CN110257122A - A kind of biomass straw shaped fuel and preparation method thereof - Google Patents
A kind of biomass straw shaped fuel and preparation method thereof Download PDFInfo
- Publication number
- CN110257122A CN110257122A CN201910550311.8A CN201910550311A CN110257122A CN 110257122 A CN110257122 A CN 110257122A CN 201910550311 A CN201910550311 A CN 201910550311A CN 110257122 A CN110257122 A CN 110257122A
- Authority
- CN
- China
- Prior art keywords
- sleeve
- fuel
- biomass
- raw material
- shaped fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
- C02F11/143—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/445—Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/46—Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/06—Firelighters or wicks, as additive to a solid fuel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/30—Pressing, compressing or compacting
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/32—Molding or moulds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention discloses a kind of biomass straw shaped fuels, are made of the raw material of following parts by weight: 80-100 parts of tangerine bar, 10-14 parts of activated sludge, 2-3 parts of compound additive；The invention also discloses the preparation methods of the shaped fuel.The present invention is using tangerine bar as base matter, and it is mixed with activated sludge and compound additive, activated sludge contains more fats, protein and carbohydrate volatile matter, largely can be precipitated and burn in lower temperature, can improve its flammability after mixing shaped fuel；It acts synergistically between each component in compound additive, can reduce SO in biomass molding fuel2And NOxRelease；Processing and forming is carried out using special biomass solid fuel compression-molding apparatus again, pass through the optimization of technological parameter, obtain the good biomass fuel of a kind of good forming effect, combustion efficiency, and shaped fuel obtained is not in broken phenomenon, can guarantee the integrality and original sample retentivity of shaped fuel to greatest extent.
Description
Technical field
The invention belongs to biomass fuel technical fields, and in particular, to a kind of biomass straw shaped fuel and its system
Preparation Method.
Background technique
Biomass fuel has drawn from generated waste, such as stalk, husk etc. in agricultural production.Biomass solid combustion
Material is a kind of Land use systems of biomass energy, and raw materials for production are that (wood machining residues, forest harvesting are surplus for forestry " three surplus objects "
Excess, producing material residue), various wooden leftover bits and pieces, wood wastes, agricultural crop straw and shrub etc..Production process be by
Then open-textured biomass material is processed into biology through ring moulds pressure roller extrusion forming mode by the processes such as crushing, drying
Matter solid particle fuel.The epigranular of biomass granule fuel, unit intensity can reach 1~1.4g/cm3, intensity increase, fortune
Defeated and storage is convenient, and combustibility is obviously improved, and energy utilization rate can be improved 80% or more after burning, almost without sulfur dioxide
Discharge, ashes or good organic fertilizer after burning.
Chinese patent CN201410704873.0 discloses a kind of environment-friendly type and adds charcoal biomass fuel and processing method, the party
Method is cooperated by corn stover and auxiliary agent, and biomass carbon and animals and plants greasy filth is added, and is processed respectively, hot-pressed, system
At adding charcoal biomass granule fuel.Although the biomass fuel carbonaceous content that this method obtains is high, there are molding effects not
It reaches, be easy to be scattered, the defects of combustion efficiency is not good enough.
Summary of the invention
The purpose of the present invention is to provide a kind of biomass straw shaped fuel and preparation method thereof, molding combustion of the invention
Material, as base matter, and is mixed with activated sludge and compound additive using tangerine bar, activated sludge contain more fats,
Protein and carbohydrate volatile matter largely can be precipitated and burn in lower temperature, can improve its kindling after mixing shaped fuel
Performance；It acts synergistically between each component in compound additive, can reduce SO in biomass molding fuel2And NOxRelease；Again
Processing and forming is carried out using special biomass solid fuel compression-molding apparatus, one kind is obtained by the optimization of technological parameter
The good biomass fuel of good forming effect, combustion efficiency, and shaped fuel obtained is not in the broken phenomenon of material, energy
Guarantee the integrality and original sample retentivity of shaped fuel to greatest extent.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of biomass straw shaped fuel, is made of the raw material of following parts by weight: 80-100 parts of tangerine bar, activated sludge
10-14 parts, 2-3 parts of compound additive；
The biomass straw shaped fuel is made of following steps:
The first step, the pretreatment of tangerine bar: adding water into stalk, and adjusting its moisture content is 50%, under 1.0MPa pressure
Steam blasting is carried out, material after the completion of processing, is quickly taken out, dries, crushes naturally by dwell time 5min；
Second step will crush in pulverizer by pretreated stalk, cross 80 meshes and obtain stalk powder, by tangerine bar powder
End is put into air dry oven, and dry 72-80h makes its constant weight at 105 DEG C；
Third step, the tangerine bar powder by after drying, activated sludge and compound additive mixing, will be a certain amount of with spraying apparatus
Water be uniformly sprayed in raw material and be stirred for uniformly, obtain moisture content be 8%-11% raw material；
4th step, using biomass solid fuel compression-molding apparatus carry out processing and forming, make sleeve move down until
It contacts support chassis and engages in a ring groove, the raw material that third step is obtained is put into sleeve, by heating coil in sleeve
Raw material heated, be heated to setting 128-133 DEG C of temperature after stop heating, with upright jack to the raw material in sleeve
Uniform load, control briquetting pressure are 90Mpa, remove jack after keeping 3min, remove after jack to molding in sleeve
Fuel presses, and adjust sleeve and be slowly move upwardly until and completely disengage shaped fuel, obtained shaped fuel stays in annular groove
It is interior, biomass molding fuel is made.
Further, the activated sludge is made by the following method:
(1) sludge is crossed into 24 meshes to remove suspension and solid impurity, the activated sludge solid content after sieve is adjusted to
2.5%, obtain pretreated sludge；
(2) the pretreated sludge of 100mL is taken to be placed in tetrafluoroethene beaker, it is 2% that 3-4mL mass fraction, which is inwardly added,
Ferric chloride solution after, first 200r/min quickly stirs 1min, then 60r/min mixes slowly 2min, cover cup lid be placed on it is micro-
In wave furnace, takes out and be cooled to room temperature after microwave radiation；
Microwave radiation parameter: power density 7W/mL, radiated time 100s；
(3) moisture content of the sludge after microwave treatment is reduced to 5% hereinafter, obtaining activity by belt-type drying technique again
Sludge.
Further, the compound additive includes Ca (OH)2、SiO2、Al2O3, Ca (OH)2、SiO2、Al2O3Quality it
Than for 10:2-3:0.5-1.
A kind of preparation method of biomass straw shaped fuel, includes the following steps:
The first step, the pretreatment of tangerine bar: adding water into stalk, and adjusting its moisture content is 50%, under 1.0MPa pressure
Steam blasting is carried out, material after the completion of processing, is quickly taken out, dries, crushes naturally by dwell time 5min；
Second step will crush in pulverizer by pretreated stalk, cross 80 meshes and obtain stalk powder, by tangerine bar powder
End is put into air dry oven, and dry 72-80h makes its constant weight at 105 DEG C；
Third step, the tangerine bar powder by after drying, activated sludge and compound additive mixing, will be a certain amount of with spraying apparatus
Water be uniformly sprayed in raw material and be stirred for uniformly, obtain moisture content be 8%-11% raw material；
4th step, using biomass solid fuel compression-molding apparatus carry out processing and forming, make sleeve move down until
It contacts support chassis and engages in a ring groove, the raw material that third step is obtained is put into sleeve, by heating coil in sleeve
Raw material heated, be heated to setting 128-133 DEG C of temperature after stop heating, with upright jack to the raw material in sleeve
Uniform load, control briquetting pressure are 90Mpa, remove jack after keeping 3min, remove after jack to molding in sleeve
Fuel presses, and adjust sleeve and be slowly move upwardly until and completely disengage shaped fuel, obtained shaped fuel stays in annular groove
It is interior, biomass molding fuel is made.
Further, biomass solid fuel compression-molding apparatus, including pedestal, linkage mechanism and sleeve mechanism, linkage
Mechanism is mounted on the base, and sleeve mechanism is installed on linkage mechanism, and pedestal and sleeve mechanism are connected by linkage mechanism；
Pedestal includes support chassis, and support chassis includes the circular support disks of two connections, in the support panel surface of side
Heart position is fixed with annular groove, and the upper surface of the support plate of the other side is vertically and fixedly provided with three support rods, and the upper end of support rod is solid
Surely there is the first mounting plate, the angle of the first mounting plate and support rod inner surface is 130-140 °, and the surface of the first mounting plate is opened
There is the first mounting hole；The inner surface of support rod is fixed with mounting ring by connecting plate, and the surface of support chassis is vertically and fixedly provided with
Second mounting plate, the surface of the second mounting plate are provided with the second mounting hole；
Linkage mechanism includes first bevel gear, second bevel gear and interlocking bar, and the surface of first bevel gear is fixed with first
Installation axle, the first installation axle are installed on the second mounting plate by bearing, wherein the first installation axle other end is connected with motor；
Second bevel gear is fixedly connected with disk by the second installation axle, and the second installation axle is run through by bearing to be installed in mounting ring,
Second bevel gear is located at below mounting ring, and disk is located above mounting ring, and second bevel gear is engaged with first bevel gear；Disk
Upper surface is equipped with helical raised；Interlocking bar one end is fixed with gear, and gear is movably installed on the first mounting plate, gear and spiral shell
Revolve the engagement of shape protrusion；The interlocking bar other end is movably installed with connecting rod, and the connecting rod other end is installed on upper clamp plate；
Sleeve mechanism includes circular slab, and there are three mounting rack, connecting rod is movably installed in installation for the lower surface installation of circular slab
On frame；The side of circular slab is connected with loading plate, runs through on loading plate and is fixed with sleeve, and sleeve and annular groove cooperate.
Further, the marginal position and three support rods that the support rod is located at support chassis upper surface are along support chassis
Circumferencial direction be distributed in its surface.
Further, the mounting ring and support chassis are arranged in parallel and the center of circle of mounting ring and the center of circle of support chassis position
In on same vertical line.
Further, the sleeve week side external surface is equipped with heating coil, and heating coil is uniformly distributed in the side of sleeve simultaneously
It is in close contact with sleeve.
Beneficial effects of the present invention:
The present invention is mixed with activated sludge in fuel feedstocks, is handled by iron chloride and microwave sludge and is lived
Property sludge, microwave radiation can enhance the flocculation of activated sludge, and under microwave radiation, active pollution index is by microwave thermal
With it is non-thermal under the action of occur rupture release a large amount of dissolubility biopolymer, the iron chloride being added at this time generates in water
A large amount of Fe3+, these positively charged ions and the binding sites of dissolubility biopolymer exposure interact to be formed more
Closely knit wadding body can also be released with combination water intracellular between wadding body in the process, therefore reach good dewatering；
In addition, small part forms iron hydroxide after iron chloride is dissolved in water, plays the role of skeleton during activated sludge dehydration and builds body,
Play the effect of enhancing dewatering performance of sludge；Activated sludge after dehydration, desiccation can improve it after mixing shaped fuel
Flammability；The ignition temperature of shaped fuel and the type of its contained volatile matter are closely related, the volatile matter in activated sludge with
Based on fats, protein and carbohydrate, largely it can be precipitated and burn in lower temperature, and the CaO in activated sludge can be incited somebody to action
Hardly possible decomposes volatile matter and is changed into easily decomposition volatile matter, so as to improve the flammability of shaped fuel；
The present invention is mixed with compound additive in fuel feedstocks, and compound additive includes Ca (OH)2、SiO2、Al2O3, Ca
(OH)2It is decomposed into CaO, meeting and SO at high temperature2Reaction generates metastable CaSO4, can reach and reduce SO2The effect of discharge
Fruit, also, SiO2In combustion with CaSO4Effect generates the Ca of stability height and compact structure5(SiO4)2(SO4) or
2C2S·CaSO4, to reduce SO2Release；In terms of denitration, K content is higher in stalk, and Si, Ca, K content are higher under high temperature
Eutectic is easily formed, on the one hand coke is inhibited to burn, promotes NOxIn coke surface heterogeneous reduction, another aspect eutectic
With being complexed compared with the structure containing N in strong cohesive property, with stalk, reduce NOxRelease, in addition, Al2O3With certain
Catalytic combustion-supporting effect, can also inhibit NOxRelease；Therefore, it acts synergistically between compound additive each component, can reduce life
SO in substance shaped fuel2And NOxRelease；
The present invention during the preparation process, first pre-processes tangerine bar, the cellulosic molecule after steam pre-treatment
Chain is broken, and by a degree of destruction, the mobility of cellulose chain increases intramolecular hydrogen bond, be conducive to cellulose to
Disordered structure variation, therefore, the intensity of shaped fuel is 1.8-2.5 times higher than before handling after steam pre-treatment, and combustion heat value is also shown
It writes and is promoted；Meanwhile the structure of cellulose changes after pretreatment, fiber size attenuates, becomes smaller, lignin increased activity, and
It penetrates between cellulose and forms new connection, internal cohesion significantly increases, and lignin degradation meets again and moves to cellulose
Surface softens to form solid bridge joint in compression forming, can be improved processability；
The present invention carries out processing and forming using special biomass solid fuel compression-molding apparatus, easy to operate, passes through
Moving up and down for sleeve can be realized in motor, easily controllable, and the processing and forming of fuel, processing method can be realized by jack
It is easy, it is easy to accomplish the molding of fuel；It removes after jack to fuel presses molding in sleeve, moves up sleeve slowly
Until completely disengaging shaped fuel, obtained shaped fuel is stayed in a ring groove；Shaped fuel in release sleeve in this way
It not will cause the broken phenomenon of material, can guarantee the integrality and original sample retentivity of shaped fuel to greatest extent；
Shaped fuel of the invention uses tangerine bar as base matter, and is mixed with activated sludge and compound additive, living
Property sludge contain more fats, protein and carbohydrate volatile matter, largely can be precipitated and burn in lower temperature, incorporation at
Its flammability can be improved after type fuel；It acts synergistically between each component in compound additive, can reduce biomass moulding
SO in fuel2And NOxRelease；Processing and forming is carried out using special biomass solid fuel compression-molding apparatus again, passes through work
The optimization of skill parameter obtains the good biomass fuel of a kind of good forming effect, combustion efficiency, and shaped fuel obtained will not
There is the broken phenomenon of material, can guarantee the integrality and original sample retentivity of shaped fuel to greatest extent.
Detailed description of the invention
In order to facilitate the understanding of those skilled in the art, the present invention will be further described below with reference to the drawings.
Fig. 1 is the structural schematic diagram of biomass solid fuel compression-molding apparatus in the present invention；
Fig. 2 is the structural schematic diagram of the pedestal of biomass solid fuel pressure contracting molding machine；
Fig. 3 is the structural schematic diagram of the linkage mechanism of biomass solid fuel pressure contracting molding machine；
Fig. 4 is the structural schematic diagram of the sleeve mechanism of biomass solid fuel pressure contracting molding machine.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described reality
Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff all other embodiment obtained without creative efforts belongs to what the present invention protected
Range.
A kind of biomass straw shaped fuel, is made of the raw material of following parts by weight: 80-100 parts of tangerine bar, activated sludge
10-14 parts, 2-3 parts of compound additive；
The activated sludge is made by the following method:
(1) sludge is crossed into 24 meshes to remove suspension and solid impurity, the activated sludge solid content after sieve is adjusted to
2.5%, obtain pretreated sludge；
(2) the pretreated sludge of 100mL is taken to be placed in tetrafluoroethene beaker, it is 2% that 3-4mL mass fraction, which is inwardly added,
Ferric chloride solution after, first 200r/min quickly stirs 1min, then 60r/min mixes slowly 2min, cover cup lid be placed on it is micro-
In wave furnace, (power density 7W/mL, radiated time 100s) takes out and is cooled to room temperature after microwave radiation；
(3) moisture content of the sludge after microwave treatment is reduced to 5% hereinafter, obtaining activity by belt-type drying technique again
Sludge；
Microwave radiation can enhance the flocculation of activated sludge, and under microwave radiation, active pollution index is by microwave
Rupture occurs under the action of hot and non-thermal and releases a large amount of dissolubility biopolymer, the iron chloride being added at this time produces in water
Raw a large amount of Fe3+, these positively charged ions and the binding sites of dissolubility biopolymer exposure interact to be formed more
It for closely knit wadding body, can be also released between wadding body with combination water intracellular in the process, therefore reach good dehydration property
Energy；In addition, small part forms iron hydroxide after iron chloride is dissolved in water, the work that skeleton builds body is played during activated sludge dehydration
With, play enhancing dewatering performance of sludge effect；Activated sludge after dehydration, desiccation can change after mixing shaped fuel
It is apt to its flammability；The ignition temperature of shaped fuel and the type of its contained volatile matter are closely related, the volatilization in activated sludge
Divide based on fats, protein and carbohydrate, largely can be precipitated and burn in lower temperature, and the CaO energy in activated sludge
Enough be changed into hardly possible decomposition volatile matter easily decomposes volatile matter, so as to improve the flammability of shaped fuel, after tested, molding combustion
The ignition temperature of material is 283-298 DEG C；
The compound additive includes Ca (OH)2、SiO2、Al2O3, Ca (OH)2、SiO2、Al2O3Mass ratio be 10:2-
3:0.5-1；
Ca(OH)2It is decomposed into CaO, meeting and SO at high temperature2Reaction generates metastable CaSO4, reduction can be reached
SO2The effect of discharge, also, SiO2In combustion with CaSO4Effect generates the Ca of stability height and compact structure5
(SiO4)2(SO4) or 2C2S·CaSO4, to reduce SO2Release；In terms of denitration, K content is higher in stalk, under high temperature
The higher easy formation eutectic of Si, Ca, K content, on the one hand inhibits coke to burn, promotes NOxIn coke surface heterogeneous reduction,
Another aspect eutectic has to be complexed compared with the structure containing N in strong cohesive property, with stalk, reduces NOxRelease, in addition,
Al2O3With certain catalytic combustion-supporting effect, NO can also be inhibitedxRelease；Therefore, it is cooperateed between compound additive each component
Effect, can reduce SO in biomass molding fuel2And NOxRelease；
A kind of preparation method of biomass straw shaped fuel, includes the following steps:
The first step, the pretreatment of tangerine bar: adding water into stalk, and adjusting its moisture content is 50%, under 1.0MPa pressure
Steam blasting is carried out, the dwell time is 5min, after the completion of processing, is quickly taken out material, dries, crushes naturally；
Cellulose molecular chain after steam pre-treatment is broken, intramolecular hydrogen bond by a degree of destruction,
The mobility of cellulose chain increases, and is conducive to cellulose and changes to disordered structure, therefore, shaped fuel after steam pre-treatment
Intensity is 1.8-2.5 times higher than before handling, and combustion heat value is also obviously improved；Meanwhile the structure of cellulose changes after pretreatment,
Fiber size attenuates, becomes smaller, lignin increased activity, and penetrates between cellulose and form new connection, and internal cohesion is aobvious
Enhancing is write, lignin degradation meets again and moves to cellulose surface, softens to form solid bridge joint, Neng Gouti in compression forming
High-mouldability energy；
Second step will crush in pulverizer by pretreated stalk, cross 80 meshes and obtain stalk powder, by tangerine bar powder
End is put into air dry oven, and dry 72-80h makes its constant weight at 105 DEG C；
Third step, the tangerine bar powder by after drying, activated sludge and compound additive mixing, will be a certain amount of with spraying apparatus
Water be uniformly sprayed in raw material and be stirred for uniformly, obtain moisture content be 8%-11% raw material；
Moisture in raw material primarily serves the effect of bonding and lubrication in forming process, helps to reduce intergranular rub
It wipes, promotes particle be combineding with each other under pressure；When moisture content is too low, intergranular frictional force is larger, leads to particle
Sufficiently it cannot extend and flow, so that particle can not combine closely；On the contrary, particle can preferably expand when moisture content is excessively high
It opens up and flows, between extra moisture is extruded under the action of briquetting pressure and intersperses among particle in raw material, cause particle cannot
It tightly engages；Through density and durability test, when moisture content of the raw material is 8%-11%, shaped fuel has preferable molding effect,
The shaped fuel processed within this range is convenient for the transport and storage in later period；
4th step carries out processing and forming using biomass solid fuel compression-molding apparatus, specifically, keeping sleeve 34 downward
Movement is until contacting support chassis 11 and being fastened in annular groove 12, the raw material that third step is obtained is put into sleeve 34, is passed through
Heating coil heats the material in sleeve 34, and (128-133 DEG C, temperature sensor detection) stops after being heated to the temperature of setting
It only heats, with upright jack to the raw material uniform load in sleeve 34, control briquetting pressure is 90Mpa, keeps 3min recession
Jack (to prevent material rebounds while guaranteeing the well-bonded of internal particle) is gone, is removed after jack to being formed in sleeve 34
Fuel presses, and adjust sleeve 34 and be slowly move upwardly until and completely disengage shaped fuel, obtained shaped fuel stays in ring
In shape slot 12, biomass molding fuel is made；
It please refers to shown in Fig. 1-4, biomass solid fuel compression-molding apparatus, as shown in Figure 1, including pedestal 1, gear
Structure 2 and sleeve mechanism 3, wherein linkage mechanism 2 is installed on pedestal 1, and sleeve mechanism 3 is installed on linkage mechanism 2,1 He of pedestal
Sleeve mechanism 3 is connected by linkage mechanism 2；
As shown in Fig. 2, bottom pedestal 1 include support chassis 11, support chassis 11 include two connection circular support disks, one
The support plate centre of surface position of side is fixed with annular groove 12, and the upper surface of the support plate of the other side is vertically and fixedly provided with three supports
Bar 13, preferably, support rod 13 are located at the marginal position of 11 upper surface of support chassis and three support rods 13 along support chassis 11
Circumferencial direction be distributed in its surface；The upper end of support rod 13 is fixed with the first mounting plate 14, the first mounting plate 14 and support rod
The angle of 13 inner surfaces is 130-140 °, and the surface of the first mounting plate 14 is provided with the first mounting hole；The inside table of support rod 13
Face is fixed with mounting ring 16 by connecting plate 15, and preferably, mounting ring 16 and support chassis 11 are arranged in parallel and mounting ring 16
The center of circle and the center of circle of support chassis 11 are located on same vertical line；In addition, the surface of support chassis 11 is vertically and fixedly provided with the second peace
The surface of loading board 17, the second mounting plate 17 is provided with the second mounting hole；
As shown in figure 3, linkage mechanism 2 includes first bevel gear 21, second bevel gear 22 and interlocking bar 23, first bevel gear
21 surface is fixed with the first installation axle 211, and the first installation axle 211 is installed on the second mounting plate 17 by bearing, wherein the
One installation axle, 211 other end is connected with motor, its rotation of motor driven；Second bevel gear 22 is connected by the second installation axle 221
It is fixed with disk 222, the second installation axle 221 is run through by bearing to be installed in mounting ring 16, specifically, second bevel gear 22
In 16 lower section of mounting ring, disk 222 is located at 16 top of mounting ring, and second bevel gear 22 is engaged with first bevel gear 21；Disk 222
Upper surface be equipped with helical raised 223；23 one end of interlocking bar is fixed with gear 231, and gear 231 is movably installed in the first installation
On plate 14, gear 231 is engaged with helical raised 223；23 other end of interlocking bar is movably installed with connecting rod 232, and connecting rod 232 is another
End is installed on upper clamp plate 3；
As shown in figure 4, sleeve mechanism 3 includes circular slab 31, there are three mounting racks 32 for the lower surface installation of circular slab 31, even
Bar 232 is movably installed on mounting rack 31；The side of circular slab 31 is connected with loading plate 33, preferably, loading plate 33 and circle
Plate 31 is located in same level, and through sleeve 34 is fixed on loading plate 33, sleeve 34 and annular groove 12 cooperate, specifically,
Sleeve 34 is when vertical direction moves down, and when touching support chassis 11, can just be fastened in annular groove 12；Sleeve
34 weeks side external surfaces are equipped with heating coil, and heating coil is uniformly distributed in the side of sleeve 34 and is in close contact with sleeve 34, guarantees
Heat transfer is fast and uniform；
The working principle and mode of the biomass solid fuel compression-molding apparatus:
Start the motor that first bevel gear 21 connects, is engaged by first bevel gear 21 with second bevel gear 22, drive the
The rotation of two bevel gears 22, and then disk 222 rotates, and during disk 222 rotates, passes through helical raised 223 and gear 231
Engagement band moving gear 231 rotate, the rotation of gear 231 can be realized interlocking bar 23 around a rotation, then pass through the biography of connecting rod 232
It is dynamic, realize moving up and down for circular slab 31, circular slab 31, which moves up and down, to be moved up and down along the vertical direction with moving sleeve 34；Make
Used time moves down sleeve 34 until contacting support chassis 11 and being fastened in annular groove 12, material is put into sleeve 34,
The material in sleeve 34 is heated by heating coil, (temperature sensor detection) stops adding after being heated to the temperature of setting
Heat removes jack (to prevent material from returning after keeping 3min with hoisting jack to the material uniform load in sleeve 34
Bullet guarantees the well-bonded of internal particle simultaneously), it removes after jack to fuel presses molding in sleeve, keeps sleeve 34 slow
It is move upwardly until and completely disengages shaped fuel, obtained shaped fuel stays in annular groove 12；Release sleeve 34 in this way
Interior shaped fuel not will cause the broken phenomenon of material, can guarantee the integrality of shaped fuel to greatest extent and keep as former state
Property.
Embodiment 1
A kind of biomass straw shaped fuel, is made of the raw material of following parts by weight: 80 parts of tangerine bar, 10 parts of activated sludge,
2 parts of compound additive；
A kind of preparation method of biomass straw shaped fuel, includes the following steps:
The first step, the pretreatment of tangerine bar: adding water into stalk, and adjusting its moisture content is 50%, is added to steam explosion reaction
In device, explosion is carried out under 1.0MPa pressure, the dwell time is 5min, after the completion of processing, is quickly taken out material, is shone naturally
Dry, crushing；
Second step will crush in pulverizer by pretreated stalk, cross 80 meshes and obtain stalk powder, by tangerine bar powder
End is put into air dry oven, the dry 72h at 105 DEG C；
Third step, the tangerine bar powder by after drying, activated sludge and compound additive mixing, will be a certain amount of with spraying apparatus
Water be uniformly sprayed in raw material and be stirred for uniformly, obtain moisture content be 8% raw material；
4th step carries out processing and forming using biomass solid fuel compression-molding apparatus, specifically, keeping sleeve 34 downward
Movement is until contacting support chassis 11 and being fastened in annular groove 12, the raw material that third step is obtained is put into sleeve 34, is passed through
Heating coil heats the material in sleeve 34, stops heating after being heated to 128 DEG C of temperature of setting, with upright jack pair
Raw material uniform load in sleeve 34, control briquetting pressure are 90Mpa, jack are removed after keeping 3min, after removing jack
It to molding fuel presses in sleeve 34, and adjusts slow be move upwardly until of sleeve 34 and completely disengages shaped fuel, obtain
Shaped fuel stays in annular groove 12, and biomass molding fuel is made.
Embodiment 2
A kind of biomass straw shaped fuel, is made of the raw material of following parts by weight: 90 parts of tangerine bar, 12 parts of activated sludge,
2.5 parts of compound additive；
A kind of preparation method of biomass straw shaped fuel, includes the following steps:
The first step, the pretreatment of tangerine bar: adding water into stalk, and adjusting its moisture content is 50%, is added to steam explosion reaction
In device, explosion is carried out under 1.0MPa pressure, the dwell time is 5min, after the completion of processing, is quickly taken out material, is shone naturally
Dry, crushing；
Second step will crush in pulverizer by pretreated stalk, cross 80 meshes and obtain stalk powder, by tangerine bar powder
End is put into air dry oven, the dry 76h at 105 DEG C；
Third step, the tangerine bar powder by after drying, activated sludge and compound additive mixing, will be a certain amount of with spraying apparatus
Water be uniformly sprayed in raw material and be stirred for uniformly, obtain moisture content be 10% raw material；
4th step carries out processing and forming using biomass solid fuel compression-molding apparatus, specifically, keeping sleeve 34 downward
Movement is until contacting support chassis 11 and being fastened in annular groove 12, the raw material that third step is obtained is put into sleeve 34, is passed through
Heating coil heats the material in sleeve 34, stops heating after being heated to 130 DEG C of temperature of setting, with upright jack pair
Raw material uniform load in sleeve 34, control briquetting pressure are 90Mpa, jack are removed after keeping 3min, after removing jack
It to molding fuel presses in sleeve 34, and adjusts slow be move upwardly until of sleeve 34 and completely disengages shaped fuel, obtain
Shaped fuel stays in annular groove 12, and biomass molding fuel is made.
Embodiment 3
A kind of biomass straw shaped fuel, is made of the raw material of following parts by weight: 100 parts of tangerine bar, 14 parts of activated sludge,
3 parts of compound additive；
A kind of preparation method of biomass straw shaped fuel, includes the following steps:
The first step, the pretreatment of tangerine bar: adding water into stalk, and adjusting its moisture content is 50%, is added to steam explosion reaction
In device, explosion is carried out under 1.0MPa pressure, the dwell time is 5min, after the completion of processing, is quickly taken out material, is shone naturally
Dry, crushing；
Second step will crush in pulverizer by pretreated stalk, cross 80 meshes and obtain stalk powder, by tangerine bar powder
End is put into air dry oven, the dry 80h at 105 DEG C；
Third step, the tangerine bar powder by after drying, activated sludge and compound additive mixing, will be a certain amount of with spraying apparatus
Water be uniformly sprayed in raw material and be stirred for uniformly, obtain moisture content be 11% raw material；
4th step carries out processing and forming using biomass solid fuel compression-molding apparatus, specifically, keeping sleeve 34 downward
Movement is until contacting support chassis 11 and being fastened in annular groove 12, the raw material that third step is obtained is put into sleeve 34, is passed through
Heating coil heats the material in sleeve 34, stops heating after being heated to 133 DEG C of temperature of setting, with upright jack pair
Raw material uniform load in sleeve 34, control briquetting pressure are 90Mpa, jack are removed after keeping 3min, after removing jack
It to molding fuel presses in sleeve 34, and adjusts slow be move upwardly until of sleeve 34 and completely disengages shaped fuel, obtain
Shaped fuel stays in annular groove 12, and biomass molding fuel is made.
Comparative example 1
Activated sludge raw material in embodiment 1 is removed, remaining is constant.
Comparative example 2
Compound additive in embodiment 1 is removed, remaining is constant.
Comparative example 3
Common process molding machine 1 is used to process during the preparation process the raw material in embodiment 1.
Comparative example 4
In process, tangerine bar is without pretreatment for embodiment 1.
Following performance test is done to fuel made from embodiment 1-3 and comparative example 1-4:
Physical property: test density；Durability: according to CEN/TS 15210-2, using special dust-proof drum apparatus into
Row measurement, falls fragility: according to ASTMD 440-86, residual mass and protoplasm after solid fuel is placed in after 1.83m eminence is fallen
The ratio between amount；
Combustibility: the ignition temperature of fuel is tested；After burning at 900 DEG C, test 50s, 100s discharge SO2And NOx's
Amount；
Test test result is as follows table:
It is found that the density of shaped fuel made from embodiment 1-3 is 1.05-1.09gcm-3, durability 99.1-
99.7%, Shatter resistance 99.1-99.5% illustrate the good forming effect of fuel produced by the present invention, in conjunction with comparative example 3, say
It is bright that processing and forming is carried out using homemade biomass solid fuel compression-molding apparatus, it can be improved fuel forming performance, in conjunction with
Comparative example 4 illustrates that tangerine bar can be improved the processability of fuel by pretreatment；It is found that shaped fuel made from embodiment 1-3
Ignition temperature be 283-286 DEG C, illustrate that shaped fuel flammability produced by the present invention is good, in conjunction with comparative example 2, illustrate activity
The incorporation of sludge can improve the flammability of fuel；SO of the fuel made from embodiment 1-3 in 50s, 100s2Burst size difference
For 162-170mgm-3、84-88mg·m-3, in the NO of 50s, 100sxBurst size is respectively 250-257mgm-3、60-
65mg·m-3, illustrate the SO of fuel produced by the present invention2And NOxBurst size is lower, in conjunction with comparative example 2, illustrates compound addition
The addition of agent can effectively reduce SO2And NOxBurst size.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment
All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification,
It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention
Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only
It is limited by claims and its full scope and equivalent.
Claims (8)
1. a kind of biomass straw shaped fuel, which is characterized in that be made of the raw material of following parts by weight: 80-100 parts of tangerine bar,
10-14 parts of activated sludge, 2-3 parts of compound additive；
The biomass straw shaped fuel is made of following steps:
The first step, the pretreatment of tangerine bar: adding water into stalk, and adjusting its moisture content is 50%, carries out under 1.0MPa pressure
Steam blasting, dwell time 5min after the completion of processing, quickly take out material, dry, crush naturally；
Second step will crush in pulverizer by pretreated stalk, cross 80 meshes and obtain stalk powder, tangerine bar powder is put
Enter in air dry oven, dry 72-80h makes its constant weight at 105 DEG C；
Third step, the tangerine bar powder by after drying, activated sludge and compound additive mixing, with spraying apparatus by a certain amount of water
It is uniformly sprayed in raw material and is stirred for uniformly obtaining the raw material that moisture content is 8%-11%；
4th step, using biomass solid fuel compression-molding apparatus carry out processing and forming, make sleeve (34) move down until
Contact support chassis (11) is simultaneously fastened in annular groove (12), and the raw material that third step is obtained is put into sleeve (34), by adding
Gas ket heats the raw material in sleeve (34), stops heating after being heated to 128-133 DEG C of temperature of setting, with vertical very heavy
To the raw material uniform load in sleeve (34), control briquetting pressure is 90Mpa on top, removes jack after keeping 3min, removes thousand
To molding fuel presses in sleeve (34) behind jin top, and adjusts sleeve (34) and be slowly move upwardly until that completely disengaging molding fires
Material, obtained shaped fuel stay in annular groove (12), and biomass molding fuel is made.
2. a kind of biomass straw shaped fuel according to claim 1, which is characterized in that the activated sludge is by as follows
Method is made:
(1) sludge is crossed into 24 meshes to remove suspension and solid impurity, the activated sludge solid content after sieve is adjusted to 2.5%, is obtained
To pretreated sludge；
(2) it takes the pretreated sludge of 100mL to be placed in tetrafluoroethene beaker, the chlorine that 3-4mL mass fraction is 2% is inwardly added
After changing ferrous solution, first 200r/min quickly stirs 1min, then 60r/min mixes slowly 2min, covers cup lid and is placed on micro-wave oven
In, it takes out and is cooled to room temperature after microwave radiation；
Microwave radiation parameter: power density 7W/mL, radiated time 100s；
(3) moisture content of the sludge after microwave treatment is reduced to 5% hereinafter, obtaining active dirt by belt-type drying technique again
Mud.
3. a kind of biomass straw shaped fuel according to claim 1, which is characterized in that the compound additive includes
Ca(OH)2、SiO2、Al2O3, Ca (OH)2、SiO2、Al2O3Mass ratio be 10:2-3:0.5-1.
4. a kind of preparation method of biomass straw shaped fuel, which comprises the steps of:
The first step, the pretreatment of tangerine bar: adding water into stalk, and adjusting its moisture content is 50%, carries out under 1.0MPa pressure
Steam blasting, dwell time 5min after the completion of processing, quickly take out material, dry, crush naturally；
Second step will crush in pulverizer by pretreated stalk, cross 80 meshes and obtain stalk powder, tangerine bar powder is put
Enter in air dry oven, dry 72-80h makes its constant weight at 105 DEG C；
Third step, the tangerine bar powder by after drying, activated sludge and compound additive mixing, with spraying apparatus by a certain amount of water
It is uniformly sprayed in raw material and is stirred for uniformly obtaining the raw material that moisture content is 8%-11%；
4th step, using biomass solid fuel compression-molding apparatus carry out processing and forming, make sleeve (34) move down until
Contact support chassis (11) is simultaneously fastened in annular groove (12), and the raw material that third step is obtained is put into sleeve (34), by adding
Gas ket heats the raw material in sleeve (34), stops heating after being heated to 128-133 DEG C of temperature of setting, with vertical very heavy
To the raw material uniform load in sleeve (34), control briquetting pressure is 90Mpa on top, removes jack after keeping 3min, removes thousand
To molding fuel presses in sleeve (34) behind jin top, and adjusts sleeve (34) and be slowly move upwardly until that completely disengaging molding fires
Material, obtained shaped fuel stay in annular groove (12), and biomass molding fuel is made.
5. a kind of preparation method of biomass straw shaped fuel according to claim 4, which is characterized in that biomass is solid
Fluid fuel compression-molding apparatus, including pedestal (1), linkage mechanism (2) and sleeve mechanism (3), linkage mechanism (2) are installed on pedestal
(1) on, sleeve mechanism (3) is installed on linkage mechanism (2), and pedestal (1) and sleeve mechanism (3) are connected by linkage mechanism (2)；
Pedestal (1) includes support chassis (11), and support chassis (11) includes the circular support disk of two connections, the support plate of side
Centre of surface position is fixed with annular groove (12), and the upper surface of the support plate of the other side is vertically and fixedly provided with three support rods (13),
The upper end of support rod (13) is fixed with the first mounting plate (14), the angle of the first mounting plate (14) and support rod (13) inner surface
It is 130-140 °, the surface of the first mounting plate (14) is provided with the first mounting hole；The inner surface of support rod (13) passes through connecting plate
(15) it is fixed with mounting ring (16), the surface of support chassis (11) is vertically and fixedly provided with the second mounting plate (17), the second mounting plate
(17) surface is provided with the second mounting hole；
Linkage mechanism (2) includes first bevel gear (21), second bevel gear (22) and interlocking bar (23), first bevel gear (21)
Surface is fixed with the first installation axle (211), and the first installation axle (211) is installed on the second mounting plate (17) by bearing, wherein
First installation axle (211) other end is connected with motor；Second bevel gear (22) is fixedly connected with circle by the second installation axle (221)
Disk (222), for the second installation axle (221) by bearing through being installed on mounting ring (16), second bevel gear (22) is located at installation
Below ring (16), disk (222) is located above mounting ring (16), and second bevel gear (22) is engaged with first bevel gear (21)；Circle
The upper surface of disk (222) is equipped with helical raised (223)；Interlocking bar (23) one end is fixed with gear (231), and gear (231) is living
Dynamic to be installed on the first mounting plate (14), gear (231) is engaged with helical raised (223)；The activity of interlocking bar (23) other end
It is equipped with connecting rod (232), connecting rod (232) other end is installed on upper clamp plate (3)；
Sleeve mechanism (3) includes circular slab (31), and there are three mounting rack (32), connecting rods for the lower surface installation of circular slab (31)
(232) it is movably installed on mounting rack (31)；The side of circular slab (31) is connected with loading plate (33), and loading plate runs through on (33)
It is fixed with sleeve (34), sleeve (34) and annular groove (12) cooperate.
6. a kind of preparation method of biomass straw shaped fuel according to claim 5, which is characterized in that the support
Bar (13) be located at the marginal position of support chassis (11) upper surface and three support rods (13) along support chassis (11) circumference side
To being distributed in its surface.
7. a kind of preparation method of biomass straw shaped fuel according to claim 5, which is characterized in that the installation
Ring (16) and support chassis (11) are arranged in parallel and the center of circle of the center of circle of mounting ring (16) and support chassis (11) is located at same erect
On straight line.
8. a kind of preparation method of biomass straw shaped fuel according to claim 4, which is characterized in that the sleeve
(34) all side external surfaces are equipped with heating coil, and heating coil is uniformly distributed in the side of sleeve (34) and closely connects with sleeve (34)
Touching.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910550311.8A CN110257122A (en) | 2019-06-24 | 2019-06-24 | A kind of biomass straw shaped fuel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910550311.8A CN110257122A (en) | 2019-06-24 | 2019-06-24 | A kind of biomass straw shaped fuel and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110257122A true CN110257122A (en) | 2019-09-20 |
Family
ID=67920965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910550311.8A Pending CN110257122A (en) | 2019-06-24 | 2019-06-24 | A kind of biomass straw shaped fuel and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110257122A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102285234B1 (en) * | 2021-02-15 | 2021-08-03 | 구경신 | Solidification automatic device for livestock manure |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993752A (en) * | 2010-11-25 | 2011-03-30 | 东南大学 | Method and device for preparing fuel by utilizing sludge and straw |
| CN103060044A (en) * | 2013-01-17 | 2013-04-24 | 湖南大学 | Method for preparing solid fuel by mixing sludge and biomass |
| CN104212531A (en) * | 2014-09-25 | 2014-12-17 | 江南大学 | Method for preparing solid fuel by exploding biomass waste through external gas assisted by steam |
| CN106635226A (en) * | 2016-08-30 | 2017-05-10 | 钟波 | Sludge and straw cooperation harmless treatment process |
| CN109467304A (en) * | 2017-09-08 | 2019-03-15 | 湖南大学 | A kind of method of sludge pretreatment |
-
2019
- 2019-06-24 CN CN201910550311.8A patent/CN110257122A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993752A (en) * | 2010-11-25 | 2011-03-30 | 东南大学 | Method and device for preparing fuel by utilizing sludge and straw |
| CN103060044A (en) * | 2013-01-17 | 2013-04-24 | 湖南大学 | Method for preparing solid fuel by mixing sludge and biomass |
| CN104212531A (en) * | 2014-09-25 | 2014-12-17 | 江南大学 | Method for preparing solid fuel by exploding biomass waste through external gas assisted by steam |
| CN106635226A (en) * | 2016-08-30 | 2017-05-10 | 钟波 | Sludge and straw cooperation harmless treatment process |
| CN109467304A (en) * | 2017-09-08 | 2019-03-15 | 湖南大学 | A kind of method of sludge pretreatment |
Non-Patent Citations (4)
| Title |
|---|
| 戴伟等: "荞麦秸秆固体燃料成型工艺参数优化", 《山西农业大学学报（自然科学版）》 * |
| 曹忠耀: "生物质预处理制成型燃料研究进展", 《洁净煤技术》 * |
| 林志宏等: "《工业锅炉节能技术与管理》", 31 July 2008, 中国计量出版社 * |
| 林浚铭: "活性污泥脱水、干化及混合木屑制备生物质燃料", 《中国优秀硕士学位论文全文数据库（工程科技Ι辑）》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102285234B1 (en) * | 2021-02-15 | 2021-08-03 | 구경신 | Solidification automatic device for livestock manure |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Chen et al. | Progress in biomass torrefaction: Principles, applications and challenges | |
| Ighalo et al. | Recent advances in hydrochar application for the adsorptive removal of wastewater pollutants | |
| AU2011264855B2 (en) | Methods for the manufacture of fuel pellets and other products from lignocellulosic biomass | |
| Reza et al. | Hydrothermal carbonization of biomass for energy and crop production | |
| AU2020100229A4 (en) | Activated carbon prepared from biomass waste, preparation method thereof, and use thereof in treatment of nitrophenol compounds in wastewater | |
| Tsai et al. | Porous and adsorption properties of activated carbon prepared from cocoa pod husk by chemical activation | |
| JP6407506B2 (en) | Solid fuel production method and solid fuel | |
| CN100335408C (en) | Production of active carbon with Chinese chestnut | |
| Liu et al. | Fabrication, characterization and sorption properties of activated biochar from livestock manure via three different approaches | |
| MX2012010137A (en) | Pyrolysis of biomass. | |
| CN104593116B (en) | Method for preparing solid formed fuel from biomass liquefaction residues | |
| Neme et al. | Preparation and characterization of activated carbon from castor seed hull by chemical activation with H3PO4 | |
| JP2016511308A (en) | Method for producing carbon-enriched biomass material | |
| Oliveira et al. | Low-cost adsorbents from agri-food wastes | |
| CN103666620A (en) | Biomass fuel with good formability | |
| Liang et al. | Physical and combustion properties of binder-assisted hydrochar pellets from hydrothermal carbonization of tobacco stem | |
| CN107488477A (en) | Environmentally friendly biomass fuel and its production technology | |
| Waheed et al. | An overview of torrefied bioresource briquettes: quality-influencing parameters, enhancement through torrefaction and applications | |
| CN111330541A (en) | Modified biochar and preparation method thereof | |
| CN110257122A (en) | A kind of biomass straw shaped fuel and preparation method thereof | |
| CN113477218A (en) | Potassium dihydrogen phosphate modified biochar and preparation method and application thereof | |
| Ding et al. | Production of biochar from tropical fruit tree residues and ecofriendly applications–A review | |
| Adekanye et al. | Pyrolysis of maize cob at different temperatures for biochar production: Proximate, ultimate and spectroscopic characterisation. | |
| JP7261176B2 (en) | Method for producing solid fuel | |
| CN110918058A (en) | Biochar and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190920 |