-chloride water solution that step prepares washs to PH and stablizes section, rotate it is dry completely after filter out Solid content, obtain shallow
Yellow oily liquid；
8. the stage 1 is mixed into pale yellowish oil liquid) 1. thionyl chloride that step prepares, 42 DEG C -45 DEG C are heated to, instead
13h-14h is answered, vacuum distillation processing is carried out to reaction solution, the component of 120 DEG C -124 DEG C of vapo(u)rizing temperature of interception, which is yellow
Liquid is mixed into the lead powder of its quality 22%-25% in the yellow liquid of acquisition, then stirs evenly, this is mixed with lead powder
Yellow liquid is required thermoinduction liquid；
4) solar panel manufactures
1. by the stage 1) step 1. prepare polyimide resin, the stage 3) obtain thermoinduction liquid and the stage 1) step is 1.
The bismuth telluride powder of preparation is with mass ratio 30:(32-38): (30-40) proportion uniformly, is then heated to polyamides in vacuum environment
Imide resin is completely melt, then after mixing evenly by three kinds of compositions, is uniformly coated on the stage 2) composite construction that obtains is former eventually
In system on the outer surface of ito glass, be then heated to 80 DEG C -100 DEG C be fully cured to coated film after, then adopt under vacuum conditions
With 250 DEG C -300 DEG C, heat preservation 40min-50min is made annealing treatment, high ultraviolet light needed for obtaining after furnace cooling to room temperature
Mine open country high energy solar panel.
Compared with prior art, the invention has the following advantages that (1) present invention is integrated with photoelectric conversion and heat to electricity conversion
Function, but be not the superposition of simple physics, and the mixture of function whole is realized two different functions with same: both being had
Standby Seebeck effect has excellent photoelectric conversion efficiency again, and does not have ultraviolet photoelectric in another way around the prior art
The pain spot of the mature technology of conversion, the lead by the way that higher density is arranged obstruct the high-energy rays such as ultraviolet light, are on the one hand radiated
On the one hand protection is converted into heat to electricity conversion mode using excitation heat, to complete the absorption of energy.(2) feelings of daylight abundance
Under condition, the photoelectric conversion section of lower layer's (photoelectric conversion section) of the present invention can be realized 17% or so photoelectric conversion rate, in conjunction with
The room temperature ZT coefficient of upper layer (heat to electricity conversion part) 0.4-0.6 of the present invention, the gross energy that actual measurement can averagely reach 25%-32% are inhaled
It receives, while the present invention is due to still keeping the glass matrix structure of surface cure weathering film layer, thus is in fact used directly for
The house top material in the unobstructed region in overhead is manufactured, or is erected above roof or for Tour region sunshade corridor etc., Ke Yiyou
Effect prevents skin sunburn.(3) present invention is substantially to produce heat with low cost, brief processing step, low manufacture threshold
Heat/photoelectric conversion material that electrical property is good, photoelectric properties are outstanding, weatherability is excellent.Thus the present invention turns with integrated electro
Change with heat to electricity conversion function, gross efficiency is high, it is applied widely, ultraviolet light can be assimilated, suitable for the characteristic in wilderness area.
Specific embodiment
Embodiment 1:
A kind of manufacturing method of high ultraviolet light mine open country high energy solar panel, comprising the following steps:
1) raw material prepare
1. raw material prepare: preparing the hydrogen iodide ethanol solution of molar concentration 52mol/L-58mol/L by weight
10.4Kg, aminomethane 17.2Kg, enough lead iodides, butyl titanate 51.6Kg, diethanol amine 14.2Kg, poly- 3 hexyl thiophene
1.14Kg, the carbon nano-tube film of enough 70nm-120nm thickness, metallic sodium 6.8Kg, dimethyl malonic ester 47.4Kg, 2-
Bromine bromobenzyl 58.8Kg, sodium hydroxide 46.5Kg, thionyl chloride 21.6Kg, enough lead powder, enough ito glasses, enough polyimides
The bismuth telluride powder of resin, enough partial size 100nm-200nm；
2. auxiliary material prepares: preparing enough ethyl alcohol, enough ethyl acetate, the hydrochloric acid of enough Solute mass fractions 20% is water-soluble
Liquid, enough saturated sodium-chloride water solutions, enough N,N-dimethylformamides, Enough Dl water, Solute mass fraction 10%
Aqueous solution of nitric acid, enough ether, enough nitrogen, enough dichloro-benzenes, sufficient isopropanol；
2) light-sensing region manufacturing method
1. prepare two pieces of stages 1) ito glass that 1. prepares of step,；
2. by the stage 1) step butyl titanate, diethanol amine and 150 parts of -160 parts of second by weight for 1. preparing
Alcohol is uniformly mixed, and stirs 1.5h-2h with the rate of 600rpm/min-800rpm/min, obtains mixed liquid A；It will by weight
15 parts of -17 parts of deionized waters and 75 parts of -80 parts of ethyl alcohol are compounded into alcohol water miscible fluid, as mixed liquid B；Mixed liquid A and mixed liquid B is mixed
And after mixing evenly, mixed liquid C is obtained, mixed liquid C is stood into 28h-30h in closed environment, mixes liquid C solation, obtains sol solutions
C；
3. 2. sol solutions C that step is obtained is with the spin coating rate of 1200rpm/min-1300rpm/min, each 45s-
The spin-coating time of 50s, spin coating twice, the technique of thickness 150nm-180nm, two pieces 1. obtained in step respectively after coating is dry and hard
Upper and lower total four surfaces of ito glass carry out spin-coat process, obtain in spin coating ito glass under ito glass and spin coating；
4. ito glass under ito glass in 3. spin coating that step obtains and spin coating is placed in resistance furnace, using 460 DEG C-
480 DEG C of temperature toasts 80min-100min, obtains prefabricated upper ito glass and prefabricated lower ito glass
5. by the stage 1) 2 parts -2.5 parts of the lead iodide by weight that 1. prepares of step and 5 parts -6 parts of N, N dimethyl
Diamides is uniformly mixed, and is heated to 75 DEG C -80 DEG C and is completely dissolved to lead iodide, obtains mixed liquid D；
6. by the stage 1) the hydrogen iodide ethanol solution that 1. prepares of step and aminomethane be uniformly mixed, then in ice-water bath 0
45min-50min is persistently stirred in DEG C environment, is then heated to 55 DEG C -60 DEG C while stirring until drying completely, drying is produced
Object is uniformly mixed with 250 parts -280 parts by weight of ether, is filtered after recrystallization, will filter the solid of acquisition under vacuum
Using 55 DEG C -60 DEG C drying completely, stand-by product a is obtained；
7. by 6. stand-by product a that step obtains and stage 1) isopropanol that 2. prepares of step is compounded into Solid content concentration
The mixed liquid E of 9mg/ml-12mg/ml；
8. in the lower surface of 4. prefabricated upper ito glass that step obtains and the upper surface of prefabricated lower ito glass, with
The spin coating rate of 1500rpm/min-1600rpm/min, 5. whole that the uniform spin-coating step of the spin-coating time of 65s-70s obtains are mixed
Liquid D, then by after spin coating prefabricated upper ito glass and prefabricated lower ito glass be placed in vacuum environment using 65 DEG C -70 DEG C completely
The upper ito glass of drying and lower ito glass, are then completely immersed in 7. mixed liquid E that step obtains by drying, keep 25min-
30min, then in the stage 1) under enough nitrogen protections for 2. preparing of step, dries and then be furnace-cooled to completely using 65 DEG C -70 DEG C
Room temperature obtains and makes upper ito glass eventually and make lower ito glass eventually；
9. by the stage 1) poly- 3 hexyl thiophene that 1. prepares of step and stage 1) dichloro-benzenes that 2. prepares of step is compounded into matter
Measure concentration 10mg/ml mixed liquid F, by mixed liquid F with the spin coating rate of 750rpm/min-800rpm/min, 32s-35s spin coating when
Between be spin-coated on the 8. whole lower surface for making upper ito glass and the upper surface for making lower ito glass eventually that step obtains respectively, then will rotation
The whole lower surface for making upper ito glass and the whole upper surface for making lower ito glass coated fits closely in vacuum environment, and in foot
35min-40min is dried under amount nitrogen protection, with being taken out after being furnace-cooled to room temperature, the following table of ito glass under the former system eventually of extract
Face fits closely the fixed stage 1) carbon nano-tube film that 1. prepares of step, the composite construction of acquisition be needed for light-sensing region；
3) thermoinduction liquid manufactures
1. by the stage 1) metallic sodium that 1. prepares of step puts into the ethyl alcohol of 30 times -40 times of its quality, stirs to Quan Rong, obtain
Liquid A must be mixed；
2. by the stage 1) the ethyl alcohol mixture of 1.2 times -1.3 times of the dimethyl malonic ester that 1. prepares of step and its volume
Uniformly, mixed liquid B is obtained；
3. 2. mixed liquid B that step obtains is slowly dropped in 1. mixed liquid A that step obtains by constant pressure funnel, stir
12min-15min obtains mixed liquid C；
4. be slowly added to the stage 1 in 3. mixed liquid C that step obtains) the 2- bromine bromobenzyl that 1. prepares of step, be warming up to 92 DEG C-
95 DEG C, stabilization is back to fully reacting, is cooled to room temperature, there is the mixed liquid D of Solid content in acquisition；
5. the Solid content in 4. mixed liquid D that step obtains is filtered out, by the solution of acquisition using enough ethyl acetate washing rotation
Extraction 3 times -5 times is steamed, colourless liquid is obtained；
It, will be with colourless liquid volume phase 6. 5. colourless liquid that step is obtained is dissolved in the ethyl alcohol of 5 times -8 times of its volume
Deng deionized water and the stage 1) sodium hydroxide that 1. prepares of step is uniformly added into the mixed liquor of colourless liquid and ethyl alcohol, heats
To boiling, be cooled to room temperature after being back to fully reacting, after revolving removal solvent, be added former colourless liquid volume 10% go from
Then sub- water uses the stage 1) aqueous hydrochloric acid solution that 2. prepares of step adjusts PH to 1-1.5, it is kept under 0 DEG C of -5 DEG C of environment
Then 18h-20h rotates to being completely dried, obtains white solid；
7. 6. white solid that step is obtained is dissolved in the n,N-Dimethylformamide of 2 times of its quality, it is heated to 135
DEG C -140 DEG C, 2.5h-3h is kept, revolving removal n,N-Dimethylformamide, residue, which is adopted, to be extracted with ethyl acetate, then uses rank
1) 2. saturated sodium-chloride water solution that step prepares washs to PH and stablizes section, rotate it is dry completely after filter out Solid content, obtain shallow
Yellow oily liquid；
8. the stage 1 is mixed into pale yellowish oil liquid) 1. thionyl chloride that step prepares, 42 DEG C -45 DEG C are heated to, instead
13h-14h is answered, vacuum distillation processing is carried out to reaction solution, the component of 120 DEG C -124 DEG C of vapo(u)rizing temperature of interception, which is yellow
Liquid is mixed into the lead powder of its quality 22%-25% in the yellow liquid of acquisition, then stirs evenly, this is mixed with lead powder
Yellow liquid is required thermoinduction liquid；
4) solar panel manufactures
1. by the stage 1) step 1. prepare polyimide resin, the stage 3) obtain thermoinduction liquid and the stage 1) step is 1.
The bismuth telluride powder of preparation is with mass ratio 30:(32-38): (30-40) proportion uniformly, is then heated to polyamides in vacuum environment
Imide resin is completely melt, then after mixing evenly by three kinds of compositions, is uniformly coated on the stage 2) composite construction that obtains is former eventually
In system on the outer surface of ito glass, be then heated to 80 DEG C -100 DEG C be fully cured to coated film after, then adopt under vacuum conditions
With 250 DEG C -300 DEG C, heat preservation 40min-50min is made annealing treatment, high ultraviolet light needed for obtaining after furnace cooling to room temperature
Mine open country high energy solar panel.
According to the product that the present embodiment produces, average conductivity 310S/cm-350S/cm, 200 μ V/K- of Seebeck coefficient
240 μ V/K, photoelectric conversion rate 16.8%-17.5%, average thermal conductivity 0.45W/ (mK) -0.50W/ (mK), at room temperature ZT
Coefficient is 0.4-0.6, similarly hereinafter.
Embodiment 2:
It is whole consistent with embodiment 1, it is in place of difference:
A kind of manufacturing method of high ultraviolet light mine open country high energy solar panel, comprising the following steps:
1) raw material prepare
1. raw material prepare: the hydrogen iodide ethanol solution 12Kg of preparation molar concentration 52mol/L-58mol/L by weight,
It is aminomethane 18Kg, enough lead iodides, butyl titanate 55Kg, diethanol amine 15Kg, poly- 3 hexyl thiophene 1.2Kg, enough
Carbon nano-tube film, metallic sodium 6.5Kg, dimethyl malonic ester 45Kg, 2- bromine bromobenzyl 58Kg, hydrogen of 70nm-120nm thickness
Sodium oxide molybdena 45Kg, thionyl chloride 20Kg, enough lead powder, enough ito glasses, enough polyimide resins, enough partial size 100nm-
The bismuth telluride powder of 200nm；
Embodiment 3:
It is whole consistent with embodiment 1, it is in place of difference:
A kind of manufacturing method of high ultraviolet light mine open country high energy solar panel, comprising the following steps:
1) raw material prepare
1. raw material prepare: the hydrogen iodide ethanol solution 9Kg of preparation molar concentration 52mol/L-58mol/L by weight,
Aminomethane 16Kg, enough lead iodides, butyl titanate 50Kg, diethanol amine 12Kg, poly- 3 hexyl thiophene 1Kg, enough 70nm-
Carbon nano-tube film, metallic sodium 7Kg, dimethyl malonic ester 50Kg, 2- bromine bromobenzyl 60Kg, sodium hydroxide of 120nm thickness
48Kg, thionyl chloride 22Kg, enough lead powder, enough ito glasses, enough polyimide resins, enough partial size 100nm-200nm
Bismuth telluride powder；
The foregoing description of the disclosed embodiments, only for can be realized professional and technical personnel in the field or use this
Invention.Various modifications to these embodiments will be readily apparent to those skilled in the art, institute herein
The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore,
The present invention will not be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent widest scope of point.
Claims (1)
1. a kind of manufacturing method of high ultraviolet light mine open country high energy solar panel, it is characterised in that the following steps are included:
1) raw material prepare
1. raw material prepare: by weight preparation molar concentration 52mol/L-58mol/L 9 parts -12 parts of hydrogen iodide ethanol solution,
16 parts -18 parts of aminomethane, enough lead iodides, 50 parts -55 parts of butyl titanate, 12 parts -15 parts of diethanol amine, poly- 3 hexyl thiophene
1 part -1.2 parts of pheno, the carbon nano-tube film of enough 70nm-120nm thickness, 6.5 parts -7 parts of metallic sodium, dimethyl malonic ester
45 parts -50 parts, it is 58 parts -60 parts of 2- bromine bromobenzyl, 45 parts -48 parts of sodium hydroxide, 20 parts -22 parts of thionyl chloride, enough lead powder, enough
Ito glass, enough polyimide resins, enough partial size 100nm-200nm bismuth telluride powder；
2. auxiliary material prepares: preparing enough ethyl alcohol, enough ethyl acetate, aqueous hydrochloric acid solution, the foot of enough Solute mass fractions 20%
Measure the nitric acid aqueous solution of saturated sodium-chloride water solution, enough N,N-dimethylformamides, Enough Dl water, Solute mass fraction 10%
Solution, enough ether, enough nitrogen, enough dichloro-benzenes, sufficient isopropanol；
2) light-sensing region manufacturing method
1. prepare two pieces of stages 1) ito glass that 1. prepares of step,；
2. by the stage 1) step butyl titanate, diethanol amine and 150 parts of -160 parts of ethyl alcohol by weight for 1. preparing are mixed
It closes uniformly, 1.5h-2h is stirred with the rate of 600rpm/min-800rpm/min, obtain mixed liquid A；By 15 parts by weight-
17 parts of deionized waters and 75 parts of -80 parts of ethyl alcohol are compounded into alcohol water miscible fluid, as mixed liquid B；Mixed liquid A and mixed liquid B are mixed and stirred
After mixing uniformly, mixed liquid C is obtained, mixed liquid C is stood into 28h-30h in closed environment, mixes liquid C solation, obtains sol solutions C；
3. 2. sol solutions C that step is obtained with the spin coating rate of 1200rpm/min-1300rpm/min, each 45s-50s's
Spin-coating time, spin coating twice, the technique of thickness 150nm-180nm, the two pieces of ITO glass 1. obtained in step respectively after coating is dry and hard
Upper and lower total four surfaces of glass carry out spin-coat process, obtain in spin coating ito glass under ito glass and spin coating；
4. ito glass under ito glass in 3. spin coating that step obtains and spin coating is placed in resistance furnace, using 460 DEG C -480 DEG C
Temperature toast 80min-100min, obtain prefabricated upper ito glass and prefabricated lower ito glass
5. by the stage 1) 2 parts -2.5 parts of the lead iodide by weight that 1. prepares of step and 5 parts -6 parts of N, two acyl of N dimethyl
Amine is uniformly mixed, and is heated to 75 DEG C -80 DEG C and is completely dissolved to lead iodide, obtains mixed liquid D；
6. by the stage 1) the hydrogen iodide ethanol solution that 1. prepares of step and aminomethane be uniformly mixed, then in 0 DEG C of ring of ice-water bath
Persistently stir 45min-50min within the border, be then heated to while stirring 55 DEG C -60 DEG C until completely drying, will drying product with
250 parts -280 parts by weight of ether is uniformly mixed, and is filtered after recrystallization, will be filtered the solid obtained and is used under vacuum
55 DEG C -60 DEG C drying completely, obtain stand-by product a；
7. by 6. stand-by product a that step obtains and stage 1) isopropanol that 2. prepares of step is compounded into Solid content concentration 9mg/
The mixed liquid E of ml-12mg/ml；
8. in the lower surface of 4. prefabricated upper ito glass that step obtains and the upper surface of prefabricated lower ito glass, with 1500rpm/
The spin coating rate of min-1600rpm/min, 5. whole that the uniform spin-coating step of the spin-coating time of 65s-70s obtains mix liquid D, then
By after spin coating prefabricated upper ito glass and prefabricated lower ito glass be placed in vacuum environment using 65 DEG C -70 DEG C completely drying, so
The upper ito glass of drying and lower ito glass are completely immersed in 7. mixed liquid E that step obtains afterwards, keep 25min-30min, so
Afterwards in the stage 1) under enough nitrogen protections for 2. preparing of step, room temperature is dried and then be furnace-cooled to completely using 65 DEG C -70 DEG C, is obtained
Upper ito glass is made eventually and makes lower ito glass eventually；
9. by the stage 1) poly- 3 hexyl thiophene that 1. prepares of step and stage 1) to be compounded into quality dense for the dichloro-benzenes that 2. prepares of step
The mixed liquid F for spending 10mg/ml, by mixed liquid F with the spin-coating time of the spin coating rate of 750rpm/min-800rpm/min, 32s-35s point
It is not spin-coated on the 8. whole lower surface for making upper ito glass and the upper surface for making lower ito glass eventually that step obtains, it is then that spin coating is good
The whole lower surface for making upper ito glass and make the upper surface of lower ito glass eventually and fitted closely in vacuum environment, and in sufficient amount of nitrogen
35min-40min is dried under gas shielded, with taking out after being furnace-cooled to room temperature, the lower surface of ito glass is tight under the former system eventually of extract
It is closely connected to close the fixed stage 1) carbon nano-tube film that 1. prepares of step, the composite construction of acquisition be needed for light-sensing region；
3) thermoinduction liquid manufactures
1. by the stage 1) metallic sodium that 1. prepares of step puts into the ethyl alcohol of 30 times -40 times of its quality, stirs to Quan Rong, mixed
Liquid A；
2. by the stage 1) the ethyl alcohol mixture of 1.2 times -1.3 times of the dimethyl malonic ester that 1. prepares of step and its volume is
It is even, obtain mixed liquid B；
3. 2. mixed liquid B that step obtains is slowly dropped in 1. mixed liquid A that step obtains by constant pressure funnel, 12min- is stirred
15min obtains mixed liquid C；
4. the stage 1 is slowly added in 3. mixed liquid C that step obtains) 1. 2- bromine bromobenzyl that step prepares, it is warming up to 92 DEG C -95
DEG C, stabilization is back to fully reacting, is cooled to room temperature, there is the mixed liquid D of Solid content in acquisition；
5. the Solid content in 4. mixed liquid D that step obtains is filtered out, by the solution of acquisition using enough ethyl acetate washing revolving extraction
It takes 3 times -5 times, obtains colourless liquid；
It, will be equal with colourless liquid volume 6. 5. colourless liquid that step is obtained is dissolved in the ethyl alcohol of 5 times -8 times of its volume
Deionized water and stage 1) sodium hydroxide that 1. prepares of step is uniformly added into the mixed liquor of colourless liquid and ethyl alcohol, is heated to boiling
It rises, is cooled to room temperature after being back to fully reacting, after revolving removal solvent, the deionization of former colourless liquid volume 10% is added
Then water uses the stage 1) aqueous hydrochloric acid solution that 2. prepares of step adjusts PH to 1-1.5,18h- is kept under 0 DEG C of -5 DEG C of environment
Then 20h rotates to being completely dried, obtains white solid；
7. 6. white solid that step is obtained is dissolved in the n,N-Dimethylformamide of 2 times of its quality, it is heated to 135 DEG C -140
DEG C, 2.5h-3h is kept, revolving removal n,N-Dimethylformamide, residue, which is adopted, to be extracted with ethyl acetate, then uses the stage 1) step
Suddenly the saturated sodium-chloride water solution 2. prepared, which is washed to PH, to be stablized, and is filtered out Solid content after rotating drying completely, is obtained light yellow oil
Shape liquid；
8. the stage 1 is mixed into pale yellowish oil liquid) thionyl chloride that 1. prepares of step, 42 DEG C -45 DEG C are heated to, reaction
13h-14h carries out vacuum distillation processing to reaction solution, and the component of 120 DEG C -124 DEG C of vapo(u)rizing temperature of interception, which is yellow liquid
Body is mixed into the lead powder of its quality 22%-25% in the yellow liquid of acquisition, then stirs evenly, this is mixed with the Huang of lead powder
Color liquid is required thermoinduction liquid；
4) solar panel manufactures
1. by the stage 1) step 1. prepare polyimide resin, the stage 3) the thermoinduction liquid that obtains and stage 1) 1. step prepares
Bismuth telluride powder with mass ratio 30:(32-38): (30-40) proportion uniformly, polyimides is then heated in vacuum environment
Resin is completely melt, then after mixing evenly by three kinds of compositions, is uniformly coated on the stage 2) in the former system eventually of composite construction that obtains
On the outer surface of ito glass, be then heated to 80 DEG C -100 DEG C be fully cured to coated film after, then use under vacuum conditions
250 DEG C -300 DEG C, heat preservation 40min-50min is made annealing treatment, high ultraviolet light mine needed for obtaining after furnace cooling to room temperature
Open country high energy solar panel.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910615656.7A CN110289328B (en) | 2019-07-09 | 2019-07-09 | High-ultraviolet light mine high-energy solar cell panel and manufacturing method thereof |
| PCT/CN2019/096368 WO2021003762A1 (en) | 2019-07-09 | 2019-07-17 | High-ultraviolet high-energy solar cell panel for open field and manufacturing method therefor |
| ZA2021/06143A ZA202106143B (en) | 2019-07-09 | 2021-08-25 | High-energy solar panel for high-ultraviolet (uv) wilderness, and manufacturing method thereof |
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| CN201910615656.7A CN110289328B (en) | 2019-07-09 | 2019-07-09 | High-ultraviolet light mine high-energy solar cell panel and manufacturing method thereof |
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|---|---|---|---|---|
| CN105575964A (en) * | 2015-12-22 | 2016-05-11 | 苏州大学 | Self-driven photoelectric detection system combining with solar energy battery and optical detector and preparation method |
| CN106024775A (en) * | 2016-07-15 | 2016-10-12 | 华中科技大学 | Integrated device with thermoelectric power generation sheet and manufacturing method thereof |
| CN106449627A (en) * | 2016-10-26 | 2017-02-22 | 华中科技大学 | Perovskite solar cell integrated device and preparation method thereof |
| CN109346461A (en) * | 2018-10-11 | 2019-02-15 | 西安电子科技大学 | A kind of photoelectric heat replies the photodetector and preparation method thereof of oneself driving of conjunction by cable |
| KR20190073895A (en) * | 2017-12-19 | 2019-06-27 | 한국에너지기술연구원 | Solar photovoltaic-thermoelectric fusion device |
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| CN202018969U (en) * | 2010-12-25 | 2011-10-26 | 紫光股份有限公司 | Solar cell simultaneously performing photoelectric conversion and thermoelectric conversion |
| JP2018116993A (en) * | 2017-01-17 | 2018-07-26 | 東レフィルム加工株式会社 | Rear surface protective sheet for solar cell module |
| CN208127224U (en) * | 2018-04-28 | 2018-11-20 | 贵州中益能新材料科技有限公司 | A kind of solar energy power generating plate that generating efficiency is high |
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2019
- 2019-07-09 CN CN201910615656.7A patent/CN110289328B/en active Active
- 2019-07-17 WO PCT/CN2019/096368 patent/WO2021003762A1/en active Application Filing
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105575964A (en) * | 2015-12-22 | 2016-05-11 | 苏州大学 | Self-driven photoelectric detection system combining with solar energy battery and optical detector and preparation method |
| CN106024775A (en) * | 2016-07-15 | 2016-10-12 | 华中科技大学 | Integrated device with thermoelectric power generation sheet and manufacturing method thereof |
| CN106449627A (en) * | 2016-10-26 | 2017-02-22 | 华中科技大学 | Perovskite solar cell integrated device and preparation method thereof |
| KR20190073895A (en) * | 2017-12-19 | 2019-06-27 | 한국에너지기술연구원 | Solar photovoltaic-thermoelectric fusion device |
| CN109346461A (en) * | 2018-10-11 | 2019-02-15 | 西安电子科技大学 | A kind of photoelectric heat replies the photodetector and preparation method thereof of oneself driving of conjunction by cable |
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