CN110257723A - A kind of high silicon hot forming steel continuous casting producing method - Google Patents

A kind of high silicon hot forming steel continuous casting producing method Download PDF

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Publication number
CN110257723A
CN110257723A CN201910677547.8A CN201910677547A CN110257723A CN 110257723 A CN110257723 A CN 110257723A CN 201910677547 A CN201910677547 A CN 201910677547A CN 110257723 A CN110257723 A CN 110257723A
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CN
China
Prior art keywords
continuous casting
hot forming
forming steel
high silicon
silicon hot
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Pending
Application number
CN201910677547.8A
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Chinese (zh)
Inventor
刘启龙
朱伦才
司小明
曹成虎
崔磊
舒宏富
罗霄
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Maanshan Iron and Steel Co Ltd
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Maanshan Iron and Steel Co Ltd
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Priority to CN201910677547.8A priority Critical patent/CN110257723A/en
Publication of CN110257723A publication Critical patent/CN110257723A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/11Treating the molten metal
    • B22D11/111Treating the molten metal by using protecting powders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/11Treating the molten metal
    • B22D11/114Treating the molten metal by using agitating or vibrating means
    • B22D11/115Treating the molten metal by using agitating or vibrating means by using magnetic fields
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/12Accessories for subsequent treating or working cast stock in situ
    • B22D11/1206Accessories for subsequent treating or working cast stock in situ for plastic shaping of strands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium

Abstract

The invention discloses a kind of high silicon hot forming steel continuous casting producing methods, wherein, described high its chemical component weight percentage content of silicon hot forming steel are as follows: C:0.12~0.25%, Si:1.20~2.0%, Mn:1.15~2.5%, P :≤0.025%, S :≤0.0030%, Als: 0.015~0.065%, Nb :≤0.055%;The production method is the following steps are included: molten iron pretreatment → top and bottom combined blown converter → Argon station → ladle refining → molten steel vacuum processing → slab caster → hot charging.The high silicon hot forming steel continuous casting producing method design is reasonable, high silicon hot forming steel center segregation of casting blank stability contorting is in C0.5-C1.5, and casting billet surface is without longitudinal crack and deep oscillation mark defect, and slab is without phenomenon of rupture, hot rolled coil surface quality with it is functional, realize stably producing for the steel grade.

Description

A kind of high silicon hot forming steel continuous casting producing method
Technical field
The present invention relates to metallurgy industry slab continuous casting steel machine technical fields, more particularly, to a kind of high silicon hot forming steel continuous casting Production method.
Background technique
Increasingly strict with energy-saving and emission-reduction requirement, on the basis of ensuring safety, vehicle complete vehicle lightweight is general trend of events institute Become, and the lightweight of body frame part is the light-weighted key point of vehicle, is the second generation high-strength steel of representative with TRIP, DP etc. It has been commonly utilized on body structural member and safety member, but still has not been able to satisfy the intensity and forming synthesis of partial shape complex component Demand.Major steel looks forward to all active development, production using QP980 as the third generation automobile super-high strength steel of representative both at home and abroad, however by In its complicated component system and special microstructure characteristic, there is deep oscillation mark, surface longitudinal crack and transverse breakage etc. in slab Many defects bring great difficulty with quality control to stably producing for slab slab.
Summary of the invention
In view of the shortcomings of the prior art, technical problem to be solved by the invention is to provide a kind of high silicon hot forming steel continuous casting is raw Production method eliminates the mass defects such as crackle and the fracture of high silicon hot forming steel slab, realizes stably producing for the steel grade.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is as follows: a kind of high silicon hot forming steel continuous casting is raw Production method, wherein
Described high its chemical component weight percentage content of silicon hot forming steel are as follows:
C:0.12~0.25%, Si:1.20~2.0%, Mn:1.15~2.5%, P :≤0.025%, S :≤ 0.0030%, Als: 0.015~0.065%, Nb :≤0.055%;
The production method the following steps are included:
Molten iron pretreatment → top and bottom combined blown converter → Argon station → ladle refining → molten steel vacuum processing → slab caster → hot charging.
The continuous casting steel billet specifications section of the continuous casting are as follows: thickness (210~250) × width (900~1600) mm2
Its chemical component weight percentage content of the crystallizer protecting residue of continuous casting in the slab caster are as follows:
SiO2: 26~32%, MgO:3~7%, CaO:31~37%, Fe2O3:≤3%, Al2O3:≤4%, R2O:8~ 12%, F:4.5~8.5%, H2O :≤0.5%, C:4~8%.
The Water Rate for Secondary Cooling Water used in the slab caster are as follows: 0.61 ± 0.05L/Kg and poring rate be 1.0~ 1.3m/min。
Two cold electromagnetism roller techniques, technological parameter specifically: first pair of electromagnetic stirring roller are used in the slab caster Electric current/frequency is respectively 200~300A/2~4Hz;Second pair of electromagnetic stirring roller electric current/frequency be respectively 300~400A/3~ 5Hz。
In the slab caster use dynamic soft-reduction technique, technological parameter specifically: overall reduction be 4.0~ 5.5mm;Pressure range is solid rate (fS) 10%~80%;Reduction ratio is 0.8~1.5mm/m;
The slab hot charging temperature is 400 DEG C~680 DEG C.
The crystallizer protecting residue basicity R (CaO/SiO2) it is 1.29 ± 0.05.
Compared with prior art, the present invention having the advantage that
Rationally, high silicon hot forming steel center segregation of casting blank stability contorting exists for the high silicon hot forming steel continuous casting producing method design C0.5-C1.5, casting billet surface is without longitudinal crack and deep oscillation mark defect, and for slab without phenomenon of rupture, hot rolled coil surface quality and performance are good It is good, realize stably producing for the steel grade.
Detailed description of the invention
Content expressed by each width attached drawing of this specification and the label in figure are briefly described below:
Fig. 1 is electromagnetic agitation rod schematic view of the mounting position in the present invention.
Fig. 2 is slab temperature measuring point schematic diagram of the present invention.
Specific embodiment
Below against attached drawing, by the description of the embodiment, making to a specific embodiment of the invention further details of Explanation.
The high silicon hot forming steel chemical composition weight percent content are as follows:
C:0.12~0.25%, Si:1.20~2.0%, Mn:1.15~2.5%, P :≤0.025%, S :≤ 0.0030%, Als: 0.015~0.065%, Nb :≤0.055%;
The high silicon hot forming steel continuous casting producing method following steps:
Molten iron pre-processes (KR) → top and bottom combined blown converter → Argon station → ladle refining (LF) → molten steel and is vacuum-treated (RH) → slab caster → hot charging.
Wherein,
The continuous casting steel billet specifications section of continuous casting are as follows: thickness (210~250) × width (900~1600) mm2
Its chemical component weight percentage content of the crystallizer protecting residue of continuous casting in slab caster are as follows:
SiO2: 26~32%, MgO:3~7%, CaO:31~37%, Fe2O3:≤3%, Al2O3:≤4%, R2O:8~ 12%, F-:4.5~8.5%, H2O :≤0.5%, C (Gu): 4~8%.Crystallizer protecting residue basicity R (CaO/SiO2) it is 1.29 ±0.05。
As depicted in figs. 1 and 2,
The Water Rate for Secondary Cooling Water that crystallizer 1 uses in slab caster are as follows: 0.61 ± 0.05L/Kg and poring rate are 1.0 ~1.3m/min.
Two cold electromagnetism roller techniques, technological parameter are used in slab caster specifically: first pair of 3 electricity of electromagnetic stirring roller Stream/frequency is respectively 200~300A/2~4Hz;Second pair of 4 electric currents of electromagnetic stirring roller/frequency be respectively 300~400A/3~ 5Hz;Electromagnetic stirring roller installation site is in 3.5~8m apart from 2 vertical range of crystallizer meniscus.
Dynamic soft-reduction technique, technological parameter are used in slab caster specifically: overall reduction is 4.0~5.5mm; Pressure range is solid rate (fS) 10%~80%;Reduction ratio is 0.8~1.5mm/m;
Slab hot charging temperature is 400 DEG C~680 DEG C, and temperature measurement location is at a of slab upper surface centre.High silicon hot forming steel casting Base center segregation stability contorting is in C0.5-C1.5, and casting billet surface is without longitudinal crack and deep oscillation mark defect, and slab is without phenomenon of rupture, warm Roll volume surface quality with it is functional.
Preferred embodiment are as follows:
Embodiment 1:
The high silicon hot forming steel that production specification is 230mm × 1400mm, carbon content 0.17%, silicone content are 2.0%, is poured Teeming speed degree is 1.2m/min.Crystallizer protecting residue basicity is 1.28;Water Rate for Secondary Cooling Water is 0.60L/Kg;First pair of electromagnetic stirring roller Being mounted on apart from crystallizer meniscus vertical range is at 4.5m, and second pair of electromagnetic stirring roller is mounted on apart from crystallizer meniscus Vertical range is at 7.2m, and first pair is respectively 250A/3Hz, 350A/4Hz with second pair of electromagnetic stirring roller electric current and frequency;It is dynamic State slighter compress overall reduction is 5.5mm, and pressure range is solid rate 20%~65%, reduction ratio 1.0mm/m.Hot charging temperature is 512℃。
It is C1.0, slab flawless and fracture defect, heat by the center segregation of continuous cast slab that above-mentioned technique is produced Roll volume surface quality with it is functional.
Embodiment 2:
The high silicon hot forming steel that production specification is 220mm × 1600mm, carbon content 0.19%, silicone content are 1.8%, is poured Teeming speed degree is 1.1m/min.Crystallizer protecting residue basicity is 1.27;Water Rate for Secondary Cooling Water is 0.60L/Kg;First pair of electromagnetic stirring roller Being mounted on apart from crystallizer meniscus vertical range is at 4.5m, and second pair of electromagnetic stirring roller is mounted on apart from crystallizer meniscus Vertical range is at 7.2m, and first pair is respectively 220A/2.5Hz, 330A/3Hz with second pair of electromagnetic stirring roller electric current and frequency; Dynamic soft-reduction overall reduction is 5.5mm, and pressure range is solid rate 20%~65%, reduction ratio 1.0mm/m.Hot charging temperature It is 560 DEG C.
It is C0.5, slab flawless and fracture defect, heat by the center segregation of continuous cast slab that above-mentioned technique is produced Roll volume surface quality with it is functional.
It above are only and preferred embodiments of the present invention are illustrated, above-mentioned technical characteristic can form multiple hairs in any combination Bright example scheme.
The present invention is exemplarily described above in conjunction with attached drawing, it is clear that the present invention implements not by aforesaid way Limitation, if use the improvement for the various unsubstantialities that conception and technical scheme of the invention carry out, or it is not improved will Conception and technical scheme of the invention directly apply to other occasions, within the scope of the present invention.

Claims (8)

1. a kind of high silicon hot forming steel continuous casting producing method, it is characterised in that:
Described high its chemical component weight percentage content of silicon hot forming steel are as follows:
C:0.12~0.25%, Si:1.20~2.0%, Mn:1.15~2.5%, P :≤0.025%, S :≤0.0030%, Als: 0.015~0.065%, Nb :≤0.055%;
The production method the following steps are included:
Molten iron pretreatment → top and bottom combined blown converter → Argon station → ladle refining → molten steel vacuum processing → slab caster → heat Dress.
2. high silicon hot forming steel continuous casting producing method as described in claim 1, it is characterised in that: the continuous casting steel of the continuous casting Base specifications section are as follows: thickness (210~250) × width (900~1600) mm2
3. high silicon hot forming steel continuous casting producing method as described in claim 1, it is characterised in that: continuous casting in the slab caster Crystallizer protecting residue its chemical component weight percentage content are as follows:
SiO2: 26~32%, MgO:3~7%, CaO:31~37%, Fe2O3:≤3%, Al2O3:≤4%, R2O:8~12%, F:4.5~8.5%, H2O :≤0.5%, C:4~8%.
4. high silicon hot forming steel continuous casting producing method as described in claim 1, it is characterised in that: used in the slab caster Water Rate for Secondary Cooling Water are as follows: 0.61 ± 0.05L/Kg and poring rate are 1.0~1.3m/min.
5. high silicon hot forming steel continuous casting producing method as described in claim 1, it is characterised in that: used in the slab caster Two cold electromagnetism roller techniques, technological parameter specifically: first pair of electromagnetic stirring roller electric current/frequency be respectively 200~300A/2~ 4Hz;Second pair of electromagnetic stirring roller electric current/frequency is respectively 300~400A/3~5Hz.
6. high silicon hot forming steel continuous casting producing method as described in claim 1, it is characterised in that: used in the slab caster Dynamic soft-reduction technique, technological parameter specifically: overall reduction is 4.0~5.5mm;Pressure range is solid rate (fS) 10% ~80%;Reduction ratio is 0.8~1.5mm/m.
7. high silicon hot forming steel continuous casting producing method as described in claim 1, it is characterised in that: the slab hot charging temperature is 400 DEG C~680 DEG C.
8. high silicon hot forming steel continuous casting producing method as claimed in claim 3, it is characterised in that: the crystallizer protecting residue basicity R(CaO/SiO2) it is 1.29 ± 0.05.
CN201910677547.8A 2019-07-25 2019-07-25 A kind of high silicon hot forming steel continuous casting producing method Pending CN110257723A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111876678A (en) * 2020-07-14 2020-11-03 马鞍山钢铁股份有限公司 Process method for solving cracks of high-strength steel casting blank
CN112045157A (en) * 2020-07-24 2020-12-08 邯郸钢铁集团有限责任公司 Production method of low-alloy high-strength wear-resistant steel slab

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109536666A (en) * 2018-12-24 2019-03-29 马鞍山钢铁股份有限公司 A kind of high silicon hot forming steel continuous casting producing method

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109536666A (en) * 2018-12-24 2019-03-29 马鞍山钢铁股份有限公司 A kind of high silicon hot forming steel continuous casting producing method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111876678A (en) * 2020-07-14 2020-11-03 马鞍山钢铁股份有限公司 Process method for solving cracks of high-strength steel casting blank
CN112045157A (en) * 2020-07-24 2020-12-08 邯郸钢铁集团有限责任公司 Production method of low-alloy high-strength wear-resistant steel slab

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