CN110253704A - A kind of decoration wood wool board and preparation method thereof - Google Patents
A kind of decoration wood wool board and preparation method thereof Download PDFInfo
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- CN110253704A CN110253704A CN201910522038.8A CN201910522038A CN110253704A CN 110253704 A CN110253704 A CN 110253704A CN 201910522038 A CN201910522038 A CN 201910522038A CN 110253704 A CN110253704 A CN 110253704A
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- wood wool
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/001—Heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/02—Staining or dyeing wood; Bleaching wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/04—Combined bleaching or impregnating and drying of wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/002—Manufacture of substantially flat articles, e.g. boards, from particles or fibres characterised by the type of binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/10—Moulding of mats
- B27N3/14—Distributing or orienting the particles or fibres
- B27N3/143—Orienting the particles or fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2200/00—Wooden materials to be treated
- B27K2200/10—Articles made of particles or fibres consisting of wood or other lignocellulosic material
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The invention discloses a kind of decoration wood wool board and its manufacturing methods, belong to building decorative plates field.A kind of decoration wood wool board, it is suppressed after dyeing with epoxy resin adhesive hot pressing by wood wool monomer, wood wool monomer sand paper sanding to the smooth no hangnail in surface, monomer arrangement mode is divided into tri- kinds of modes of a, b, c, the assemble pattern of the wood wool board is that the monomer orientation of odd even layer wood wool is mutually perpendicular to, five layers of assembly;Dyeing agent solution for dyeing includes the peregal O-25 of the direct fast scarlet 4BS of mass fraction 0.2%, direct yellow R or reactive brilliant blue X-3B, 1~2g/L, and the penetrating agent JFC of 20~25g/L, color fixing agent is the natrium carbonicum calcinatum of 25g/L.
Description
Technical field
The present invention relates to building decorative plates field, a kind of decoration wood wool board and preparation method thereof is more particularly related to.
Background technique
It is widely used in decorations etc. since timber has unique material property and excellent environmentology characteristic
Field, the type of wood wool board mainly has using materials such as cement and polyurethane foams as crosslinking agent at present, and wood wool increases as fiber
Wood wool cement board and polyurethane foam wood wool board made of strong material compacting.Wood wool board has sound-absorbing, insulation, fire prevention anti-
The multifrequency natures such as tide, antiseptic insect-repelling, light-weight and easy for construction, the noble quality with decorating board is chiefly used in broadcasting studio, opera
The occasions such as institute, stadium and club.
Wood-based Panel Production total amount is gradually reduced in recent years, and there are the statuses that the reduction of outlet rate, import unit price rise, and studies people
Make the emphasis that plate is current industry of artificial boards.But timber there are its decorative and physical and mechanical properties when in use cannot be same
When the limitation that meets, therefore dyeing processing carried out to wood wool and heat pressing process processing prepare decorative wood wool board have reality and
Important meaning.
Summary of the invention
To solve the above-mentioned problems of the prior art, the purpose of the present invention is to provide a kind of decorative performance is strong, and its
The impregnable wood wool board of his properties.
In order to achieve the above objectives, the technical scheme is that a kind of decorate uses wood wool board, by wood wool monomer through dyeing it
It is suppressed afterwards with epoxy resin adhesive hot pressing, wood wool monomer sand paper sanding to the smooth no hangnail in surface, width 4
~5mm, length are 100~300mm, and monomer arrangement mode is divided into tri- kinds of modes of a, b, c,
A. every layer of every row's wood wool monomer length and quantity arrangement mode are alternately arranged by 150mm*2,100mm*3;
B. every layer of every row's wood wool monomer length and quantity are alternately arranged by 300mm*1,150mm*2;
C. every layer of every row's wood wool monomer length and quantity are arranged by 300mm*1;
The assemble pattern of the wood wool board is that the monomer orientation of odd even layer wood wool is mutually perpendicular to, five layers of assembly.
Further, the wood wool monomer without furuncle and is damaged by worms.
Further, the wood wool monomer is poplar wood wool monomer.
Further, the decoration manufacturing method of wood wool board, comprising the following steps:
(1) prepared by wood wool monomer: poplar plate being placed in wood wool molding machine inlet, prepares wood wool monomer, the wood wool
Hull beam is 4~5mm;
(2) length of wood wool monomer obtained in step (1) wood wool post-processing: is cut to 100~300mm;
(3) wood wool dyes: the wood wool monomer in step (2) being placed in 40~60min of heating water bath in dyeing agent solution, so
After be added color fixing agent, continue 40~60min of heating water bath, then wash color, drying;
(4) it suppresses: decoration being pressed by heat pressing process with the resulting wood wool monomer of step (3) and epoxy resin adhesive
With wood wool board, hot pressing uses 14%~26% resin added, 130 DEG C~190 DEG C of hot pressing temperature, the hot pressing time of 4~7min,
The hot pressing pressure of 1~4MPa.
Further, the dyeing agent solution in step (3) include mass fraction 0.2% direct fast scarlet 4BS, directly
The peregal O-25 of yellow R or reactive brilliant blue X-3B, 1~2g/L, the penetrating agent JFC of 20~25g/L.
Further, the wood wool monomer in step (3) and bath solution volume ratio are 1:30~1:50.
Further, bath temperature is 70 DEG C~100 DEG C in step (3).
Further, the color fixing agent in step (3) is the natrium carbonicum calcinatum of 20~25g/L.
Compared with the existing technology, the invention has the benefit that
(1) dicoration of wood wool board had not only can be improved in the present invention, but also can not influence its properties.
(2) treatment process of the present invention includes direct dyes and reactive dyeing heat pressing process, including when resin added, hot pressing
Between, hot pressing temperature and hot pressing pressure, probed into and prepared the optimal wood of every physical and mechanical property in the case where cost is minimum
Filament plate.
(3) wood wool board is made of wood wool monomer and epoxy resin adhesive hot pressing in the present invention, and every layer of wood wool monomer hangs down
In line column have many advantages, such as sound absorption properties, wearability and weatherability using five layers of assembly.
(4) it is incompatible with half sugared fiber, the carbohydrate of wood wool to overcome cement using epoxy resin as adhesive by the present invention
Problem, and epoxy resin is a kind of formaldehydeless Environment-friendlyadhesive adhesive.
Detailed description of the invention
Fig. 1 is decoration wood wool board production process schematic diagram
Fig. 2 is wood wool monomer arrangement mode schematic diagram
Specific embodiment
Technical solution of the present invention is described in further detail with reference to the accompanying drawings and detailed description:
Embodiment 1
A kind of decoration wood wool board, is suppressed after dyeing with epoxy resin adhesive hot pressing, institute by wood wool monomer
Stating wood wool monomer is poplar wood wool monomer, and without furuncle and damaging by worms, wood wool monomer with sand paper sanding to the smooth no hangnail in surface, it is wide
Degree is 4~5mm, and length is 100~300mm, and monomer arrangement mode is divided into tri- kinds of modes of a, b, c,
A. every layer of every row's wood wool monomer length and quantity arrangement mode are alternately arranged by 150mm*2,100mm*3;
B. every layer of every row's wood wool monomer length and quantity are alternately arranged by 300mm*1,150mm*2;
C. every layer of every row's wood wool monomer length and quantity are arranged by 300mm*1;
The assemble pattern of the wood wool board is that the monomer orientation of odd even layer wood wool is mutually perpendicular to, five layers of assembly.
The decoration manufacturing method of wood wool board, comprising the following steps:
(1) prepared by wood wool monomer: poplar plate being placed in wood wool molding machine inlet, prepares wood wool monomer, the wood wool
Hull beam is 4~5mm;
(2) length of wood wool monomer obtained in step (1) wood wool post-processing: is cut to 100~300mm;
(3) wood wool dyes: the wood wool monomer in step (2) being placed in 70 DEG C of heating 40min of water-bath in dyeing agent solution, so
The natrium carbonicum calcinatum of color fixing agent 20g/L is added afterwards, continues 70 DEG C of DEG C of heating 60min of water-bath, then washes color, drying;
(4) it suppresses: decoration being pressed by heat pressing process with the resulting wood wool monomer of step (3) and epoxy resin adhesive
With wood wool board, hot pressing uses 14% resin added, 130 DEG C of hot pressing temperature, the hot pressing time of 4min, the hot pressing pressure of 1MPa.
Further, the dyeing agent solution in step (3) include mass fraction 0.2% direct fast scarlet 4BS, directly
The peregal O-25 of yellow R or reactive brilliant blue X-3B, 1g/L, the penetrating agent JFC of 20g/L.
Further, the wood wool monomer in step (3) and bath solution volume ratio are 1:30.
Embodiment 2
A kind of decoration wood wool board, is suppressed after dyeing with epoxy resin adhesive hot pressing, institute by wood wool monomer
Stating wood wool monomer is poplar wood wool monomer, and without furuncle and damaging by worms, wood wool monomer with sand paper sanding to the smooth no hangnail in surface, it is wide
Degree is 4~5mm, and length is 100~300mm, and monomer arrangement mode is divided into tri- kinds of modes of a, b, c,
A. every layer of every row's wood wool monomer length and quantity arrangement mode are alternately arranged by 150mm*2,100mm*3;
B. every layer of every row's wood wool monomer length and quantity are alternately arranged by 300mm*1,150mm*2;
C. every layer of every row's wood wool monomer length and quantity are arranged by 300mm*1;
The assemble pattern of the wood wool board is that the monomer orientation of odd even layer wood wool is mutually perpendicular to, five layers of assembly.
The decoration manufacturing method of wood wool board, comprising the following steps:
(1) prepared by wood wool monomer: poplar plate being placed in wood wool molding machine inlet, prepares wood wool monomer, the wood wool
Hull beam is 4~5mm;
(2) length of wood wool monomer obtained in step (1) wood wool post-processing: is cut to 100~300mm;
(3) wood wool dyes: the wood wool monomer in step (2) being placed in 80 DEG C of heating 50min of water-bath in dyeing agent solution, so
The natrium carbonicum calcinatum of color fixing agent 22g/L is added afterwards, continues 80 DEG C of heating 460min of water-bath, then washes color, drying;
(4) it suppresses: decoration being pressed by heat pressing process with the resulting wood wool monomer of step (3) and epoxy resin adhesive
With wood wool board, hot pressing uses 18% resin added, 150 DEG C of hot pressing temperature, the hot pressing time of 5min, the hot pressing pressure of 2MPa.
Further, the dyeing agent solution in step (3) include mass fraction 0.2% direct fast scarlet 4BS, directly
The peregal O-25 of yellow R or reactive brilliant blue X-3B, 2g/L, the penetrating agent JFC of 25g/L.
Further, the wood wool monomer in step (3) and bath solution volume ratio are 1:40.
Embodiment 3
A kind of decoration wood wool board, is suppressed after dyeing with epoxy resin adhesive hot pressing, institute by wood wool monomer
Stating wood wool monomer is poplar wood wool monomer, and without furuncle and damaging by worms, wood wool monomer with sand paper sanding to the smooth no hangnail in surface, it is wide
Degree is 4~5mm, and length is 100~300mm, compression strength 50.79MPa, and monomer arrangement mode is divided into tri- kinds of modes of a, b, c,
A. every layer of every row's wood wool monomer length and quantity arrangement mode are alternately arranged by 150mm*2,100mm*3;
B. every layer of every row's wood wool monomer length and quantity are alternately arranged by 300mm*1,150mm*2;
C. every layer of every row's wood wool monomer length and quantity are arranged by 300mm*1;
The assemble pattern of the wood wool board is that the monomer orientation of odd even layer wood wool is mutually perpendicular to, five layers of assembly.
The decoration manufacturing method of wood wool board, comprising the following steps:
(1) prepared by wood wool monomer: poplar plate being placed in wood wool molding machine inlet, prepares wood wool monomer, the wood wool
Hull beam is 4~5mm;
(2) length of wood wool monomer obtained in step (1) wood wool post-processing: is cut to 100~300mm;
(3) wood wool dyes: the wood wool monomer in step (2) being placed in 90 DEG C of heating 60min of water-bath in dyeing agent solution, so
The natrium carbonicum calcinatum of 20~25g/L of color fixing agent is added afterwards, continues 90 DEG C of heating 40min of water-bath, then washes color, drying;
(4) it suppresses: decoration being pressed by heat pressing process with the resulting wood wool monomer of step (3) and epoxy resin adhesive
With wood wool board, hot pressing uses 22% resin added, 170 DEG C of hot pressing temperature, the hot pressing time of 6min, the hot pressing pressure of 3MPa.
Further, the dyeing agent solution in step (3) include mass fraction 0.2% direct fast scarlet 4BS, directly
The peregal O-25 of yellow R or reactive brilliant blue X-3B, 1g/L, the penetrating agent JFC of 25g/L.
Further, the wood wool monomer in step (3) and bath solution volume ratio are 1:50.
Embodiment 4
A kind of decoration wood wool board, is suppressed after dyeing with epoxy resin adhesive hot pressing, institute by wood wool monomer
Stating wood wool monomer is poplar wood wool monomer, and without furuncle and damaging by worms, wood wool monomer with sand paper sanding to the smooth no hangnail in surface, it is wide
Degree is 4~5mm, and length is 100~300mm, and monomer arrangement mode is divided into tri- kinds of modes of a, b, c,
A. every layer of every row's wood wool monomer length and quantity arrangement mode are alternately arranged by 150mm*2,100mm*3;
B. every layer of every row's wood wool monomer length and quantity are alternately arranged by 300mm*1,150mm*2;
C. every layer of every row's wood wool monomer length and quantity are arranged by 300mm*1;
The assemble pattern of the wood wool board is that the monomer orientation of odd even layer wood wool is mutually perpendicular to, five layers of assembly.
The decoration manufacturing method of wood wool board, comprising the following steps:
(1) prepared by wood wool monomer: poplar plate being placed in wood wool molding machine inlet, prepares wood wool monomer, the wood wool
Hull beam is 4~5mm;
(2) length of wood wool monomer obtained in step (1) wood wool post-processing: is cut to 100~300mm;
(3) wood wool dyes: the wood wool monomer in step (2) is placed in 100 DEG C of heating 40min of water-bath in dyeing agent solution,
Then the natrium carbonicum calcinatum of 20~25g/L of color fixing agent is added, continues 100 DEG C of heating 50min of water-bath, then washes color, drying;
(4) it suppresses: decoration being pressed by heat pressing process with the resulting wood wool monomer of step (3) and epoxy resin adhesive
With wood wool board, hot pressing uses 26% resin added, 190 DEG C of hot pressing temperature, the hot pressing time of 7min, the hot pressing pressure of 4MPa.
Further, the dyeing agent solution in step (3) include mass fraction 0.2% direct fast scarlet 4BS, directly
The peregal O-25 of yellow R or reactive brilliant blue X-3B, 2g/L, the penetrating agent JFC of 25g/L.
Further, the wood wool monomer in step (3) and bath solution volume ratio are 1:30.
Embodiment 5
By taking poplar as an example, the present invention tests decoration in the present invention with wood wool board performance, studies wood wool sheet metal forming
Technique under conditions of 1 four single factor tests of table, four levels, is tested using experiments of single factor using omnipotent mechanics tester
Decoration static bending strength, elasticity modulus, interior bonding strength and the thickness swelling rate of wood wool board, the results are shown in Table 2.
1 experiment of single factor parameter of table
2 wood wool board experimental results of table
Can be seen that best preparation technology parameter from 2 experimental result of table is resin added 18%, 170 DEG C of hot pressing temperature, hot pressing
Time 5min, hot pressing pressure 3MPa.
Embodiment 6
Equally by taking poplar as an example, wood wool board decorative performance is evaluated:
(1) absorbent properties are evaluated: within the scope of 125Hz~500Hz, frequency is bigger, and the acoustic absorptivity of wood wool board is smaller,
Occurs minimum value at 500Hz.Within the scope of 500Hz~2000Hz, frequency is bigger, and acoustic absorptivity is bigger, reaches most at 2000Hz
Big value.In frequency after 2000Hz, acoustic absorptivity is basically unchanged, close to 1.0;Wood wool board acoustic absorptivity is 0.75.
The 3 wood wool decorative panel (acoustic absorptivity of arrangement mode c) of table
(2) aids abrasion resistance evaluation
Wearability is consistent everywhere for wood wool plaque surface, no significant difference.
4 wearability experimental results of table
(3) weather resistance is evaluated
Dyeing processing influences significantly the weatherability of plate, and direct dyeing can improve plate weatherability.Using
0.2% coloring agent is dyed, the results show that the respectively weatherability sequence of dyeing wood wool decorative panel are as follows: direct fast scarlet 4BS
> direct yellow R > control group > reactive dye.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
The change or replacement expected without creative work, should be covered by the protection scope of the present invention.Therefore, of the invention
Protection scope should be determined by the scope of protection defined in the claims.
Claims (8)
1. a kind of decoration wood wool board, it is characterised in that: by wood wool monomer after dyeing and epoxy resin adhesive hot pressing pressure
It makes, wood wool monomer sand paper sanding to the smooth no hangnail in surface, width is 4~5mm, and length is 100~300mm,
Monomer arrangement mode is divided into tri- kinds of modes of a, b, c,
A. every layer of every row's wood wool monomer length and quantity arrangement mode are alternately arranged by 150mm*2,100mm*3;
B. every layer of every row's wood wool monomer length and quantity are alternately arranged by 300mm*1,150mm*2;
C. every layer of every row's wood wool monomer length and quantity are arranged by 300mm*1;
The assemble pattern of the wood wool board is that the monomer orientation of odd even layer wood wool is mutually perpendicular to, five layers of assembly.
2. decoration wood wool board as described in claim 1, it is characterised in that: the wood wool monomer is without furuncle and damages by worms.
3. decoration wood wool board as described in claim 1, it is characterised in that: the wood wool monomer is poplar wood wool monomer.
4. the manufacturing method that decoration as described in claim 1 uses wood wool board, it is characterised in that: the following steps are included:
(1) prepared by wood wool monomer: poplar plate being placed in wood wool molding machine inlet, prepares wood wool monomer, the wood wool monomer
Width is 4~5mm;
(2) length of wood wool monomer obtained in step (1) wood wool post-processing: is cut to 100~300mm;
(3) wood wool dye: by the wood wool monomer in step (2) be placed in dyeing agent solution in 40~60min of heating water bath, then plus
Enter color fixing agent, continue 40~60min of heating water bath, then washes color, drying;
(4) it suppresses: decoration wood being pressed by heat pressing process with the resulting wood wool monomer of step (3) and epoxy resin adhesive
Filament plate, hot pressing use 14%~26% resin added, 130 DEG C~190 DEG C of hot pressing temperature, the hot pressing time of 4~7min, 1~
The hot pressing pressure of 4MPa.
5. the manufacturing method that decoration as claimed in claim 4 uses wood wool board, it is characterised in that: the coloring agent in step (3) is molten
Liquid includes the paregal O-of the sun-proof 4BS of direct scarlet of mass fraction 0.2%, direct yellow R or reactive brilliant blue X-3B, 1~2g/L
The penetrating agent JFC of 25,20~25g/L.
6. the manufacturing method that decoration as claimed in claim 3 uses wood wool board, it is characterised in that: the wood wool monomer in step (3)
It is 1:30~1:50 with bath solution volume ratio.
7. the manufacturing method that decoration as claimed in claim 3 uses wood wool board, it is characterised in that: bath temperature is in step (3)
70 DEG C~100 DEG C.
8. the manufacturing method that decoration as claimed in claim 3 uses wood wool board, it is characterised in that: the color fixing agent in step (3) is
The natrium carbonicum calcinatum of 20~25g/L.
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Application publication date: 20190920 |