CN110252415A - For eliminating the preparation method of the amino functional MOFs of indoor formaldehyde - Google Patents
For eliminating the preparation method of the amino functional MOFs of indoor formaldehyde Download PDFInfo
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- CN110252415A CN110252415A CN201910626203.4A CN201910626203A CN110252415A CN 110252415 A CN110252415 A CN 110252415A CN 201910626203 A CN201910626203 A CN 201910626203A CN 110252415 A CN110252415 A CN 110252415A
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- lafeo3
- indoor formaldehyde
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- 239000012621 metal-organic framework Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 title claims abstract description 14
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title abstract description 33
- 229910002321 LaFeO3 Inorganic materials 0.000 claims abstract description 33
- 239000002131 composite material Substances 0.000 claims abstract description 19
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 17
- 239000011941 photocatalyst Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 13
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 230000031700 light absorption Effects 0.000 claims abstract description 6
- 229910007932 ZrCl4 Inorganic materials 0.000 claims abstract description 5
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 claims abstract description 5
- KOUKXHPPRFNWPP-UHFFFAOYSA-N pyrazine-2,5-dicarboxylic acid;hydrate Chemical compound O.OC(=O)C1=CN=C(C(O)=O)C=N1 KOUKXHPPRFNWPP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000001338 self-assembly Methods 0.000 claims abstract description 5
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims abstract description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract 4
- GPNNOCMCNFXRAO-UHFFFAOYSA-N 2-aminoterephthalic acid Chemical compound NC1=CC(C(O)=O)=CC=C1C(O)=O GPNNOCMCNFXRAO-UHFFFAOYSA-N 0.000 claims abstract 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- 230000035484 reaction time Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000001157 Fourier transform infrared spectrum Methods 0.000 claims description 4
- 238000002441 X-ray diffraction Methods 0.000 claims description 4
- 238000012512 characterization method Methods 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000013049 sediment Substances 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- 238000004626 scanning electron microscopy Methods 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 8
- 239000003054 catalyst Substances 0.000 abstract description 6
- 230000003197 catalytic effect Effects 0.000 abstract description 3
- 238000013461 design Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 238000012545 processing Methods 0.000 abstract description 2
- -1 g-C3N4 Inorganic materials 0.000 description 4
- 230000001699 photocatalysis Effects 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910000161 silver phosphate Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
Abstract
The invention discloses the preparation methods of the amino functional MOFs for eliminating indoor formaldehyde, are related to indoor formaldehyde processing technology field.The present invention is dissolved in deionized water the following steps are included: the ferric nitrate and lanthanum nitrate that SS01 taking-up molar ratio is 1:1, prepares LaFeO3 by hydrothermal synthesis method；SS02 is modified by surface of the thioacetic acid to the LaFeO3 in SS01；Material after SS03 modifies SS02 is sequentially placed into the N of ZrCl4 and 2- amino terephthalic acid (TPA), in dinethylformamide solution, the self assembly that the surface LaFeO3 UIO-66-NH2 is realized in 100-200 DEG C of reaction kettle, to construct out LaFeO3/UIO-66-NH2 composite photo-catalyst.The present invention is strong by the Technology design visible light absorption capacity that hydrothermal synthesis method and self-assembly method combine, and the metal organic framework LaFeO3/UIO-66-NH2 composite photo-catalyst with high catalytic activity, indoor formaldehyde can be effectively eliminated, it is insufficient to solve the problems, such as that existing photochemical catalyst eliminates effect of formaldehyde.
Description
Technical field
The invention belongs to indoor formaldehyde processing technology fields, more particularly to the amino functional for eliminating indoor formaldehyde
The preparation method of MOFs.
Background technique
Photochemical catalyst is the key that determine light-catalyzed reaction efficiency, has developed TiO2, g-C3N4, Ag3PO4, CdS at present
With a variety of photochemical catalysts such as metal organic framework (MOFs), wherein metal organic framework (MOFs) is by rigid organic ligand and gold
Belong to the novel porous materials with infinite network structure that ion or metal cluster are formed by coordinate bond bridging.
Since the raw material of metal organic framework (MOFs) are simple and easy to get, there is high porosity, high-specific surface area, pattern ruler
Very little adjustable, structure-rich, synthetic strategy are simply and various, and can need the advantages that making various chemical modifications according to experiment,
MOFs is widely used in the fields such as gas absorption and storage, catalysis, photoelectricity, material, sensing and medical diagnosis.
The rise of interior decoration and it is universal bring air pollution problem inside rooms very serious, formaldehyde is in room air
Main pollutant, in numerous methods of purifying formaldehyde, photocatalysis technology is that most probable realizes a kind of technology promoted and applied,
And had the air purifier based on photocatalysis technology currently on the market, but it is undesirable there are clean-up effect the problems such as, light
Catalyst is the key that determine photocatalytic activity, therefore the MOFs for designing the efficiently amino functional of elimination indoor formaldehyde is this
Field personnel's problem to be solved.
Summary of the invention
The purpose of the present invention is to provide the preparation methods of the amino functional MOFs for eliminating indoor formaldehyde, pass through water
The Technology design visible light absorption capacity that thermal synthesis method and self-assembly method combine is strong, and the metal with high catalytic activity is organic
It is insufficient to solve the problems, such as that existing photochemical catalyst eliminates effect of formaldehyde for skeleton LaFeO3/UIO-66-NH2 composite photo-catalyst.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions:
The present invention is the preparation method for eliminating the amino functional MOFs of indoor formaldehyde, comprising the following steps:
The preparation of SS01LaFeO3: the ferric nitrate and lanthanum nitrate that molar ratio is 1:1 are taken out, is dissolved in deionized water, will mix
It closes in solution merging hydrothermal reaction kettle and carries out hydro-thermal reaction, cool down and take out after hydro-thermal and isolate sediment, obtain
LaFeO3；
SS02 modification: it is modified by surface of the thioacetic acid to the LaFeO3 obtained in SS01；
SS03 constructs composite photo-catalyst: the material after SS02 is modified is sequentially placed into ZrCl4 and 2- amino terephthaldehyde
In the n,N-Dimethylformamide solution of acid, oneself of the surface LaFeO3 UIO-66-NH2 is realized in 100-200 DEG C of reaction kettle
Assembling, to construct out LaFeO3/UIO-66-NH2 composite photo-catalyst.
Further, temperature setting is at 150 DEG C in hydrothermal reaction kettle in the SS01, reaction time 12h.
Further, temperature setting is at 200 DEG C in hydrothermal reaction kettle in the SS01, reaction time 12h.
Further, after reaction kettle is cooled to room temperature in the SS01, by centrifuge and with deionized water and anhydrous second
Alcohol alternately washing 3 times, after sufficiently cleaning 60 DEG C at a temperature of it is dry, it is dry after grinding obtain LaFeO3 material.
Further, using in conjunction with X-ray diffraction (XRD), FTIR spectrum analyzer (FT-IR) after the SS03
Structure, ingredient, pattern and light is carried out to LaFeO3/UIO-66-NH2 composite photo-catalyst with scanning electron microscope (SEM) to inhale
Receive the characterization that performance carries out physico-chemical property.
The invention has the following advantages:
The present invention is strong by the Technology design visible light absorption capacity that hydrothermal synthesis method and self-assembly method combine, and has
The metal organic framework LaFeO3/UIO-66-NH2 composite photo-catalyst of high catalytic activity, on the one hand, by UIO-66-NH2 material
Expect that preferable pore property improves the diffusion of contaminant molecule and the absorption on composite catalyst surface in reaction system, from
And it is conducive to the progress of light-catalyzed reaction, and on the other hand, band structure between LaFeO3 and UIO-66-NH2 in composite photo-catalyst
The matching of feature makes composite material exhibits go out stronger light absorpting ability, photocatalytic activity and structural stability, can be effective
Indoor formaldehyde is eliminated, to realize that the green of crowd is lived.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's all other embodiment obtained without creative efforts belongs to the model that the present invention protects
It encloses.
Embodiment one
The present invention is the preparation method for eliminating the amino functional MOFs of indoor formaldehyde, comprising the following steps:
The preparation of SS01LaFeO3: the ferric nitrate and lanthanum nitrate that molar ratio is 1:1 are taken out, is dissolved in deionized water, will mix
It closes in solution merging hydrothermal reaction kettle and carries out hydro-thermal reaction, cool down and take out after hydro-thermal and isolate sediment, obtain
LaFeO3；
SS02 modification: it is modified by surface of the thioacetic acid to the LaFeO3 obtained in SS01；
SS03 constructs composite photo-catalyst: the material after SS02 is modified is sequentially placed into ZrCl4 and 2- amino terephthaldehyde
In the n,N-Dimethylformamide solution of acid, oneself of the surface LaFeO3 UIO-66-NH2 is realized in 100-200 DEG C of reaction kettle
Assembling, to construct out LaFeO3/UIO-66-NH2 composite photo-catalyst.
Wherein, temperature setting is at 150 DEG C in hydrothermal reaction kettle in the SS01, reaction time 12h.
Wherein, it after reaction kettle is cooled to room temperature in the SS01, is handed over by centrifuge and with deionized water and dehydrated alcohol
For washing 3 times, after sufficiently cleaning 60 DEG C at a temperature of it is dry, it is dry after grinding obtain LaFeO3 material.
Wherein, it uses in conjunction with X-ray diffraction (XRD), FTIR spectrum analyzer (FT-IR) and sweeps after the SS03
It retouches electron microscope (SEM) and structure, ingredient, pattern and light absorption is carried out to LaFeO3/UIO-66-NH2 composite photo-catalyst
It can be carried out the characterization of physico-chemical property.
Embodiment two
The present invention is the preparation method for eliminating the amino functional MOFs of indoor formaldehyde, comprising the following steps:
The preparation of SS01LaFeO3: the ferric nitrate and lanthanum nitrate that molar ratio is 1:1 are taken out, is dissolved in deionized water, will mix
It closes in solution merging hydrothermal reaction kettle and carries out hydro-thermal reaction, cool down and take out after hydro-thermal and isolate sediment, obtain
LaFeO3；
SS02 modification: it is modified by surface of the thioacetic acid to the LaFeO3 obtained in SS01；
SS03 constructs composite photo-catalyst: the material after SS02 is modified is sequentially placed into ZrCl4 and 2- amino terephthaldehyde
In the n,N-Dimethylformamide solution of acid, oneself of the surface LaFeO3 UIO-66-NH2 is realized in 100-200 DEG C of reaction kettle
Assembling, to construct out LaFeO3/UIO-66-NH2 composite photo-catalyst.
Wherein, temperature setting is at 200 DEG C in hydrothermal reaction kettle in the SS01, reaction time 12h.
Wherein, it after reaction kettle is cooled to room temperature in the SS01, is handed over by centrifuge and with deionized water and dehydrated alcohol
For washing 3 times, after sufficiently cleaning 60 DEG C at a temperature of it is dry, it is dry after grinding obtain LaFeO3 material.
Wherein, it uses in conjunction with X-ray diffraction (XRD), FTIR spectrum analyzer (FT-IR) and sweeps after the SS03
It retouches electron microscope (SEM) and structure, ingredient, pattern and light absorption is carried out to LaFeO3/UIO-66-NH2 composite photo-catalyst
It can be carried out the characterization of physico-chemical property.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means
Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the invention
In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example.
Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close
Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment
All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification,
It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention
Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only
It is limited by claims and its full scope and equivalent.
Claims (5)
1. the preparation method for the amino functional MOFs for eliminating indoor formaldehyde, it is characterised in that: the following steps are included:
The preparation of SS01 LaFeO3: the ferric nitrate and lanthanum nitrate that molar ratio is 1:1 are taken out, is dissolved in deionized water, will mix molten
Hydro-thermal reaction is carried out in liquid merging hydrothermal reaction kettle, cools down and takes out after hydro-thermal and isolate sediment, obtain LaFeO3；
SS02 modification: it is modified by surface of the thioacetic acid to the LaFeO3 obtained in SS01；
SS03 constructs composite photo-catalyst: the material after SS02 is modified is sequentially placed into ZrCl4 and 2- amino terephthalic acid (TPA)
In n,N-Dimethylformamide solution, the self assembly of the surface LaFeO3 UIO-66-NH2 is realized in 100-200 DEG C of reaction kettle,
To construct out LaFeO3/UIO-66-NH2 composite photo-catalyst.
2. according to claim 1 for eliminating the preparation method of the amino functional MOFs of indoor formaldehyde, feature exists
In temperature setting is at 150 DEG C in hydrothermal reaction kettle in the SS01, reaction time 12h.
3. according to claim 1 for eliminating the preparation method of the amino functional MOFs of indoor formaldehyde, feature exists
In temperature setting is at 200 DEG C in hydrothermal reaction kettle in the SS01, reaction time 12h.
4. according to claim 1 for eliminating the preparation method of the amino functional MOFs of indoor formaldehyde, feature exists
In, after reaction kettle is cooled to room temperature in the SS01, alternately washed 3 times by centrifuge and with deionized water and dehydrated alcohol,
After sufficiently cleaning 60 DEG C at a temperature of it is dry, it is dry after grinding obtain LaFeO3 material.
5. according to claim 1 for eliminating the preparation method of the amino functional MOFs of indoor formaldehyde, feature exists
In using in conjunction with X-ray diffraction (XRD), FTIR spectrum analyzer (FT-IR) and scanning electron microscopy after the SS03
Mirror (SEM), which carries out structure, ingredient, pattern and light absorption to LaFeO3/UIO-66-NH2 composite photo-catalyst, can be carried out materialization
The characterization of property.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910626203.4A CN110252415A (en) | 2019-07-11 | 2019-07-11 | For eliminating the preparation method of the amino functional MOFs of indoor formaldehyde |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910626203.4A CN110252415A (en) | 2019-07-11 | 2019-07-11 | For eliminating the preparation method of the amino functional MOFs of indoor formaldehyde |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113769714A (en) * | 2021-09-28 | 2021-12-10 | 西南大学 | UIO-66-X-loaded glass fiber composite, preparation method and application |
| WO2024077411A1 (en) * | 2022-10-09 | 2024-04-18 | 苏州大学 | Bismuth titanate nanosheet/uio-66-nh2 heterojunction containing bismuth vacancies, preparation method therefor and use thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106140177A (en) * | 2015-03-16 | 2016-11-23 | 中智环保新材料江苏有限公司 | A kind of superstructure visible light responsive BiFeO3the preparation method and application of photocatalyst |
| CN107042087A (en) * | 2017-01-19 | 2017-08-15 | 中国石油大学(华东) | A kind of method that Situ Hydrothermal prepares magnetic metal organic framework core-shell material |
| CN107626319A (en) * | 2017-10-09 | 2018-01-26 | 河南师范大学 | A kind of preparation method of flower-shaped cadmium ferrite photochemical catalyst |
| KR20180043061A (en) * | 2016-10-19 | 2018-04-27 | 한국에너지기술연구원 | Self-assembled 3D hybrid structure, method for preparing the same, and photocatalysts using the same |
-
2019
- 2019-07-11 CN CN201910626203.4A patent/CN110252415A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106140177A (en) * | 2015-03-16 | 2016-11-23 | 中智环保新材料江苏有限公司 | A kind of superstructure visible light responsive BiFeO3the preparation method and application of photocatalyst |
| KR20180043061A (en) * | 2016-10-19 | 2018-04-27 | 한국에너지기술연구원 | Self-assembled 3D hybrid structure, method for preparing the same, and photocatalysts using the same |
| CN107042087A (en) * | 2017-01-19 | 2017-08-15 | 中国石油大学(华东) | A kind of method that Situ Hydrothermal prepares magnetic metal organic framework core-shell material |
| CN107626319A (en) * | 2017-10-09 | 2018-01-26 | 河南师范大学 | A kind of preparation method of flower-shaped cadmium ferrite photochemical catalyst |
Non-Patent Citations (2)
| Title |
|---|
| CAM LOC LUU ET AL.: "Thin film nano-photocatalyts with low band gap energy for gas phase degradation of p-xylene: TiO2 doped Cr, UiO66-NH2 and LaBO3 (B = Fe, Mn, and Co)", 《ADVANCES IN NATURAL SCIENCE: NANOSCIENCE AND NANOTECHNOLOGY》 * |
| YUNHUI SI ET AL.: "Photocatalytic Performance of a Novel MOF/BiFeO3 Composite", 《MATERIALS》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113769714A (en) * | 2021-09-28 | 2021-12-10 | 西南大学 | UIO-66-X-loaded glass fiber composite, preparation method and application |
| CN113769714B (en) * | 2021-09-28 | 2022-11-29 | 西南大学 | UIO-66-X-loaded glass fiber composite, preparation method and application |
| WO2024077411A1 (en) * | 2022-10-09 | 2024-04-18 | 苏州大学 | Bismuth titanate nanosheet/uio-66-nh2 heterojunction containing bismuth vacancies, preparation method therefor and use thereof |
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