CN110260990A - For measuring the thermocouple assembly of reactor temperature - Google Patents

For measuring the thermocouple assembly of reactor temperature Download PDF

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Publication number
CN110260990A
CN110260990A CN201910673213.3A CN201910673213A CN110260990A CN 110260990 A CN110260990 A CN 110260990A CN 201910673213 A CN201910673213 A CN 201910673213A CN 110260990 A CN110260990 A CN 110260990A
Authority
CN
China
Prior art keywords
thermocouple
sleeve pipe
protection sleeve
shank
thermocouple assembly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910673213.3A
Other languages
Chinese (zh)
Inventor
俞永尧
骆国荣
张斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Advanced Chemicals Co Ltd
Original Assignee
BASF Auxiliary Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Auxiliary Chemicals Co Ltd filed Critical BASF Auxiliary Chemicals Co Ltd
Priority to CN201910673213.3A priority Critical patent/CN110260990A/en
Publication of CN110260990A publication Critical patent/CN110260990A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K1/00Details of thermometers not specially adapted for particular types of thermometer
    • G01K1/14Supports; Fastening devices; Arrangements for mounting thermometers in particular locations
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K15/00Testing or calibrating of thermometers
    • G01K15/007Testing

Abstract

The present invention provides a kind of thermocouple assembly (1) for measuring reactor temperature; include: the protection sleeve pipe (2) with first end (21) and opposite second end (22), is configured to the casing from second end towards the tapered general conical of first end;Thermocouple (3); the thermocouple includes shank (31) and the temperature sensor (32) for being connected to the shank; the shank is removably secured the second end (22) for being connected to the protection sleeve pipe, which extends into the protection sleeve pipe towards the first end (21);With installation pedestal (4), it is used to thermocouple assembly being fixedly installed to reaction kettle;Wherein, shank (31) is equipped with fexible bias pressure mechanism (5); the fexible bias pressure mechanism is configured to when the shank is fixedly attached to the protection sleeve pipe, and temperature sensor (32) described in the fexible bias pressure mechanism bias contacts it with the first end of protection sleeve pipe (21) always.The invention further relates to a kind of reaction kettle devices for being equipped with above-mentioned thermocouple assembly.

Description

For measuring the thermocouple assembly of reactor temperature
Technical field
The present invention relates to reaction kettle technical fields, more particularly, to measure the thermocouple assembly of reactor temperature, with And the reaction kettle using this thermocouple assembly.
Background technique
In reaction kettle technical field, the thermometer boss of the thermocouple assembly for measuring reactor temperature is usually Cylinder, in reaction kettle work, the thermometer boss in reaction kettle will receive the impact of high-speed rotating material in kettle, at it Root can generate very big bending stress, it is possible to will cause thermometer boss fracture.
It is different additionally, due to the material of thermometer and casing, when being influenced by reactor temperature, the journey expanded with heat and contract with cold Degree is different, and thermometer and casing is caused to disengage, so as to cause temperature-measuring results inaccurate.
Currently, generally using a temperature measuring equipment such as thermocouple come thermometric in reaction kettle, if temperature measuring equipment damages It has no way of finding out about it.
Summary of the invention
To solve the above-mentioned problems, the present invention provides a kind of new thermocouple assembly, and with an improved the structure of casing, enhancings The intensity of sleeve bottom, and thermocouple can always with casing-contact, to have improved thermometric accuracy.
For this purpose, the present invention provide it is a kind of for measuring the thermocouple assembly of reactor temperature, comprising: protection sleeve pipe, With first end and opposite second end, which is configured to the general conical tapered towards the first end from the second end Casing;Thermocouple, the thermocouple include shank and the temperature sensor for being connected to the shank, which is removably secured company It is connected to the second end of the protection sleeve pipe, which extends into the protection sleeve pipe towards the first end;With installation base Seat, the installation pedestal are used to thermocouple assembly being fixedly installed to reaction kettle;Wherein, shank is equipped with fexible bias pressure mechanism, described Fexible bias pressure mechanism is configured to when the shank is fixedly attached to the protection sleeve pipe, which can be biased described Temperature sensor make its always with first end in contact of the protection sleeve pipe.
In the above-mentioned technical solutions, since protection sleeve pipe is configured to the casing of general conical, so that compared to cylinder Casing, in reaction kettle operation, the impact force that the casing of general conical receives is smaller, can prevent the ontology of protection sleeve pipe from rolling over It is disconnected, especially prevent sleeve body fractureing in root.In addition, the shank, which is removably secured, is connected to the protection sleeve pipe, So that can easily be replaced when temperature sensor breaks down.Also, fexible bias pressure mechanism is set, so that temperature sensing Device can be contacted with protection sleeve pipe always, improve the thermometric accuracy of thermocouple.
In a scheme of the invention, shank passes through the inner thread piece being arranged on the shank and is arranged in protection sleeve pipe Second end at external thread piece be threadedly coupled to the protection sleeve pipe.It should be appreciated that shank can be detachable by other mechanisms Ground is connected to protection sleeve pipe, these are also covered by within the scope of application.
In another scheme of the invention, shank can have hollow housing portion, which is located at hollow shell In body portion, the one end in the hollow housing portion is equipped with through-hole, which extends through the through-hole and be connected to the fexible bias pressure Mechanism.
In a concrete scheme, fexible bias pressure mechanism includes being fixed on the one end in hollow housing portion at interval At least two screw elements, the plate-like piece being installed at least two screw element, and wear on each screw element Helical spring, wherein helical spring between plate-like piece and the head of the screw element and be configured to the plate-like piece apply Biasing force, and the temperature sensor is fixedly attached to the plate-like piece.When thermocouple is influenced by the temperature change in reaction kettle, And when gap occur in temperature sensor and protection sleeve pipe, due to the tension force effect of helical spring, to apply to plate-like piece inclined Therefore pressure is simultaneously biased power to temperature sensor.
In an arrangement, installation pedestal is configured with the form of the ring flange of mounting hole, passes through ring flange and fastening Part such as bolt cooperates, and thermocouple assembly can be installed to reaction kettle.
In the present invention, protection sleeve pipe is made of the high material of thermal coefficient, these materials are, for example, that copper, aluminium or copper aluminium close Gold.Thus one, it can be ensured that the thermometric accuracy of thermocouple.
It can be coated with corrosion-resistant, anti-stick metal coating in the outer surface of an advantageous scheme, the protection sleeve pipe, Such as nickel coating.By the way that such coating is arranged, it can prevent the reactant in reaction kettle from corroding casing and adhere to protection Casing, in order to avoid influence the thermometric accuracy of thermocouple assembly.
The present invention also provides a kind of reaction kettle devices comprising: the autoclave body with circular arc-shaped bottom portion;Stirrer paddle;With it is upper At least two thermocouple assemblies are stated, thermocouple assembly is installed to autoclave body and extended into inside reaction kettle device.By being arranged at least Two thermocouple assemblies, proofread thermometric numerical value mutually, and if one of thermocouple assembly damage, can and Shi Zhixiao.
In a preferred embodiment, reaction kettle device includes two thermocouple assemblies, stirrer paddle close to this is arc-shaped The end of bottom offers two recesses corresponding with two thermocouple assemblies, so that not contacting when stirrer paddle rotation The thermocouple assembly.
Detailed description of the invention
The attached drawing constituted part of this application is used to provide further understanding of the present invention, schematic reality of the invention It applies example and its explanation is used to explain the present invention, do not constitute improper limitations of the present invention.In the accompanying drawings:
Fig. 1 is that the structure according to the present invention for measuring one embodiment of the thermocouple assembly of reactor temperature is shown It is intended to;
Fig. 2 is the structural schematic diagram of the protection sleeve pipe of thermocouple assembly shown in FIG. 1;
Fig. 3 is the structural schematic diagram of the thermocouple of thermocouple assembly shown in FIG. 1;
Fig. 4 is the structural schematic diagram for being equipped with the reaction kettle device of thermocouple assembly shown in FIG. 1;With
Fig. 5 is the portion the A enlarged drawing in Fig. 4.
Specific embodiment
Describe to realize according to the present invention below with reference to accompanying drawings and by embodiment is used to measure reactor temperature Thermocouple assembly.In the following description, numerous specific details are set forth to make person of ordinary skill in the field more Comprehensively understand the present invention.But for the technical staff in technical field it is evident that realization of the invention can not have Have some in these details.However, it should be understood that the specific embodiment that the present invention is not limited to be introduced.Phase Instead, it may be considered that implement the present invention with any combination of following feature and element, regardless of they whether be related to it is different Embodiment.
Fig. 1 shows according to the present invention for measuring one embodiment of the thermocouple assembly 1 of reactor temperature.From As can be seen that thermocouple assembly 1 includes protection sleeve pipe 2 in figure, it is removably secured the thermocouple 3 for being connected to the protection sleeve pipe, And the installation pedestal 4 between protection sleeve pipe 2 and thermocouple 3 is set, which is used for the fixed peace of thermocouple assembly 1 It is filled to reaction kettle.In this embodiment, protection sleeve pipe 2 is the casing of general conical, with first end 21 and opposite second End 22, the protection sleeve pipe is substantially tapered from second end 22 towards first end 21.Thermocouple 3 includes shank 31 and is connected to the shank Temperature sensor 32 (or referred to as thermometer), wherein the shank is removably secured the second end for being connected to protection sleeve pipe 2 22, and temperature sensor 31 extends into protection sleeve pipe 2 towards the first end 21.Advantageously, shank 31 is equipped with elasticity partially Press mechanism 5 is configured under the assembled state of thermocouple 3, i.e., when the shank is fixedly attached to the protection sleeve pipe, elasticity is partially Press mechanism 5 can apply the biasing force of the first end towards protection sleeve to temperature sensor 32, so that temperature sensor 32 is special It is not that it keeps contacting with the first end 21 of protection sleeve pipe always towards one end of the first end of protection sleeve pipe 3.
Referring to Fig. 1 and Fig. 2, for example, the casing of general conical can be configured to the first cylinder positioned at first end 21 Shape section 21a positioned at the second cylindrical section 22a of second end 22, and is located between the first and second cylindrical section Conical section.Herein, installation pedestal 4 is configured to that the form for the ring flange being attached on the second cylindrical section 22a can be covered, Ring flange has mounting hole 4a, and by the cooperation of mounting hole and the autoclave body of fastener and reaction kettle, thermocouple assembly 1 is installed To reaction kettle.
In this embodiment, as shown in figures 1 and 3, shank 31 can be by 33 He of inner thread piece that is arranged on the shank External thread piece 23 at the second end of the protection sleeve pipe 2 is set and is threadedly coupled to the protection sleeve pipe 2.Particularly, shank 31 It is configured with hollow housing portion 30, the one end towards protection sleeve pipe 2 in the hollow housing portion 30 is equipped with through-hole 6, inner thread piece 33 be connected to the hollow housing portion 30 the end or the pipe that is integrally formed therewith, the pipe have interior Screw thread.External thread piece 23 is to be connected to the second cylinder section 22a or integrally extend to form from second cylinder section 22a Pipe, which has external screw thread with above-mentioned screw-internal thread fit.Threaded connection shown here is only It is schematically, other suitable detachable connection methods between shank 31 and protection sleeve pipe 2 are also covered by the guarantor in the application It protects in range.
Referring particularly to Fig. 3, a specific embodiment of fexible bias pressure mechanism 5 is shown.Fexible bias pressure mechanism 5 is located at hollow In housing section 30, and temperature sensor 32 extends through the through-hole and is connected to the fexible bias pressure mechanism 5.In one example, bullet Property bias mechanism 5 include be fixed at interval hollow housing portion 30 described one end two screw elements 51, be installed on this two Plate-like piece 52 on a screw element, and the helical spring 53 on each screw element is worn, wherein the helical spring is located at To apply the plate-like piece towards protection sleeve between the plate-like piece and the head of the screw element and in compressive state Biasing force, and the temperature sensor is fixedly attached to the plate-like piece 52.Screw element 51 may be configured to only be screwed into hollow housing Part in portion 30 has screw thread, and does not set screw thread between the part and the head of screw, enables plate-like piece 52 sliding along screw It is dynamic.In this embodiment, though it is shown that being provided only with two screw elements, it is to be understood that, more screw elements, example can be equipped with Such as three, four are also covered by within the scope of protection of this application.
Under the assembled state of thermocouple assembly 1, when the first end of the free end contact protection sleeve 2 of temperature sensor 32 When 21, gap is advantageously present between the plate-like piece 52 and the inner wall in hollow housing portion 30.When thermocouple assembly 1 is reacted It, can temperature if the degrees of expansion of protection sleeve pipe is greater than the degrees of expansion of temperature sensor itself when high temperature in kettle influences The first end of sensor and protection sleeve pipe will be disengaged from contacting, this will affect the measurement accuracy of thermocouple.However due in plate It is equipped with helical spring 53 between part 52 and the head of screw element, and is deposited between plate-like piece 52 and the inner wall in hollow housing portion 30 In gap, helical spring 53 is enabled to be biased power to plate-like piece 52, so that plate-like piece 52 be pushed to move towards protection sleeve pipe 2 It is dynamic, and then drive the temperature sensor for being fixed to plate-like piece 52 mobile towards protection sleeve pipe 2, until protective case described in abutting contact The first end 21 of pipe, so that it is guaranteed that the thermometric accuracy of thermocouple assembly.
When the thermocouple protective casing applied under hot conditions is wanted in production, material removes the gas for having common thermocouple requirement It outside close property, mechanical strength, stability and thermal conductivity, also requires: high temperature resistant: using, do not generate in the electric thermo-couple temperature measurement upper limit Rotten and deformation, antioxygenic property is good at high temperature;Heat resistance: do not soften at use temperature in thermocouple;Corrosion resistance: work as thermoelectricity When even protection sleeve pipe must immerse in reaction medium, there should be the corrosion resistance to these media;With certain resistance to jump in temperature Performance, the comprehensive performance of anti-thermal shock, thermal conductivity is high, thermally expands small.In the present invention, in order to ensure the thermometric of thermocouple assembly is accurate Property, protection sleeve pipe are made of the high material of thermal coefficient, and the material is, for example, copper, aluminium or albronze.Advantageously, protection The outer surface of casing 2 can also be coated with corrosion-resistant, anti-stick metal coating, such as nickel coating.
Fig. 4 and Fig. 5 shows to be equipped with the structural representation of the reaction kettle device 11 of thermocouple assembly 1 according to the present invention Figure.As shown, reaction kettle device 11 includes the autoclave body 12 with circular arc-shaped bottom portion, stirrer paddle 13, and installation is to the kettle Body simultaneously extends into two thermocouple assemblies 1 inside the reaction kettle device.Wherein, close arc-shaped bottom of stirrer paddle 13 The end in portion offers two recesses 14 corresponding with two thermocouple assemblies, so that not when stirrer paddle rotation Contact the thermocouple assembly.Herein, using double temperature thermocouples, so that thermometric numerical value can be proofreaded mutually.If There is a thermocouple break, can know in time.It will be appreciated, however, that more than two thermocouple assemblies can also be used.
Although the present invention has been disclosed in the preferred embodiments as above, present invention is not limited to this.Any art technology Personnel, made various changes and modification, should all be included in protection model of the invention without departing from the spirit and scope of the present invention In enclosing, therefore protection scope of the present invention should be defined by the scope defined by the claims..

Claims (10)

1. a kind of thermocouple assembly (1) for measuring reactor temperature, comprising:
Protection sleeve pipe (2), with first end (21) and opposite second end (22), which is configured to from the second end The casing of the general conical tapered towards the first end;
Thermocouple (3), the thermocouple include shank (31) and the temperature sensor (32) for being connected to the shank, and the shank is detachable Ground is fixedly attached to the second end (22) of the protection sleeve pipe, which extends into this towards the first end (21) In protection sleeve pipe (2),
Installation pedestal (4), the installation pedestal are used to thermocouple assembly being fixedly installed to reaction kettle;
Wherein, the shank (31) is equipped with fexible bias pressure mechanism (5), and the fexible bias pressure mechanism is configured to connect when the shank is fixed When being connected to the protection sleeve pipe, the fexible bias pressure mechanism can be biased the temperature sensor (32) make its always with the protection The first end (21) of casing contacts.
2. thermocouple assembly according to claim 1, wherein the shank (31) passes through the interior spiral shell being arranged on the shank Line part (33) and the external thread piece (23) being arranged at the second end of the protection sleeve pipe (2) are threadedly coupled to the protection sleeve pipe.
3. thermocouple assembly according to claim 2, wherein the shank (31) has hollow housing portion (30), described Fexible bias pressure mechanism is located in the hollow housing portion (30), and the one end in the hollow housing portion is equipped with through-hole (6), the temperature sensing Device extends through the through-hole and is connected to the fexible bias pressure mechanism (5).
4. thermocouple assembly according to claim 3, wherein the fexible bias pressure mechanism (5) includes fixing at interval At least two screw elements (51) in the one end in the hollow housing portion (30), are installed at least two screw element Plate-like piece (52), and the helical spring (53) on each screw element is worn, wherein the helical spring is positioned at described It between plate-like piece and the head of the screw element and is configured to be biased the plate-like piece power, and the temperature sensor is fixed It is connected to the plate-like piece (52).
5. thermocouple assembly according to claim 1, which is characterized in that the installation pedestal (4) is configured with installation The form of the ring flange in hole (4a).
6. thermocouple assembly according to any one of claim 1 to 5, wherein the protection sleeve pipe is by thermal coefficient height Material be made, the material be copper, aluminium or albronze.
7. thermocouple assembly according to any one of claim 1 to 5, wherein the outer surface of the protection sleeve pipe coats There is corrosion-resistant, anti-stick metal coating.
8. thermocouple assembly according to claim 7, wherein the metal coating is nickel coating.
9. a kind of reaction kettle device (11), comprising:
Autoclave body (12) with circular arc-shaped bottom portion;
Stirrer paddle (13);With
Installation is to the autoclave body (12) and extends at least two inside the reaction kettle device according to claim 1 in 8 Described in any item thermocouple assemblies (1).
10. reaction kettle device according to claim 9, wherein the reaction kettle device includes two thermocouple assemblies (1), the end close to the circular arc-shaped bottom portion of the stirrer paddle (13) offers corresponding with two thermocouple assemblies Two recesses (14) so that when the stirrer paddle rotation when do not contact the thermocouple assembly.
CN201910673213.3A 2019-07-24 2019-07-24 For measuring the thermocouple assembly of reactor temperature Pending CN110260990A (en)

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CN201910673213.3A CN110260990A (en) 2019-07-24 2019-07-24 For measuring the thermocouple assembly of reactor temperature

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Application Number Priority Date Filing Date Title
CN201910673213.3A CN110260990A (en) 2019-07-24 2019-07-24 For measuring the thermocouple assembly of reactor temperature

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113405680A (en) * 2021-05-19 2021-09-17 中国原子能科学研究院 Thermocouple clamping device for inner wall of pipeline
CN114061778A (en) * 2021-11-11 2022-02-18 苏州凯迪泰医学科技有限公司 Temperature sensor for integrated detection of connection-effective device

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB996748A (en) * 1962-05-16 1965-06-30 Bailey Meter Co Improvements in or relating to temperature measuring apparatus
CN201819750U (en) * 2010-08-20 2011-05-04 丁锡端 Thermocouple or thermal resistor convenient for disassembly
CN102563862A (en) * 2010-11-29 2012-07-11 株式会社田洼精密机械制造厂 Heat exchanger
CN103357287A (en) * 2013-08-06 2013-10-23 中国石油大学(华东) Visual oil-water mixing and stirring device used for laboratory
EP3184980A1 (en) * 2015-12-21 2017-06-28 ENDRESS + HAUSER WETZER GmbH + Co. KG Temperature sensor for measuring the temperature of a medium in a vessel or a pipe
CN210051449U (en) * 2019-07-24 2020-02-11 巴斯夫新材料有限公司 Thermocouple device for measuring temperature in reaction kettle

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB996748A (en) * 1962-05-16 1965-06-30 Bailey Meter Co Improvements in or relating to temperature measuring apparatus
CN201819750U (en) * 2010-08-20 2011-05-04 丁锡端 Thermocouple or thermal resistor convenient for disassembly
CN102563862A (en) * 2010-11-29 2012-07-11 株式会社田洼精密机械制造厂 Heat exchanger
CN103357287A (en) * 2013-08-06 2013-10-23 中国石油大学(华东) Visual oil-water mixing and stirring device used for laboratory
EP3184980A1 (en) * 2015-12-21 2017-06-28 ENDRESS + HAUSER WETZER GmbH + Co. KG Temperature sensor for measuring the temperature of a medium in a vessel or a pipe
CN210051449U (en) * 2019-07-24 2020-02-11 巴斯夫新材料有限公司 Thermocouple device for measuring temperature in reaction kettle

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113405680A (en) * 2021-05-19 2021-09-17 中国原子能科学研究院 Thermocouple clamping device for inner wall of pipeline
CN114061778A (en) * 2021-11-11 2022-02-18 苏州凯迪泰医学科技有限公司 Temperature sensor for integrated detection of connection-effective device

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