CN110259538A - A kind of multilevel power generation system using cement kiln waste heat - Google Patents

A kind of multilevel power generation system using cement kiln waste heat Download PDF

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Publication number
CN110259538A
CN110259538A CN201910460796.1A CN201910460796A CN110259538A CN 110259538 A CN110259538 A CN 110259538A CN 201910460796 A CN201910460796 A CN 201910460796A CN 110259538 A CN110259538 A CN 110259538A
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China
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orc
sco
generation system
working medium
turbine
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CN201910460796.1A
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CN110259538B (en
Inventor
张荻
王雨琦
谢永慧
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Xian Jiaotong University
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Xian Jiaotong University
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K23/00Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
    • F01K23/02Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
    • F01K23/06Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
    • F01K23/10Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle with exhaust fluid of one cycle heating the fluid in another cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/08Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
    • F01K25/10Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
    • F01K25/103Carbon dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K27/00Plants for converting heat or fluid energy into mechanical energy, not otherwise provided for
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/004Systems for reclaiming waste heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/004Systems for reclaiming waste heat
    • F27D2017/006Systems for reclaiming waste heat using a boiler
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • Y02P40/121Energy efficiency measures, e.g. improving or optimising the production methods

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)

Abstract

The invention discloses a kind of multilevel power generation systems using cement kiln waste heat, including SCO2Electricity generation system, steam generating system and ORC electricity generation system, wherein cement kiln waste gas waste-heat SCO2Working medium in electricity generation system enters SCO2It is expanded in turbine, drives SCO2System generator power generation, subsequently enters in steam heater and cools down via SCO2Compressor cycle;Working medium in steam generating system absorbs SCO in steam heater2The after-heat of working medium, which enters in vapor turbine, to be expanded, and vapour system electrical power generators are driven, and is subsequently entered in ORC heater and is cooled down via water supply pump circulation;The after-heat that working medium in ORC electricity generation system absorbs vapor working medium in ORC heater, which enters in ORC turbine, to be expanded, and ORC system electrical power generators is driven, through condenser and intensifier pumping cycle after.The present invention utilizes SCO2, vapor and ORC electricity generation system three-level utilize the waste heat of cement kiln waste gas, utilization efficiency of heat energy, engineering value and economic benefit with higher can be obviously improved.

Description

A kind of multilevel power generation system using cement kiln waste heat
Technical field
The present invention relates to a kind of afterheat generating systems, and in particular to a kind of multilevel power generation system using cement kiln waste heat.
Background technique
Have in a large amount of in cement kiln, cryogenic waste heat resource fails to be fully utilized, the phenomenon that energy waste, is very general Time.New Type Dry-process Cement Production is quickly grown in recent years, and technology, equipment, management etc. are increasingly mature.It is domestic at present to be completed The clinker production line of a large amount of 2000t/d or more is run, dry method production line has in terms of heat consumption aobvious compared with other kiln types The reduction of work, but New Type Dry-process Cement Production is still powerful to the consumption and dependence of electric energy.Novel dry-method cement clinker production enterprise In industry by shake the head chamotte cooler and kiln tail preheater discharge exhaust gas temperature be about 350 DEG C, thermal energy account for about clinker burning At the 35% of system heat consumption.Therefore, if can recycle the thermal energy of this part using cogeneration technology, cement enterprise is improved The energy utilization rate of industry can bring high economic benefit.
The cement kiln residual heat generating technology in China is that directly to cement kiln, kiln head and tail is arranged during clinker burning at present The waste heat exhaust gas put is recycled, and is generated steam by waste heat boiler and is driven Turbo-generator Set power generation, one is produced daily 5000 tons Cement clinker production line daily using ten thousand degree of cogeneration 21-24, can solve about 60% clinker produce from electricity consumption, product is comprehensive About 18% can be declined by closing energy consumption, annual to save about 2.5 ten thousand tons of standard coal, about 60,000 tons of reducing emission of carbon dioxide.As it can be seen that more than cement kiln The utility value of heat is high, if generating efficiency can be promoted further, can obtain higher economic value.
Summary of the invention
It is an object of the invention to be directed to the deficiency of existing cement kiln residual heat generating technology, provide a kind of using cement kiln The multilevel power generation system of waste heat is mainly used in the UTILIZATION OF VESIDUAL HEAT IN of cement kiln waste gas, promotes utilization rate of waste heat, realizes energy ladder Grade utilizes, and has important engineering significance and wide application prospect.
The present invention adopts the following technical scheme that realize:
A kind of multilevel power generation system using cement kiln waste heat, including cement kiln waste gas, SCO2Heater, SCO2Turbine, SCO2System generator, SCO2Compressor, motor, steam heater, vapor turbine, vapour system generator, feed pump, ORC heater, ORC turbine, ORC system generator, ORC condenser and booster pump;Wherein,
Multilevel power generation system using cement kiln waste heat includes SCO2Electricity generation system, water vapour electricity generation system and ORC power generation System;SCO2When electricity generation system operation, cement kiln waste gas heats SCO2SCO in heater2Working medium subsequently enters SCO2Turbine Middle expansion drives SCO2System generator rotation power generation, SCO2Working medium subsequently enters in steam heater and in steam generating system Working medium exchanged heat and cooled down, into SCO2Compressor adherence pressure, wherein electric energy needed for compressor is mentioned by motor For so recycling;When steam generating system operation, steam working medium absorbs SCO in steam heater2The after-heat of working medium, It subsequently enters and is expanded in vapor turbine, drive the rotation power generation of vapour system generator, steam working medium subsequently enters ORC heater In exchanged heat and cooled down with the working medium in ORC electricity generation system, be finally pumped into steam heater and carried out again by feed pump Circulation;When ORC electricity generation system operation, ORC working medium absorbs the after-heat of vapor working medium in ORC heater, subsequently enters It is expanded in ORC turbine, drives the rotation power generation of ORC system generator, subsequently enter and condense recycling in ORC condenser, via pressurization Pump, which is pumped into again in ORC heater, to be recycled.
A further improvement of the present invention lies in that SCO2Turbine uses inward flow turbine.
A further improvement of the present invention lies in that vapor turbine uses inward flow turbine.
A further improvement of the present invention lies in that ORC turbine uses inward flow turbine.
A further improvement of the present invention lies in that SCO2Compressor uses centrifugal compressor.
A further improvement of the present invention lies in that the working medium that ORC electricity generation system uses is R134a, R290, R601a and penta Alkane low boiling working fluid.
The present invention has following beneficial technical effect:
The present invention passes through the advantage for successfully integrating a variety of prior arts, carries out for traditional cement kiln afterheat utilizing system Reformed AHP, proposes a kind of multilevel power generation system using cement kiln waste heat.Conventional cement kiln UTILIZATION OF VESIDUAL HEAT IN uses steam Turbine unit heats vapor using about 350 DEG C of cement kiln waste gas, and the vapor of high temperature and pressure does work in turbine exports electricity Energy.However, individually vapor power generation cycle capacity usage ratio is lower, the present invention focuses on promoting energy utilization efficiency, first Cement kiln waste gas waste heat is absorbed using supercritical carbon dioxide Brayton Cycle system, it is overcritical as first order electricity generation system Waste-heat vapor in carbon dioxide electricity generation system is utilized in the vapor electricity generation system of the second level, finally, water steams The waste heat of gas electricity generation system is used for the ORC electricity generation system of the third level.It so, it is possible the energy of Multi-class propagation cement kiln waste gas waste heat Amount, is substantially improved generating efficiency.
Supercritical carbon dioxide circulation is mainly made of heat source, turbine, cooler and the big equipment of compressor four.Overcritical two Aoxidizing carbon cycle has numerous advantages: supercritical carbon dioxide working medium viscosity is small, and system thermal efficiency is high;Working medium density is big, thoroughly Flat compact mechanical structure;System structure is simple, and amount of parts is few;System belongs to single-phase circulation, without phase transition process, is not required to make With condenser, the quantity of used valve, only 1/10th of Rankine cycle;System temperature is lower, can be used conventional Stainless steel material, manufacturing cost are low.The working fluids characteristic of supercritical carbon dioxide makes compact-sized, the efficiency of entire electricity generation system It is high, at low cost.
It is different from conventional vapor electricity generation system, ORC be using low-boiling-point organic compound as working medium, mainly by waste heat boiler (or Heat exchanger), turbine, condenser and the big capital equipment of working medium pump four composition.ORC has numerous in terms of using low-grade energy Advantage: firstly, ORC working medium energy density is larger, such as the ORC plant air-cooled condenser that uses is used than vapor power plant The volume of air-cooled condenser is much smaller, and price is also much lower, it can be ensured that system structure is compact, low in cost;Secondly, because of its work Matter low boiling point, ORC electricity generation system is suitable for low-temperature heat source, is particularly suitable in afterheat utilizing system, at low temperatures, organic The efficiency of Rankine cycle is obviously more much higher as the Rankine cycle efficiency of working medium than water, the main reason is that ORC is in Exposure degree Aspect has higher efficiency, therefore more heat can be recycled using ORC technology.
In conclusion the present invention establishes a kind of multilevel power generation system using cement kiln waste heat, using overcritical dioxy Change the waste heat that carbon, vapor, ORC electricity generation system three-level utilize cement kiln waste gas, utilization efficiency of heat energy can be obviously improved, had Higher engineering value and economic benefit.
Detailed description of the invention
Fig. 1 is a kind of system diagram of the multilevel power generation system using cement kiln waste heat of the present invention.
Description of symbols:
1- cement kiln waste gas, 2-SCO2(supercritical carbon dioxide) heater, 3-SCO2Turbine, 4-SCO2System generator, 5-SCO2Compressor, 6- motor, 7- steam heater, 8- vapor turbine, 9- vapour system generator, 10- feed pump, 11-ORC heater, 12-ORC turbine, 13-ORC system generator, 14-ORC condenser, 15- booster pump.
Specific embodiment
The present invention will be further explained below with reference to the attached drawings.
Referring to Fig.1, a kind of multilevel power generation system using cement kiln waste heat provided by the invention, including cement kiln waste gas 1, SCO2Heater 2, SCO2Turbine 3, SCO2System generator 4, SCO2Compressor 5, motor 6, steam heater 7, vapor are saturating Flat 8, vapour system generator 9, feed pump 10, ORC heater 11, ORC turbine 12, ORC system generator 13, ORC condenser 14 and booster pump 15.
The present invention includes SCO using the multilevel power generation system of cement kiln waste heat2Electricity generation system, steam generating system and ORC Electricity generation system;SCO2When electricity generation system operation, cement kiln waste gas 1 heats SCO2SCO in heater 22Working medium subsequently enters SCO2It is expanded in turbine 3, drives SCO2The rotation power generation of system generator 4, SCO2Working medium subsequently enter in steam heater 7 with steaming Working medium in vapour electricity generation system, which is exchanged heat, to be cooled down, into SCO25 adherence pressure of compressor, wherein electricity needed for compressor It can be provided by motor 6, so be recycled;When steam generating system operation, steam working medium absorbs SCO in steam heater 72Work The after-heat of matter is subsequently entered and is expanded in vapor turbine 8, drive vapour system generator 9 rotation power generation, steam working medium with Enter in ORC heater 11 to be exchanged heat with the working medium in ORC electricity generation system afterwards and be cooled down, is finally pumped again by feed pump 10 Enter and is recycled in steam heater 7;When ORC electricity generation system operation, ORC working medium absorbs vapor work in ORC heater 11 The after-heat of matter is subsequently entered and is expanded in ORC turbine 12, is driven the rotation power generation of ORC system generator 13, is subsequently entered ORC Recycling is condensed in condenser 14, is pumped into ORC heater 11 and is recycled again via booster pump 15.
In conclusion the present invention is directed to the UTILIZATION OF VESIDUAL HEAT IN problem of cement kiln waste gas, steamed using supercritical carbon dioxide, water Gas, ORC electricity generation system three-level utilize the waste heat of cement kiln waste gas, can be obviously improved utilization efficiency of heat energy, work with higher Journey value and economic benefit.

Claims (6)

1. a kind of multilevel power generation system using cement kiln waste heat, which is characterized in that including cement kiln waste gas (1), SCO2Heater (2)、SCO2Turbine (3), SCO2System generator (4), SCO2Compressor (5), motor (6), steam heater (7), vapor Turbine (8), vapour system generator (9), feed pump (10), ORC heater (11), ORC turbine (12), ORC system generator (13), ORC condenser (14) and booster pump (15);Wherein,
Multilevel power generation system using cement kiln waste heat includes SCO2Electricity generation system, water vapour electricity generation system and ORC electricity generation system; SCO2When electricity generation system operation, cement kiln waste gas (1) heats SCO2SCO in heater (2)2Working medium subsequently enters SCO2Turbine (3) expansion in, drives SCO2System generator (4) rotation power generation, SCO2Working medium subsequently enter in steam heater (7) with steam Working medium in electricity generation system, which is exchanged heat, to be cooled down, into SCO2Compressor (5) adherence pressure, wherein electricity needed for compressor It can be provided by motor (6), so be recycled;When steam generating system operation, steam working medium absorbs in steam heater (7) SCO2The after-heat of working medium subsequently enters expansion in vapor turbine (8), drives vapour system generator (9) rotation power generation, Steam working medium is subsequently entered to be exchanged heat in ORC heater (11) with the working medium in ORC electricity generation system and be cooled down, finally by giving Water pump (10) is pumped into steam heater (7) again and is recycled;When ORC electricity generation system operation, ORC working medium is in ORC heater (11) after-heat that vapor working medium is absorbed in subsequently enters expansion in ORC turbine (12), drives ORC system generator (13) rotation power generation subsequently enters condensation recycling in ORC condenser (14), is pumped into ORC heater again via booster pump (15) (11) circulation in.
2. a kind of multilevel power generation system using cement kiln waste heat according to claim 1, which is characterized in that SCO2Turbine (3) inward flow turbine is used.
3. a kind of multilevel power generation system using cement kiln waste heat according to claim 1, which is characterized in that vapor is saturating Flat (8) use inward flow turbine.
4. a kind of multilevel power generation system using cement kiln waste heat according to claim 1, which is characterized in that ORC turbine (12) inward flow turbine is used.
5. a kind of multilevel power generation system using cement kiln waste heat according to claim 1, which is characterized in that SCO2Compression Machine (5) uses centrifugal compressor.
6. a kind of multilevel power generation system using cement kiln waste heat according to claim 1, which is characterized in that ORC power generation The working medium that system uses is R134a, R290, R601a and pentane low boiling working fluid.
CN201910460796.1A 2019-05-30 2019-05-30 Utilize multistage power generation system of cement kiln waste heat Active CN110259538B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103089439A (en) * 2013-01-27 2013-05-08 南京瑞柯徕姆环保科技有限公司 Britton-steam Rankine-organic Rankine combined cycle heat and power cogeneration device
CN106884692A (en) * 2017-04-18 2017-06-23 长沙紫宸科技开发有限公司 A kind of utilization cement plant waste heat realizes the method that carbon dioxide recycle generates electricity
KR20170076220A (en) * 2015-12-24 2017-07-04 (주)에이치티알디 Hybrid Air-Brayton Cycle Power Generator System using Waste Heat, which generates simultaneously both high temperature steam and air

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103089439A (en) * 2013-01-27 2013-05-08 南京瑞柯徕姆环保科技有限公司 Britton-steam Rankine-organic Rankine combined cycle heat and power cogeneration device
KR20170076220A (en) * 2015-12-24 2017-07-04 (주)에이치티알디 Hybrid Air-Brayton Cycle Power Generator System using Waste Heat, which generates simultaneously both high temperature steam and air
CN106884692A (en) * 2017-04-18 2017-06-23 长沙紫宸科技开发有限公司 A kind of utilization cement plant waste heat realizes the method that carbon dioxide recycle generates electricity

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