CN110265620A - Lead-acid accumulator saddle and lead-acid accumulator - Google Patents

Lead-acid accumulator saddle and lead-acid accumulator Download PDF

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Publication number
CN110265620A
CN110265620A CN201910580452.4A CN201910580452A CN110265620A CN 110265620 A CN110265620 A CN 110265620A CN 201910580452 A CN201910580452 A CN 201910580452A CN 110265620 A CN110265620 A CN 110265620A
Authority
CN
China
Prior art keywords
lead
saddle
acid accumulator
liquid
plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910580452.4A
Other languages
Chinese (zh)
Inventor
陈冬
黄冬艳
相佳媛
唐明跃
倪丹
丁一
王德力
王德金
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Nuclear Engineering Research and Design Institute Co Ltd
Zhejiang Narada Power Source Co Ltd
Original Assignee
Shanghai Nuclear Engineering Research and Design Institute Co Ltd
Zhejiang Narada Power Source Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Nuclear Engineering Research and Design Institute Co Ltd, Zhejiang Narada Power Source Co Ltd filed Critical Shanghai Nuclear Engineering Research and Design Institute Co Ltd
Priority to CN201910580452.4A priority Critical patent/CN110265620A/en
Publication of CN110265620A publication Critical patent/CN110265620A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/463Separators, membranes or diaphragms characterised by their shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/60Arrangements or processes for filling or topping-up with liquids; Arrangements or processes for draining liquids from casings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/70Arrangements for stirring or circulating the electrolyte
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

It includes plate, porous electrolyte adsorption layer and bracket that the present invention, which provides a kind of lead-acid accumulator saddle and lead-acid accumulator, lead-acid accumulator saddle,.The liquid-leaking nozzle that there is plate electrolysis liquid stream to lead to;Porous electrolyte adsorption layer is for adsorbing electrolyte;The side that branch is set up in plate is used to support plate, and branch is set up in porous electrolyte adsorption layer.Lead-acid accumulator includes any lead-acid accumulator saddle as described above, and lead-acid accumulator further includes battery case and battery cluster, and lead-acid accumulator saddle is between battery cluster and the bottom of battery case.

Description

Lead-acid accumulator saddle and lead-acid accumulator
Technical field
The present invention relates to Lead-acid Battery Technology field, relate more specifically to a kind of lead-acid accumulator saddle and lead acid storage battery Pond.
Background technique
Lead-acid accumulator has many advantages, such as cheap, high reliablity, technology maturation, is widely used in standby, storage The fields such as energy.But with the growth of battery-using time, the anode plate grid of lead-acid accumulator can corrode, and corrode meeting Cause anode plate grid to extend, is easy to cause positive plate to touch below negative bus-bar, causes battery short circuit.Therefore, in battery Certain grid elongate space can be suitably left when design.
The distance for increasing anode plate grid and busbar connector is generallyd use in the prior art or is encased inside in pole group bottom with bullet The saddle method of property.However, aggravation battery cathode busbar connector corrosion can be easy using the distance for increasing anode plate grid and busbar connector. And the method that flexible saddle is encased inside using bottom, usual pressure is again and decrement is in a linear relationship, and the material of selection is not deformation Pressure is too small to be flattened by pole group's own wt, and being exactly that rock deformation pressure is excessive leads in entire life cycle that decrement is less than normal to ask Topic.
Summary of the invention
The present invention in order to overcome the prior art at least one is insufficient, a kind of lead-acid accumulator saddle and lead acid storage battery are provided Pond prevents battery short circuit to provide elongate space when anode plate grid increases, meanwhile, it is capable to electrolyte be stored, to make for a long time Battery supplements electrolyte, extends battery life.
To achieve the goals above, the present invention provides a kind of lead-acid accumulator saddle, including the absorption of plate, porous electrolyte Layer and bracket.The liquid-leaking nozzle that there is plate electrolysis liquid stream to lead to;Porous electrolyte adsorption layer is for adsorbing electrolyte;Branch is set up in The side of plate is used to support plate, and branch is set up in porous electrolyte adsorption layer.
Optionally, liquid-leaking nozzle and bracket are staggered, and bracket includes at least two support legs, and at least two support legs are homogeneous Tie point is met at, the range of the angle between the central axis of each support leg and the plane where plate is 30 °~60 °.
Optionally, liquid-leaking nozzle and bracket are staggered, and bracket includes at least two support legs and support portion, each support leg Intersect with support portion, the range of the angle between the central axis of each support leg and the plane where plate is 30 °~60 °.
Optionally, liquid-leaking nozzle is elongated in the plane where plate, liquid-leaking nozzle have it is multiple, between all liquid-leaking nozzles mutually It is parallel or close to arranged in parallel.
Optionally, each liquid-leaking nozzle is formed by least two opposite leakage side walls, is had on each leakage side wall Multiple leakage apertures, liquid-leaking nozzle are funnel-shaped.
Optionally, liquid-leaking nozzle the plane where plate in a ring, circle, triangle, it is rectangular, oval and be more than four Any one or the combination of several of them in the polygon on side.
Optionally, the range of the porosity of porous electrolyte adsorption layer is between 60%~99%.
Optionally, bracket is by polyethylene, polypropylene, polyvinyl chloride, polystyrene, ABS, polyamide, polycarbonate, poly- four Any one or more in vinyl fluoride, phenolic resin and epoxy resin is made, and porous electrolyte adsorption layer is by glass fibre, poly- Any one or more in urethane and polytetrafluoroethylene (PTFE) is made.
Optionally, the thickness range of plate is 1mm~3mm, and the range in the aperture of liquid-leaking nozzle is 5mm~10mm, support leg The range of thickness be 1mm~3mm, the length range of support leg is 5mm~20mm.
The present invention also provides a kind of lead-acid accumulators, including any lead-acid accumulator saddle as described above, lead acid storage battery Pond further includes battery case and battery cluster, and lead-acid accumulator saddle is between battery cluster and the bottom of battery case.
In conclusion lead-acid accumulator provided by the invention, electrolyte flows to porous electrolyte absorption after penetrating liquid-leaking nozzle In layer, since porous electrolyte adsorption layer has porous structure, electrolyte can adsorb and be stored in the hole of electrolyte adsorption layer It is interior.With the growth of ageing time, corrosion elongation occurs for anode plate grid, and so as to cause the contraction of saddle, the extruding of stress is from more Electrolyte is released in the electrolyte adsorbent material of hole, so as to effectively supplement battery dehydration, extends battery life.Furthermore Bracket is that entire lead-acid accumulator saddle provides a supporting role, and prevents saddle from deforming, provides space for the elongation of electrode plate.
Detailed description of the invention
Fig. 1 is a kind of side view for lead-acid accumulator saddle that the embodiment one in the present invention provides;
Fig. 2 is a kind of bottom view for lead-acid accumulator saddle that the embodiment one in the present invention provides;
Fig. 3 is the shrinkage for the lead-acid accumulator saddle that each embodiment in the present invention provides and the change curve of pressure Figure;
Fig. 4 is floating-charge durable test curve of the lead-acid accumulator of each embodiment offer in the present invention at 60 DEG C Figure;
Fig. 5 is the structural schematic diagram of another bracket in the present invention;
Fig. 6 is the bottom view of another lead-acid accumulator saddle in the present invention.
Specific embodiment
For above and other objects of the present invention, feature and advantage can be clearer and more comprehensible, preferred embodiment is cited below particularly, And cooperate attached drawing, it is described in detail below.
Plane in the present invention where plate refers to the plane where the contact surface of plate and bracket.
Embodiment one
Fig. 1 is please referred to 2.The present invention provides a kind of lead-acid accumulator saddle A, including plate 1, porous electrolyte adsorption layer 4 and bracket 3.The liquid-leaking nozzle 2 that there is plate 1 electrolysis liquid stream to lead to;Porous electrolyte adsorption layer 4 is for adsorbing electrolyte;Bracket 3 It is used to support plate 1 set on the side of plate 1, bracket 3 is set in porous electrolyte adsorption layer 4.
The present invention also provides a kind of lead-acid accumulators, including any lead-acid accumulator saddle as described above, lead acid storage battery Pond further includes battery case 5 and battery cluster, and lead-acid accumulator saddle is between battery cluster and the bottom of battery case 5.
In the use process of lead-acid accumulator, electrolyte flows in porous electrolyte adsorption layer 4 after penetrating liquid-leaking nozzle 2, Since porous electrolyte adsorption layer 4 has porous structure, electrolyte can be adsorbed and is stored in the hole of electrolyte adsorption layer 4. With the growth of ageing time, corrosion elongation occurs for anode plate grid, and so as to cause the contraction of saddle, the extruding of stress is from porous electricity Electrolyte is released in solution liquid adsorbent material, so as to effectively supplement battery dehydration, extends battery life.Furthermore bracket 3 It is provided a supporting role for entire lead-acid accumulator saddle, prevents saddle from deforming, provide space for the elongation of electrode plate.
As depicted in figs. 1 and 2, bracket 3 of the invention and liquid-leaking nozzle 2 are staggered, and bracket 3 includes two support legs 31, In 180 ° of settings, two support legs 31 intersect at tie point for two support legs 31, and two of two 31 support phases pair of support leg Direction.During actual setting, the direction of the support leg 31 of adjacent bracket 3 can be orthogonal, such as first bracket 3 Support leg 31 is that left and right is put and the adjacent support leg 31 of first bracket 3 is put for front and back, so that entire saddle be made to have more There is stability.In other embodiments, bracket 3 can also include any more than two or multiple support legs 31, such as three, three 120 ° of settings, three support legs 31 provide comprehensive stability for entire saddle to a support leg 31 each other.
In other embodiments, as shown in figure 5, bracket 3 can also include at least two support legs 31 and support portion 32, branch For connecting respectively with plate 1, support leg 31, each support leg 31 and support portion 32 intersect for support part 32.Electrolyte is in support leg 31 and support portion 32 near intersections mobility it is weaker.The intersection point of support leg 31 and support portion 32 is not overlapped, 31 He of support leg The angle position of support portion 32 is staggered, more conducively to the flowing of electrolyte.
In this present embodiment, bracket 3 is a club shaped structure, is porous under the premise of guaranteeing has excellent support effect Electrolyte adsorption layer 4 provides space.But in other embodiments, bracket 3 can also be planar distribution or block structure, For example, support leg 31 can also be circular conical surface in cone, support leg 31, better stability is provided.
In this present embodiment, bracket 3 is made of polyacrylic acid material, but in other embodiments, and bracket 3 can be with Using polyethylene, polypropylene, polyvinyl chloride, polystyrene, ABS, polyamide, polycarbonate, polytetrafluoroethylene (PTFE), phenolic resin and Any one or more of the medium plastic material of epoxy resin is made.Bracket 3 is prepared using plastics, is guaranteeing bracket 3 with one Under the premise of determining hardness and can supporting battery cluster, also there is good insulation performance and will not occur with electrolyte anti- It answers.In this present embodiment, porous electrolyte adsorption layer 4 is made of glass fibre.But in other embodiments, porous electrolyte Adsorption layer 4 can also be made of any one or more in glass fibre, polyurethane and polytetrafluoroethylene (PTFE).
In this present embodiment, plate 1 is plate-like structure, but in other embodiments, plate 1 can also be multiple small Flat plate splicing is formed, and " V " type groove is spliced between multiple tablets, and bracket 3 is connected with the high-end place of " V " type groove, leakage Hole 2 is set to the lower end of " V " type groove.It can also be integrally formed to the plate 1 with " V " type groove.
In this present embodiment, liquid-leaking nozzle 2 is elongated in the plane where plate 1, and liquid-leaking nozzle 2 has multiple, all leakages It is parallel to each other or close to arranged in parallel between fluid apertures 2.Further, each liquid-leaking nozzle 2 is opposite by least two Leakage side wall 21 is formed, and has multiple leakage apertures on each leakage side wall 21, and liquid-leaking nozzle 2 is funnel-shaped.
In other embodiments, liquid-leaking nozzle 2 the plane where plate 1 in a ring, it is circle, triangle, rectangular, oval And more than any one or the combination of several of them in the polygon on four sides.As shown in fig. 6, liquid-leaking nozzle 2 is flat where plate 1 Face in a ring, 2 interlaced arrangement of bracket 3 and liquid-leaking nozzle.
In this present embodiment, the range of the porosity of porous electrolyte adsorption layer 4 is between 60%~99%.
Lead-acid accumulator saddle in the present embodiment the production method is as follows described: with polypropylene material preparation having a size of The thickness of the bracket 3 of 160mm × 130mm, bracket 3 and support leg 31 is respectively 1.5mm and 1mm, and 31 length of support leg is 15mm, The aperture of liquid-leaking nozzle 2 is 5mm, and the angle between the central axis of each support leg 31 and the plane where plate 1 is 45 DEG C;It is complete It after glass fibre slurrying, will be filled in 3 bottom gap of plastic stent after preparing at plastic stent 3, cut compression moulding, obtain The saddle A of 2V500Ah model lead-acid battery.
In other embodiments, the thickness of plate 1 can be 1mm or 3mm or 2mm or the model arbitrarily belonging to claim Enclose other interior numerical value, the aperture of liquid-leaking nozzle 2 can be for 5mm or 10mm or 6mm or 7mm or 8mm or 9mm or arbitrarily in right Other numerical value in range belonging to it is required that.The thickness of support leg 31 can arbitrarily be wanted for 1mm or 3mm or 2mm or in right Seek other numerical value in affiliated range, the length of support leg 31 can weighed for 5mm or 20mm or 10mm or 15mm or arbitrarily Benefit requires other numerical value in affiliated range.These numerical value are configured according to the size of lead-acid accumulator battery case 5.
Embodiment two
The shape and structure and embodiment one of bracket 3 in embodiment two are identical, and identical structure uses identical label, Only difference is explained below.The bracket 3 having a size of 160mm × 130mm, bracket 3 and branch are prepared with pvc material The thickness of support foot 31 is respectively 2mm and 1.5mm, and 31 length of support leg is 15mm, the central axis and plate 1 of each support leg 31 Angle between the plane at place is 45 DEG C;It completes that porous polyurethane material is filled in plastic stent 3 after prepared by bracket 3 Bottom gap obtains the saddle B of 2V500Ah model lead-acid battery.
Comparative example
It is prepared using conventional polyurethanes material and makees ratio having a size of 160mm × 130mm × 10mm lead-acid battery saddle C Compared with;
The saddle in testing example one, embodiment two and comparative example cashes size as the variation of pressure is bent respectively Line (as shown in Figure 3), it is seen that common saddle C has occurred and that in the case where being less than 500N pressure hands over big deformation, i.e., in pole group's gravity Common saddle has occurred and that serious deformation down, can not play the role of providing elongate space, and embodiment in life cycle The flexible of 2mm then only occurring under the power of 800N for the saddle B in saddle A and embodiment one in one, the later period 800~ The flexible of about 5mm can still occur for 1500N, it means that saddle A and saddle B can be provided more in battery use process Elongate space.
Furthermore three kinds of saddles are further placed in 2V500Ah battery bottom, pour into acid solution be melted into obtain battery A, battery B, Battery C;Battery is subjected to 60 DEG C of durability tests (as shown in Figure 4) by national standard GB/T 19638.1-2014 requirement, it is therefore prevented that general The battery C of logical saddle, which has only recycled 9 times and just fallen, has arrived 80% or less rated capacity;And it placed the battery A and B of invention saddle It can achieve 12 times and 13 times respectively, the high-temperature floating-charge service life is obviously improved, this is because a large amount of using storing in invention saddle Electrolyte, with the growth of ageing time, corrosion elongation occurs for anode plate grid, and so as to cause the contraction of saddle, stress is squeezed Pressure releases electrolyte from porous electrolyte adsorbent material, so as to effectively supplement battery dehydration, extends battery life.
It will be understood by those skilled in the art that in exposure of the invention, term " on ", "lower", "front", "rear", The orientation or positional relationship of the instructions such as "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside" is based on attached drawing institute The orientation or positional relationship shown, is merely for convenience of description of the present invention and simplification of the description, rather than indication or suggestion meaning Device or element must have a particular orientation, be constructed and operated in a specific orientation, therefore above-mentioned term should not be understood as pair The limitation of invention.
Although the present invention is disclosed above by preferred embodiment, however, it is not intended to limit the invention, this any known skill Skill person can make some changes and embellishment without departing from the spirit and scope of the present invention, therefore protection scope of the present invention is worked as Subject to claims range claimed.

Claims (10)

1. a kind of lead-acid accumulator saddle characterized by comprising
Plate, the liquid-leaking nozzle led to electrolysis liquid stream;
Porous electrolyte adsorption layer, for adsorbing electrolyte;And
Bracket is used to support the plate set on the side of the plate, and the branch is set up in the porous electrolyte adsorption layer It is interior.
2. lead-acid accumulator saddle described in accordance with the claim 1, which is characterized in that the liquid-leaking nozzle and the bracket staggered row Cloth, the bracket include at least two support legs, and at least two support leg intersects at tie point, in each support leg The range of the angle between plane where mandrel line and the plate is 30 °~60 °.
3. lead-acid accumulator saddle described in accordance with the claim 1, which is characterized in that the liquid-leaking nozzle and the bracket staggered row Cloth, bracket include at least two support legs and support portion, and each support leg and the support portion intersect, the center of each support leg The range of the angle between plane where axis and the plate is 30 °~60 °.
4. according to lead-acid accumulator saddle any one of claims 1 to 3, which is characterized in that the liquid-leaking nozzle is described Plane where plate is elongated, the liquid-leaking nozzle have it is multiple, it is parallel to each other between all liquid-leaking nozzles or close to parallel Arrangement.
5. lead-acid accumulator saddle according to claim 4, which is characterized in that each liquid-leaking nozzle is by least two phases Pair leakage side wall formed, there are multiple leakage apertures, the liquid-leaking nozzle is funnel-shaped on each leakage side wall.
6. according to lead-acid accumulator saddle any one of claims 1 to 3, which is characterized in that the liquid-leaking nozzle is described Plane where plate in a ring, circle, triangle, any one in rectangular, oval and polygon more than four sides Or several combination.
7. lead-acid accumulator saddle described in accordance with the claim 1, which is characterized in that the hole of the porous electrolyte adsorption layer The range of rate is between 60%~99%.
8. lead-acid accumulator saddle described in accordance with the claim 1, which is characterized in that the bracket is by polyethylene, polypropylene, poly- Any one in vinyl chloride, polystyrene, ABS, polyamide, polycarbonate, polytetrafluoroethylene (PTFE), phenolic resin and epoxy resin Or it is a variety of be made, the porous electrolyte adsorption layer by glass fibre, polyurethane and polytetrafluoroethylene (PTFE) any one or it is more Kind is made.
9. lead-acid accumulator saddle described in accordance with the claim 1, which is characterized in that the thickness range of the plate be 1mm~ 3mm, the range in the aperture of the liquid-leaking nozzle are 5mm~10mm.
10. a kind of lead-acid accumulator, including the lead-acid accumulator saddle as described in any in claim 1 to 9, the plumbic acid stores Battery further includes battery case and battery cluster, and the lead-acid accumulator saddle is located at the bottom of the battery cluster and the battery case Between portion.
CN201910580452.4A 2019-06-28 2019-06-28 Lead-acid accumulator saddle and lead-acid accumulator Pending CN110265620A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910580452.4A CN110265620A (en) 2019-06-28 2019-06-28 Lead-acid accumulator saddle and lead-acid accumulator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910580452.4A CN110265620A (en) 2019-06-28 2019-06-28 Lead-acid accumulator saddle and lead-acid accumulator

Publications (1)

Publication Number Publication Date
CN110265620A true CN110265620A (en) 2019-09-20

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CN201910580452.4A Pending CN110265620A (en) 2019-06-28 2019-06-28 Lead-acid accumulator saddle and lead-acid accumulator

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001351671A (en) * 2000-06-09 2001-12-21 Furukawa Battery Co Ltd:The Lead storage battery
CN1794485A (en) * 2005-12-18 2006-06-28 山西通用集团股份有限公司 Elastic pad for fixing valve control lead-acid battery
CN201853775U (en) * 2010-07-17 2011-06-01 山西吉天利科技实业有限公司 Service life extender for valve regulated sealed lead acid storage battery
CN208157563U (en) * 2018-04-23 2018-11-27 安徽理士电源技术有限公司 A kind of lead-acid accumulator
CN210837927U (en) * 2019-06-28 2020-06-23 浙江南都电源动力股份有限公司 Lead-acid storage battery saddle and lead-acid storage battery

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001351671A (en) * 2000-06-09 2001-12-21 Furukawa Battery Co Ltd:The Lead storage battery
CN1794485A (en) * 2005-12-18 2006-06-28 山西通用集团股份有限公司 Elastic pad for fixing valve control lead-acid battery
CN201853775U (en) * 2010-07-17 2011-06-01 山西吉天利科技实业有限公司 Service life extender for valve regulated sealed lead acid storage battery
CN208157563U (en) * 2018-04-23 2018-11-27 安徽理士电源技术有限公司 A kind of lead-acid accumulator
CN210837927U (en) * 2019-06-28 2020-06-23 浙江南都电源动力股份有限公司 Lead-acid storage battery saddle and lead-acid storage battery

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