CN110283667A - A kind of Nano-meter SiO_22Multienzyme composite enzyme detergent and preparation method thereof - Google Patents
A kind of Nano-meter SiO_22Multienzyme composite enzyme detergent and preparation method thereof Download PDFInfo
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- CN110283667A CN110283667A CN201910576928.7A CN201910576928A CN110283667A CN 110283667 A CN110283667 A CN 110283667A CN 201910576928 A CN201910576928 A CN 201910576928A CN 110283667 A CN110283667 A CN 110283667A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides a kind of Nano-meter SiO_22Multienzyme composite enzyme detergent, belongs to detergent technical field.The Nano-meter SiO_22Multienzyme composite enzyme detergent is as unit of parts by weight, including following components: Nano-meter SiO_2225-35 parts of dispersion liquid, 64-73 parts, APG1-4 parts of multienzyme composite enzyme.Preparation method is in Nano-meter SiO_22APG is added in dispersion liquid, the mixing of multienzyme composite enzyme is added after being uniformly dispersed, is packed after ageing 48 hours.Detergent of the present invention is by using multienzyme biologic ferment and Nano-meter SiO_22Dispersion liquid improves clean effect, has washing effect good, small and other effects to pollution of waterhead.
Description
Technical field
The invention belongs to detergent technical fields, and in particular to a kind of Nano-meter SiO_22Multienzyme composite enzyme detergent and its system
Preparation Method.
Background technique
The cleaning product that standard detergent mostly uses industrial chemicals and industrial surface activity agent to form, although there is certain wash
The effect of washing, but be a very big pollution sources to water body environment, also there is a degree of damage to washings.Annual discharge
Washes to rivers, Hu Hai is great quantity.For this purpose, reducing pollution of the standard detergent to water source, that is, change washing
The ingredient of agent and to improve washing effect be a problem anxious to be resolved, washes processing for it is resource-effective, environmental-friendly,
Sustainable development is of great significance.
Summary of the invention
The present invention is by providing a kind of Nano-meter SiO_22Multienzyme composite enzyme detergent, it is more to solve detergent in the prior art
The technical issues of easily causing pollution of waterhead for chemicals.
To achieve the above object, the technical solution of the invention is as follows:
A kind of Nano-meter SiO_22Multienzyme composite enzyme detergent, the detergent is as unit of parts by weight, including following components:
Nano-meter SiO_2225-35 parts of dispersion liquid, 64-73 parts, APG1-4 parts of multienzyme composite enzyme.
Preferably, the Nano-meter SiO_2228-30 parts of dispersion liquid, 68-70 parts, APG2-3 parts of multienzyme composite enzyme.
Preferably, the Nano-meter SiO_22Dispersion liquid is as unit of parts by weight, by Nano-meter SiO_221-2 parts, 3-5 parts of glycerine, water
93-96 parts of compositions.
Preferably, the multienzyme composite enzyme by 8-12 parts of citrus, 11-17 parts of pineapple, 3-6 parts of pawpaw, 7-12 parts of brown sugar,
90-110 parts of negative hydrogen ion water, 0.3-0.6 parts of hay bacillus, 0.3-0.7 parts of aspergillus oryzae, 0.3-0.6 parts of aspergillus niger, lichens gemma
0.3-0.7 parts of bacillus mixing, after being sealed by fermentation 30-35 days, filter stock residue extracts fermentation liquid to obtain the final product.
Preferably, in Nano-meter SiO_22APG is added in dispersion liquid, the mixing of multienzyme composite enzyme, ageing are added after being uniformly dispersed
It is packed after 48 hours.
The beneficial effects of the present invention are:
1. the present invention joined Nano-meter SiO_2 in detergent2Have the following characteristics that (1) large specific surface area, adsorption capacity
By force, can very adsorptive enzyme large biological molecule securely, increase the adsorbance and stability of enzyme, keep bioactivity；(2) as solid
The carrier for determining enzyme improves the washing effect of enzyme, into the washes in environment, moreover it is possible to and the contaminant water in environment purification is and more
Enzyme composite enzyme synergistic effect has good catalyticing decomposition action to organic dirt.(3) Nano-meter SiO_22Skin effect and volume
Effect determines that it has good catalytic activity and catalysis reaction selectivity, is much higher than traditional catalyst, thus can be big
The big use for reducing detergent surfactant achievees the effect that good decontamination and protection water ecological setting.
2. multienzyme composite enzyme includes the biological enzyme such as multiple-microorganism protease, plant rennet, lipase, amylase,
The spot of the complicated types such as multiple protein spot in clothes fiber, fatty spot, natural pigment can be decomposed, moreover it is possible to inhibit micro- life
The bad fermentation of object, is not easy smelly impregnating clothing for a long time in summer, and decontamination, raising detergent cooperate withs with other compositions
Clean effect.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiment is only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts,
It shall fall within the protection scope of the present invention.
It in addition, the technical solution between each embodiment of the present invention can be combined with each other, but must be general with this field
Based on logical technical staff can be realized, it will be understood that when the combination of technical solution appearance is conflicting or cannot achieve this
The combination of technical solution is not present, also not the present invention claims protection scope within.
Embodiment 1
A kind of Nano-meter SiO_22Multienzyme composite enzyme detergent, as unit of parts by weight, including following components: Nano-meter SiO_22Point
25 parts of dispersion liquid, 73 parts of multienzyme composite enzyme, APG4 parts, in Nano-meter SiO_22APG is added in dispersion liquid, multienzyme is added after being uniformly dispersed
Composite enzyme mixing, ageing are packed after 48 hours to obtain the final product.
Wherein, the Nano-meter SiO_22Dispersion liquid is as unit of parts by weight, by Nano-meter SiO_221 part, 93 parts of 5 parts of glycerine, water groups
At.
The multienzyme composite enzyme by 12 parts of citrus, 11 parts of pineapple, 5 parts of pawpaw, 12 parts of brown sugar, 100 parts of negative hydrogen ion water,
0.3 part of hay bacillus, 0.4 part of aspergillus oryzae, 0.6 part of aspergillus niger, 0.3 part of bacillus licheniformis mixing, after being sealed by fermentation 33 days, mistake
It filters raw material residue, extracts fermentation liquid to obtain the final product.
Embodiment 2
A kind of Nano-meter SiO_22Multienzyme composite enzyme detergent, as unit of parts by weight, including following components: Nano-meter SiO_22Point
35 parts of dispersion liquid, 64 parts of multienzyme composite enzyme, APG1 parts, in Nano-meter SiO_22APG is added in dispersion liquid, multienzyme is added after being uniformly dispersed
Composite enzyme mixing, ageing are packed after 48 hours to obtain the final product.
Wherein, the Nano-meter SiO_22Dispersion liquid is as unit of parts by weight, by Nano-meter SiO_222 parts, 94 parts of 3 parts of glycerine, water groups
At.
The multienzyme composite enzyme is by 8 parts of citrus, 14 parts of pineapple, 6 parts of pawpaw, 7 parts of brown sugar, 110 parts of negative hydrogen ion water, withered
0.5 part of straw bacterium, 0.7 part of aspergillus oryzae, 0.3 part of aspergillus niger, 0.5 part of bacillus licheniformis mixing, after being sealed by fermentation 35 days, filtering
Raw material residue extracts fermentation liquid to obtain the final product.
Embodiment 3
A kind of Nano-meter SiO_22Multienzyme composite enzyme detergent, as unit of parts by weight, including following components: Nano-meter SiO_22Point
28 parts of dispersion liquid, 68 parts of multienzyme composite enzyme, APG2 parts, in Nano-meter SiO_22APG is added in dispersion liquid, multienzyme is added after being uniformly dispersed
Composite enzyme mixing, ageing are packed after 48 hours to obtain the final product.
Wherein, the Nano-meter SiO_22Dispersion liquid is as unit of parts by weight, by Nano-meter SiO_221 part, 96 parts of 4 parts of glycerine, water groups
At.
The multienzyme composite enzyme by 10 parts of citrus, 17 parts of pineapple, 3 parts of pawpaw, 10 parts of brown sugar, 90 parts of negative hydrogen ion water,
0.6 part of hay bacillus, 0.3 part of aspergillus oryzae, 0.4 part of aspergillus niger, 0.7 part of bacillus licheniformis mixing, after being sealed by fermentation 30 days, mistake
It filters raw material residue, extracts fermentation liquid to obtain the final product.
Embodiment 4
A kind of Nano-meter SiO_22Multienzyme composite enzyme detergent, as unit of parts by weight, including following components: Nano-meter SiO_22Point
30 parts of dispersion liquid, 70 parts of multienzyme composite enzyme, APG3 parts, in Nano-meter SiO_22APG is added in dispersion liquid, multienzyme is added after being uniformly dispersed
Composite enzyme mixing, ageing are packed after 48 hours to obtain the final product.
Wherein, the Nano-meter SiO_22Dispersion liquid is as unit of parts by weight, by Nano-meter SiO_222 parts, 95 parts of 4 parts of glycerine, water groups
At.
The multienzyme composite enzyme is by 11 parts of citrus, 12 parts of pineapple, 5 parts of pawpaw, 8 parts of brown sugar, 95 parts of negative hydrogen ion water, withered
0.5 part of straw bacterium, 0.4 part of aspergillus oryzae, 0.4 part of aspergillus niger, 0.6 part of bacillus licheniformis mixing, after being sealed by fermentation 35 days, filtering
Raw material residue extracts fermentation liquid to obtain the final product.
Test case
1, test method
According to the condition close to Actual laundering, in washing machine using detergent made from the embodiment of the present invention 1 with
Commercially available washing powder A, two kinds of liquid detergents (A, B) carry out decantation test, with the cleaning solution of normal concentration, are added a certain amount of artificial
Carbon black oil soiling solution washs white tee shirt (cotton).It detects detergency and washs pH value, active matter content that heel row discharges water.
2, instrument and equipment and reagent
2.1 domestic full-automatic washing machines 1
2.2 magnetic agitation heaters
2.3 defile template: diameter 5cm
2.4 hard water: 250mg/kg is prepared by GB 6367
3, material
3.1 cloth: white fourth sympathizes (cotton)
The preparation of 3.2 artificial carbon black oil soiling solutions: it is prepared by 5.2 and 5.3 regulations in GB/T13174.
4, it tests
4.1 experimental condition
According to domestic consumer washing habit, following wash conditions think representative.
| The detergent dissolving time | 2 minutes |
| Soaking time | 10 minutes |
| Wash time | 10 minutes |
| Dry the time | 1 minute |
| It rinses for the first time | 4 minutes |
| Dry the time | 3 minutes |
| Second of rinsing | 3 minutes |
| Dry the time | 3 minutes |
4.2 testing procedure
See standard GB/T13174.
5 test results
5.1, the embodiment of the present invention 1 is shown in Table 1 compared with the performance of commercial laundry powder A, liquid detergent A and liquid detergent B.
Each detergent performance comparison result of table 1
5.2 embodiment of the present invention 1 are shown in Table 2 compared with the water-saving performance of commercial laundry powder A, liquid detergent A and liquid detergent B.
Each detergent water-saving performance comparison result of table 2
From the above test it is found that as shown in table 1, the synthesis detergency of detergent of the present invention is higher than similar on the market up to 7.9
The dirt-removing power of laundry product.Simultaneously as shown in Table 1 and Table 2, the pH value of waste water discharged using detergent of the present invention is small, is in neutrality
If or it is acid, and active matter content is low or nothing, performance are better than commercially available laundry product, and environmental pollution is small.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair
Equivalent transformation made by bright description is applied directly or indirectly in other relevant technical fields, is similarly included in
In scope of patent protection of the invention.
Claims (5)
1. a kind of Nano-meter SiO_22Multienzyme composite enzyme detergent, which is characterized in that the detergent as unit of parts by weight, including
Following components: Nano-meter SiO_2225-35 parts of dispersion liquid, 64-73 parts, APG1-4 parts of multienzyme composite enzyme.
2. Nano-meter SiO_2 according to claim 12Multienzyme composite enzyme detergent, which is characterized in that the Nano-meter SiO_22Point
28-30 parts of dispersion liquid, 68-70 parts, APG2-3 parts of multienzyme composite enzyme.
3. Nano-meter SiO_2 according to claim 1 or 22Multienzyme composite enzyme detergent, which is characterized in that the Nano-meter SiO_22
Dispersion liquid is as unit of parts by weight, by Nano-meter SiO_221-2 parts, 3-5 parts of glycerine, 93-96 parts of water compositions.
4. Nano-meter SiO_2 according to claim 1 or 22Multienzyme composite enzyme detergent, which is characterized in that the multienzyme is compound
Ferment is by 8-12 parts of citrus, 11-17 parts of pineapple, 3-6 parts of pawpaw, 7-12 parts of brown sugar, 90-110 parts of negative hydrogen ion water, hay bacillus
0.3-0.6 parts, 0.3-0.7 parts of aspergillus oryzae, 0.3-0.6 parts of aspergillus niger, 0.3-0.7 parts of bacillus licheniformis mixing, are sealed by fermentation
After 30-35 days, filter stock residue extracts fermentation liquid to obtain the final product.
5. a kind of Nano-meter SiO_2 according to claim 1 or 22The preparation method of multienzyme composite enzyme detergent, feature exist
In in Nano-meter SiO_22APG is added in dispersion liquid, the mixing of multienzyme composite enzyme is added after being uniformly dispersed, ageing is packed after 48 hours
?.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910576928.7A CN110283667A (en) | 2019-06-28 | 2019-06-28 | A kind of Nano-meter SiO_22Multienzyme composite enzyme detergent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910576928.7A CN110283667A (en) | 2019-06-28 | 2019-06-28 | A kind of Nano-meter SiO_22Multienzyme composite enzyme detergent and preparation method thereof |
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| CN110283667A true CN110283667A (en) | 2019-09-27 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111171975A (en) * | 2020-01-16 | 2020-05-19 | 广东丽臣奥威实业有限公司 | High-efficiency decontamination surfactant composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101077999A (en) * | 2006-05-25 | 2007-11-28 | 常锋 | Method for preparing multienzyme cleaning agent for medical purpose |
| CN103525593A (en) * | 2013-11-05 | 2014-01-22 | 苏州万隆汽车零部件股份有限公司 | Novel cleaning agent formula for automobile windscreen |
| BR102014003807A2 (en) * | 2014-02-18 | 2014-09-09 | Demoiselle Ind E Com De Prod Para Revitalizacao Ltda | COMPOSITION FOR CLEANING, PROTECTION AND RECOVERY OF SURFACES IN GENERAL AND PRODUCT OBTAINED |
| CN104498211A (en) * | 2014-11-18 | 2015-04-08 | 浙江大学自贡创新中心 | Automobile nano-grade cleaning agent used in waterless car washing |
-
2019
- 2019-06-28 CN CN201910576928.7A patent/CN110283667A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101077999A (en) * | 2006-05-25 | 2007-11-28 | 常锋 | Method for preparing multienzyme cleaning agent for medical purpose |
| CN103525593A (en) * | 2013-11-05 | 2014-01-22 | 苏州万隆汽车零部件股份有限公司 | Novel cleaning agent formula for automobile windscreen |
| BR102014003807A2 (en) * | 2014-02-18 | 2014-09-09 | Demoiselle Ind E Com De Prod Para Revitalizacao Ltda | COMPOSITION FOR CLEANING, PROTECTION AND RECOVERY OF SURFACES IN GENERAL AND PRODUCT OBTAINED |
| CN104498211A (en) * | 2014-11-18 | 2015-04-08 | 浙江大学自贡创新中心 | Automobile nano-grade cleaning agent used in waterless car washing |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111171975A (en) * | 2020-01-16 | 2020-05-19 | 广东丽臣奥威实业有限公司 | High-efficiency decontamination surfactant composition |
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Application publication date: 20190927 |
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